Biomimic Vein-Like Transparent Conducting Electrodes with Low Sheet Resistance and Metal Consumption

In this contribution,inspired by the excellent resource management and material transport function of leaf veins,the electrical transport function of metallized leaf veins is mimicked from the material transport function of the vein networks.By electroless copper plating on real leaf vein networks with copper thickness of only several hundred nanometre up to several micrometre,certain leaf veins can be converted to transparent conductive electrodes with an ultralow sheet resistance 100 times lower than that of state-of-the-art indium tin oxide thin films,combined with a broadband optical transmission of above 80%in the UV–VIS–IR range.Additionally,the resource efficiency of the vein-like electrode is characterized by the small amount of material needed to build up the networks and the low copper consumption during metallization.In particular,the high current density transport capability of the electrode of>6000 A cm^−2 was demonstrated.These superior properties of the vein-like structures inspire the design of high-performance transparent conductive electrodes without using critical materials and may significantly reduce the Ag consumption down to<10%of the current level for mass production of solar cells and will contribute greatly to the electrode for high power density concentrator solar cells,high power density Li-ion batteries,and supercapacitors.

Differential transformation method for studying flow and heat transfer due to stretching sheet embedded in porous medium with variable thickness, variable thermal conductivity,and thermal radiation

This article presents a numerical solution for the flow of a Newtonian fluid over an impermeable stretching sheet embedded in a porous medium with the power law surface velocity and variable thickness in the presence of thermal radiation. The flow is caused by non-linear stretching of a sheet. Thermal conductivity of the fluid is assumed to vary linearly with temperature. The governing partial differential equations （PDEs） are transformed into a system of coupled non-linear ordinary differential equations （ODEs） with appropriate boundary conditions for various physical parameters. The remaining system of ODEs is solved numerically using a differential transformation method （DTM）. The effects of the porous parameter, the wall thickness parameter, the radiation parameter, the thermal conductivity parameter, and the Prandtl number on the flow and temperature profiles are presented. Moreover, the local skin-friction and the Nusselt numbers are presented. Comparison of the obtained numerical results is made with previously published results in some special cases, with good agreement. The results obtained in this paper confirm the idea that DTM is a powerful mathematical tool and can be applied to a large class of linear and non-linear problems in different fields of science and engineering.

Carreau fluid flow due to nonlinearly stretching sheet with thermal radiation, heat flux, and variable conductivity

A sophisticated theoretical and mathematical model is proposed.It is verified that this model can estimate and monitor the detailed behavior for the steady Carreau fluid flow past a nonlinear stretching surface and the predicted phenomena due to the presence of heat flux,thermal radiation,and viscous dissipation.Despite the fact that some properties of the fluid do not depend on the temperature,the fluid thermal conductivity is assumed to depend on the temperature.Based on accelerating the fluid elements,some of the kinetic energy for the fluid can be turned to the internal heating energy in the form of viscous dissipation phenomena.The contribution in this study is that a similar solution is obtained,in spite of the high nonlinearity of the Carreau model,especially,with the heat flux,variable conductivity,and viscous dissipation phenomena.Some of the major significant findings of this study can be observed from the reduction in the fluid velocity with enhancing the Weissenberg number.Likewise,the increase in the sheet temperature is noted with increasing the Eckert number while the reverse behavior is observed for increasing both the radiation parameter and the conductivity parameter.Finally,the accuracy and trust in the proposed numerical method are validated after benchmarking for our data onto the earlier results.

Numerical Study for Simulation the MHD Flow and Heat-Transfer Due to a Stretching Sheet on Variable Thickness and Thermal Conductivity with Thermal Radiation

The main aim of this article is to introduce the approximate solution for MHD flow of an electrically conducting Newtonian fluid over an impermeable stretching sheet with a power law surface velocity and variable thickness in the presence of thermal-radiation and internal heat generation/absorption. The flow is caused by the non-linear stretching of a sheet. Thermal conductivity of the fluid is assumed to vary linearly with temperature. The obtaining PDEs are transformed into non-linear system of ODEs using suitable boundary conditions for various physical parameters. We use the Chebyshev spectral method to solve numerically the resulting system of ODEs. We present the effects of more parameters in the proposed model, such as the magnetic parameter, the wall thickness parameter, the radiation parameter, the thermal conductivity parameter and the Prandtl number on the flow and temperature profiles are presented, moreover, the local skin-friction and Nusselt numbers. A comparison of obtained numerical results is made with previously published results in some special cases, and excellent agreement is noted. The obtained numerical results confirm that the introduced technique is powerful mathematical tool and it can be implemented to a wide class of non-linear systems appearing in more branches in science and engineering.

Preparation and Characterization of Reduced Graphene-P3HT Composite Thin Films for Use as Transparent Conducting Electrodes

With the aim of producing simple and effective transparent conducting electrodes, the conducting polymer poly(3-hexylthiophene) (P3HT) incorporated with reduced graphene oxide film (rGO) (called rGO-P3HT) was prepared by spin-coating method. Structural, electrical and optical characterization showed that rGO-P3HT films 9.0 wt% P3HT exhibited good stability when exposed to the ambient atmosphere. These composite films of 200 nm thickness possess a sheet resistance and transparency of R□~ 17Ω and T ~ 72%, respectively. Owing to containing conducting polymer, rGO-P3HT-coated glass could be efficiently used in photovoltaic applications, in organic solar cells in particular, with the replacement of the indium tin oxide (ITO) and fluorine tin oxide (FTO) electrodes.

Optical-Electronic Properties of Carbon-Nanotubes Based Transparent Conducting Films

Three coating methods (slot, dip and blade coatings) were used separately to coat a well-dispersed single-wall carbonnanotube (SWCNT) solution on polyethylene terephthalate (PET) film, and the resulting optical and electronic properties were measured and compared. It was found that the sheet resistance and the transparency of the SWCNT coated film decreased as the coating speed increased for dip and blade coatings, but were independent of the coating speed for slot coating. All three coating methods were able to produce transparent conductive film with transparency above 85% and sheet resistance close to 1000 ohm/sq. For industrial production, the slot die coating method appears to be more suitable in terms of high coating speed and uniformity of optical and electronic properties.

石墨烯基导热薄膜的研究进展

随着现代技术的发展,散热和导热已成为制约芯片器件小型化和大功率制造业发展的关键问题之一。由于传统的金属导热材料存在密度大和易氧化等问题,近年来以石墨烯基材料为代表的非金属碳基材料逐渐成为国内外的研究热点。本文综述了近年国内外石墨烯导热薄膜的制备方法及最新研究成果,分析讨论了热处理工艺、晶粒尺寸、薄膜密度及杂质原子和缺陷等对石墨烯导热薄膜性能的影响和物理机理,并对该领域的发展趋势进行了展望。

Flow of Burgers' fluid over an inclined stretching sheet with heat and mass transfer

Effects of heat and mass transfer in the flow of Burgers fluid over an inclined sheet are discussed. Problems formulation and relevant analysis are given in the presence of thermal radiation and non-uniform heat source/sink. Thermal conductivity is taken temperature dependent. The nonlinear partial differential equations are simplified using boundary layer approximations. The resultant nonlinear ordinary differential equations are solved for the series solutions. The convergence of series solutions is obtained by plotting theη-curves for the velocity, temperature and concentration fields. Results of this work describe the role of different physical parameters involved in the problem. The Deborah numbers corresponding to relaxation time(β1 and β2) and angle of inclination(α) decrease the fluid velocity and concentration field. Concentration field decays as Deborah numbers corresponding to retardation time(β3) and mixed convection parameter(G) increase. Large values of heat generation/absorption parameters A/B, and the temperature distribution across the boundary layer increase. Numerical values of local Nusselt number,-θ′(0), and local Sherwood number,-f′(0), are computed and analyzed. It is found that θ′(0) increases with an increase in β3.

Heat transfer characteristics of thin power-law liquid films over horizontal stretching sheet with internal heating and variable thermal coefficient

The effect of internal heating source on the film momentum and thermal transport characteristic of thin finite power-law liquids over an accelerating unsteady horizontal stretched interface is studied. Unlike most classical works in this field, a general surface temperature distribution of the liquid film and the generalized Fourier＇s law for varying thermal conductivity are taken into consideration. Appropriate similarity transformations are used to convert the strongly nonlinear governing partial differential equations （PDEs） into a boundary value problem with a group of two-point ordinary differential equations （ODEs）. The correspondence between the liquid film thickness and the unsteadiness parameter is derived with the BVP4C program in MATLAB. Numerical solutions to the self-similarity ODEs are obtained using the shooting technique combined with a Runge-Kutta iteration program and Newton＇s scheme. The effects of the involved physical parameters on the fluid＇s horizontal velocity and temperature distribution are presented and discussed.

The development of advanced Cr-free organic composite coated electrogalvanized steel sheet with excellent grounding property

In recent years,the concern about environmental protection is increasing on a world scale.Major manufacturers of home appliances and OA equipment have introduced so-called 'green procurement schemes' for reducing environmentally harmful substances in manufacturing process and end products. Under such background,a new type of chromate-free organic composite coated electro-galvanized steel sheet with high conductivity was developed by Baosteel,which meets the EU RoHS Directive(Restriction of the Hazardous Substances) and other related laws and regulations on environmental safety.It also provides excellent surface electrical conductivity,corrosion resistance,fingerprint resistance,solvent resistance,coating adhesion, heat resistance,formability and other special properties to meet the demand of manufacture's process of OA machine. Compared with previously developed anti-fingerprinting coated electro-galvanized steel sheet,this newly developed product has a good balance between high corrosion resistance(time to 5%white rust in salt spray test is 120 h for flat panel and 72 h for worked potion) and conductivity(surface electro-resistivity in accordance with LOREAST is less than 0.1 milliohm ) due to the special design of coating's structure.Besides,It also provides the properties of grounding and shielding against electromagnetic waves.The evaluation of surface performances of new product showed that it is comparable or even better than the similar products. Currently,the newly developed product has been commercialized. In this paper,the major properties are discussed,such as corrosion resistance,surface electrical conductivity, fingerprint resistance,solvent resistance,coating adhesion(ink/melamine alkyd paint),heat resistance and formability.Furthermore,the application is also briefly described.

Dopant-Tunable Ultrathin Transparent Conductive Oxides for Efficient Energy Conversion Devices

Ultrathin film-based transparent conductive oxides(TCOs)with a broad work function(WF)tunability are highly demanded for e cient energy conversion devices.However,reducing the film thickness below 50 nm is limited due to rapidly increasing resistance;furthermore,introducing dopants into TCOs such as indium tin oxide(ITO)to reduce the resistance decreases the transparency due to a trade-o between the two quantities.Herein,we demonstrate dopant-tunable ultrathin(≤50 nm)TCOs fabricated via electric field-driven metal implantation(m-TCOs;m=Ni,Ag,and Cu)without com-promising their innate electrical and optical properties.The m-TCOs exhibit a broad WF variation(0.97 eV),high transmittance in the UV to visible range(89–93%at 365 nm),and low sheet resistance(30–60Ωcm-2).Experimental and theoretical analyses show that interstitial metal atoms mainly a ect the change in the WF without substantial losses in optical transparency.The m-ITOs are employed as anode or cathode electrodes for organic light-emitting diodes(LEDs),inorganic UV LEDs,and organic photovoltaics for their universal use,leading to outstanding performances,even without hole injection layer for OLED through the WF-tailored Ni-ITO.These results verify the proposed m-TCOs enable e ective carrier transport and light extraction beyond the limits of traditional TCOs.

Induced magnetic field stagnation point flow of nanofluid past convectively heated stretching sheet with Buoyancy effects

This paper presents the buoyancy effects on the magneto-hydrodynamics stagnation point flow of an incompressible,viscous,and electrically conducting nanofluid over a vertically stretching sheet.The impacts of an induced magnetic field and viscous dissipation are taken into account.Both assisting and opposing flows are considered.The overseeing nonlinear partial differential equations with the associated boundary conditions are reduced to an arrangement of coupled nonlinear ordinary differential equations utilizing similarity transformations and are then illuminated analytically by using the optimal homotopy investigation strategy（OHAM）.Graphs are introduced and examined for different parameters of the velocity,temperature,and concentration profile.Additionally,numerical estimations of the skin friction,local Nusselt number,and local Sherwood number are explored using numerical values.

EXPERIMENT STUDIES OF THE RELATIONS BETWEEN TRANSPARENT CONDUCTIVE Al FILM THICKNESS AND TRANSMITTANCE,SQUARE RESISTANCE

The transmittance of the thin A1 film with sheet resistance less than 10Ω/□ is able to be over 50％ . In this paper the effects of A1 film thickness on its properties have been investigated.

半导体制冷片温控系统应用研究

随着半导体材料的技术发展,半导体制冷技术越来越成熟,并且广泛地运用于便携制冷设备。研究将半导体制冷片温控系统应用于冰的导热系数测量装置之中,具有所占空间体积小、控温效果好、环境适应强、噪声小、稳定性高等特点。该装置是通过负温度特性NTC电阻来读取冰的表面温度,使用单片机获取温度数值,增量式PID控制电压幅值,达到控制半导体制冷片表面温度的效果。借助单片机来读取热流计的热流密度,并计算出冰的导热系数。整个装置结构简单,对环境要求不高,控温速度迅速,控温效果良好,有着良好的稳定性。

微米级金属箔电导率无损测试

高导电性薄金属箔电导率难以准确测定一直是该研究领域的痛点问题。研究了金属箔厚度对超薄金属箔-空气界面电场反射、金属箔表面阻抗、涡流线圈阻抗的影响,进而提出了一种适用于厚度小于100μm金属箔的电导率无损测试新方法。新方法利用两片厚度不同的同种金属箔定义了“厚度系数”,从而规避了界面处电场反射对测试的影响。结果表明:新方法可应用到银、铜、铜铬锆箔等电导率处于80%~110%IACS范围内的箔类材料,测试偏差可控制在约3%以内,且可以通过厚度设计缩小误差至小于2%IACS,远小于叠层结构法误差(约20%)。该研究将有助于完善科学研究和工业领域所需要的高导电超薄金属箔测试标准。

Multi-dimensional Simulation of Phase Change by a 0D-2D Model Coupling via Stefan Condition

Considering phase changes associated with a high-temperature molten material cooled down from the outside,this work presents an improvement of the modelling and the numerical simulation of such processes for an application pertaining to the safety of light water nuclear reactors.Postulating a core meltdown accident,the behaviour of the core melt(aka corium)into a steel vessel is of tremendous importance when evaluating the vessel integrity.Evaluating correctly the heat fluxes requires the numerical simulation of the interaction between the liquid material and its solid counterpart which forms during the solidification process,but also may melt back.To simulate this configuration,encoun-tered in various industrial applications,one considers a bi-phase model constituted by a liquid phase in contact and interaction with its solid phase.The liquid phase may solidify in presence of low energetic source,while the solid phase may melt due to an intense heat flux from the high-temperature liquid.In the frame of the in-house legacy code,several simplifying assumptions(0D multi-layer discretization,instantaneous heat transfer via a quadratic temperature profile in solids)are made for the modelling of such phase changes.In the present work,these shortcomings are illustrated and further overcome by solving a 2D heat conduction model in the solid by a mixed Raviart-Thomas finite element method coupled to the liquid phase due to heat and mass exchanges through Stefan condition.The liquid phase is modeled with a 0D multi-layer approach.The 0D-liquid and 2D-solid mod-els are coupled by a Stefan like phase change interface model.Several sanity checks are performed to assess the validity of the approach on 1D and 2D academical configurations for which exact or reference solutions are available.Then more advanced situations(genu-ine multi-dimensional phase changes and an"industrial-like scenario")are simulated to verify the appropriate behavior of the obtained coupled simulation scheme.

A Comprehensive Review on Multi-Dimensional Heat Conduction of Multi-Layer and Composite Structures:Analytical Solutions

Heat conduction in multi-layer and composite materials is one of the fundamental heat transfer problems in many industrial applications.Due to different materials types,interface conditions,and various geometries of these laminates,the heat conduction mechanism is more complicated than that of one-layer isotropic media.Analytical solutions are the best ways to study and understand such problems in depth.In this study,different existing analytical solutions for heat conduction in multi-layer and composite materials are reviewed and classified in rectangular,cylindrical,spherical,and conical coordinates.Applied boundary conditions,internal heat source,and thermal contact resistance as the most critical parameters in the solution complexity investigated in the literature,are discussed and summarized in different tables.Various types of multi-layer structures such as isotropic,anisotropic,orthotropic,and reinforced laminates are included in this study.It is found that although more than half a century has passed since the beginning of the research on heat transfer in multi-layer composites,new researches that can help with a better understanding in this area are still being offered.The challenges and shortcomings in this area are also discussed to guide future researches.

Thermally conductive MWCNTs/Fe_(3)O_(4)/Ti_(3)C_(2)T_(x) MXene multi-layer films for broadband electromagnetic interference shielding

The Ti_(3)C_(2)T_(x)MXene is thought to be a promising candidate for next-generation electromagnetic interference(EMI) shielding materials.However,its broadband shielding capability and thermal conduction performance are insufficient to meet the growing demands.Herein,we reported a layer-by-layer composite film composed of Ti_(3)C_(2)T_(x)MXene,multi-walled carbon nanotubes(MWCNTs),and Fe_(3)O_(4)nanoparticles.Benefitting from the architecture and the synergistic effect of components,the obtained composite film exhibited high comprehensive performance.Specifically,the introduction of Fe_(3)O_(4)magnetic nanoparticles effectively reduced the impedance mismatch between the composite film and air and enhanced the magnetic loss of the composite film.The layered structure prolonged the transmission path of electromagnetic waves inside the composite film and constructed a rich conductive network,causing interfacial polarization and ohmic loss.The results indicated that the composite film(52 μm) delivered a high EMI shielding effectiveness of 49 dB in the frequency range from X-band to Ku-band.Furthermore,the MWCNTs layers in the composite films provided numerous heat transfer channels,reducing phonon scattering during heat transfer and resulting in a maximum thermal conductivity of 8.241 W/(m K).

提高种板始极片产品质量生产实践

在始极片生产过程中,始极片的质量直接影响到产品的质量。通过分析影响始极片质量的各种因素,从生产工艺、物料、环境等方面出发,采取了改变打磨方式,更换槽组导电排、钛母板的导电棒及精细生产过程管控等一系列措施稳定生产,以达到提高始极片质量的目的。