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Changes in soil microbial communities induced by warming and N deposition accelerate the CO 2 emissions of coarse woody debris
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作者 Hankun Wang Chunsheng Wu +5 位作者 Junping Liu Qi Chen Chao Li Chunjie Shu Yi Zhang Yuanqiu Liu 《Journal of Forestry Research》 SCIE CAS CSCD 2023年第4期1051-1063,共13页
Warming and nitrogen(N)deposition are two important drivers of global climate changes.Coarse woody debris(CWD)contains a large proportion of the carbon(C)in the total global C pool.The composition of soil microbial co... Warming and nitrogen(N)deposition are two important drivers of global climate changes.Coarse woody debris(CWD)contains a large proportion of the carbon(C)in the total global C pool.The composition of soil microbial communities and environmental changes(i.e.,N deposition and warming)are the key drivers of CWD decomposition,but the interactive impact between N deposition and warming on the composition of soil microbial communities and CWD decomposition is still unclear.In a laboratory experiment,we study and simulate respiration during decomposition of the CWD(C 98)of Cryptomeria japonica(CR)and Platycarya strobilacea(PL)in response to warming and N deposition over 98 days.Resuts show that either warming or N addition signifi cantly accelerated the C 98 of the two tree species by altering the soil microbial community(bacterial:fungi and G+:G–).The combined treatment(warming+N)resulted in a decomposition eff ect equal to the sum of the individual eff ects.In addition,the species composition of bacteria and fungi was obviously aff ected by warming.However,N deposition had a remarkable infl uence on G+:G–.Our results indicated that N deposition and warming will observably alter the composition and growth of the microbial community and thus work synergistically to accelerate CWD decomposition in forest ecosystems.We also present evidence that N deposition and warming infl uenced the composition and balance of soil microbial communities and biogeochemical cycling of forest ecosystems. 展开更多
关键词 WARMInG n deposition Coarse woody debris DECOMPOSITIOn Soil microbial community
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Allocation patterns of nonstructural carbohydrates in response to CO_(2)elevation and nitrogen deposition in Cunninghamia lanceolata saplings
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作者 Wenhui Zheng Renshan Li +7 位作者 Qingpeng Yang Weidong Zhang Ke Huang Xin Guan Longchi Chen Xin Yu Qingkui Wang Silong Wang 《Journal of Forestry Research》 SCIE CAS CSCD 2023年第1期87-98,共12页
Stored nonstructural carbohydrates(NSC)indicate a balance between photosynthetic carbon(C)assimilation and growth investment or loss through respiration and root exudation.They play an important role in plant function... Stored nonstructural carbohydrates(NSC)indicate a balance between photosynthetic carbon(C)assimilation and growth investment or loss through respiration and root exudation.They play an important role in plant function and whole-plant level C cycling.CO_(2)elevation and nitrogen(N)deposition,which are two major environmental issues worldwide,aff ect plant photosynthetic C assimilation and C release in forest ecosystems.However,information regarding the eff ect of CO_(2)elevation and N deposition on NSC storage in diff erent organs remains limited,especially regarding the trade-off between growth and NSC reserves.Therefore,here we analyzed the variations in the NSC storage in diff erent organs of Chinese fi r(Cunninghamia lanceolata)under CO_(2)elevation and N addition and found that NSC concentrations and contents in all organs of Chinese fi r saplings increased remarkably under CO_(2)elevation.However,N addition induced diff erential accumulation of NSC among various organs.Specifi cally,N addition decreased the NSC concentrations of needles,branches,stems,and fi ne roots,but increased the NSC contents of branches and coarse roots.The increase in the NSC contents of roots was more pronounced than that in the NSC content of aboveground organs under CO_(2)elevation.The role of N addition in the increase in the structural biomass of aboveground organs was greater than that in the increase in the structural biomass of roots.This result indicated that a diff erent tradeoff between growth and NSC storage occurred to alleviate resource limitations under CO_(2)elevation and N addition and highlights the importance of separating biomass into structural biomass and NSC reserves when investigating the eff ects of environmental change on biomass allocation. 展开更多
关键词 Biomass partition CO_(2)elevation n deposition nonstructural carbohydrates Structural biomass
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Response of soil fauna to simulated nitrogen deposition: A nursery experiment in subtropical China 被引量:10
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作者 XU Guo-liang MO Jiang-ming +3 位作者 FU Sheng-lei PER Gundersen ZHOU Guo-yi XUE Jing-Hua 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2007年第5期603-609,共7页
We studied the responses of soil fauna to a simulated nitrogen deposition in nursery experimental plots in Subtropical China. Dissolved NH4NO3 was applied to the soil by spraying twice per month for 16 months, startin... We studied the responses of soil fauna to a simulated nitrogen deposition in nursery experimental plots in Subtropical China. Dissolved NH4NO3 was applied to the soil by spraying twice per month for 16 months, starting January 2003 with treatments of 0, 5, 10, 15 and 30 gN/(m^2·a). Soil fauna was sampled after 6, 9, 13 and 16 months of treatment in three soil depths (0-5 cm, 5-10 cm, 10-15 cm). Soil available N increased in correspondence with the increasing N treatment, whereas soil pH decreased. Bacterial and fungal densities were elevated by the N treatment. Soil fauna increased in the lower nitrogen treatments but decreased in the higher N treatments, which might indicate that there was a threshold around 10 gN/(m^2·a) for the stimulating effects of N addition. The N effects were dependent on the soil depth and sampling time. The data also suggested that the effects of the different N treatments were related to the level of N saturation, especially the concentration of NO3^- in the soil. 展开更多
关键词 soil fauna n deposition RESPOnSE Subtropical China
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Effects of six years of simulated N deposition on gross soil N transformation rates in an old-growth temperate forest 被引量:3
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作者 Peng Tian Jinbo Zhang +2 位作者 Christoph Müller Zucong Cai Guangze Jin 《Journal of Forestry Research》 SCIE CAS CSCD 2018年第3期644-653,共10页
Elevated atmospheric nitrogen(N) deposition has been detected in many regions of China, but its effects on soil N transformation in temperate forest ecosystems are not well known. We therefore simulated N deposition w... Elevated atmospheric nitrogen(N) deposition has been detected in many regions of China, but its effects on soil N transformation in temperate forest ecosystems are not well known. We therefore simulated N deposition with four levels of N addition rate(N0, N30, N60, and N120) for6 years in an old-growth temperate forest in Xiaoxing’an Mountains in Northeastern China. We measured gross N transformation rates in the laboratory usingN tracing technology to explore the effects of N deposition on soil gross N transformations taking advantage of N deposition soils. No significant differences in gross soil N transformation rates were observed after 6 years of N deposition with various levels of N addition rate. For all N deposition soils, the gross NH~+ immobilization rates were consistently lower than the gross N mineralization rates,leading to net N mineralization. Nitrate(NO~-) was primarily produced via oxidation of NH~+(i.e., autotrophic nitrification), whereas oxidation of organic N(i.e., heterotrophic nitrification) was negligible. Differences between the quantity of ammonia-oxidizing bacteria and ammonia-oxidizing archaea were not significant for any treatment, which likely explains the lack of a significant effect on gross nitrification rates. Gross nitrification rates were much higher than the total NO~- consumption rates,resulting in a build-up of NO~-, which highlights the high risk of N losses via NO~- leaching or gaseous N emissions from soils. This response is opposite that of typical N-limited temperate forests suffering from N deposition,suggesting that the investigated old-growth temperate forest ecosystem is likely to approach N saturation. 展开更多
关键词 n deposition Gross soil n transformation Temperate forest ecosystem ^(15)n tracing technology
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Effect of Simulated N Deposition on Soil Exchangeable Cations in Three Forest Types of Subtropical China 被引量:21
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作者 LU Xian-Kai MO Jiang-Ming +4 位作者 P.GUNDERSERN ZHU Wei-Xing ZHOU Guo-Yi LI De-Jun ZHANGXu 《Pedosphere》 SCIE CAS CSCD 2009年第2期189-198,共10页
The effects of simulated nitrogen(N)deposition on soil exchangeable cations were studied in three forest types of subtropical China.Four N treatments with three replications were designed for the monsoon evergreen bro... The effects of simulated nitrogen(N)deposition on soil exchangeable cations were studied in three forest types of subtropical China.Four N treatments with three replications were designed for the monsoon evergreen broadleaf forest (mature forest):control(0 kg N ha-1 year-1),low N(50 kg N ha-1 year-1),medium N(100 kg N ha-1 year-1)and high N(150 kg N ha-1 year-1),and only three treatments(i.e.,control,low N,medium N)were established for the pine and mixed forests.Nitrogen had been applied continuously for 26 months before the measurement.The mature forest responded more rapidly and intensively to N additions than the pine and mixed forests,and exhibited some significant negative symptoms,e.g.,soil acidification,Al mobilization and leaching of base cations from soil.The pine and mixed forests responded slowly to N additions and exhibited no significant response of soil cations.Response of soil exchangeable cations to N deposition varied in the forests of subtropical China,depending on soil N status and land-use history. 展开更多
关键词 交换性阳离子 亚热带森林 土壤酸化 森林类型 氮沉降 模拟 可交换 季风常绿阔叶林
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Preliminary Response of Soil Fauna to Simulated N Deposition in Three Typical Subtropical Forests 被引量:22
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作者 XU Guo-Liang MO Jiang-Ming +1 位作者 ZHOU Guo-Yi FU Sheng-Lei 《Pedosphere》 SCIE CAS CSCD 2006年第5期596-601,共6页
A field-scale experiment arranged in a complete randomized block design with three N addition treatments including a control (no addition of N), a low N (5 g m-2 year-1), and a medium N (10 g m-2 year-1) was performed... A field-scale experiment arranged in a complete randomized block design with three N addition treatments including a control (no addition of N), a low N (5 g m-2 year-1), and a medium N (10 g m-2 year-1) was performed in each of the three typical forests, a pine (Pinus massoniana Lamb.) forest (PF), a pine-broadleaf mixed forest (MF) and a mature monsoon evergreen broadleaf forest (MEBF), of the Dinghushan Biosphere Reserve in subtropical China to study the response of soil fauna community to additions of N. Higher NH4+ and NO3- concentrations and a lower soil pH occurred in the medium N treatment of MEBF, whereas the NO3- concentration was the lowest in PF after the additions of N. The response of the density, group abundance and diversity index of soil fauna to addition of N varied with the forest type, and all these variables decreased with increasing N under MEBF but the trend was opposite under PF. The N treatments had no significant effects on these variables under MF. Compared with the control plots, the medium N treatment had significant negative effect on soil fauna under MEBF. The group abundance of soil fauna increased significantly with additions of higher N rates under PF. These results suggested that the response of soil fauna to N deposition varied with the forest type and N deposition rate, and soil N status is one of the important factors affecting the response of soil fauna to N deposition. 展开更多
关键词 生物圈 沉积作用 土壤 亚热带
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Response of Nitrogen Leaching to Nitrogen Deposition in Disturbed and Mature Forests of Southern China 被引量:5
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作者 FANG Yun-Ting M. YOH +2 位作者 MO Jiang-Ming P. GUNDERSEN ZHOU Guo-Yi 《Pedosphere》 SCIE CAS CSCD 2009年第1期111-120,共10页
Current nitrogen (N) leaching losses and their responses to monthly N additions were investigated under a disturbed pine (Pinus massoniana) forest and a mature monsoon broadleaf forest in southern China. N leaching lo... Current nitrogen (N) leaching losses and their responses to monthly N additions were investigated under a disturbed pine (Pinus massoniana) forest and a mature monsoon broadleaf forest in southern China. N leaching losses from both disturbed and mature forests were quite high (14.6 and 29.2 kg N ha-1 year-1, respectively), accounting for 57% and 80% of their corresponding atmospheric N inputs. N leaching losses were substantially increased following the first 1.5 years of N applications in both forests. The average increases induced by the addition of 50 and 100 kg N ha-1 year-1 were 36.5 and 24.9 kg N ha-1 year-1, respectively, in the mature forest, accounting for 73.0% and 24.9% of the annual amount of N added, and 14.2 and 16.8 kg N ha-1 year-1 in the disturbed forest, accounting for 28.4% and 16.8% of the added N. Great N leaching and a fast N leaching response to N additions in the mature forest might result from long-term N accumulation and high ambient N deposition load (greater than 30 kg N ha-1 year-1 over the past 15 years), whereas in the disturbed forest, it might result from the human disturbance and high ambient N deposition load. These results suggest that both disturbed and mature forests in the study region may be sensitive to increasing N deposition. 展开更多
关键词 大气氮沉积 氮增加 氮流失 氮饱和 亚热带森林
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Nitrogen Deposition and Its Spatial Pattern in Main Forest Ecosystems along North-South Transect of Eastern China 被引量:10
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作者 ZHAN Xiaoyun YU Guirui +9 位作者 HE Nianpeng FANG Huajun JIA Bingrui ZHOU Mei WANG Chuankuan ZHANG Junhui ZHAO Guangdong WANG Silong LIU Yunfen YAN Junhua 《Chinese Geographical Science》 SCIE CSCD 2014年第2期137-146,共10页
A continuous three-year observation(from May 2008 to April 2011)was conducted to characterize the spatial variation of dissolved inorganic nitrogen(DIN)deposition at eight main forest ecosystems along the north-south ... A continuous three-year observation(from May 2008 to April 2011)was conducted to characterize the spatial variation of dissolved inorganic nitrogen(DIN)deposition at eight main forest ecosystems along the north-south transect of eastern China(NSTEC).The results show that both throughfall DIN deposition and bulk DIN deposition increase from north to south along the NSTEC.Throughfall DIN deposition varies greatly from 2.7 kg N/(ha·yr)to 33.0 kg N/(ha·yr),with an average of 10.6 kg N/(ha·yr),and bulk DIN deposition ranges from 4.1 kg N/(ha·yr)to 25.4 kg N/(ha·yr),with an average of 9.8 kg N/(ha·yr).NH4+-N is the dominant form of DIN deposition at most sampling sites.Additionally,the spatial variation of DIN deposition is controlled mainly by precipitation.Moreover,in the northern part of the NSTEC,bulk DIN deposition is 17%higher than throughfall DIN deposition,whereas the trend is opposite in the southern part of the NSTEC.The results demonstrate that DIN deposition would likely threaten the forest ecosystems along the NSTEC,compared with the critical loads(CL)of N deposition,and DIN deposition in this region is mostly controlled by agricultural activities rather than industrial activities or transportation. 展开更多
关键词 中国东部南北样带 森林生态系统 空间格局 氮沉降 空间变化特征 沉积差异 DIn 交通控制
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p-Si/n-Ga_(2)O_(3)异质结制备与特性研究
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作者 陈沛然 焦腾 +6 位作者 陈威 党新明 刁肇悌 李政达 韩宇 于含 董鑫 《人工晶体学报》 北大核心 2024年第1期73-81,共9页
本实验采用金属有机化学气相沉积(MOCVD)工艺,在p(111)型Si衬底上制备了p-Si/n-Ga_(2)O_(3)结构的PN结。通过X射线衍射仪、原子力显微镜等对样品进行了晶体结构、表面形貌、表面粗糙度等的表征分析;通过磁控溅射与蒸镀方法在样品上生长T... 本实验采用金属有机化学气相沉积(MOCVD)工艺,在p(111)型Si衬底上制备了p-Si/n-Ga_(2)O_(3)结构的PN结。通过X射线衍射仪、原子力显微镜等对样品进行了晶体结构、表面形貌、表面粗糙度等的表征分析;通过磁控溅射与蒸镀方法在样品上生长Ti/Au电极并进行I-V特性曲线、开启电压、开关电流比、反向饱和电流、理想因子、零偏压下的势垒高度等结特性测试,研究了掺杂浓度与薄膜厚度对PN结特性的影响,并对其原因进行了分析;通过二步生长法和缓冲层温度优化实验,减少了Si衬底与β-Ga_(2)O_(3)之间的晶格失配与热失配带来的影响,对薄膜与器件特性进行了优化。最终获得了表面粗糙度最低可达到4.21 nm的高质量n型β-Ga_(2)O_(3)薄膜,以及具有较低理想因子(42.1)的PN结。 展开更多
关键词 β-Ga_(2)O_(3)薄膜 金属有机化学气相沉积 p-Si/n-Ga_(2)O_(3) Pn 晶体质量 电学特性
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抑制剂NBPT对紫色土稻油轮作体系氨挥发和产量的影响
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作者 张奇 王宏 +4 位作者 罗付香 姚莉 郑盛华 周长秀 林超文 《四川农业大学学报》 CSCD 北大核心 2023年第1期14-20,74,共8页
【目的】施用尿素时使用脲酶抑制剂有利于减少稻田氨挥发损失提高稻田氮肥利用效率,但对水稻-油菜轮作体系下氨挥发损失的影响并不是很清楚。研究紫色土丘陵区域稻油轮作模式体系下,不同脲酶抑制剂n-丁基硫代磷酰三胺(NBPT)添加量对氨... 【目的】施用尿素时使用脲酶抑制剂有利于减少稻田氨挥发损失提高稻田氮肥利用效率,但对水稻-油菜轮作体系下氨挥发损失的影响并不是很清楚。研究紫色土丘陵区域稻油轮作模式体系下,不同脲酶抑制剂n-丁基硫代磷酰三胺(NBPT)添加量对氨挥发、氮沉降和产量的影响,可为四川省紫色土丘陵区域农业面源污染防治提供技术支撑。【方法】结合当地农民施肥习惯,设置了5个处理,分别为T0(不施肥)、T1(尿素)、T2(添加为纯氮施用量的0.1%脲酶抑制剂NBPT处理的尿素)、T3(添加为纯氮施用量的0.2%脲酶抑制剂NBPT处理的尿素)和T4(添加为纯氮施用量的0.5%脲酶抑制剂NBPT处理的尿素),均为基肥一次性施入,分别在水稻季和油菜季开展试验。【结果】T1、T2、T3和T4处理在水稻季累积氨挥发损失率为26.54%、18.28%、14.88%和12.78%,在油菜季为5.22%、1.57%、1.36%和1.31%。与T1相比,T2、T3和T4处理在水稻季累积氨挥发降低了31.14%、43.96%和51.82%,在油菜季降低了70%、74.04%和74.89%。但是在水稻季和油菜季T2、T3和T4之间处理累积氨挥发损失没有显著性变化。在整个稻油轮作体系,铵态氮沉降量约为硝态氮沉降量的1.86倍,占整个无机氮沉降的63.94%。此外,与T1处理相比,T2、T3和T4处理能够显著增加作物产量和氮肥农学利用效率,但T2、T3和T4处理之间作物产量和氮肥农学利用效率并不存在显著性差异。【结论】与单纯施用尿素相比,使用脲酶抑制剂NBPT能够显著降低氨挥发损失、提高作物产量和氮肥利用率。铵态氮为农田氮沉降的主要沉降形式。 展开更多
关键词 紫色土 稻油轮作 氨挥发 氮沉降
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Simulated NH_4^+-N Deposition Inhibits CH_4 Uptake and Promotes N_2O Emission in the Meadow Steppe of Inner Mongolia, China 被引量:4
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作者 LIU Xingren ZHANG Qingwen +2 位作者 LI Shenggong ZHANG Leiming REN Jianqiang 《Pedosphere》 SCIE CAS CSCD 2017年第2期306-317,共12页
Few studies are conducted to quantify the effects of enhanced N deposition on soil nitrous oxide(N_2O) emission and methane(CH_4) uptake in the meadow steppe of Inner Mongolia, China. A two-year field experiment was c... Few studies are conducted to quantify the effects of enhanced N deposition on soil nitrous oxide(N_2O) emission and methane(CH_4) uptake in the meadow steppe of Inner Mongolia, China. A two-year field experiment was conducted to assess the effects of nitrogen(N) deposition rates(0, 10, and 20 kg N ha^(-1)year^(-1) as(NH_4)2SO_4) on soil N_2O and CH_4 fluxes. The seasonal and diurnal variations of soil N_2O and CH_4 fluxes were determined using the static chamber-gas chromatography method during the two growing seasons of 2008 and 2009. Soil temperature, moisture and mineral N(NH_4^+-N and NO-3-N) concentration were simultaneously measured. Results showed that low level of(NH_4)2SO_4(10 kg N ha-1year-1) did not significantly affect soil CH_4 and N_2O fluxes and other variables. High level of(NH_4)_2SO_4(20 kg N ha^(-1)year) significantly increased soil NO-3-N concentration by 24.1% to35.6%, decreased soil CH_4 uptake by an average of 20.1%, and significantly promoted soil N_2O emission by an average of 98.2%.Soil N_2O emission responded more strongly to the added N compared to CH_4 uptake. However, soil CH_4 fluxes were mainly driven by soil moisture, followed by soil NO-3-N concentration. Soil N_2O fluxes were mainly driven by soil temperature, followed by soil moisture. Soil inorganic N availability was a key integrator of soil CH_4 uptake and N_2O emission. These results suggest that the changes of availability of inorganic N induced by the increased N deposition in soil may affect the CH_4 and N_2O fluxes in the cold semi-arid meadow steppe over the short term. 展开更多
关键词 n2O排放量 CH4通量 CH4吸收 草原土壤 草甸草原 氮沉降 内蒙古 (nH4)2SO4
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施N对云南松凋落叶和枝早期分解过程中养分动态变化的影响
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作者 张乃木 王克勤 +3 位作者 宋娅丽 潘禹 郑兴蕊 安文雄 《中南林业科技大学学报》 CAS CSCD 北大核心 2023年第3期135-144,共10页
【目的】探讨N沉降条件下森林生态系统凋落物养分的变化规律,以期为亚热带云南松林的保护、生态系统的恢复及其可持续经营发展提供理论依据,并为在全球N沉降普遍持续增加背景下的养分循环变化特征提供基础数据。【方法】本研究以滇中亚... 【目的】探讨N沉降条件下森林生态系统凋落物养分的变化规律,以期为亚热带云南松林的保护、生态系统的恢复及其可持续经营发展提供理论依据,并为在全球N沉降普遍持续增加背景下的养分循环变化特征提供基础数据。【方法】本研究以滇中亚高山云南松林凋落叶和枝为研究对象,自2018年2月至2019年1月,采用凋落物分解袋法进行原位分解试验,设置不同施氮水平(对照-CK,0 g·m^(-2)·a^(-1)、低N-LN,5 g·m^(-2)·a^(-1)、中N-MN,15 g·m^(-2)·a^(-1)和高N-HN,30 g·m^(-2)·a^(-1)),探究云南松林凋落物营养元素的动态变化、元素释放以及元素周转率对不同施N水平的响应特征。【结果】1)经过12个月的N沉降实验,云南松林凋落叶和枝在不同施N水平下总体表现为:LN降低、MN和HN提高了C、N、P、K的元素含量;2)凋落叶和枝的元素释放在N沉降过程中表现不同,凋落叶和枝C元素总体表现为直接释放;凋落叶N元素在分解初期(第1个月)呈短暂富集,随后呈释放模式;凋落枝N元素在分解1—10个月均表现为富集状态,在第6个月时残留率达到最高值;凋落叶和枝的P和K的释放过程一致,残留率表现为初期(前3个月)上升,达到峰值后不断下降;3)不同施N处理下,凋落叶和枝整体上呈LN处理促进元素释放,MN和HN处理抑制元素释放;N沉降对各元素周转期影响则表现为:LN缩短了各元素周转期(0.05~0.79 a),MN与HN则分别延长了各元素周转期(0.42~1.93 a和0.07~2.19 a)。【结论】施N并未改变云南松凋落叶和枝分解过程中C、N、P、K元素的释放模式;但随着施N浓度的增加,对分解过程中C、N、P、K元素释放速率表现出持续的抑制作用;施N浓度高于15 g·m^(-2)·a^(-1)均延长了各元素周转期,可能会延缓养分向土壤系统的归还,研究结果为不同水平N沉降对森林碳循环的关键过程提供了理论依据。 展开更多
关键词 n沉降 凋落叶 凋落枝 元素释放 元素周转率
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Atomic Layer Deposition-Assisted Construction of Binder-Free Ni@N-Doped Carbon Nanospheres Films as Advanced Host for Sulfur Cathode 被引量:2
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作者 Jun Liu Aixiang Wei +4 位作者 Guoxiang Pan Qinqin Xiong Fang Chen Shenghui Shen Xinhui Xia 《Nano-Micro Letters》 SCIE EI CAS CSCD 2019年第4期147-160,共14页
Rational design of hybrid carbon host with high electrical conductivity and strong adsorption toward soluble lithium polysulfides is the main challenge for achieving high-performance lithium-sulfur batteries(LSBs).Her... Rational design of hybrid carbon host with high electrical conductivity and strong adsorption toward soluble lithium polysulfides is the main challenge for achieving high-performance lithium-sulfur batteries(LSBs).Herein,novel binder-free Ni@N-doped carbon nanospheres(N-CNSs)films as sulfur host are firstly synthesized via a facile combined hydrothermal-atomic layer deposition method.The cross-linked multilayer N-CNSs films can effectively enhance the electrical conductivity of electrode and provide physical blocking“dams”toward the soluble long-chain polysulfides.Moreover,the doped N heteroatoms and superficial NiO layer on Ni layer can work synergistically to suppress the shuttle of lithium polysulfides by effective chemical interaction/adsorption.In virtue of the unique composite architecture and reinforced dual physical and chemical adsorption to the soluble polysulfides,the obtained Ni@N-CNSs/S electrode is demonstrated with enhanced rate performance(816 mAh g?1 at 2 C)and excellent long cycling life(87%after 200 cycles at 0.1 C),much better than N-CNSs/S electrode and other carbon/S counterparts.Our proposed design strategy offers a promising prospect for construction of advanced sulfur cathodes for applications in LSBs and other energy storage systems. 展开更多
关键词 Atomic layer deposition nickel n-DOPED carbon nAnOSPHERES SULFUR CATHODE Lithium-sulfur batteries
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Influence of nitrogen wet deposition on nitrogen output in a typical watershed in the Three Gorges Reservoir Area
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作者 LU Chen-dong ZHANG Liu-yi +5 位作者 YAN Kun WANG Yu-kuan XIONG Shan-gao HUANG Chen-tao LI Ting-zhen NI Mao-fei 《Journal of Mountain Science》 SCIE CSCD 2022年第8期2214-2225,共12页
In order to explore the influence of wet nitrogen(N)deposition on N output in watersheds,this study selected a typical small watershed(Chenjiagou,CJG)in the Three Gorges Reservoir(TGR)area based on one-year observatio... In order to explore the influence of wet nitrogen(N)deposition on N output in watersheds,this study selected a typical small watershed(Chenjiagou,CJG)in the Three Gorges Reservoir(TGR)area based on one-year observation of rainfallrunoff N forms.Characteristics and sources of N output were clarified by chemical statistics and isotopic abundance,and the contribution of N deposition to the N output was quantified by the output coefficient method.The N flux of wet deposition was estimated at 18.53 kg N ha^(-1) yr^(-1),and originated mostly from agricultural activities.Watershed N was significantly accumulated from upper to lower reaches due to frequent human activities.Seasonal changes of riverine N were strongly affected by chemical fertilizer,with the highest concentration in spring and the lowest in winter.Nitrate was mainly derived from chemical fertilizer,accounting for 38.83% of all sources.N concentration in processes of different rainfall events had a hysteresis effect corresponding to the flow rate.Three rainfall events greatly changed DTN(Dissolved total N)outputs:rainstorm caused 91.26 kg DTN output,which was 11 times that of moderate rain(8.46 kg)and 4 times that of heavy rain(20.80 kg).N deposition contributed 19.89% of riverine N output in the watershed.The results can provide theoretical support for the control of N pollution in the TGR area. 展开更多
关键词 n wet deposition Riverine n load ISOTOPE Watershed n output
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Microstructure evolution and mechanical properties of Ti-B-N coatings deposited by plasma-enhanced chemical vapor deposition 被引量:13
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作者 Jung Ho SHIN Kwang Soo CHOI +2 位作者 Tie-gang WANG Kwang Ho KIM Roman NOWAK 《中国有色金属学会会刊:英文版》 CSCD 2012年第S3期722-728,共7页
Ternary Ti-B-N coatings were synthesized on AISI 304 and Si wafer by plasma-enhanced chemical vapor deposition (PECVD) technique using a gaseous mixture of TiCl4,BCl3,H2,N2,and Ar.By virtue of X-ray diffraction analys... Ternary Ti-B-N coatings were synthesized on AISI 304 and Si wafer by plasma-enhanced chemical vapor deposition (PECVD) technique using a gaseous mixture of TiCl4,BCl3,H2,N2,and Ar.By virtue of X-ray diffraction analysis,X-ray photoelectron spectroscopy,scanning electron microscope,and high-resolution transmission electron microscope,the influences of B content on the microstructure and properties of Ti B N coatings were investigated systematically.The results indicated that the microstructure and mechanical properties of Ti-B-N coatings largely depend on the transformation from FCC-TiN phase to HCP-TiB2 phase.With increasing B content and decreasing N content in the coatings,the coating microstructure evolves gradually from FCC-TiN/a-BN to HCP-TiB2 /a-BN via FCC-TiN+HCP-TiB2/a-BN.The highest microhardness of about 34 GPa is achieved,which corresponds to the nanocomposite Ti-63%B-N (mole fraction) coating consisting of the HCP-TiB2 nano-crystallites and amorphous BN phase.The lowest friction-coefficient was observed for the nanocomposite Ti-41%B-N (mole fraction) coating consisting of the FCC-TiN nanocrystallites and amorphous BN 展开更多
关键词 Ti-B-n COATInG plasma-enhanced chemical vapor deposition (PECVD) nAnOCOMPOSITE COATInG hardness friction coefficient
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In-Situ Nitrogen Doping of the TiO2 Photocatalyst Deposited by PEALD for Visible Light Activity 被引量:1
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作者 饶志鹏 万军 +4 位作者 李超波 陈波 刘键 黄成强 夏洋 《Plasma Science and Technology》 SCIE EI CAS CSCD 2014年第3期239-243,共5页
In this paper, an N-doped titanium oxide (TiO2) photocatalyst is deposited by a plasma-enhanced atomic layer deposition (PEALD) system through the in-situ doping method. X-ray photoelectron spectroscopy (XPS) an... In this paper, an N-doped titanium oxide (TiO2) photocatalyst is deposited by a plasma-enhanced atomic layer deposition (PEALD) system through the in-situ doping method. X-ray photoelectron spectroscopy (XPS) analysis indicates that substitutional nitrogen atoms (-395.9 eV) with 1 atom% are effectively doped into TiO2 films. UV-VIS spectrometry shows that the in-situ nitrogen doping method indeed enhances the visible-activity of TiO2 films in the 425-550 nm range, and the results of the performance tests of the N-doped TiO2 films also imply that the photocatalysis activity is improved by in-situ doping. The in-situ doping mechanism of the N-doped TiO2 film is suggested according to the XPS results and the typical atomic layer deposition process. 展开更多
关键词 plasma-enhanced atomic layer deposition In-SITU nitrogen plasma n-dopedTiO2 PHOTOCATALYST
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The properties of GaMnN films grown by metalorganic chemical vapour deposition using Raman spectroscopy
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作者 邢海英 牛萍娟 谢玉芯 《Chinese Physics B》 SCIE EI CAS CSCD 2012年第7期513-517,共5页
An investigation of room-temperature Raman scattering is carried out on ferromagnetic semiconductor GaMnN films grown by metalorganic chemical vapour deposition with different Mn content values. New bands around 300 a... An investigation of room-temperature Raman scattering is carried out on ferromagnetic semiconductor GaMnN films grown by metalorganic chemical vapour deposition with different Mn content values. New bands around 300 and 669 cm-1, that are not observed in undoped GaN, are found. They are assigned to disorder-activated mode and local vibration mode (LYM), respectively. After annealing, the intensity ratio between the LVM and E2(high) mode, i.e., ILVM/IE2 (high), increases. The LO phonon-plasmon coupled (LOPC) mode is found in GaMnN, and the frequency of the LOPC mode of GaMnN shifting toward higher side is observed with the increase in the Mn doping in GaN. The ferromagnetic character and the carrier density of our GaMnN sample are discussed. 展开更多
关键词 diluted magnetic semiconductor metalorganic chemical vapour deposition Ram^n scat-tering
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N添加对西南亚高山红桦林根系分泌物及其介导的养分转化过程的影响 被引量:1
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作者 徐正刚 许航 +4 位作者 彭修涛 梁时军 刘榕 罗尚华 肖娟 《植物研究》 CAS CSCD 北大核心 2023年第2期194-206,共13页
目前缺乏对根系分泌物通量以及相关生态后果对不同氮(N)沉降水平响应方向和幅度的深入理解,该研究以西南亚高山典型的红桦(Betula albosinensis)林为研究对象,通过野外原位N添加试验模拟不同氮沉降水平(对照组,0 kg·hm^(-2)·a... 目前缺乏对根系分泌物通量以及相关生态后果对不同氮(N)沉降水平响应方向和幅度的深入理解,该研究以西南亚高山典型的红桦(Betula albosinensis)林为研究对象,通过野外原位N添加试验模拟不同氮沉降水平(对照组,0 kg·hm^(-2)·a(-1);低氮处理,25 kg·hm^(-2)·a(-1);高氮处理,50 kg·hm^(-2)·a(-1)),分析了红桦林根系分泌物C输入通量及其介导的根际土壤养分循环过程对不同N添加水平的差异化响应,试图揭示不同N添加处理对红桦根系分泌物C输入通量及其介导的土壤养分转化过程的影响。结果表明:(1)N添加显著抑制了红桦林根系分泌物C输入速率(其中低氮(N25)条件下单位根生物量根系分泌速率均值降低约14.87%)和年C输入通量(低氮条件下降低了约45.01%)(P<0.05),其高氮处理的抑制效应更强。(2)N添加显著抑制了红桦林N矿化速率及其相关的微生物胞外酶活性(P<0.05),并显著降低了其根际效应;N沉降显著抑制了根系分泌物C输入通量及其介导的土壤养分转化过程,并且这种抑制效应随N沉降水平的升高而增强。该研究结果可丰富全球气候变化下森林地下碳养分循环过程的认识和理解。 展开更多
关键词 红桦林 根系分泌物 土壤n转化 根际效应 n沉降
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Optimizing electrophoretic deposition conditions for enhancement in electrical conductivity of carbon fiber/carbon nanotube/epoxy hybrid composites 被引量:1
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作者 王一奇 BYUN Joon-hyung +1 位作者 KIM Byung-sun SONG Jung-il 《Journal of Central South University》 SCIE EI CAS 2012年第11期3017-3022,共6页
The effectiveness of optimizing electrical conductivity of carbon fiber/carbon nanotube (CNT)/epoxy hybrid composites via Taguchi method was demonstrated.CNTs were induced on carbon fabric by electrophoretic depositio... The effectiveness of optimizing electrical conductivity of carbon fiber/carbon nanotube (CNT)/epoxy hybrid composites via Taguchi method was demonstrated.CNTs were induced on carbon fabric by electrophoretic deposition (EPD) technique.The essential deposition parameters were identified as 1) the deposition time,2) the deposition voltage,3) the mass fraction of CNTs in suspension,and 4) the distance between the electrodes.An experimental design was then performed to establish the appropriate levels for each factor.An orthogonal array of L9 (34) was designed to conduct the experiments.Electrical conductivity results were collected as the response.The relative influences of design parameters on the response were discussed.Using the model,signal to noise (S/N) ratio and response characteristics for the optimized deposition parameter combination were predicted.The results show clearly that the optimum condition of electrophoretic deposition (EPD) process improves the electrical conductivity of carbon/epoxy hybrid composites. 展开更多
关键词 碳纤维织物 碳纳米管 环氧树脂 电泳沉积 沉积条件 导电性 优化 杂化材料
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鼎湖山苗圃和主要森林土壤CO_2排放和CH_4吸收对模拟N沉降的短期响应 被引量:63
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作者 莫江明 方运霆 +2 位作者 徐国良 李德军 薛璟花 《生态学报》 CAS CSCD 北大核心 2005年第4期682-690,共9页
研究了鼎湖山生物圈保护区苗圃(幼苗)、马尾松、混交林和季风常绿阔叶林(季风林)土壤CO2 排放和CH4 吸收的一些特征及其对模拟N沉降增加的响应。结果表明,土壤CO2 日(白天)平均排放量的大小顺序为(平均值±标准误) :苗圃(2 5 8±... 研究了鼎湖山生物圈保护区苗圃(幼苗)、马尾松、混交林和季风常绿阔叶林(季风林)土壤CO2 排放和CH4 吸收的一些特征及其对模拟N沉降增加的响应。结果表明,土壤CO2 日(白天)平均排放量的大小顺序为(平均值±标准误) :苗圃(2 5 8±6 2mg·m- 2 ·h- 1 ) >季风林(177±4 2 mg·m- 2 ·h- 1 ) >马尾松林(16 2±39mg·m- 2 ·h- 1 ) >混交林(12 6±30 mg·m- 2 ·h- 1 )。土壤CH4 日(白天)平均吸收量的大小顺序为:马尾松林(- 0 .15±0 .0 2 mg·m- 2 ·h- 1 ) >季风林(- 0 .0 8±0 .0 1mg·m- 2 ·h- 1 ) >混交林(- 0 .0 7±0 .0 1mg·m- 2·h- 1 ) >苗圃(- 0 .0 5±0 .0 1m g·m- 2·h- 1 )。低N(5 0 kg N·hm- 2·a- 1 )和中N(10 0kg N·hm- 2·a- 1 )处理对苗圃、马尾松林和混交林样地土壤CO2 日平均排放量的影响均不明显,高N(15 0 kg N·hm- 2·a- 1 )处理对苗圃土壤CO2 的日平均排放量也无显著影响,但倍高N(30 0 kg N·hm- 2 ·a- 1 )处理显著促进苗圃样地土壤CO2 的排放。然而,所有N(低N、中N和高N)处理均显著促进季风林土壤CO2 日平均排放量,且这种促进作用随N处理水平的升高而增加。N处理显著促进季风林和马尾松林土壤对CH4 吸收速率,但对混交林土壤CH4 吸收则无明显的影响。在苗圃样地,除倍高N外,N? 展开更多
关键词 n沉降 CO2排放 CH4吸收 响应 全球变化 南亚热带
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