The mode splitting induced by electro-optic birefringence in a P-I-N InGaAs/GaAs/A1GaAs vertical-cavity surface- emitting laser (VCSEL) has been studied by polarized electroluminescence (EL) at room temperature. T...The mode splitting induced by electro-optic birefringence in a P-I-N InGaAs/GaAs/A1GaAs vertical-cavity surface- emitting laser (VCSEL) has been studied by polarized electroluminescence (EL) at room temperature. The polarized EL spectra with E||[110] and E || [150] directions, are extracted for different injected currents. The mode splitting of the two orthogonal polarized modes for a VCSEL device is determined, and its value increases linearly with the increasing injected current due to electro-optic birefringence; This article demonstrates that the polarized EL is a powerful tool to study the mode splitting and polarization anisotropy of a VCSEL device.展开更多
In this paper, the generalized nonlinear Schrodinger equation (GNLSE) is solved by an adaptive split-step Fourier method (ASSFM). It is found that ASSFM must be used to solve GNLSE to ensure precision when the sol...In this paper, the generalized nonlinear Schrodinger equation (GNLSE) is solved by an adaptive split-step Fourier method (ASSFM). It is found that ASSFM must be used to solve GNLSE to ensure precision when the soliton selffrequency shift is remarkable and the photonic crystal fibre (PCF) parameters vary with the frequency considerably. The precision of numerical simulation by using ASSFM is higher than that by using split-step Fourier method in the process of laser pulse propagation in PCFs due to the fact that the variation of fibre parameters with the peak frequency in the pulse spectrum can be taken into account fully.展开更多
The Zeeman splitting effect is observed in a strong magnetic field generated by a laser-driven coil.The expanding plasma from the coil wire surface is concentrated at the coil center and interacts with the simultaneou...The Zeeman splitting effect is observed in a strong magnetic field generated by a laser-driven coil.The expanding plasma from the coil wire surface is concentrated at the coil center and interacts with the simultaneously generated magnetic field.The Cu I spectral lines at wavelengths of 510.5541,515.3235,and 521.8202 nm are detected and analyzed.The splittings of spectral lines are used to estimate the magnetic field strength at the coil center as∼31.4±15.7 T at a laser intensity of∼5.6310^(15) W/cm^(2),which agrees well with measurements using a B-dot probe.Some other plasma parameters of the central plasma disk are also studied.The temperature is evaluated from the Cu I spectral line intensity ratio,while the electron density is estimated from the Stark broadening effect.展开更多
Here,furfural oxidation was performed to replace the kinetically sluggish O_(2)evolution reaction(OER).Pt-Co_(3)O_(4)nanospheres were developed via pulsed laser ablation in liquid(PLAL)in a single step for the paired ...Here,furfural oxidation was performed to replace the kinetically sluggish O_(2)evolution reaction(OER).Pt-Co_(3)O_(4)nanospheres were developed via pulsed laser ablation in liquid(PLAL)in a single step for the paired electrocatalysis of an H_(2)evolution reaction(HER)and furfural oxidation reaction(FOR).The FOR afforded a high furfural conversion(44.2%)with a major product of 2-furoic acid after a 2-h electrolysis at 1.55 V versus reversible hydrogen electrode in a 1.0-M KOH/50-mM furfural electrolyte.The Pt-Co_(3)O_(4)electrode exhibited a small overpotential of 290 mV at 10 mA cm^(-2).As an anode and cathode in an electrolyzer system,the Pt-Co_(3)O_(4)electrocatalyst required only a small applied cell voltage of~1.83 V to deliver 10 mA cm^(-2),compared with that of the pure water electrolyzer(OER||HER,~1.99 V).This study simultaneously realized the integrated production of energy-saving H_(2)fuel at the cathode and 2-furoic acid at the anode.展开更多
A novel laser processing technique was developed for making channels in the nano regime in this paper.A Nd:YAG laser was used to dry fabricate micro channels(25μm~100μm di- ameter)in a 1 cm^3 fused silica substrate...A novel laser processing technique was developed for making channels in the nano regime in this paper.A Nd:YAG laser was used to dry fabricate micro channels(25μm~100μm di- ameter)in a 1 cm^3 fused silica substrate by thermal-induced processing.By controlling the locations of these initiating micro channels on a silica cube,1D-controllable self-connecting nano fractures can be formed as rectangular channels.These nano channels are smooth and with extremely high aspect ratio(~10~4 depth to width ratio).A possible mechanism is proposed to explain the formation of the nano channels.This laser-based nano channel fabrication technique is fast and inexpensive,and with potential applications in capillary electrophoresis and electro-osmosis driven nano-filtration.展开更多
Carbon nitride,an emerging polymeric semiconductor,has attracted attention in research ranging from photocatalysis to photodetection due to its favorable visible light response and high physicochemical stability.For i...Carbon nitride,an emerging polymeric semiconductor,has attracted attention in research ranging from photocatalysis to photodetection due to its favorable visible light response and high physicochemical stability.For its practical device application,the fabrication of high-quality carbon nitride films on substrates is essential.However,conventional methodologies to achieve high polymerization of carbon nitride are often accompanied by its decomposition,significantly compromising the film quality.Herein,we report an ultrafast fabrication of carbon nitride film by laser direct writing(LDW).The instantaneous high temperature and pressure during LDW can efficiently boost the polymerization of carbon nitride and suppress its decomposition,resulting in high-quality carbon nitride film with excellent mechanical stability with the substrate.Due to the efficient photon-to-electron conversion,it exhibits an outstanding photoelectrochemical water splitting and optoelectronic detection capability,even under strong acid/alkaline conditions.This study thus offers a facile and efficient LDW strategy for the rapid fabrication of carbon nitride film photoelectrodes,demonstrating its great feasibility in multifunctional photoelectrical applications,including but not limited to photoelectrochemical water splitting and optoelectronic detection.展开更多
In this study,a laser-assisted pulsed plasma thruster(LA-PPT)with a novel configuration is proposed as an electric propulsion thruster which separates laser ablation and electromagnetic acceleration.Owing to the uniqu...In this study,a laser-assisted pulsed plasma thruster(LA-PPT)with a novel configuration is proposed as an electric propulsion thruster which separates laser ablation and electromagnetic acceleration.Owing to the unique structure of the thruster,metals can also be used as propellants,and a higher specific impulse is expected.The ablation quality,morphology,and plume distribution of various metals(aluminium alloy,red copper,and carbon steel)with different laser energies were studied experimentally.The ablation morphology and plume distribution of red copper were more uniform,as compared to those of other metals,and the ablation quality was higher,indicating its greater suitability for LA-PPT.The plume generated by nanosecond laser ablation of aluminium alloy expanded faster,which indicated that the response time of the thruster with aluminium alloy as the propellant was shorter.In addition,when the background pressure was 0.005 Pa,an obvious plume splitting phenomenon was observed in the ablation plume of the pulsed laser irradiating aluminium alloy,which may significantly reduce the utilisation rate of the propellant.展开更多
Near-infrared (NIR) spectrometer based on semiconductor lasers can combine light source and splitter into one, which is an important direction for development of miniature instruments. In order to avoid random interfe...Near-infrared (NIR) spectrometer based on semiconductor lasers can combine light source and splitter into one, which is an important direction for development of miniature instruments. In order to avoid random interference caused by inconsistency between light sources, the novel evaluation indicators for global stability of multi-channels spectral system were proposed based on the correlation between dynamic deviation spectra of any two channels. The NIR analysis of moisture for corn powder samples based on the partial least squares combined with Savitzky-Golay (SG) smoothing was taken as an example, and a spectral correction method for enhancing prediction performance of multi-channels spectral system was further provided using above evaluation indicators. The experiment results showed that the global stability evaluation indicators significantly increased after SG smoothing correction. Meanwhile, the root-mean-square errors of prediction for corn moisture reduced from 0.373 to 0.283 (%), and the correlation coefficient between predicted and actual values was improved from 0.702 to 0.855. The above results indicated that by improving global stability indicators, the prediction ability of multi-channels spectral system can be improved. The proposed method provided a valuable reference for designing multi-channels diminutive spectrometer with high prediction performance, which had significance for large-scale application of NIR technology.展开更多
Micrometric-thin cells(MCs)with alkali vapor atoms have been valuable for research and applications of hyperfine Zeeman splitting and atomic magnetometers under strong magnetic fields.We theoretically and experimental...Micrometric-thin cells(MCs)with alkali vapor atoms have been valuable for research and applications of hyperfine Zeeman splitting and atomic magnetometers under strong magnetic fields.We theoretically and experimentally study the saturated absorption spectra using a 100-μm cesium MC,where the pump and probe beams are linearly polarized with mutually perpendicular polarizations,and the magnetic field is along the pump beam.Because of the distinctive thin chamber of the MC,crossover spectral lines in saturated absorption spectra are largely suppressed leading to clear splittings of hyperfine Zeeman transitions in experiments,and the effect of spatial magnetic field gradient is expected to be reduced.A calculation method is proposed to achieve good agreements between theoretical calculations and experimental results.This method successfully explains the suppression of crossover lines in MCs,as well as the effects of magnetic field direction,propagation and polarization directions of the pump/probe beam on saturated absorption spectrum.The saturated absorption spectrum with suppressed crossover lines is used for laser frequency stabilization,which may provide the potential value of MCs for high spatial resolution strong-field magnetometry with high sensitivity.展开更多
基金Project supported the National Key Basic Research and Development Program of China (Grant Nos.2012CB921304 and 2013CB632805)the National Natural Science Foundation of China (Grant Nos.60990313,61306120,and 6106003)the Foundation of Fuzhou University (Grant No.022498)
文摘The mode splitting induced by electro-optic birefringence in a P-I-N InGaAs/GaAs/A1GaAs vertical-cavity surface- emitting laser (VCSEL) has been studied by polarized electroluminescence (EL) at room temperature. The polarized EL spectra with E||[110] and E || [150] directions, are extracted for different injected currents. The mode splitting of the two orthogonal polarized modes for a VCSEL device is determined, and its value increases linearly with the increasing injected current due to electro-optic birefringence; This article demonstrates that the polarized EL is a powerful tool to study the mode splitting and polarization anisotropy of a VCSEL device.
文摘In this paper, the generalized nonlinear Schrodinger equation (GNLSE) is solved by an adaptive split-step Fourier method (ASSFM). It is found that ASSFM must be used to solve GNLSE to ensure precision when the soliton selffrequency shift is remarkable and the photonic crystal fibre (PCF) parameters vary with the frequency considerably. The precision of numerical simulation by using ASSFM is higher than that by using split-step Fourier method in the process of laser pulse propagation in PCFs due to the fact that the variation of fibre parameters with the peak frequency in the pulse spectrum can be taken into account fully.
基金This work was supported in part by the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant Nos.XDA25010100,XDA25010300,and XDA25030100)the National Natural Science Foundation of China(Grant Nos.U1930107 and 11827807)the Japanese Ministry of Education,Science,Sports,and Culture through Grants-in-Aid,KAKENHI(Grant No.21H04454).
文摘The Zeeman splitting effect is observed in a strong magnetic field generated by a laser-driven coil.The expanding plasma from the coil wire surface is concentrated at the coil center and interacts with the simultaneously generated magnetic field.The Cu I spectral lines at wavelengths of 510.5541,515.3235,and 521.8202 nm are detected and analyzed.The splittings of spectral lines are used to estimate the magnetic field strength at the coil center as∼31.4±15.7 T at a laser intensity of∼5.6310^(15) W/cm^(2),which agrees well with measurements using a B-dot probe.Some other plasma parameters of the central plasma disk are also studied.The temperature is evaluated from the Cu I spectral line intensity ratio,while the electron density is estimated from the Stark broadening effect.
基金supported by Korea Basic Science Institute(National research Facilities and Equipment Center)grant funded by the Ministry of Education(Nos.2019R1A6C1010042 and 2021R1A6C103A427)the financial support from National Research Foundation of Korea(NRF),(2022R1A2C2010686,2022R1A4A3033528,2019H1D3A1A01071209,and 2021R1I1A1A01060380)
文摘Here,furfural oxidation was performed to replace the kinetically sluggish O_(2)evolution reaction(OER).Pt-Co_(3)O_(4)nanospheres were developed via pulsed laser ablation in liquid(PLAL)in a single step for the paired electrocatalysis of an H_(2)evolution reaction(HER)and furfural oxidation reaction(FOR).The FOR afforded a high furfural conversion(44.2%)with a major product of 2-furoic acid after a 2-h electrolysis at 1.55 V versus reversible hydrogen electrode in a 1.0-M KOH/50-mM furfural electrolyte.The Pt-Co_(3)O_(4)electrode exhibited a small overpotential of 290 mV at 10 mA cm^(-2).As an anode and cathode in an electrolyzer system,the Pt-Co_(3)O_(4)electrocatalyst required only a small applied cell voltage of~1.83 V to deliver 10 mA cm^(-2),compared with that of the pure water electrolyzer(OER||HER,~1.99 V).This study simultaneously realized the integrated production of energy-saving H_(2)fuel at the cathode and 2-furoic acid at the anode.
基金The project supported by the National Natural Science Foundation of China (50375031)the Hong Kong Research Grants Council (CUHK 4416/99E)
文摘A novel laser processing technique was developed for making channels in the nano regime in this paper.A Nd:YAG laser was used to dry fabricate micro channels(25μm~100μm di- ameter)in a 1 cm^3 fused silica substrate by thermal-induced processing.By controlling the locations of these initiating micro channels on a silica cube,1D-controllable self-connecting nano fractures can be formed as rectangular channels.These nano channels are smooth and with extremely high aspect ratio(~10~4 depth to width ratio).A possible mechanism is proposed to explain the formation of the nano channels.This laser-based nano channel fabrication technique is fast and inexpensive,and with potential applications in capillary electrophoresis and electro-osmosis driven nano-filtration.
基金Australian Research Council,Grant/Award Number:DP200100365National Natural Science Foundation of China,Grant/Award Numbers:21905144,21905202,22002107,22179093+1 种基金Qinghai Provincial Department of Science and Technology,Grant/Award Number:2021-zj-702Tianjin University,Grant/Award Number:2021XZC-0052。
文摘Carbon nitride,an emerging polymeric semiconductor,has attracted attention in research ranging from photocatalysis to photodetection due to its favorable visible light response and high physicochemical stability.For its practical device application,the fabrication of high-quality carbon nitride films on substrates is essential.However,conventional methodologies to achieve high polymerization of carbon nitride are often accompanied by its decomposition,significantly compromising the film quality.Herein,we report an ultrafast fabrication of carbon nitride film by laser direct writing(LDW).The instantaneous high temperature and pressure during LDW can efficiently boost the polymerization of carbon nitride and suppress its decomposition,resulting in high-quality carbon nitride film with excellent mechanical stability with the substrate.Due to the efficient photon-to-electron conversion,it exhibits an outstanding photoelectrochemical water splitting and optoelectronic detection capability,even under strong acid/alkaline conditions.This study thus offers a facile and efficient LDW strategy for the rapid fabrication of carbon nitride film photoelectrodes,demonstrating its great feasibility in multifunctional photoelectrical applications,including but not limited to photoelectrochemical water splitting and optoelectronic detection.
基金supported by National Natural Science Foundation of China(No.11772354)。
文摘In this study,a laser-assisted pulsed plasma thruster(LA-PPT)with a novel configuration is proposed as an electric propulsion thruster which separates laser ablation and electromagnetic acceleration.Owing to the unique structure of the thruster,metals can also be used as propellants,and a higher specific impulse is expected.The ablation quality,morphology,and plume distribution of various metals(aluminium alloy,red copper,and carbon steel)with different laser energies were studied experimentally.The ablation morphology and plume distribution of red copper were more uniform,as compared to those of other metals,and the ablation quality was higher,indicating its greater suitability for LA-PPT.The plume generated by nanosecond laser ablation of aluminium alloy expanded faster,which indicated that the response time of the thruster with aluminium alloy as the propellant was shorter.In addition,when the background pressure was 0.005 Pa,an obvious plume splitting phenomenon was observed in the ablation plume of the pulsed laser irradiating aluminium alloy,which may significantly reduce the utilisation rate of the propellant.
文摘Near-infrared (NIR) spectrometer based on semiconductor lasers can combine light source and splitter into one, which is an important direction for development of miniature instruments. In order to avoid random interference caused by inconsistency between light sources, the novel evaluation indicators for global stability of multi-channels spectral system were proposed based on the correlation between dynamic deviation spectra of any two channels. The NIR analysis of moisture for corn powder samples based on the partial least squares combined with Savitzky-Golay (SG) smoothing was taken as an example, and a spectral correction method for enhancing prediction performance of multi-channels spectral system was further provided using above evaluation indicators. The experiment results showed that the global stability evaluation indicators significantly increased after SG smoothing correction. Meanwhile, the root-mean-square errors of prediction for corn moisture reduced from 0.373 to 0.283 (%), and the correlation coefficient between predicted and actual values was improved from 0.702 to 0.855. The above results indicated that by improving global stability indicators, the prediction ability of multi-channels spectral system can be improved. The proposed method provided a valuable reference for designing multi-channels diminutive spectrometer with high prediction performance, which had significance for large-scale application of NIR technology.
基金Supported by Foundamental of Research Funds for the Centre Universities (No.2021RC05)National Natural Science Foundation of China (No.61675046, No.61935005)。
基金Project supported by the National Natural Science Foundation of China(Grant Nos.61571018 and 61531003).
文摘Micrometric-thin cells(MCs)with alkali vapor atoms have been valuable for research and applications of hyperfine Zeeman splitting and atomic magnetometers under strong magnetic fields.We theoretically and experimentally study the saturated absorption spectra using a 100-μm cesium MC,where the pump and probe beams are linearly polarized with mutually perpendicular polarizations,and the magnetic field is along the pump beam.Because of the distinctive thin chamber of the MC,crossover spectral lines in saturated absorption spectra are largely suppressed leading to clear splittings of hyperfine Zeeman transitions in experiments,and the effect of spatial magnetic field gradient is expected to be reduced.A calculation method is proposed to achieve good agreements between theoretical calculations and experimental results.This method successfully explains the suppression of crossover lines in MCs,as well as the effects of magnetic field direction,propagation and polarization directions of the pump/probe beam on saturated absorption spectrum.The saturated absorption spectrum with suppressed crossover lines is used for laser frequency stabilization,which may provide the potential value of MCs for high spatial resolution strong-field magnetometry with high sensitivity.