The distillation column with side reactors (SRC) can overcome the temperature/pressure mismatch in the traditional reactive distillation, the column operates at temperature/pressure favorable for vapor-liquid separati...The distillation column with side reactors (SRC) can overcome the temperature/pressure mismatch in the traditional reactive distillation, the column operates at temperature/pressure favorable for vapor-liquid separation, while the reactors operate at temperatures/pressures favorable for reaction kinetics. According to the smooth operation and automatic control problem of the distillation column with side reactors (SRC), the design, simulation calculation and dynamic control of the SCR process for chlorobenzene production are discussed in the paper. Firstly, the mechanism models, the integrated structure optimal design and process simulation systems are established, respectively. And then multivariable control schemes are designed, the controllability of SRC process based on the optimal steady-state integrated structure is explored. The dynamic response performances of closed-loop system against several disturbances are discussed to verify the effectiveness of control schemes for the SRC process. The simulating results show that the control structure using conventional control strategies can effectively overcome feeding disturbances in a specific range.展开更多
The historical simulation of phase five of the Coupled Model Intercomparison Project （CMIP5） ex- periments performed by the Beijing Climate Center cli- mate system model （BCC_CSM1.1） is evaluated regard- ing the t...The historical simulation of phase five of the Coupled Model Intercomparison Project （CMIP5） ex- periments performed by the Beijing Climate Center cli- mate system model （BCC_CSM1.1） is evaluated regard- ing the time evolutions of the global and China mean sur- face air temperature （SAT） and surface climate change over China in recent decades. BCC CSM1.1 has better capability at reproducing the time evolutions of the global and China mean SAT than BCC_CSM1.0. By the year 2005, the BCC_CSM1.1 model simulates a warming am- plitude of approximately I℃ in China over the 1961- 1990 mean, which is consistent with observation. The distributions of the warming trend over China in the four seasons during 1958-2004 are basically reproduced by BCC CSM1.1, with the warmest occurring in winter. Al- though the cooling signal of Southwest China in spring is partly reproduced by BCC_CSM1.1, the cooling trend over central eastern China in summer is omitted by the model. For the precipitation change, BCC_CSM1.1 has good performance in spring, with drought in Southeast China. After removing the linear trend, the interannual correlation map between the model and the observation shows that the model has better capability at reproducing the summer SAT over China and spring precipitation over Southeast China.展开更多
基金Supported by the National Natural Science Foundation of China (61203020, 21276126)the Natural Science Foundation of Jiangsu Province (BK2011795)+1 种基金Jiangsu Province Higher Education Natural Science Foundation (09KJA530004)China Postdoctoral Science Foundation (20100471325)
文摘The distillation column with side reactors (SRC) can overcome the temperature/pressure mismatch in the traditional reactive distillation, the column operates at temperature/pressure favorable for vapor-liquid separation, while the reactors operate at temperatures/pressures favorable for reaction kinetics. According to the smooth operation and automatic control problem of the distillation column with side reactors (SRC), the design, simulation calculation and dynamic control of the SCR process for chlorobenzene production are discussed in the paper. Firstly, the mechanism models, the integrated structure optimal design and process simulation systems are established, respectively. And then multivariable control schemes are designed, the controllability of SRC process based on the optimal steady-state integrated structure is explored. The dynamic response performances of closed-loop system against several disturbances are discussed to verify the effectiveness of control schemes for the SRC process. The simulating results show that the control structure using conventional control strategies can effectively overcome feeding disturbances in a specific range.
基金supported by the National Basic Research Program of China (973 Program,2010CB951903)the National Natural Science Foundation of China (41105054)the China Meteorological Administration (GYHY200706010)
文摘The historical simulation of phase five of the Coupled Model Intercomparison Project （CMIP5） ex- periments performed by the Beijing Climate Center cli- mate system model （BCC_CSM1.1） is evaluated regard- ing the time evolutions of the global and China mean sur- face air temperature （SAT） and surface climate change over China in recent decades. BCC CSM1.1 has better capability at reproducing the time evolutions of the global and China mean SAT than BCC_CSM1.0. By the year 2005, the BCC_CSM1.1 model simulates a warming am- plitude of approximately I℃ in China over the 1961- 1990 mean, which is consistent with observation. The distributions of the warming trend over China in the four seasons during 1958-2004 are basically reproduced by BCC CSM1.1, with the warmest occurring in winter. Al- though the cooling signal of Southwest China in spring is partly reproduced by BCC_CSM1.1, the cooling trend over central eastern China in summer is omitted by the model. For the precipitation change, BCC_CSM1.1 has good performance in spring, with drought in Southeast China. After removing the linear trend, the interannual correlation map between the model and the observation shows that the model has better capability at reproducing the summer SAT over China and spring precipitation over Southeast China.
