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Multi-Physics Coupled Acoustic-Mechanics Analysis and Synergetic Optimization for a Twin-Fluid Atomization Nozzle
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作者 Wenying Li Yanying Li +4 位作者 Yingjie Lu Jinhuan Xu Bo Chen Li Zhang Yanbiao Li 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2024年第3期204-223,共20页
Fine particulate matter produced during the rapid industrialization over the past decades can cause significant harm to human health.Twin-fluid atomization technology is an effective means of controlling fine particul... Fine particulate matter produced during the rapid industrialization over the past decades can cause significant harm to human health.Twin-fluid atomization technology is an effective means of controlling fine particulate matter pollution.In this paper,the influences of the main parameters on the droplet size,effective atomization range and sound pressure level(SPL)of a twin-fluid nozzle(TFN)are investigated,and in order to improve the atomization performance,a multi-objective synergetic optimization algorithm is presented.A multi-physics coupled acousticmechanics model based on the discrete phase model(DPM),large eddy simulation(LES)model,and Ffowcs Williams-Hawkings(FW-H)model is established,and the numerical simulation results of the multi-physics coupled acoustic-mechanics method are verified via experimental comparison.Based on the analysis of the multi-physics coupled acoustic-mechanics numerical simulation results,the effects of the water flow on the characteristics of the atomization flow distribution were obtained.A multi-physics coupled acoustic-mechanics numerical simulation result was employed to establish an orthogonal test database,and a multi-objective synergetic optimization algorithm was adopted to optimize the key parameters of the TFN.The optimal parameters are as follows:A gas flow of 0.94 m^(3)/h,water flow of 0.0237 m^(3)/h,orifice diameter of the self-excited vibrating cavity(SVC)of 1.19 mm,SVC orifice depth of 0.53 mm,distance between SVC and the outlet of nozzle of 5.11 mm,and a nozzle outlet diameter of 3.15 mm.The droplet particle size in the atomization flow field was significantly reduced,the spray distance improved by 71.56%,and the SPL data at each corresponding measurement point decreased by an average of 38.96%.The conclusions of this study offer a references for future TFN research. 展开更多
关键词 Twin-fluid nozzle BP neural network Multi-objective optimization multi-physics coupled Acousticmechanics analysis Genetic algorithm
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Transient multi-physics behavior of an insert high temperature superconducting no-insulation coil in hybrid superconducting magnets with inductive coupling 被引量:1
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作者 Xiang KANG Yujin TONG +1 位作者 Wei WU Xingzhe WANG 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2023年第2期255-272,共18页
A transient multi-physics model incorporated with an electromagneto-thermomechanical coupling is developed to capture the multi-field behavior of a single-pancake(SP)insert no-insulation(NI)coil in a hybrid magnet dur... A transient multi-physics model incorporated with an electromagneto-thermomechanical coupling is developed to capture the multi-field behavior of a single-pancake(SP)insert no-insulation(NI)coil in a hybrid magnet during the charging and discharging processes.The coupled problem is resolved by means of the finite element method(FEM)for the magneto-thermo-elastic behaviors and the Runge-Kutta method for the transient responses of the electrical circuits of the hybrid superconducting magnet system.The results reveal that the transient multi-physics responses of the insert NI coil primarily depend on the charging/discharging procedure of the hybrid magnet.Moreover,a reverse azimuthal current and a compressive hoop stress are induced in the insert NI coil during the charging process,while a forward azimuthal current and a tensile hoop stress are observed during the discharging process.The induced voltages in the insert NI coil can drive the currents flowing across the radial turns where the contact resistance exists.Therefore,it brings forth significant Joule heat,causing a temperature rise and a uniform distribution of this heat in the coil turns.Accordingly,a thermally/mechanically unstable or quenching event may be encountered when a high operating current is flowing in the insert NI coil.It is numerically predicted that a quick charging will induce a compressive hoop stress which may bring a risk of buckling instability in the coil,while a discharging will not.The simulations provide an insight of hybrid superconducting magnets under transient start-up or shutdown phases which are inevitably encountered in practical applications. 展开更多
关键词 hybrid superconducting magnet high temperature superconducting(HTS)no-insulation(NI)coil inductive coupling multi-physics field thermal stability
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Electrochemical machining gap prediction with multi-physics coupling model based on two-phase turbulence flow 被引量:3
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作者 Yuanlong CHEN Xiaochao ZHOU +1 位作者 Peixuan CHEN Ziquan WANG 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2020年第3期1057-1063,共7页
Considering the influence of hydrogen gas generated during electrochemical machining on the conductivity of electrolyte, a two-phase turbulent flow model is presented to describe the gas bubbles distribution.The k-e t... Considering the influence of hydrogen gas generated during electrochemical machining on the conductivity of electrolyte, a two-phase turbulent flow model is presented to describe the gas bubbles distribution.The k-e turbulent model is used to describe the electrolyte flow field.The Euler–Euler model based on viscous drag and pressure force is used to calculate the twodimensional distribution of gas volume fraction.A multi-physics coupling model of electric field,two-phase flow field and temperature field is established and solved by weak coupling iteration method.The numerical simulation results of gas volume fraction, temperature and conductivity in equilibrium state are discussed.The distributions of machining gap at different time are analyzed.The predicted results of the machining gap are consistent with the experimental results, and the maximum deviation between them is less than 50 lm. 展开更多
关键词 Electrochemical machining EQUILIBRIUM Machining gap prediction multi-physics coupling Two-phase turbulent flow
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Multi-physics coupling field finite element analysis on giant magnetostrictive materials smart component 被引量:2
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作者 Zhang-rong ZHAO Yiojie WU +2 位作者 Xin-jian GU Lei ZHANG Ji-feng YANG 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2009年第5期653-660,共8页
This study presents a new method to solve the difficult problem of precise machining a non-cylinder pinhole of a piston using embedded giant magnetostrictive material (GMM) in the component. We propose the finite elem... This study presents a new method to solve the difficult problem of precise machining a non-cylinder pinhole of a piston using embedded giant magnetostrictive material (GMM) in the component. We propose the finite element model of GMM smart component in electric, magnetic, and mechanical fields by step computation to optimize the design of GMM smart com-ponent. The proposed model is implemented by using COMSOL multi-physics V3.2a. The effects of the smart component on the deformation and the system resonance frequencies are studied. The results calculated by the model are in excellent agreement (relative errors are below 10%) with the experimental values. 展开更多
关键词 Smart component Giant magnetostrictive Finite element method (FEM) modeling Non-cylinder piston pinhole multi-physics coupling field
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An internal ballistic model of electromagnetic railgun based on PFN coupled with multi-physical field and experimental validation
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作者 Benfeng Gu Haiyuan Li Baoming Li 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第2期254-261,共8页
To accelerate the practicality of electromagnetic railguns,it is necessary to use a combination of threedimensional numerical simulation and experiments to study the mechanism of bore damage.In this paper,a three-dime... To accelerate the practicality of electromagnetic railguns,it is necessary to use a combination of threedimensional numerical simulation and experiments to study the mechanism of bore damage.In this paper,a three-dimensional numerical model of the augmented railgun with four parallel unconventional rails is introduced to simulate the internal ballistic process and realize the multi-physics field coupling calculation of the rail gun,and a test experiment of a medium-caliber electromagnetic launcher powered by pulse formation network(PFN)is carried out.Various test methods such as spectrometer,fiber grating and high-speed camera are used to test several parameters such as muzzle initial velocity,transient magnetic field strength and stress-strain of rail.Combining the simulation results and experimental data,the damage condition of the contact surface is analyzed. 展开更多
关键词 Internal ballistic modeling Electromagnetic rail gun multi-physics field coupling Experimental validation PFN
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Influence of water coupling coefficient on the blasting effect of red sandstone specimens 被引量:2
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作者 Yang Li Renshu Yang +1 位作者 Yanbing Wang Dairui Fu 《International Journal of Coal Science & Technology》 EI CAS CSCD 2024年第1期148-166,共19页
This study investigates the impact of different water coupling coefficients on the blasting effect of red sandstone.The analysis is based on the theories of detonation wave and elastic wave,focusing on the variation i... This study investigates the impact of different water coupling coefficients on the blasting effect of red sandstone.The analysis is based on the theories of detonation wave and elastic wave,focusing on the variation in wall pressure of the blasting holes.Using DDNP explosive as the explosive load,blasting tests were conducted on red sandstone specimens with four different water coupling coefficients:1.20,1.33,1.50,and 2.00.The study examines the morphologies of the rock specimens after blasting under these different water coupling coefficients.Additionally,the fractal dimensions of the surface cracks resulting from the blasting were calculated to provide a quantitative evaluation of the extent of rock damage.CT scanning and 3D reconstruction were performed on the post-blasting specimens to visually depict the extent of damage and fractures within the rock.Additionally,the volume fractal dimension and damage degree of the post-blasting specimens are calculated.The findings are then combined with numerical simulation to facilitate auxiliary analysis.The results demonstrate that an increase in the water coupling coefficient leads to a reduction in the peak pressure on the hole wall and the crushing zone,enabling more of the explosion energy to be utilized for crack propagation following the explosion.The specimens exhibited distinct failure patterns,resulting in corresponding changes in fractal dimensions.The simulated pore wall pressure–time curve validated the derived theoretical results,whereas the stress cloud map and explosion energy-time curve demonstrated the buffering effect of the water medium.As the water coupling coefficient increases,the buffering effect of the water medium becomes increasingly prominent. 展开更多
关键词 Water coupling coefficient Radial uncoupled charge Numerical simulation Fractal dimension
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Strong coupling and catenary field enhancement in the hybrid plasmonic metamaterial cavity and TMDC monolayers 被引量:2
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作者 Andergachew Mekonnen Berhe Khalil As’ham +2 位作者 Ibrahim Al-Ani Haroldo T.Hattori Andrey E.Miroshnichenko 《Opto-Electronic Advances》 SCIE EI CAS CSCD 2024年第5期20-32,共13页
Strong coupling between resonantly matched surface plasmons of metals and excitons of quantum emitters results in the formation of new plasmon-exciton hybridized energy states.In plasmon-exciton strong coupling,plasmo... Strong coupling between resonantly matched surface plasmons of metals and excitons of quantum emitters results in the formation of new plasmon-exciton hybridized energy states.In plasmon-exciton strong coupling,plasmonic nanocavities play a significant role due to their ability to confine light in an ultrasmall volume.Additionally,two-dimensional transition metal dichalcogenides(TMDCs) have a significant exciton binding energy and remain stable at ambient conditions,making them an excellent alternative for investigating light-matter interactions.As a result,strong plasmon-exciton coupling has been reported by introducing a single metallic cavity.However,single nanoparticles have lower spatial confinement of electromagnetic fields and limited tunability to match the excitonic resonance.Here,we introduce the concept of catenary-shaped optical fields induced by plasmonic metamaterial cavities to scale the strength of plasmon-exciton coupling.The demonstrated plasmon modes of metallic metamaterial cavities offer high confinement and tunability and can match with the excitons of TMDCs to exhibit a strong coupling regime by tuning either the size of the cavity gap or thickness.The calculated Rabi splitting of Au-MoSe_2 and Au-WSe_2 heterostructures strongly depends on the catenary-like field enhancement induced by the Au cavity,resulting in room-temperature Rabi splitting ranging between 77.86 and 320 me V.These plasmonic metamaterial cavities can pave the way for manipulating excitons in TMDCs and operating active nanophotonic devices at ambient temperature. 展开更多
关键词 catenary-shaped field enhancement strong coupling PLASMON EXCITON Rabi splitting
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Research on heat dissipation characteristics of magnetic fluid bearings under multiple field coupling effects
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作者 CHEN Liwen WU Weiying +2 位作者 GAO Dianrong ZHAO Jianhua CUI Bingyan 《High Technology Letters》 EI CAS 2024年第3期263-270,共8页
This paper analyzes the sources of heat losses in magnetic fluid bearings,proposes various cou-pling relationships of physical fields,divides the coupled heat transfer surfaces while ensuring the continuity of heat fl... This paper analyzes the sources of heat losses in magnetic fluid bearings,proposes various cou-pling relationships of physical fields,divides the coupled heat transfer surfaces while ensuring the continuity of heat flux density,and analyzes the overall heat dissipation pathways of the bearings.By changing parameters such as input current,rotor speed,and inlet oil flow rate,the study applies a multi-physics field coupling method to investigate the influence of different parameters on the temper-ature field and heat dissipation patterns of the bearings,which is then validated through experi-ments.This research provides a theoretical basis for the optimal design of magnetic fluid bearing sys-tems. 展开更多
关键词 magnetic fluid bearing multi-physics field coupling multiple parameter varia-tion heat dissipation pattern
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Icariin accelerates bone regeneration by inducing osteogenesisangiogenesis coupling in rats with type 1 diabetes mellitus 被引量:2
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作者 Sheng Zheng Guan-Yu Hu +2 位作者 Jun-Hua Li Jia Zheng Yi-Kai Li 《World Journal of Diabetes》 SCIE 2024年第4期769-782,共14页
BACKGROUND Icariin(ICA),a natural flavonoid compound monomer,has multiple pharmacological activities.However,its effect on bone defect in the context of type 1 diabetes mellitus(T1DM)has not yet been examined.AIM To e... BACKGROUND Icariin(ICA),a natural flavonoid compound monomer,has multiple pharmacological activities.However,its effect on bone defect in the context of type 1 diabetes mellitus(T1DM)has not yet been examined.AIM To explore the role and potential mechanism of ICA on bone defect in the context of T1DM.METHODS The effects of ICA on osteogenesis and angiogenesis were evaluated by alkaline phosphatase staining,alizarin red S staining,quantitative real-time polymerase chain reaction,Western blot,and immunofluorescence.Angiogenesis-related assays were conducted to investigate the relationship between osteogenesis and angiogenesis.A bone defect model was established in T1DM rats.The model rats were then treated with ICA or placebo and micron-scale computed tomography,histomorphometry,histology,and sequential fluorescent labeling were used to evaluate the effect of ICA on bone formation in the defect area.RESULTS ICA promoted bone marrow mesenchymal stem cell(BMSC)proliferation and osteogenic differentiation.The ICA treated-BMSCs showed higher expression levels of osteogenesis-related markers(alkaline phosphatase and osteocalcin)and angiogenesis-related markers(vascular endothelial growth factor A and platelet endothelial cell adhesion molecule 1)compared to the untreated group.ICA was also found to induce osteogenesis-angiogenesis coupling of BMSCs.In the bone defect model T1DM rats,ICA facilitated bone formation and CD31hiEMCNhi type H-positive capillary formation.Lastly,ICA effectively accelerated the rate of bone formation in the defect area.CONCLUSION ICA was able to accelerate bone regeneration in a T1DM rat model by inducing osteogenesis-angiogenesis coupling of BMSCs. 展开更多
关键词 ICARIIN Osteogenesis-angiogenesis coupling Type 1 diabetes mellitus Bone defect Bone regeneration
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Rheological properties and concentration evolution of thickened tailings under the coupling effect of compression and shear 被引量:1
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作者 Aixiang Wu Zhenqi Wang +3 位作者 Zhuen Ruan Raimund Bürger Shaoyong Wang Yi Mo 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第5期862-876,共15页
Cemented paste backfill(CPB)is a key technology for green mining in metal mines,in which tailings thickening comprises the primary link of CPB technology.However,difficult flocculation and substandard concentrations o... Cemented paste backfill(CPB)is a key technology for green mining in metal mines,in which tailings thickening comprises the primary link of CPB technology.However,difficult flocculation and substandard concentrations of thickened tailings often occur.The rheological properties and concentration evolution in the thickened tailings remain unclear.Moreover,traditional indoor thickening experiments have yet to quantitatively characterize their rheological properties.An experiment of flocculation condition optimization based on the Box-Behnken design(BBD)was performed in the study,and the two response values were investigated:concentration and the mean weighted chord length(MWCL)of flocs.Thus,optimal flocculation conditions were obtained.In addition,the rheological properties and concentration evolution of different flocculant dosages and ultrafine tailing contents under shear,compression,and compression-shear coupling experimental conditions were tested and compared.The results show that the shear yield stress under compression and compression-shear coupling increases with the growth of compressive yield stress,while the shear yield stress increases slightly under shear.The order of shear yield stress from low to high under different thickening conditions is shear,compression,and compression-shear coupling.Under compression and compression-shear coupling,the concentration first rapidly increases with the growth of compressive yield stress and then slowly increases,while concentration increases slightly under shear.The order of concentration from low to high under different thickening conditions is shear,compression,and compression-shear coupling.Finally,the evolution mechanism of the flocs and drainage channels during the thickening of the thickened tailings under different experimental conditions was revealed. 展开更多
关键词 thickened tailings compression-shear coupling compressive yield stress shear yield stress CONCENTRATION
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Algorithm Selection Method Based on Coupling Strength for Partitioned Analysis of Structure-Piezoelectric-Circuit Coupling
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作者 Daisuke Ishihara Naoto Takayama 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第2期1237-1258,共22页
In this study, we propose an algorithm selection method based on coupling strength for the partitioned analysis ofstructure-piezoelectric-circuit coupling, which includes two types of coupling or inverse and direct pi... In this study, we propose an algorithm selection method based on coupling strength for the partitioned analysis ofstructure-piezoelectric-circuit coupling, which includes two types of coupling or inverse and direct piezoelectriccoupling and direct piezoelectric and circuit coupling. In the proposed method, implicit and explicit formulationsare used for strong and weak coupling, respectively. Three feasible partitioned algorithms are generated, namely(1) a strongly coupled algorithm that uses a fully implicit formulation for both types of coupling, (2) a weaklycoupled algorithm that uses a fully explicit formulation for both types of coupling, and (3) a partially stronglycoupled and partially weakly coupled algorithm that uses an implicit formulation and an explicit formulation forthe two types of coupling, respectively.Numerical examples using a piezoelectric energy harvester,which is a typicalstructure-piezoelectric-circuit coupling problem, demonstrate that the proposed method selects the most costeffectivealgorithm. 展开更多
关键词 MULTIPHYSICS coupling strength partitioned algorithm structure-piezoelectric-circuit coupling strongly coupled algorithm weakly coupled algorithm
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A review on electrocatalytic CO_(2) conversion via C-C and C-N coupling
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作者 Zhuangzhi Zhang Sijun Li +6 位作者 Zheng Zhang Zhou Chen Hua Wang Xianguang Meng Wenquan Cui Xiwei Qi Jiacheng Wang 《Carbon Energy》 SCIE EI CAS CSCD 2024年第2期167-194,共28页
Electrochemical C-C and C-N coupling reactions with the conversion of abundant and inexpensive small molecules,such as CO_(2) and nitrogencontaining species,are considered a promising route for increasing the value of... Electrochemical C-C and C-N coupling reactions with the conversion of abundant and inexpensive small molecules,such as CO_(2) and nitrogencontaining species,are considered a promising route for increasing the value of CO_(2) reduction products.The development of high-performance catalysts is the key to the both electrocatalytic reactions.In this review,we present a systematic summary of the reaction systems for electrocatalytic CO_(2) reduction,along with the coupling mechanisms of C-C and C-N bonds over outstanding electrocatalytic materials recently developed.The key intermediate species and reaction pathways related to the coupling as well as the catalyst-structure relationship will be also discussed,aiming to provide insights and guidance for designing efficient CO_(2) reduction systems. 展开更多
关键词 C-C coupling C-N coupling CO_(2) conversion ELECTROCATALYSIS urea synthesis
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Strong light-matter coupling in van der Waals materials
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作者 Yuan Luo Jiaxin Zhao +10 位作者 Antonio Fieramosca Quanbing Guo Haifeng Kang Xiaoze Liu Timothy C.H.Liew Daniele Sanvitto Zhiyuan An Sanjib Ghosh Ziyu Wang Hongxing Xu Qihua Xiong 《Light(Science & Applications)》 SCIE EI CSCD 2024年第10期2009-2026,共18页
In recent years,two-dimensional(2D)van der Waals materials have emerged as a focal point in materials research,drawing increasing attention due to their potential for isolating and synergistically combining diverse at... In recent years,two-dimensional(2D)van der Waals materials have emerged as a focal point in materials research,drawing increasing attention due to their potential for isolating and synergistically combining diverse atomic layers.Atomically thin transition metal dichalcogenides(TMDs)are one of the most alluring van der Waals materials owing to their exceptional electronic and optical properties.The tightly bound excitons with giant oscillator strength render TMDs an ideal platform to investigate strong light-matter coupling when they are integrated with optical cavities,providing a wide range of possibilities for exploring novel polaritonic physics and devices.In this review,we focused on recent advances in TMD-based strong light-matter coupling.In the foremost position,we discuss the various optical structures strongly coupled to TMD materials,such as Fabry-Perot cavities,photonic crystals,and plasmonic nanocavities.We then present several intriguing properties and relevant device applications of TMD polaritons.In the end,we delineate promising future directions for the study of strong light-matter coupling in van der Waals materials. 展开更多
关键词 coupling LIGHT RENDER
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Analysis of Strong Coupling Constant with Machine Learning and Its Application
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作者 王晓云 董晨 刘翔 《Chinese Physics Letters》 SCIE EI CAS CSCD 2024年第3期15-22,共8页
We investigate the nature of the strong coupling constant and related physics.Through the analysis of accumulated experimental data around the world,we employ the ability of machine learning to unravel its physical la... We investigate the nature of the strong coupling constant and related physics.Through the analysis of accumulated experimental data around the world,we employ the ability of machine learning to unravel its physical laws.The result of our efforts is a formula that captures the expansive panorama of the distribution of the strong coupling constant across the entire energy range. 展开更多
关键词 STRONG coupling accumulated
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Seismic performance evaluation of hybrid coupled shear wall system with shear and flexural fuse-type steel coupling beams
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作者 Zahra Ramezandoust Abbas Tajaddini Panam Zarfam 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2024年第3期691-712,共22页
Replaceable flexural and shear fuse-type coupling beams are used in hybrid coupled shear wall(HCSW)systems,enabling concrete buildings to be promptly recovered after severe earthquakes.This study aimed to analytically... Replaceable flexural and shear fuse-type coupling beams are used in hybrid coupled shear wall(HCSW)systems,enabling concrete buildings to be promptly recovered after severe earthquakes.This study aimed to analytically evaluate the seismic behavior of flexural and shear fuse beams situated in short-,medium-and high-rise RC buildings that have HCSWs.Three building groups hypothetically located in a high seismic hazard zone were studied.A series of 2D nonlinear time history analyses was accomplished in OpenSees,using the ground motion records scaled at the design basis earthquake level.It was found that the effectiveness of fuses in HCSWs depends on various factors such as size and scale of the building,allowable rotation value,inter-story drift ratio,residual drift quantity,energy dissipation value of the fuses,etc.The results show that shear fuses better meet the requirements of rotations and drifts.In contrast,flexural fuses dissipate more energy,but their sectional stiffness should increase to meet other requirements.It was concluded that adoption of proper fuses depends on the overall scale of the building and on how associated factors are considered. 展开更多
关键词 hybrid coupled shear wall steel fuse coupling beam shear and flexural fuse nonlinear dynamic analysis seismic performance
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Chimera states of phase oscillator populations with nonlocal higher-order couplings
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作者 伍勇刚 余华健 +1 位作者 郑志刚 徐灿 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第4期402-407,共6页
The chimera states underlying many realistic dynamical processes have attracted ample attention in the area of dynamical systems.Here, we generalize the Kuramoto model with nonlocal coupling incorporating higher-order... The chimera states underlying many realistic dynamical processes have attracted ample attention in the area of dynamical systems.Here, we generalize the Kuramoto model with nonlocal coupling incorporating higher-order interactions encoded with simplicial complexes.Previous works have shown that higher-order interactions promote coherent states.However, we uncover the fact that the introduced higher-order couplings can significantly enhance the emergence of the incoherent state.Remarkably, we identify that the chimera states arise as a result of multi-attractors in dynamic states.Importantly, we review that the increasing higher-order interactions can significantly shape the emergent probability of chimera states.All the observed results can be well described in terms of the dimension reduction method.This study is a step forward in highlighting the importance of nonlocal higher-order couplings, which might provide control strategies for the occurrence of spatial-temporal patterns in networked systems. 展开更多
关键词 synchronization complex system coupled oscillators phase transition
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Highly selective electrosynthesis of imines via electroreduction coupling of nitroarenes with aryl aldehydes on Co_(9)S_(8)with positively charged sulfur vacancies
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作者 Dianke Xie Tianyi Yang +3 位作者 Chongyang Ma Chung-Li Dong Shuangyin Wang Yuqin Zou 《Chinese Journal of Catalysis》 SCIE CAS CSCD 2024年第10期206-216,共11页
The electrocatalytic synthesis of imines through the reductive imination of nitroarenes with aldehydes is a facile,environmentally friendly,and valuable process.In this study,high selectivity electrosynthesis of imine... The electrocatalytic synthesis of imines through the reductive imination of nitroarenes with aldehydes is a facile,environmentally friendly,and valuable process.In this study,high selectivity electrosynthesis of imines was realized through the electrocatalytic C-N coupling reaction between nitroarenes and aryl aldehydes on Co_(9)S_(8)nanoflowers with rich sulfur vacancies(Co_(9)S_(8)-Vs).Comparative experiments revealed that positively charged sulfur vacancies play a pivotal role in boosting catalytic selectivity towards imines.Electron-deficient sulfur vacancies intensified the adsorption of negatively charged Ph-NO_(2),thereby enhancing the conversion rate of the electrochemical nitrobenzene-reduction reaction(eNB-RR).Simultaneously,sulfur vacancies augmented the adsorption capability of negatively charged Ph-CHO,enriching Ph-CHO species at the electrode interface and expediting the Schiff base condensation reaction rate.The experimental results show that the reaction conditions can satisfy the different nitroarenes and aryl aldehydes in the electrocatalytic aqueous-phase system under mild conditions to obtain the corresponding imine products in high selectivity.This study provides a facile and environmentally friendly pathway for future electrocatalytic synthesis of imine. 展开更多
关键词 Co-based electrocatalyst Sulfur-vacancies Electrocatalysis Electroreduction coupling
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The impact of toroidal mode coupling on high-density discharges in J-TEXT
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作者 Peng DENG Wenzhe MAO +13 位作者 Zhipeng CHEN Yinan ZHOU Peng SHI Zhoujun YANG Li GAO Tao LAN Jinlin XIE Hong LI Zian WEI Adi LIU Chu ZHOU Weixing DING Wandong LIU Ge ZHUANG 《Plasma Science and Technology》 SCIE EI CAS CSCD 2024年第12期1-8,共8页
Density limit has long been a widely studied issue influencing the operating range of tokamaks.The rapid growth of the m/n=2/1(where m and n are poloidal and toroidal mode numbers,respectively)tearing mode is generall... Density limit has long been a widely studied issue influencing the operating range of tokamaks.The rapid growth of the m/n=2/1(where m and n are poloidal and toroidal mode numbers,respectively)tearing mode is generally regarded as a primary precursor to the density limit disruption.In this experiment,the coupling of the m/n=1/1 mode and the m/n=2/1 mode in highdensity plasma was observed.During a sawtooth cycle,the frequencies of the two modes gradually converge until they become equal.After that,toroidal coupling occurs between the 1/1 and 2/1 modes,resulting in a mutually fixed phase relationship.With the occurrence of toroidal coupling,the 2/1 mode is stabilized.Prior to the disruption,the cessation of the 1/1 and 2/1 mode coupling,along with the rapid growth in the amplitude of the 2/1 mode,can be observed.Additionally,under the same parameters,comparing discharges with or without the 1/1 mode,it is found that the presence of the 1/1 mode leads to higher plasma density and temperature parameters. 展开更多
关键词 toroidal coupling tearing mode density limit SAWTOOTH
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Bessel vortices in spin-1 Bose-Einstein condensates with Zeeman splitting and spin-orbit coupling
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作者 Huan-Bo Luo Xin-Feng Zhang +2 位作者 Runhua Li Yongyao Li Bin Liu 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第10期159-165,共7页
We investigate the ground states of spin-orbit coupled spin-1 Bose-Einstein condensates in the presence of Zeeman splitting.By introducing the generalized momentum operator,the linear version of the system is solved e... We investigate the ground states of spin-orbit coupled spin-1 Bose-Einstein condensates in the presence of Zeeman splitting.By introducing the generalized momentum operator,the linear version of the system is solved exactly,yielding a set of Bessel vortices.Additionally,based on linear solution and using variational approximation,the solutions for the full nonlinear system and their ground state phase diagrams are derived,including the vortex states with quantum numbers m=0,1,as well as mixed states.In this work,mixed states in spin-1 spin-orbit coupling(SOC)BEC are interpreted for the first time as weighted superpositions of three vortex states.Furthermore,the results also indicate that under strong Zeeman splitting,the system cannot form localized states.The variational solutions align well with numerical simulations,showing stable evolution and meeting the criteria for long-term observation in experiments. 展开更多
关键词 spin-orbit coupling Bessel vortices variational method
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Effects of asymmetric coupling and boundary on the dynamic behaviors of a random nearest neighbor coupled system
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作者 徐玲 姜磊 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第6期309-322,共14页
This study investigates the dynamical behaviors of nearest neighbor asymmetric coupled systems in a confined space.First, the study derivative analytical stability and synchronization conditions for the asymmetrically... This study investigates the dynamical behaviors of nearest neighbor asymmetric coupled systems in a confined space.First, the study derivative analytical stability and synchronization conditions for the asymmetrically coupled system in an unconfined space, which are then validated through numerical simulations. Simulation results show that asymmetric coupling has a significant impact on synchronization conditions. Moreover, it is observed that irrespective of whether the system is confined, an increase in coupling asymmetry leads to a hastened synchronization pace. Additionally, the study examines the effects of boundaries on the system's collective behaviors via numerical experiments. The presence of boundaries ensures the system's stability and synchronization, and reducing these boundaries can expedite the synchronization process and amplify its effects. Finally, the study reveals that the system's output amplitude exhibits stochastic resonance as the confined boundary size increases. 展开更多
关键词 asymmetric coupled confined space SYNCHRONIZATION stochastic resonance stability
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