This research focused on using the waste rubber powder as a kind of regenerate resources to improve the mechanical properties of cement mortar.The two kinds of hybrid modified rubber powder TRP and ATRP were prepared ...This research focused on using the waste rubber powder as a kind of regenerate resources to improve the mechanical properties of cement mortar.The two kinds of hybrid modified rubber powder TRP and ATRP were prepared by sol-gel method and then used in cement mortar.The structures and properties of them were studied.It is shown that the nano Si-O-Si network is generated in TRP and ATRP networks and the hydrophilic group is grafted on the surface of ATRP.The mechanical properties of rubber-treated mortar(RTM) were tested and the microstructures of them were also studied.Compared to the mortars with unmodified rubber powders(RP),NaOH treated rubber powder(SRP) and coupling agent treated rubber powder(CRP),the RTM with ATRP has the highest compressive strength and flexural strength.The stress-strain curves shown that the peak of stress of RTM with ATRP is increased and indicated the higher compression deformation and toughness.It is found that the interfacial adhesion between the ATRP and cement mortar is increased distinctly by SEM,which results in enhanced ductility and mechanical properties of RTM with ATRP.展开更多
This paper presents a new hybrid approach that combines Modified Priority List (MPL) with Charged System Search (CSS), termed MPL-CSS, to solve one of the most crucial power system’s operational optimization problems...This paper presents a new hybrid approach that combines Modified Priority List (MPL) with Charged System Search (CSS), termed MPL-CSS, to solve one of the most crucial power system’s operational optimization problems, known as unit commitment (UC) scheduling. The UC scheduling problem is a mixed-integer nonlinear problem, highly-dimensional and extremely constrained. Existing meta-heuristic UC solution methods have the problems of stopping at a local optimum and slow convergence when applied to large-scale, heavily-constrained UC applications. In the first step of the proposed method, initial hourly optimum solutions of UC are obtained by Modified Priority List (MPL);however, the obtained UC solution may still be possible to be further improved. Therefore, in the second step, the CSS is utilized to achieve higher quality solutions. The UC is formulated as mixed integer linear programming to ensure the tractability of the results. The proposed method is successfully applied to a popular test system up to 100 units generators for both 24-hr and 168-hr system. Computational results show that both solution cost and execution time are superior to those of published methods.展开更多
This paper deals with the modified function projective synchronization problem for general complex networks with multiple proportional delays. With the existence of multiple proportional delays, an effective hybrid fe...This paper deals with the modified function projective synchronization problem for general complex networks with multiple proportional delays. With the existence of multiple proportional delays, an effective hybrid feedback control is designed to attain modified function projective synchronization of networks. Numerical example is provided to show the effectiveness of our result.展开更多
The major concern of this work is to propose new prototypes of surface hybrid waves, in particular waves propagating without sprawl or deformation on the surface of a fluid. The model considered for this purpose is th...The major concern of this work is to propose new prototypes of surface hybrid waves, in particular waves propagating without sprawl or deformation on the surface of a fluid. The model considered for this purpose is the modified KdV (Korteweg-de Vries) equation. A peculiarity of the obtained solutions is that they form packages constituted by combinations of waves belonging to the two main families of well-known bright and dark solitary waves. This putting together creates competitions between the different components of the considered packages which, following the values assigned to the parameters of the considered system and in relation to those of the wave parameters, generate hybrid or multi-form structures. The direct method of resolution which made possible the obtained results is that of Bogning-Djeumen Tchaho-Kofane extended to the new implicit Bogning functions. The existence conditions of some solutions are obtained. The numerical simulations carried out with a view to testing the observable and applicable characters of the obtained solutions revealed their stabilities over a relatively long time, and at the same time, confirmed the recommended theoretical forecasts. We are convinced that the solutions proposed as part of this work will make it possible to detect, understand and explain some physical phenomena linked to fluid molecular interactions, former or new, which constantly occur on the fluid surfaces, mainly at the shallow water surface.展开更多
A modified direct optimization method is proposed to solve the optimal multi-revolution transfer with low-thrust between Earth-orbits. First, through parameterizing the control steering angles by costate variables, th...A modified direct optimization method is proposed to solve the optimal multi-revolution transfer with low-thrust between Earth-orbits. First, through parameterizing the control steering angles by costate variables, the search space of free parameters has been decreased. Then, in order to obtain the global optimal solution effectively and robustly, the simulated annealing and penalty function strategies were used to handle the constraints, and a GA/SQP hybrid optimization algorithm was utilized to solve the parameter optimization problem, in which, a feasible suboptimal solution obtained by GA was submitted as an initial parameter set to SQP for refinement. Comparing to the classical direct method, this novel method has fewer free parameters, needs not initial guesses, and has higher computation precision. An optimal-fuel transfer problem from LEO to GEO was taken as an example to validate the proposed approach. The results of simulation indicate that our approach is available to solve the problem of optimal muhi-revolution transfer between Earth-orbits.展开更多
High voltage,high energy density,nominal cycle life,and low cost are the most critical requirements of rechargeable batteries for their widespread energy storage applications in electric vehicles and renewable energy ...High voltage,high energy density,nominal cycle life,and low cost are the most critical requirements of rechargeable batteries for their widespread energy storage applications in electric vehicles and renewable energy technologies.Na-MnO_(2) battery could be a low-cost contender,but it suffers extensively from its low cell voltage and poor rechargeability.In this study,we modified the conventional cell structure of Na-MnO_(2) battery and established altered cell chemistry through a hybrid electrochemical process consisting of Na striping/plating at the anode and Zn^(2+) insertion/de-insertion along with MnO_(2) dissolution/deposition at the cathode.After the modification,Na-MnO_(2) battery exhibits a discharge capacity of 267.10 mA h/g and a cell voltage of 3.30 V(vs.Na/Na^(+)),resulting in a high specific energy density of 881.43 Wh/kg.After 300 cycles,the battery retains 98% of its first-cycle discharge capacity with100% coulombic efficiency.Besides,Na metal-free battery assembled using sodium biphenyl as a safer anode also delivers an excellent energy density of 810.0 Wh/kg.This work could provide a feasible method to develop an advanced Na-MnO_(2) battery for real-time energy storage applications.展开更多
Uneven power distribution,transient voltage,and frequency deviations are observed in the photovoltaic storage hybrid inverter during the switching between grid-connected and island modes.In response to these issues,th...Uneven power distribution,transient voltage,and frequency deviations are observed in the photovoltaic storage hybrid inverter during the switching between grid-connected and island modes.In response to these issues,this paper proposes a grid-connected/island switching control strategy for photovoltaic storage hybrid inverters based on the modified chimpanzee optimization algorithm.The proposed strategy incorporates coupling compensation and power differentiation elements based on the traditional droop control.Then,it combines the angular frequency and voltage amplitude adjustments provided by the phase-locked loop-free pre-synchronization control strategy.Precise pre-synchronization is achieved by regulating the virtual current to zero and aligning the photovoltaic storage hybrid inverter with the grid voltage.Additionally,two novel operators,learning and emotional behaviors are introduced to enhance the optimization precision of the chimpanzee algorithm.These operators ensure high-precision and high-reliability optimization of the droop control parameters for photovoltaic storage hybrid inverters.A Simulink model was constructed for simulation analysis,which validated the optimized control strategy’s ability to evenly distribute power under load transients.This strategy effectively mitigated transient voltage and current surges during mode transitions.Consequently,seamless and efficient switching between gridconnected and island modes was achieved for the photovoltaic storage hybrid inverter.The enhanced energy utilization efficiency,in turn,offers robust technical support for grid stability.展开更多
In order to improve the substrate diffusion properties and stability of an immobilized enzyme alginate microgels modified with TiO2 nanoparticles were employed as the enzyme immobilizing support.Ionotropic gelation wa...In order to improve the substrate diffusion properties and stability of an immobilized enzyme alginate microgels modified with TiO2 nanoparticles were employed as the enzyme immobilizing support.Ionotropic gelation was applied for the preparation of hybrid gels while Ca2+ Ce3+ Ni2+Cu2+and Fe3+were employed as the crosslinkers.Papain was selected as the model enzyme. UV-Vis spectroscopy was employed to investigate the activity of papain to evaluate kinetics and stability.Analysis results show that the highest affinity the lowest Michaelis-Menten constant Km =11.0 mg/mL and the highest stability are obtained when using Cu2+as the crosslinker.The effect of the mass ratio of TiO2 to papain on the stability and leakage of papain is also investigated and the results show that 10∶1 TiO2∶papain is optimal because the proper use of TiO2 can reduce enzyme leakage and ensure enzyme stability.Preparing Cu/alginate/TiO2 hybrid gels via ionotropic gelation can provide a satisfactory diffusion capability and enzyme stability.展开更多
Natural rubber nanocomposites filled with hybrid fillers of multi-walled carbon nanotubes(CNTs) and carbon black(CB) were prepared. CNTs were ultrasonically modified in mixture of hydrogen peroxide(H2O2) and distilled...Natural rubber nanocomposites filled with hybrid fillers of multi-walled carbon nanotubes(CNTs) and carbon black(CB) were prepared. CNTs were ultrasonically modified in mixture of hydrogen peroxide(H2O2) and distilled water(H2O). The functional groups on the surface of CNTs, changes in nanotube structure and morphology were characterized by Fourier transform infrared spectroscopy(FT-IR), Raman Spectroscopy, and transmission electron microscopy(TEM). It shows that hydroxyl(OH·) is successfully introduced. The surface defects of modified CNTs were obviously higher than those of original CNTs, and the degree of agglomeration was greatly reduced. Thermal conductivity of the composites was tested by protection heat flow meter method. Compared with unmodified CNTs/CB filling system, the thermal conductivity of hybrid composites is improved by an average of 5.8% with 1.5 phr(phr is parts per hundred rubber) of hydroxyl CNTs and 40 phr of CB filled. A three-dimensional heat conduction network composed of hydroxyl CNTs and CB, as observed by TEM, contributes to the good properties. Thermal conductivity of the hybrid composites increases as temperature rises. The mechanical properties of hybrid composites are also good with hydroxyl CNTs filled nanocomposites;the tensile strength, 100% and 300% tensile stress are improved by 10.1%, 22.4% and 26.2% respectively.展开更多
The singular hybrid boundary node method (SHBNM) is proposed for solving three-dimensional problems in linear elasticity. The SHBNM represents a coupling between the hybrid displacement variational formulations and ...The singular hybrid boundary node method (SHBNM) is proposed for solving three-dimensional problems in linear elasticity. The SHBNM represents a coupling between the hybrid displacement variational formulations and moving least squares (MLS) approximation. The main idea is to reduce the dimensionality of the former and keep the meshless advantage of the later. The rigid movement method was employed to solve the hyper-singular integrations. The 'boundary layer effect', which is the main drawback of the original Hybrid BNM, was overcome by an adaptive integration scheme. The source points of the fundamental solution were arranged directly on the boundary. Thus the uncertain scale factor taken in the regular hybrid boundary node method (RHBNM) can be avoided. Numerical examples for some 3D elastic problems were given to show the characteristics. The computation results obtained by the present method are in excellent agreement with the analytical solution. The parameters that influence the performance of this method were studied through the numerical examples.展开更多
This paper focuses on the development of a hybrid method with block extension for direct solution of initial value problems (IVPs) of general third-order ordinary differential equations. Power series was used as the b...This paper focuses on the development of a hybrid method with block extension for direct solution of initial value problems (IVPs) of general third-order ordinary differential equations. Power series was used as the basis function for the solution of the IVP. An approximate solution from the basis function was interpolated at some selected off-grid points while the third derivative of the approximate solution was collocated at all grid and off-grid points to generate a system of linear equations for the determination of the unknown parameters. The derived method was tested for consistency, zero stability, convergence and absolute stability. The method was implemented with five test problems including the Genesio equation to confirm its accuracy and usability. The rate of convergence (ROC) reveals that the method is consistent with the theoretical order of the proposed method. Comparison of the results with some existing methods shows the superiority of the accuracy of the method.展开更多
This paper proposes the use of the flexible tolerance method(FTM) modified with scaling of variables and hybridized with different unconstrained optimization methods to solve real constrained optimization problems.The...This paper proposes the use of the flexible tolerance method(FTM) modified with scaling of variables and hybridized with different unconstrained optimization methods to solve real constrained optimization problems.The benchmark problems used to analyze the performance of the methods were taken from G-Suite functions.The original method(FTM) and other four proposed methods:(i) FTM with scaling of variables(FTMS),(ii) FTMS hybridized with BFGS(FTMS-BFGS),(iii) FTMS hybridized with modified Powell's method(FTMS-Powell)and(iv) FTMS hybridized with PSO(FTMS-PSO), were implemented. The success rates of the methods were 80%,100%, 75%, 95% and 85%, for FTM, FTMS, FTMS-BFGS, FTMS-Powell and FTMS-PSO, respectively. Numerical experiments including real constrained problems indicated that FTMS gave the best performance, followed by FTMSPowell and FTMS-PSO. Despite the inferior performance compared to FTMS and FTMS-Powell, the FTMS-PSO method presented some advantages since good different initial points could be obtained, which allow exploring different routes through the solution space and to escape from local optima. The proposed methods proved to be an effective way of improving the performance of the original FTM.展开更多
In this paper the equivalence of the generalized hybrid element and the modified Wilson element, which is derived by the generalized hybrid method, is proved.
A novel super-hybrid composite (NSHC) was boron-modified phenolic resin (BPR) with three-dimensional reticulated SiC ceramic (3DRC) and high silica fibers. Ablation performance of the NSHC was studied. The results sho...A novel super-hybrid composite (NSHC) was boron-modified phenolic resin (BPR) with three-dimensional reticulated SiC ceramic (3DRC) and high silica fibers. Ablation performance of the NSHC was studied. The results show that the linear ablation rate of NSHC was lower than that of pure BPR and the high silica/BPR composite. Its linear ablation rate is 1/17 of the high silica/BPR. Mass ablation rate of the NSHC is very close to that of the pure BPR and the high silica/BPR composite. Scanning electron microscope (SEM) analysis indicates that 3DRC has scarcely changed its shape at the ablation temperature. Its special reticulated structure can restrict the materials deformation and prevent high velocity heat flow from eroding the surface of the materials largely and thus increase ablation resistance of the NSHC.展开更多
Reflector edges, sharp acceptance angles and by-pass diodes introduce large variations in the electrical performance of asymmetrical concentrating photovoltaic/thermal modules over a short incidence angle interval. It...Reflector edges, sharp acceptance angles and by-pass diodes introduce large variations in the electrical performance of asymmetrical concentrating photovoltaic/thermal modules over a short incidence angle interval. It is therefore important to quantify these impacts precisely. The impact on the electrical performance of the optical properties of an asymmetrical photovoltaic/thermal CPC-collector was measured in Maputo, Mozambique. The measurements were carried out with the focus on attaining a high resolution incidence angle modifier in both the longitudinal and transversal directions, since large variations were expected over small angle intervals. A detailed analysis of the contribution of the diffuse radiation to the total output was also carried out. The solar cells have an electrical efficiency of 18% while the maximum measured electrical efficiency of the collector was 13.9 % per active glazed area and 20.9 % per active cell area, at 25 °C. Such data make it possible to quantify not only the electrical performance for different climatic and operating conditions but also to determine potential improvements to the collector design. The electrical output can be increased by a number of different measures, e.g. removing the outermost cells, turning the edge cells 90°, dividing each receiver side into three or four parts and directing the tracking, when used, along a north-south axis.展开更多
The Nevirapine (NVP)/Polycaprolactone (PCL)/Nanoparticles hybrids systems have been developed as a potential platform for drug delivery, by solvent cast, as thin films. NVP, an antiretroviral drug, was included within...The Nevirapine (NVP)/Polycaprolactone (PCL)/Nanoparticles hybrids systems have been developed as a potential platform for drug delivery, by solvent cast, as thin films. NVP, an antiretroviral drug, was included within PCL matrix containing three types of nanoparticles: an organoclay layered silicate Viscogel S7®(3% w/w), hydrophilic silica oxide particles Aerosil®A20 (0.25% w/w) and titanium dioxide particles (0.25% w/w). These systems were characterized by X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), low-field nuclear magnetic resonance (NMR), ultraviolet-visible spectroscopy (UV), in-vitro dissolution testing and drug release mechanism kinetics. The PCL crystallization was affected by NVP incorporation, modifying its semi-crystalline structure to a less ordered structure. When nanoparticles and NVP were added, the T<sub>1</sub>H values increased, for PCL, PCL/S7, PCL/ SiO<sub>2</sub> and PCL/TiO<sub>2</sub> hybrids, suggesting that its addition produced a new material, with less molecular mobility, due to the new intermolecular interactions formation. It can consider a structure formation among the PCL chains, nanoparticles and NVP, with strong forces in the PCL/SiO<sub>2</sub>/NVP system. The amount of NVP included was around 1.5 ± 0.03 mg/cm<sup>2</sup>. In the in-vitro dissolution test, the PCL/SiO<sub>2</sub>/NVP system released the smallest amount of drug and this result could be attributed to the strong intermolecular interaction between the drug and the PCL/SiO<sub>2</sub> system. Higuchi’s model was the mathematical model chosen to treat the release data, since this model presented the highest coefficient correlation (r) value. The drug release probably occur by diffusion through the matrix pores, thus, these materials are suitable for sustained release of NVP.展开更多
This study presents hybrid clones of Corymbia spp.developed by Aperam BioEnergia as potential substitutes for Eucalyptus wood in the pulp industry.The biomass of Eucalyptus spp.was compared with that of Corymbia spp.b...This study presents hybrid clones of Corymbia spp.developed by Aperam BioEnergia as potential substitutes for Eucalyptus wood in the pulp industry.The biomass of Eucalyptus spp.was compared with that of Corymbia spp.by performing modified kraft pulping and basic density analyses.Comparisons were made by analyzing their respective mean annual increments of cellulose(MAI_(cel))and specific wood consumption(SWC),estimated using a kappa number of(19±1).The results showed that one of the hybrid clones(Corymbia citriodora×Corymbia torelliana,ID 4)had higher basic wood density,higher screened yield,better MAI_(cel#k19),and lower SWC than the other samples,reaching values of 0.608 t/m^(3),54.1%,24.6 ADt/ha/year(i.e.,air dry ton/hectare/year),and 2.74 m^(3)/ADt,respectively.Consequently,clone ID 4 had the highest MAI_(cel)/SWC ratio score(8.98).Given its high forest productivity and low industrial cost compared with other samples,as well as its advantages over Eucalyptus spp.wood,we concluded that clone ID 4 has great potential as an alternative biomass for pulp production.展开更多
Floorplanning is a prominent area in the Very Large-Scale Integrated (VLSI) circuit design automation, because it influences the performance, size, yield and reliability of the VLSI chips. It is the process of estimat...Floorplanning is a prominent area in the Very Large-Scale Integrated (VLSI) circuit design automation, because it influences the performance, size, yield and reliability of the VLSI chips. It is the process of estimating the positions and shapes of the modules. A high packing density, small feature size and high clock frequency make the Integrated Circuit (IC) to dissipate large amount of heat. So, in this paper, a methodology is presented to distribute the temperature of the module on the layout while simultaneously optimizing the total area and wirelength by using a hybrid Particle Swarm Optimization-Harmony Search (HPSOHS) algorithm. This hybrid algorithm employs diversification technique (PSO) to obtain global optima and intensification strategy (HS) to achieve the best solution at the local level and Modified Corner List algorithm (MCL) for floorplan representation. A thermal modelling tool called hotspot tool is integrated with the proposed algorithm to obtain the temperature at the block level. The proposed algorithm is illustrated using Microelectronics Centre of North Carolina (MCNC) benchmark circuits. The results obtained are compared with the solutions derived from other stochastic algorithms and the proposed algorithm provides better solution.展开更多
A novel super-hybrid composite (NSHC) is prepared with three-dimension reticulated SiC ceramic (3DRC), high performance carbon fibers and modified phenolic resin (BPR) in this paper. Ablation performance of super-hybr...A novel super-hybrid composite (NSHC) is prepared with three-dimension reticulated SiC ceramic (3DRC), high performance carbon fibers and modified phenolic resin (BPR) in this paper. Ablation performance of super-hybrid composite is studied. The results show that the NSHC has less linear ablation rate compared with pure BPR and CF/BPR composite, for example, its linear ablation rate is 50% of CF/BPR at the same fiber content. Mass ablation rate of the NSHC is slightly lower than that of pure BPR and CF/BPR composite because of their difference in the density. Scanning electron microscopic analysis indicates that 3DRC can increase anti-erosion capacity of materials because its special reticulated structure can control the deformation of materials and strengthen the stability of integral structure.展开更多
文摘This research focused on using the waste rubber powder as a kind of regenerate resources to improve the mechanical properties of cement mortar.The two kinds of hybrid modified rubber powder TRP and ATRP were prepared by sol-gel method and then used in cement mortar.The structures and properties of them were studied.It is shown that the nano Si-O-Si network is generated in TRP and ATRP networks and the hydrophilic group is grafted on the surface of ATRP.The mechanical properties of rubber-treated mortar(RTM) were tested and the microstructures of them were also studied.Compared to the mortars with unmodified rubber powders(RP),NaOH treated rubber powder(SRP) and coupling agent treated rubber powder(CRP),the RTM with ATRP has the highest compressive strength and flexural strength.The stress-strain curves shown that the peak of stress of RTM with ATRP is increased and indicated the higher compression deformation and toughness.It is found that the interfacial adhesion between the ATRP and cement mortar is increased distinctly by SEM,which results in enhanced ductility and mechanical properties of RTM with ATRP.
文摘This paper presents a new hybrid approach that combines Modified Priority List (MPL) with Charged System Search (CSS), termed MPL-CSS, to solve one of the most crucial power system’s operational optimization problems, known as unit commitment (UC) scheduling. The UC scheduling problem is a mixed-integer nonlinear problem, highly-dimensional and extremely constrained. Existing meta-heuristic UC solution methods have the problems of stopping at a local optimum and slow convergence when applied to large-scale, heavily-constrained UC applications. In the first step of the proposed method, initial hourly optimum solutions of UC are obtained by Modified Priority List (MPL);however, the obtained UC solution may still be possible to be further improved. Therefore, in the second step, the CSS is utilized to achieve higher quality solutions. The UC is formulated as mixed integer linear programming to ensure the tractability of the results. The proposed method is successfully applied to a popular test system up to 100 units generators for both 24-hr and 168-hr system. Computational results show that both solution cost and execution time are superior to those of published methods.
文摘This paper deals with the modified function projective synchronization problem for general complex networks with multiple proportional delays. With the existence of multiple proportional delays, an effective hybrid feedback control is designed to attain modified function projective synchronization of networks. Numerical example is provided to show the effectiveness of our result.
文摘The major concern of this work is to propose new prototypes of surface hybrid waves, in particular waves propagating without sprawl or deformation on the surface of a fluid. The model considered for this purpose is the modified KdV (Korteweg-de Vries) equation. A peculiarity of the obtained solutions is that they form packages constituted by combinations of waves belonging to the two main families of well-known bright and dark solitary waves. This putting together creates competitions between the different components of the considered packages which, following the values assigned to the parameters of the considered system and in relation to those of the wave parameters, generate hybrid or multi-form structures. The direct method of resolution which made possible the obtained results is that of Bogning-Djeumen Tchaho-Kofane extended to the new implicit Bogning functions. The existence conditions of some solutions are obtained. The numerical simulations carried out with a view to testing the observable and applicable characters of the obtained solutions revealed their stabilities over a relatively long time, and at the same time, confirmed the recommended theoretical forecasts. We are convinced that the solutions proposed as part of this work will make it possible to detect, understand and explain some physical phenomena linked to fluid molecular interactions, former or new, which constantly occur on the fluid surfaces, mainly at the shallow water surface.
基金Sponsored by the National Natural Science Foundation of China(Grant No.10672044)
文摘A modified direct optimization method is proposed to solve the optimal multi-revolution transfer with low-thrust between Earth-orbits. First, through parameterizing the control steering angles by costate variables, the search space of free parameters has been decreased. Then, in order to obtain the global optimal solution effectively and robustly, the simulated annealing and penalty function strategies were used to handle the constraints, and a GA/SQP hybrid optimization algorithm was utilized to solve the parameter optimization problem, in which, a feasible suboptimal solution obtained by GA was submitted as an initial parameter set to SQP for refinement. Comparing to the classical direct method, this novel method has fewer free parameters, needs not initial guesses, and has higher computation precision. An optimal-fuel transfer problem from LEO to GEO was taken as an example to validate the proposed approach. The results of simulation indicate that our approach is available to solve the problem of optimal muhi-revolution transfer between Earth-orbits.
基金supported by the Korea Research Fellowship Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science and ICT (2016H1D3A1909680)supported by Korea Institute of Energy Technology Evaluation and Planning (KETEP) grant funded by the Korea government (MOTIE) (20215610100040), Development of 20Wh seawater secondary battery unit cellminsisterio de Economia y competitividal (Spain) for the financially supporting this study through Juan de la Cierva-Incorporación program (IJC2018-038426-I)。
文摘High voltage,high energy density,nominal cycle life,and low cost are the most critical requirements of rechargeable batteries for their widespread energy storage applications in electric vehicles and renewable energy technologies.Na-MnO_(2) battery could be a low-cost contender,but it suffers extensively from its low cell voltage and poor rechargeability.In this study,we modified the conventional cell structure of Na-MnO_(2) battery and established altered cell chemistry through a hybrid electrochemical process consisting of Na striping/plating at the anode and Zn^(2+) insertion/de-insertion along with MnO_(2) dissolution/deposition at the cathode.After the modification,Na-MnO_(2) battery exhibits a discharge capacity of 267.10 mA h/g and a cell voltage of 3.30 V(vs.Na/Na^(+)),resulting in a high specific energy density of 881.43 Wh/kg.After 300 cycles,the battery retains 98% of its first-cycle discharge capacity with100% coulombic efficiency.Besides,Na metal-free battery assembled using sodium biphenyl as a safer anode also delivers an excellent energy density of 810.0 Wh/kg.This work could provide a feasible method to develop an advanced Na-MnO_(2) battery for real-time energy storage applications.
基金received funding from the Postgraduate Research&Practice Innovation Program of Jiangsu Province(SJCX23_1633)2023 University Student Innovation and Entrepreneurship Training Program(202311463009Z)+1 种基金Changzhou Science and Technology Support Project(CE20235045)Open Project of Jiangsu Key Laboratory of Power Transmission&Distribution Equipment Technology(2021JSSPD12).
文摘Uneven power distribution,transient voltage,and frequency deviations are observed in the photovoltaic storage hybrid inverter during the switching between grid-connected and island modes.In response to these issues,this paper proposes a grid-connected/island switching control strategy for photovoltaic storage hybrid inverters based on the modified chimpanzee optimization algorithm.The proposed strategy incorporates coupling compensation and power differentiation elements based on the traditional droop control.Then,it combines the angular frequency and voltage amplitude adjustments provided by the phase-locked loop-free pre-synchronization control strategy.Precise pre-synchronization is achieved by regulating the virtual current to zero and aligning the photovoltaic storage hybrid inverter with the grid voltage.Additionally,two novel operators,learning and emotional behaviors are introduced to enhance the optimization precision of the chimpanzee algorithm.These operators ensure high-precision and high-reliability optimization of the droop control parameters for photovoltaic storage hybrid inverters.A Simulink model was constructed for simulation analysis,which validated the optimized control strategy’s ability to evenly distribute power under load transients.This strategy effectively mitigated transient voltage and current surges during mode transitions.Consequently,seamless and efficient switching between gridconnected and island modes was achieved for the photovoltaic storage hybrid inverter.The enhanced energy utilization efficiency,in turn,offers robust technical support for grid stability.
基金The National Natural Science Foundation of China(No.21005016)the Foundation of Educational Commission of Jiangsu Province(No.JHB2011-2)
文摘In order to improve the substrate diffusion properties and stability of an immobilized enzyme alginate microgels modified with TiO2 nanoparticles were employed as the enzyme immobilizing support.Ionotropic gelation was applied for the preparation of hybrid gels while Ca2+ Ce3+ Ni2+Cu2+and Fe3+were employed as the crosslinkers.Papain was selected as the model enzyme. UV-Vis spectroscopy was employed to investigate the activity of papain to evaluate kinetics and stability.Analysis results show that the highest affinity the lowest Michaelis-Menten constant Km =11.0 mg/mL and the highest stability are obtained when using Cu2+as the crosslinker.The effect of the mass ratio of TiO2 to papain on the stability and leakage of papain is also investigated and the results show that 10∶1 TiO2∶papain is optimal because the proper use of TiO2 can reduce enzyme leakage and ensure enzyme stability.Preparing Cu/alginate/TiO2 hybrid gels via ionotropic gelation can provide a satisfactory diffusion capability and enzyme stability.
基金Supported by the National Natural Science Foundation of China(51606107,51576102)the Collaborative Innovation Project of Green Tire and Rubber(0200501436)
文摘Natural rubber nanocomposites filled with hybrid fillers of multi-walled carbon nanotubes(CNTs) and carbon black(CB) were prepared. CNTs were ultrasonically modified in mixture of hydrogen peroxide(H2O2) and distilled water(H2O). The functional groups on the surface of CNTs, changes in nanotube structure and morphology were characterized by Fourier transform infrared spectroscopy(FT-IR), Raman Spectroscopy, and transmission electron microscopy(TEM). It shows that hydroxyl(OH·) is successfully introduced. The surface defects of modified CNTs were obviously higher than those of original CNTs, and the degree of agglomeration was greatly reduced. Thermal conductivity of the composites was tested by protection heat flow meter method. Compared with unmodified CNTs/CB filling system, the thermal conductivity of hybrid composites is improved by an average of 5.8% with 1.5 phr(phr is parts per hundred rubber) of hydroxyl CNTs and 40 phr of CB filled. A three-dimensional heat conduction network composed of hydroxyl CNTs and CB, as observed by TEM, contributes to the good properties. Thermal conductivity of the hybrid composites increases as temperature rises. The mechanical properties of hybrid composites are also good with hydroxyl CNTs filled nanocomposites;the tensile strength, 100% and 300% tensile stress are improved by 10.1%, 22.4% and 26.2% respectively.
基金Project supported by the Program of the Key Laboratory of Rock and Soil Mechanics of Chinese Academy of Sciences (No.Z110507)
文摘The singular hybrid boundary node method (SHBNM) is proposed for solving three-dimensional problems in linear elasticity. The SHBNM represents a coupling between the hybrid displacement variational formulations and moving least squares (MLS) approximation. The main idea is to reduce the dimensionality of the former and keep the meshless advantage of the later. The rigid movement method was employed to solve the hyper-singular integrations. The 'boundary layer effect', which is the main drawback of the original Hybrid BNM, was overcome by an adaptive integration scheme. The source points of the fundamental solution were arranged directly on the boundary. Thus the uncertain scale factor taken in the regular hybrid boundary node method (RHBNM) can be avoided. Numerical examples for some 3D elastic problems were given to show the characteristics. The computation results obtained by the present method are in excellent agreement with the analytical solution. The parameters that influence the performance of this method were studied through the numerical examples.
文摘This paper focuses on the development of a hybrid method with block extension for direct solution of initial value problems (IVPs) of general third-order ordinary differential equations. Power series was used as the basis function for the solution of the IVP. An approximate solution from the basis function was interpolated at some selected off-grid points while the third derivative of the approximate solution was collocated at all grid and off-grid points to generate a system of linear equations for the determination of the unknown parameters. The derived method was tested for consistency, zero stability, convergence and absolute stability. The method was implemented with five test problems including the Genesio equation to confirm its accuracy and usability. The rate of convergence (ROC) reveals that the method is consistent with the theoretical order of the proposed method. Comparison of the results with some existing methods shows the superiority of the accuracy of the method.
基金CAPES(Coordenacao de Aperfeicoamento de Pessoal de Nível Superior)CNPq(Conselho Nacional de Desenvolvimento Científicoe Tecnológico,grant number 161464/2013-0)for the financial support
文摘This paper proposes the use of the flexible tolerance method(FTM) modified with scaling of variables and hybridized with different unconstrained optimization methods to solve real constrained optimization problems.The benchmark problems used to analyze the performance of the methods were taken from G-Suite functions.The original method(FTM) and other four proposed methods:(i) FTM with scaling of variables(FTMS),(ii) FTMS hybridized with BFGS(FTMS-BFGS),(iii) FTMS hybridized with modified Powell's method(FTMS-Powell)and(iv) FTMS hybridized with PSO(FTMS-PSO), were implemented. The success rates of the methods were 80%,100%, 75%, 95% and 85%, for FTM, FTMS, FTMS-BFGS, FTMS-Powell and FTMS-PSO, respectively. Numerical experiments including real constrained problems indicated that FTMS gave the best performance, followed by FTMSPowell and FTMS-PSO. Despite the inferior performance compared to FTMS and FTMS-Powell, the FTMS-PSO method presented some advantages since good different initial points could be obtained, which allow exploring different routes through the solution space and to escape from local optima. The proposed methods proved to be an effective way of improving the performance of the original FTM.
基金The project is supported by the National Natural Science Foundation of China
文摘In this paper the equivalence of the generalized hybrid element and the modified Wilson element, which is derived by the generalized hybrid method, is proved.
文摘A novel super-hybrid composite (NSHC) was boron-modified phenolic resin (BPR) with three-dimensional reticulated SiC ceramic (3DRC) and high silica fibers. Ablation performance of the NSHC was studied. The results show that the linear ablation rate of NSHC was lower than that of pure BPR and the high silica/BPR composite. Its linear ablation rate is 1/17 of the high silica/BPR. Mass ablation rate of the NSHC is very close to that of the pure BPR and the high silica/BPR composite. Scanning electron microscope (SEM) analysis indicates that 3DRC has scarcely changed its shape at the ablation temperature. Its special reticulated structure can restrict the materials deformation and prevent high velocity heat flow from eroding the surface of the materials largely and thus increase ablation resistance of the NSHC.
基金The Swedish International Development Cooperation Agency
文摘Reflector edges, sharp acceptance angles and by-pass diodes introduce large variations in the electrical performance of asymmetrical concentrating photovoltaic/thermal modules over a short incidence angle interval. It is therefore important to quantify these impacts precisely. The impact on the electrical performance of the optical properties of an asymmetrical photovoltaic/thermal CPC-collector was measured in Maputo, Mozambique. The measurements were carried out with the focus on attaining a high resolution incidence angle modifier in both the longitudinal and transversal directions, since large variations were expected over small angle intervals. A detailed analysis of the contribution of the diffuse radiation to the total output was also carried out. The solar cells have an electrical efficiency of 18% while the maximum measured electrical efficiency of the collector was 13.9 % per active glazed area and 20.9 % per active cell area, at 25 °C. Such data make it possible to quantify not only the electrical performance for different climatic and operating conditions but also to determine potential improvements to the collector design. The electrical output can be increased by a number of different measures, e.g. removing the outermost cells, turning the edge cells 90°, dividing each receiver side into three or four parts and directing the tracking, when used, along a north-south axis.
文摘The Nevirapine (NVP)/Polycaprolactone (PCL)/Nanoparticles hybrids systems have been developed as a potential platform for drug delivery, by solvent cast, as thin films. NVP, an antiretroviral drug, was included within PCL matrix containing three types of nanoparticles: an organoclay layered silicate Viscogel S7®(3% w/w), hydrophilic silica oxide particles Aerosil®A20 (0.25% w/w) and titanium dioxide particles (0.25% w/w). These systems were characterized by X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), low-field nuclear magnetic resonance (NMR), ultraviolet-visible spectroscopy (UV), in-vitro dissolution testing and drug release mechanism kinetics. The PCL crystallization was affected by NVP incorporation, modifying its semi-crystalline structure to a less ordered structure. When nanoparticles and NVP were added, the T<sub>1</sub>H values increased, for PCL, PCL/S7, PCL/ SiO<sub>2</sub> and PCL/TiO<sub>2</sub> hybrids, suggesting that its addition produced a new material, with less molecular mobility, due to the new intermolecular interactions formation. It can consider a structure formation among the PCL chains, nanoparticles and NVP, with strong forces in the PCL/SiO<sub>2</sub>/NVP system. The amount of NVP included was around 1.5 ± 0.03 mg/cm<sup>2</sup>. In the in-vitro dissolution test, the PCL/SiO<sub>2</sub>/NVP system released the smallest amount of drug and this result could be attributed to the strong intermolecular interaction between the drug and the PCL/SiO<sub>2</sub> system. Higuchi’s model was the mathematical model chosen to treat the release data, since this model presented the highest coefficient correlation (r) value. The drug release probably occur by diffusion through the matrix pores, thus, these materials are suitable for sustained release of NVP.
文摘This study presents hybrid clones of Corymbia spp.developed by Aperam BioEnergia as potential substitutes for Eucalyptus wood in the pulp industry.The biomass of Eucalyptus spp.was compared with that of Corymbia spp.by performing modified kraft pulping and basic density analyses.Comparisons were made by analyzing their respective mean annual increments of cellulose(MAI_(cel))and specific wood consumption(SWC),estimated using a kappa number of(19±1).The results showed that one of the hybrid clones(Corymbia citriodora×Corymbia torelliana,ID 4)had higher basic wood density,higher screened yield,better MAI_(cel#k19),and lower SWC than the other samples,reaching values of 0.608 t/m^(3),54.1%,24.6 ADt/ha/year(i.e.,air dry ton/hectare/year),and 2.74 m^(3)/ADt,respectively.Consequently,clone ID 4 had the highest MAI_(cel)/SWC ratio score(8.98).Given its high forest productivity and low industrial cost compared with other samples,as well as its advantages over Eucalyptus spp.wood,we concluded that clone ID 4 has great potential as an alternative biomass for pulp production.
文摘Floorplanning is a prominent area in the Very Large-Scale Integrated (VLSI) circuit design automation, because it influences the performance, size, yield and reliability of the VLSI chips. It is the process of estimating the positions and shapes of the modules. A high packing density, small feature size and high clock frequency make the Integrated Circuit (IC) to dissipate large amount of heat. So, in this paper, a methodology is presented to distribute the temperature of the module on the layout while simultaneously optimizing the total area and wirelength by using a hybrid Particle Swarm Optimization-Harmony Search (HPSOHS) algorithm. This hybrid algorithm employs diversification technique (PSO) to obtain global optima and intensification strategy (HS) to achieve the best solution at the local level and Modified Corner List algorithm (MCL) for floorplan representation. A thermal modelling tool called hotspot tool is integrated with the proposed algorithm to obtain the temperature at the block level. The proposed algorithm is illustrated using Microelectronics Centre of North Carolina (MCNC) benchmark circuits. The results obtained are compared with the solutions derived from other stochastic algorithms and the proposed algorithm provides better solution.
文摘A novel super-hybrid composite (NSHC) is prepared with three-dimension reticulated SiC ceramic (3DRC), high performance carbon fibers and modified phenolic resin (BPR) in this paper. Ablation performance of super-hybrid composite is studied. The results show that the NSHC has less linear ablation rate compared with pure BPR and CF/BPR composite, for example, its linear ablation rate is 50% of CF/BPR at the same fiber content. Mass ablation rate of the NSHC is slightly lower than that of pure BPR and CF/BPR composite because of their difference in the density. Scanning electron microscopic analysis indicates that 3DRC can increase anti-erosion capacity of materials because its special reticulated structure can control the deformation of materials and strengthen the stability of integral structure.