A practical system of metals-(2,4-pentanedionate) (M(acac)n (M= Fe, Zn, Co and V)) and P2O5 in the pres- ence of HNO3 catalyzes regioselective nitration of ar-himachalene 1 to mono-nitro-ar-himachalene 2 in mod- erate...A practical system of metals-(2,4-pentanedionate) (M(acac)n (M= Fe, Zn, Co and V)) and P2O5 in the pres- ence of HNO3 catalyzes regioselective nitration of ar-himachalene 1 to mono-nitro-ar-himachalene 2 in mod- erate to high yields. Under mild conditions, the selectivity of nitration of 1 to 2 is excellent compared to the classical method using the nitro-sulphuric mixture HNO3/H2SO4, both mono- and di-nitro-ar-himachalene 2 and 3 are obtained. The reaction offers a very good method for the preparation of nitro-aromatic compounds and provides a useful entry to new functionalized terpenic products.展开更多
A pot experiment was conducted in a plastic film house to evaluate the translocation and uptake of heavy metals(Pb,Cd,Cu,and Zn) into brown rice(Oryza sativa L.) and the heavy metals residues in soils which had previo...A pot experiment was conducted in a plastic film house to evaluate the translocation and uptake of heavy metals(Pb,Cd,Cu,and Zn) into brown rice(Oryza sativa L.) and the heavy metals residues in soils which had previously been irrigated with domestic wastewater for a long time(3 years).The range of Pb,Cd,Cu,and Zn was 5.10 ± 0.01,0.105 ± 0.017,5.76 ± 0.42,and 23.56 ± 1.40 mg kg-1,respectively in the domestic wastewater-irrigated soil,and 0.370 ± 0.006,0.011 ± 0.001,0.340 ± 0.04,and 2.05 ± 0.18 mg kg-1,respectively,in the domestic wastewater-irrigated brown rice.The results indicated that application of domestic wastewater to arable land slightly increased the levels of Pb,Cd,Cu,and Zn in soil and brown rice(P < 0.01).The concentrations of heavy metals in brown rice were lower than the recommended tolerable levels proposed by the Joint FAO/WHO Expert Committee on Food Additives.However,the continuous monitoring and pollution control of hazardous materials from domestic wastewater are needed in order to prevent excessive build-up of heavy metals in the food chain.展开更多
以氨基-1,2,4-三唑和2-偕二硝甲基-5-硝基四唑(HDNMNT)为原料,通过中和反应合成出两种新型含能离子盐——2-偕二硝甲基-5-硝基四唑3-氨基-1,2,4-三唑盐(3-ATDNMNT)和2-偕二硝甲基-5-硝基四唑4-氨基-1,2,4-三唑盐(4-ATDNMNT),收率分别为9...以氨基-1,2,4-三唑和2-偕二硝甲基-5-硝基四唑(HDNMNT)为原料,通过中和反应合成出两种新型含能离子盐——2-偕二硝甲基-5-硝基四唑3-氨基-1,2,4-三唑盐(3-ATDNMNT)和2-偕二硝甲基-5-硝基四唑4-氨基-1,2,4-三唑盐(4-ATDNMNT),收率分别为95.4%和96.7%;利用FT-IR、1 H NMR、13C NMR、15 N NMR及元素分析等方法对其结构进行表征;采用量子化学方法计算了3-ATDNMNT和4-ATDNMNT的爆轰性能;在标准状态下(膨胀比为70∶1),利用最小自由能原理,分别计算了两种离子盐在丁羟复合推进剂中的能量性能。结果表明,3-ATDNMNT的爆速和爆压分别为8.587km/s和33.58GPa,4-ATDNMNT的爆速和爆压分别为8.693km/s和34.31GPa。以3-ATDNMNT部分取代丁羟复合推进剂中的AP后,丁羟复合推进剂的理论比冲可达2 635.7N·s/kg。以4-ATDNMNT部分取代丁羟复合推进剂中的AP后,当HTPB、Al、AP及4-ATDNMNT各组分质量分数分别为10%、5%、15%及70%时,获得该丁羟复合推进剂的最高理论比冲为2 677.2N·s/kg。展开更多
文摘A practical system of metals-(2,4-pentanedionate) (M(acac)n (M= Fe, Zn, Co and V)) and P2O5 in the pres- ence of HNO3 catalyzes regioselective nitration of ar-himachalene 1 to mono-nitro-ar-himachalene 2 in mod- erate to high yields. Under mild conditions, the selectivity of nitration of 1 to 2 is excellent compared to the classical method using the nitro-sulphuric mixture HNO3/H2SO4, both mono- and di-nitro-ar-himachalene 2 and 3 are obtained. The reaction offers a very good method for the preparation of nitro-aromatic compounds and provides a useful entry to new functionalized terpenic products.
文摘A pot experiment was conducted in a plastic film house to evaluate the translocation and uptake of heavy metals(Pb,Cd,Cu,and Zn) into brown rice(Oryza sativa L.) and the heavy metals residues in soils which had previously been irrigated with domestic wastewater for a long time(3 years).The range of Pb,Cd,Cu,and Zn was 5.10 ± 0.01,0.105 ± 0.017,5.76 ± 0.42,and 23.56 ± 1.40 mg kg-1,respectively in the domestic wastewater-irrigated soil,and 0.370 ± 0.006,0.011 ± 0.001,0.340 ± 0.04,and 2.05 ± 0.18 mg kg-1,respectively,in the domestic wastewater-irrigated brown rice.The results indicated that application of domestic wastewater to arable land slightly increased the levels of Pb,Cd,Cu,and Zn in soil and brown rice(P < 0.01).The concentrations of heavy metals in brown rice were lower than the recommended tolerable levels proposed by the Joint FAO/WHO Expert Committee on Food Additives.However,the continuous monitoring and pollution control of hazardous materials from domestic wastewater are needed in order to prevent excessive build-up of heavy metals in the food chain.
文摘以氨基-1,2,4-三唑和2-偕二硝甲基-5-硝基四唑(HDNMNT)为原料,通过中和反应合成出两种新型含能离子盐——2-偕二硝甲基-5-硝基四唑3-氨基-1,2,4-三唑盐(3-ATDNMNT)和2-偕二硝甲基-5-硝基四唑4-氨基-1,2,4-三唑盐(4-ATDNMNT),收率分别为95.4%和96.7%;利用FT-IR、1 H NMR、13C NMR、15 N NMR及元素分析等方法对其结构进行表征;采用量子化学方法计算了3-ATDNMNT和4-ATDNMNT的爆轰性能;在标准状态下(膨胀比为70∶1),利用最小自由能原理,分别计算了两种离子盐在丁羟复合推进剂中的能量性能。结果表明,3-ATDNMNT的爆速和爆压分别为8.587km/s和33.58GPa,4-ATDNMNT的爆速和爆压分别为8.693km/s和34.31GPa。以3-ATDNMNT部分取代丁羟复合推进剂中的AP后,丁羟复合推进剂的理论比冲可达2 635.7N·s/kg。以4-ATDNMNT部分取代丁羟复合推进剂中的AP后,当HTPB、Al、AP及4-ATDNMNT各组分质量分数分别为10%、5%、15%及70%时,获得该丁羟复合推进剂的最高理论比冲为2 677.2N·s/kg。
