Molasses was used as an alternative binder to the bentonite binder. The change in moisture absorption by pellets prepared with different iron ores and different molasses contents were investigated. Iron ore properties...Molasses was used as an alternative binder to the bentonite binder. The change in moisture absorption by pellets prepared with different iron ores and different molasses contents were investigated. Iron ore properties exerted the major effect on pellet behavior and final pellet quality. The absorbed moisture content of pellets prepared without binder, bentonite-added pellets, and molasses-added pellets were in the range of 7.72%–9.95%, 9.62%–10.84%, and 6.14%-6.69%, respectively. The wet pellet compressive strength of molasses-added pellets(43–230 N/pellet) was superior to that of bentonite-added pellets(9.47–11.92 N/pellet). The compressive strength of dried molasses-modified pellets increased to 222–394 N/pellet, which is currently the highest value achieved for dried pellets.展开更多
In the research,three kinds composite materials of biomimetic laminated boards made from cross-linking starch/maize stalk fiber-the single layer jute fiber reinforced maize stalk fiber boards,the dual layer jute fiber...In the research,three kinds composite materials of biomimetic laminated boards made from cross-linking starch/maize stalk fiber-the single layer jute fiber reinforced maize stalk fiber boards,the dual layer jute fiber reinforced maize stalk fiber boards,the jute fiber hybrid reinforced maize stalk fiber boards were obtained according to the formulation of cross-linking maize starch adhesive and the preparation process of composite materials.The hygroscopicity variation of the biomimetic laminated boards made from cross-linking starch/maize stalk fiber was investigated under different relative humidity conditions.The moisture absorption rate and the variation velocity were used as important evaluation indexes to evaluate the moisture absorption properties of the straw fiber composites.The mathematical models of the moisture absorption rate and the variation velocity were established.The hygroscopicity variation curves of three kinds of composite materials were measured under the five different relative humidity conditions.The results showed that the three kinds composites had low moisture absorption rate compared with other stalk fiber composites which were good at water resistance and the waterproof property of the three kinds stalk fibers were excellent under the experimental conditions.The research provides a useful reference to improve the water resistance of fiber composites and a new idea on the development and application of the biodegradable composites,especially the straw fiber reinforced composites.展开更多
Composite materials have attracted increasing attention to replace traditional materials such as metals for aerospace and automotive components due to their excellent mechanical and lightweight properties.By reinforci...Composite materials have attracted increasing attention to replace traditional materials such as metals for aerospace and automotive components due to their excellent mechanical and lightweight properties.By reinforcing with fillers,the material properties can be tailored to suit the needs of certain requirements.Nanofillers graphene oxide(GO) and silica(SiO_2) are incorporated into carbon fibre/epoxy(CF/E)composites to enhance epoxy resin properties by impregnating into the weak area of resin and boosting the interaction forces between resin and filler interfaces.The mechanical,thermal,and morphological properties of GO and SiO_2 fillers in the CF/E were investigated.Movever,after the exposure to distilled water and salt water,effect of moisture absorption on flexural and impact properties were investigated and the CF/E composite with hybrid nanofillers exhibited strong resistance to degradation in flexural and impact properties.FESEM images of the fracture surfaces indicated that the good performance of CF/E composite with bi-hybrid nanofillers originated from the synergistic GO and SiO_2 nanofillers,which limit the motion of epoxy polymer molecular chain and give sufficient stress transfer ability to the composite system.The overall results showed that GO and SiO_2 fillers can significantly enhance the mechanical properties as well as resistance to moisture environment.展开更多
In order to explore the effect of artificial accelerated aging temperature on the performance of carbon fiber/epoxy resin composites,we used artificial seawater as the aging medium,designed the aging environment of se...In order to explore the effect of artificial accelerated aging temperature on the performance of carbon fiber/epoxy resin composites,we used artificial seawater as the aging medium,designed the aging environment of seawater at different temperatures under normal pressure,and studied the aging behavior of carbon fiber/epoxy composites.The infrared spectroscopy results show that,with the increase of aging temperature,the degree of hydrolysis of the composite is greater.At the same time,after 250 days of aging of artificial seawater at regular temperature,40 and 60 ℃,the moisture absorption rates of composite materials were 0.45%,0.63%,and 1.05%,and the retention rates of interlaminar shear strength were 91%,78%,and 62%,respectively.It is shown that the temperature of the aging environment has a significant impact on the hygroscopic behavior and mechanical properties of the composite,that is,the higher the temperature,the faster the moisture absorption of the composite,and the faster the decay of the mechanical properties of the composite.展开更多
针对普通硅胶吸水率不高、单一组分改性硅胶再生温度相对较高的缺陷,运用氯化钙和氯化镁复合改性硅胶,制备新型干燥剂。通过测定复合硅胶的差示扫描量热曲线(DSC)和热重分析(TG)曲线,考察复合硅胶的吸水性能、再生性能和对水的脱附活化...针对普通硅胶吸水率不高、单一组分改性硅胶再生温度相对较高的缺陷,运用氯化钙和氯化镁复合改性硅胶,制备新型干燥剂。通过测定复合硅胶的差示扫描量热曲线(DSC)和热重分析(TG)曲线,考察复合硅胶的吸水性能、再生性能和对水的脱附活化能的影响。研究表明:在室温饱和湿度下,用浓度均为0.25 mol L 1的氯化钙和氯化镁复合改性硅胶的吸水量约为未改性硅胶相应值的2倍,吸湿速率提高3.5倍以上。复合干燥剂的再生温度比改性前低了10℃,脱附活化能数值小,再生6次后再生率依然高达92%左右,且基本不再变化。展开更多
文摘Molasses was used as an alternative binder to the bentonite binder. The change in moisture absorption by pellets prepared with different iron ores and different molasses contents were investigated. Iron ore properties exerted the major effect on pellet behavior and final pellet quality. The absorbed moisture content of pellets prepared without binder, bentonite-added pellets, and molasses-added pellets were in the range of 7.72%–9.95%, 9.62%–10.84%, and 6.14%-6.69%, respectively. The wet pellet compressive strength of molasses-added pellets(43–230 N/pellet) was superior to that of bentonite-added pellets(9.47–11.92 N/pellet). The compressive strength of dried molasses-modified pellets increased to 222–394 N/pellet, which is currently the highest value achieved for dried pellets.
基金supported by National Science Fund for Distinguished Young Scho lars of China(Grant No.50025516)National Natural Science Foundation of China(Grant No.50675087,50673037,5030600131)+1 种基金"985 Project"of Jilin University,Natural Science Foundation of Henan Educational Committee(Grant No.2009B210006)Innovation Ability Foundation of Natural Science(Grant No.2013ZCX002)of Henan University of Science and Technology.
文摘In the research,three kinds composite materials of biomimetic laminated boards made from cross-linking starch/maize stalk fiber-the single layer jute fiber reinforced maize stalk fiber boards,the dual layer jute fiber reinforced maize stalk fiber boards,the jute fiber hybrid reinforced maize stalk fiber boards were obtained according to the formulation of cross-linking maize starch adhesive and the preparation process of composite materials.The hygroscopicity variation of the biomimetic laminated boards made from cross-linking starch/maize stalk fiber was investigated under different relative humidity conditions.The moisture absorption rate and the variation velocity were used as important evaluation indexes to evaluate the moisture absorption properties of the straw fiber composites.The mathematical models of the moisture absorption rate and the variation velocity were established.The hygroscopicity variation curves of three kinds of composite materials were measured under the five different relative humidity conditions.The results showed that the three kinds composites had low moisture absorption rate compared with other stalk fiber composites which were good at water resistance and the waterproof property of the three kinds stalk fibers were excellent under the experimental conditions.The research provides a useful reference to improve the water resistance of fiber composites and a new idea on the development and application of the biodegradable composites,especially the straw fiber reinforced composites.
基金Sponsored by the National Science Fund for Excellent Young Scholars(Grant No.51722509)the National Natural Science Foundation of China(Grant No.51575440)the Shaanxi Science and Technology Project(Grant No.2016GY-011)
文摘Composite materials have attracted increasing attention to replace traditional materials such as metals for aerospace and automotive components due to their excellent mechanical and lightweight properties.By reinforcing with fillers,the material properties can be tailored to suit the needs of certain requirements.Nanofillers graphene oxide(GO) and silica(SiO_2) are incorporated into carbon fibre/epoxy(CF/E)composites to enhance epoxy resin properties by impregnating into the weak area of resin and boosting the interaction forces between resin and filler interfaces.The mechanical,thermal,and morphological properties of GO and SiO_2 fillers in the CF/E were investigated.Movever,after the exposure to distilled water and salt water,effect of moisture absorption on flexural and impact properties were investigated and the CF/E composite with hybrid nanofillers exhibited strong resistance to degradation in flexural and impact properties.FESEM images of the fracture surfaces indicated that the good performance of CF/E composite with bi-hybrid nanofillers originated from the synergistic GO and SiO_2 nanofillers,which limit the motion of epoxy polymer molecular chain and give sufficient stress transfer ability to the composite system.The overall results showed that GO and SiO_2 fillers can significantly enhance the mechanical properties as well as resistance to moisture environment.
文摘In order to explore the effect of artificial accelerated aging temperature on the performance of carbon fiber/epoxy resin composites,we used artificial seawater as the aging medium,designed the aging environment of seawater at different temperatures under normal pressure,and studied the aging behavior of carbon fiber/epoxy composites.The infrared spectroscopy results show that,with the increase of aging temperature,the degree of hydrolysis of the composite is greater.At the same time,after 250 days of aging of artificial seawater at regular temperature,40 and 60 ℃,the moisture absorption rates of composite materials were 0.45%,0.63%,and 1.05%,and the retention rates of interlaminar shear strength were 91%,78%,and 62%,respectively.It is shown that the temperature of the aging environment has a significant impact on the hygroscopic behavior and mechanical properties of the composite,that is,the higher the temperature,the faster the moisture absorption of the composite,and the faster the decay of the mechanical properties of the composite.
文摘针对普通硅胶吸水率不高、单一组分改性硅胶再生温度相对较高的缺陷,运用氯化钙和氯化镁复合改性硅胶,制备新型干燥剂。通过测定复合硅胶的差示扫描量热曲线(DSC)和热重分析(TG)曲线,考察复合硅胶的吸水性能、再生性能和对水的脱附活化能的影响。研究表明:在室温饱和湿度下,用浓度均为0.25 mol L 1的氯化钙和氯化镁复合改性硅胶的吸水量约为未改性硅胶相应值的2倍,吸湿速率提高3.5倍以上。复合干燥剂的再生温度比改性前低了10℃,脱附活化能数值小,再生6次后再生率依然高达92%左右,且基本不再变化。
