The title compound （-）-N-[（3R）-3-cyclohexyl]-3-phenylpropananoyl]bornane-10,2sultam （C 25 H 35 NO 3 S,M r=429.60）,a derivative of camphorsultam,crystallizes in the monoclinic space group P2 1 /c with a=10.3301（...The title compound （-）-N-[（3R）-3-cyclohexyl]-3-phenylpropananoyl]bornane-10,2sultam （C 25 H 35 NO 3 S,M r=429.60）,a derivative of camphorsultam,crystallizes in the monoclinic space group P2 1 /c with a=10.3301（7）,b=19.4040（13）,c=11.8106（8）,β=100.5580（10）°,V=2327.3（3） 3,Z=4,D c=1.226 g/cm 3,λ=0.71073,μ（MoKα）=0.165 mm-1 and F（000）=928.X-ray diffraction analysis reveals that the six-membered ring of sultam shows a boat form （Fig.1）.The planes constructed by （C（4）,C（5）,C（6）,C（7）） and （C（7）,C（8）,C（9）,C（4）） form a dihedral angle of 69.5°.The C（1）-C（2）-C（3） plane forms dihedral angles to the aforementioned planes of 89.8（1） and 85.9（3）°,respectively.And molecules are linked via hydrogen bonding （C-H···N/O） interactions.展开更多
基金sponsored by the Science Foundation of Ministry of Education for the New Teacher at the University of China (No. 20070511006)the Research Initiation Funds of Huazhong Agricultural University (No. 52204-09057)
文摘The title compound （-）-N-[（3R）-3-cyclohexyl]-3-phenylpropananoyl]bornane-10,2sultam （C 25 H 35 NO 3 S,M r=429.60）,a derivative of camphorsultam,crystallizes in the monoclinic space group P2 1 /c with a=10.3301（7）,b=19.4040（13）,c=11.8106（8）,β=100.5580（10）°,V=2327.3（3） 3,Z=4,D c=1.226 g/cm 3,λ=0.71073,μ（MoKα）=0.165 mm-1 and F（000）=928.X-ray diffraction analysis reveals that the six-membered ring of sultam shows a boat form （Fig.1）.The planes constructed by （C（4）,C（5）,C（6）,C（7）） and （C（7）,C（8）,C（9）,C（4）） form a dihedral angle of 69.5°.The C（1）-C（2）-C（3） plane forms dihedral angles to the aforementioned planes of 89.8（1） and 85.9（3）°,respectively.And molecules are linked via hydrogen bonding （C-H···N/O） interactions.
