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Biomineralization of soil with crude soybean urease using different calcium salts
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作者 Yajie Weng Junjie Zheng +2 位作者 Hanjiang Lai Mingjuan Cui Xingzhi Ding 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第5期1788-1798,共11页
Calcium salt is an important contributing factor for calcium-based biomineralization.To study the effect of calcium salt on soil biomineralization using crude soybean urease,the calcium salts,including the calcium chl... Calcium salt is an important contributing factor for calcium-based biomineralization.To study the effect of calcium salt on soil biomineralization using crude soybean urease,the calcium salts,including the calcium chloride (CaCl_(2)),calcium acetate ((CH_(3)COO)_(2)Ca) and calcium nitrate (Ca(NO_(3))_(2)),were used to prepare the biotreatment solution to carry out the biomineralization tests in this paper.Two series of biomineralization tests in solution and sand column,respectively,were conducted.Scanning electron microscopy (SEM) and X-ray diffraction (XRD) were performed to determine the microscopic characteristics of the precipitated calcium carbonate (CaCO_(3)) crystals.The experimental results indicate that the biomineralization effect is the best for the CaCl2 case,followed by (CH_(3)COO)_(2)Ca,and worst for Ca(NO_(3))_(2) under the test conditions of this study (i.e.1 mol/L of calcium salt-urea).The mechanism for the effect of the calcium salt on the biomineralization of crude soybean urease mainly involves: (1) inhibition of urease activity,and (2) influence on the crystal size and morphology of CaCO_(3).Besides Ca^(2+) ,the anions in solution can inhibit the activity of crude soybean urease,and NO_(3)− has a stronger inhibitory effect on the urease activity compared with both CH_(3)COO^(−) and Cl^(−) .The co-inhibition of Ca^(2+) and NO_(3)− on the activity of urease is the key reason for the worst biomineralization of the Ca(NO_(3))_(2) case in this study.The difference in biomineralization between the CaCl_(2) and (CH_(3)COO)_(2) Ca cases is strongly correlated with the crystal morphology of the precipitated CaCO_(3). 展开更多
关键词 BIOMINERALIZATION Crude soybean urease Calcium salt Influence mechanism
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Recent Advances of Transition Metal Basic Salts for Electrocatalytic Oxygen Evolution Reaction and Overall Water Electrolysis 被引量:13
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作者 Bingrong Guo Yani Ding +4 位作者 Haohao Huo Xinxin Wen Xiaoqian Ren Ping Xu Siwei Li 《Nano-Micro Letters》 SCIE EI CAS CSCD 2023年第4期238-260,共23页
Electrocatalytic oxygen evolution reaction(OER)has been recognized as the bottleneck of overall water splitting,which is a promising approach for sustainable production of H_(2).Transition metal(TM)hydroxides are the ... Electrocatalytic oxygen evolution reaction(OER)has been recognized as the bottleneck of overall water splitting,which is a promising approach for sustainable production of H_(2).Transition metal(TM)hydroxides are the most conventional and classical non-noble metal-based electrocatalysts for OER,while TM basic salts[M^(2+)(OH)_(2-x)(A_(m^(-))_(x/m),A=CO_(3)^(2−),NO_(3)^(−),F^(−),Cl^(−)]consisting of OH−and another anion have drawn extensive research interest due to its higher catalytic activity in the past decade.In this review,we summarize the recent advances of TM basic salts and their application in OER and further overall water splitting.We categorize TM basic salt-based OER pre-catalysts into four types(CO_(3)^(2−),NO_(3)^(−),F^(−),Cl^(−)according to the anion,which is a key factor for their outstanding performance towards OER.We highlight experimental and theoretical methods for understanding the structure evolution during OER and the effect of anion on catalytic performance.To develop bifunctional TM basic salts as catalyst for the practical electrolysis application,we also review the present strategies for enhancing its hydrogen evolution reaction activity and thereby improving its overall water splitting performance.Finally,we conclude this review with a summary and perspective about the remaining challenges and future opportunities of TM basic salts as catalysts for water electrolysis. 展开更多
关键词 Transition metal basic salts ELECTROCATALYTIC Oxygen evolution reaction(OER) Overall water electrolysis
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Study on the corrosion behavior of 316H stainless steel in molten NaCl–KCl–MgCl_(2) salts with and without purification 被引量:1
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作者 Hua Ai Xin‑Mei Yang +6 位作者 Hua‑Jian Liu Bing‑Chuan Chen Ling Han Hua Sun Yan‑Jun Chen Yuan Qian Jian‑Qiang Wang 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2023年第12期123-132,共10页
The corrosion behavior of 316H stainless steel(SS)in the impure and purified Na Cl–KCl–Mg Cl_(2) salt was investigated at700°C.Results indicate that the main deleterious impurity induced corrosion in the impure... The corrosion behavior of 316H stainless steel(SS)in the impure and purified Na Cl–KCl–Mg Cl_(2) salt was investigated at700°C.Results indicate that the main deleterious impurity induced corrosion in the impure salt was the absorbed moisture,present in the form of Mg Cl_(2)·6H_(2)O.316H SS occurred severe intergranular corrosion with a corrosion depth of 130μm for1000 h in the impure Na Cl–KCl–Mg Cl_(2) salt.In contrast,the purification treatment of molten chloride salt by the dissolved Mg metal can remove the absorbed moisture,and the corresponding reactions were also discussed.As a result,the corrosiveness of Na Cl–KCl–Mg Cl_(2) salt is reduced significantly.316H SS occurred slight uniform corrosion with a depth of less than 5μm for 3000 h in the purified Na Cl–KCl–Mg Cl_(2) salt. 展开更多
关键词 Stainless steel Alloy Chloride salt Molten salt corrosion High-temperature corrosion
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Synthesis and kinetics of 2,5-dicyanofuran in the presence of hydroxylamine ionic liquid salts 被引量:2
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作者 Xuan Gao Zhihui Li +2 位作者 Dongsheng Zhang Xinqiang Zhao Yanji Wang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第1期310-316,共7页
2,5-Dicyanofuran(DCF)is an important biomass-derived platform compound primarily used to prepare bio-based adiponitrile,which is the key precursor for the synthesis of nylon 66 and 1,6-hexanediisocyanate(HDI).In this ... 2,5-Dicyanofuran(DCF)is an important biomass-derived platform compound primarily used to prepare bio-based adiponitrile,which is the key precursor for the synthesis of nylon 66 and 1,6-hexanediisocyanate(HDI).In this study,one-pot,green and safe synthesis of DCF from 2,5-diformylfuran(DFF)and hydroxylamine ionic liquid salts was proposed.Eco-friendly hydroxylamine ionic liquid salts were used as the nitrogen source.Ionic liquid exhibited three-fold function of cosolvent,catalysis and phase separation.The conversion of DFF and yield of DCF reached 100%under the following optimum reaction conditions:temperature of 120℃ for 70 min,volume ratio of paraxylene:[HSO_(3)-b-Py]HSO4 of 2:1,and molar ratio of DFF:(NH_(2)OH)_(2)[HSO_(3)-b-Py]HSO4 of 1:1.5.The reaction mechanism for the synthesis of DCF was proposed,and the kinetic model was established.The reaction order with respect to DFF and intermediate product 2,5-diformylfuran dioxime(DFFD)was 1.06 and 0.16,and the reaction activation energy was 64.07 kJ·mol^(-1) and 59.37 kJ·mol^(-1) respectively.After the reaction,the ionic liquid was easy to separate,recover and recycle. 展开更多
关键词 2 5-Dicyanofuran Hydroxylamine ionic liquid salts Green synthesis KINETICS
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Coordination states of metal ions in molten salts and their characterization methods 被引量:1
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作者 Xin Song Shaolong Li +3 位作者 Shanshan Liu Yong Fan Jilin He Jianxun Song 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2023年第7期1261-1277,共17页
The macroscopic characteristics of molten salts are governed by their microstructures.Research on the structures of molten salts provides the foundation for a full understanding of the physicochemical properties of mo... The macroscopic characteristics of molten salts are governed by their microstructures.Research on the structures of molten salts provides the foundation for a full understanding of the physicochemical properties of molten salts as well as a deeper analysis of the microscopic electrolysis process in molten salts.Information about the microstructure of matter can be obtained with the help of several speculative and experimental procedures.In this review,the advantages and disadvantages of the various test procedures used to determine the microstructures of molten salts are compared.The typical coordination configurations of metal ions in molten salt systems are also summarized.Furthermore,the impact of temperature,anions,cations,and metal oxides(O2-)on the structures of molten salts is discussed in detail.The accuracy and completeness of the information on molten salt structures need to be investigated by the integration of multiple methods and interdisciplinary fields.Information on the microstructure and coordination of molten salts deepens the understanding of the elementary elements of the microstructure of matter.This paper,which is based on the review of the coordination states of metal ions in molten salts,is hoped to inspire researchers to explore the inter-relationship between the microstructure and macroscopic properties of materials. 展开更多
关键词 MICROSTRUCTURE salts COORDINATION
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Interconnected and high cycling stability polypyrrole supercapacitors using cellulose nanocrystals and commonly used inorganic salts as dopants 被引量:1
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作者 Zuxin Sun Wim Thielemans 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第1期165-174,I0005,共11页
Polypyrrole(PPy)is wildly used as electrode material in supercapacitors due to its high conductivity,low cost,ease of handling,and ease of fabrication.However,limited capacitance and poor cycling stability hinder its ... Polypyrrole(PPy)is wildly used as electrode material in supercapacitors due to its high conductivity,low cost,ease of handling,and ease of fabrication.However,limited capacitance and poor cycling stability hinder its practical application.After developing carboxylated cellulose nanocrystals(CNC-COO^(-))as immobile dopants for PPy to improve its cycling stability,we investigated the effect of different commonly used salts(KCl,NaCl,KBr,and NaClO_(4))as dopants during electrode fabrication by electropolymerization.The film’s capacitance increased from 160.6 to 183.4 F g^(-1)after adding a combination of KCl and NaClO_(4) into the electrodeposition electrolyte.More importantly,the porous and interconnected PPy/CNC-COO^(-)-Cl-(Cl O_(4)^(-))_0.5 electrode film exhibited an excellent capacitance of 125.0 F g^(-1)(0.78 F cm^(-2))at a high current density of 2.0 Ag^(-1)(20 m A cm^(-2),allowing charging in less than 1 min),increasing almost 204%over PPy/CNC-COO-films.A symmetric PPy/CNC-COO^(-)-Cl-(ClO_(4)^(-))_0.5 supercapacitor retained its full capacitance after 5000 cycles,and displayed a high energy density of 5.2 Wh kg^(-1)at a power density of 25.4 W kg^(-1)(34.5μWh cm^(-2) at 1752.3μW cm^(-2)).These results reveal that the porous structure formed by doping with CNC-COO-and inorganic salts opens up more active reaction areas to store charges in PPy-based films as the stiff and ribbon-like CNC-COO-as permanent dopants improve the strength and stability of PPy-based films.Our demonstration provides a simple and practical way to deposit PPy based supercapacitors with high capacitance,fast charging,and excellent cycling stability. 展开更多
关键词 POLYPYRROLE Cellulose nanocrystals Cycling stability Inorganic salts SUPERCAPACITOR
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Dynamic simulation analysis of molten salt reactor-coupled air-steam combined cycle power generation system 被引量:2
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作者 Jing-Lei Huang Guo-Bin Jia +3 位作者 Li-Feng Han Wen-Qian Liu Li Huang Zheng-Han Yang 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2024年第2期222-233,共12页
A nonlinear dynamic simulation model based on coordinated control of speed and flow rate for the molten salt reactor and combined cycle systems is proposed here to ensure the coordination and stability between the mol... A nonlinear dynamic simulation model based on coordinated control of speed and flow rate for the molten salt reactor and combined cycle systems is proposed here to ensure the coordination and stability between the molten salt reactor and power system.This model considers the impact of thermal properties of fluid variation on accuracy and has been validated with Simulink.This study reveals the capability of the control system to compensate for anomalous situations and maintain shaft stability in the event of perturbations occurring in high-temperature molten salt tank outlet parameters.Meanwhile,the control system’s impact on the system’s dynamic characteristics under molten salt disturbance is also analyzed.The results reveal that after the disturbance occurs,the controlled system benefits from the action of the control,and the overshoot and disturbance amplitude are positively correlated,while the system power and frequency eventually return to the initial values.This simulation model provides a basis for utilizing molten salt reactors for power generation and maintaining grid stability. 展开更多
关键词 Molten salt reactor Combined cycle Dynamic characteristic CONTROL
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Failure transition of shear-to-dilation band of rock salt under triaxial stresses 被引量:3
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作者 Jianfeng Liu Xiaosong Qiu +3 位作者 Jianxiong Yang Chao Liang Jingjing Dai Yu Bian 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第1期56-64,共9页
Great potential of underground gas/energy storage in salt caverns seems to be a promising solution to support renewable energy.In the underground storage method,the operating cycle unfortunately may reach up to daily ... Great potential of underground gas/energy storage in salt caverns seems to be a promising solution to support renewable energy.In the underground storage method,the operating cycle unfortunately may reach up to daily or even hourly,which generates complicated pressures on the salt cavern.Furthermore,the mechanical behavior of rock salt may change and present distinct failure characteristics under different stress states,which affects the performance of salt cavern during the time period of full service.To reproduce a similar loading condition on the cavern surrounding rock mass,the cyclic triaxial loading/unloading tests are performed on the rock salt to explore the mechanical transition behavior and failure characteristics under different confinement.Experimental results show that the rock salt samples pre-sent a diffused shear failure band with significant bulges at certain locations in low confining pressure conditions(e.g.5 MPa,10 MPa and 15 MPa),which is closely related to crystal misorientation and grain boundary sliding.Under the elevated confinement(e.g.20 MPa,30 MPa and 40 MPa),the dilation band dominates the failure mechanism,where the large-size halite crystals are crushed to be smaller size and new pores are developing.The failure transition mechanism revealed in the paper provides additional insight into the mechanical performance of salt caverns influenced by complicated stress states. 展开更多
关键词 Rock salt Cyclic mechanical loading Shear band Dilation band Underground gas storage(UGS)
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Ionization Engineering of Hydrogels Enables Highly Efficient Salt‑Impeded Solar Evaporation and Night‑Time Electricity Harvesting 被引量:2
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作者 Nan He Haonan Wang +3 位作者 Haotian Zhang Bo Jiang Dawei Tang Lin Li 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第1期131-146,共16页
Interfacial solar evaporation holds immense potential for brine desalination with low carbon footprints and high energy utilization.Hydrogels,as a tunable material platform from the molecular level to the macroscopic ... Interfacial solar evaporation holds immense potential for brine desalination with low carbon footprints and high energy utilization.Hydrogels,as a tunable material platform from the molecular level to the macroscopic scale,have been considered the most promising candidate for solar evaporation.However,the simultaneous achievement of high evaporation efficiency and satisfactory tolerance to salt ions in brine remains a challenging scientific bottleneck,restricting the widespread application.Herein,we report ionization engineering,which endows polymer chains of hydrogels with electronegativity for impeding salt ions and activating water molecules,fundamentally overcoming the hydrogel salt-impeded challenge and dramatically expediting water evaporating in brine.The sodium dodecyl benzene sulfonate-modified carbon black is chosen as the solar absorbers.The hydrogel reaches a ground-breaking evaporation rate of 2.9 kg m−2 h−1 in 20 wt%brine with 95.6%efficiency under one sun irradiation,surpassing most of the reported literature.More notably,such a hydrogel-based evaporator enables extracting clean water from oversaturated salt solutions and maintains durability under different high-strength deformation or a 15-day continuous operation.Meantime,on the basis of the cation selectivity induced by the electronegativity,we first propose an all-day system that evaporates during the day and generates salinity-gradient electricity using waste-evaporated brine at night,anticipating pioneer a new opportunity for all-day resource-generating systems in fields of freshwater and electricity. 展开更多
关键词 Solar evaporation Hydrogel evaporators salt impeding Ionization engineering Cyclic vapor-electricity generation
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Synergistic effects of carbon cycle metabolism and photosynthesis in Chinese cabbage under salt stress 被引量:1
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作者 Hao Liang Qiling Shi +8 位作者 Xing Li Peipei Gao Daling Feng Xiaomeng Zhang Yin Lu Jingsen Yan Shuxing Shen Jianjun Zhao Wei Ma 《Horticultural Plant Journal》 SCIE CAS CSCD 2024年第2期461-472,共12页
Chinese cabbage(Brassica rapa ssp. pekinensis) has a long cultivation history and is one of the vegetable crops with the largest cultivation area in China. However, salt stress severely damages photosynthesis and horm... Chinese cabbage(Brassica rapa ssp. pekinensis) has a long cultivation history and is one of the vegetable crops with the largest cultivation area in China. However, salt stress severely damages photosynthesis and hormone metabolism, nutritional balances, and results in ion toxicity in plants. To better understand the mechanisms of salt-induced growth inhibition in Chinese cabbage, RNA-seq and physiological index determination were conducted to explore the impacts of salt stress on carbon cycle metabolism and photosynthesis in Chinese cabbage. Here, we found that the number of thylakoids and grana lamellae and the content of starch granules and chlorophyll in the leaves of Chinese cabbage under salt stress showed a time-dependent response, first increasing and then decreasing. Chinese cabbage increased the transcript levels of genes related to the photosynthetic apparatus and carbon metabolism under salt stress, probably in an attempt to alleviate damage to the photosynthetic system and enhance CO_(2) fixation and energy metabolism. The transcription of genes related to starch and sucrose synthesis and degradation were also enhanced;this might have been an attempt to maintain intracellular osmotic pressure by increasing soluble sugar concentrations. Soluble sugars could also be used as potential reactive oxygen species(ROS) scavengers, in concert with peroxidase(POD)enzymes, to eliminate ROS that accumulate during metabolic processes. Our study characterizes the synergistic response network of carbon metabolism and photosynthesis under salt stress. 展开更多
关键词 Chinese cabbage salt stress Carbon metabolism PHOTOSYNTHESIS CHLOROPLAST
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Wettability alteration of organo-vermiculites induced by layer charge and tailored bis-N-heterocyclic quaternary ammonium salts
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作者 Fan Ding Xin Jin +3 位作者 Tao Shen Shan-Shan Mao Qing Zhao Mang-Lai Gao 《Petroleum Science》 SCIE EI CAS CSCD 2023年第4期2596-2603,共8页
Wettability is an important surface property that deserves to further explore the factors on its alteration.Series of bis-N-heterocyclic quaternary ammonium salts with different spacer length and N-heterocyclic headgr... Wettability is an important surface property that deserves to further explore the factors on its alteration.Series of bis-N-heterocyclic quaternary ammonium salts with different spacer length and N-heterocyclic headgroups(morpholinium(BMMB,BMMD and BMMH),piperidinium(BPMH)and piperazinium(BMPMH))have been synthesized and employed for altering the wettability of vermiculite and its derivates(Vts)treated by Li^(+)-saturated heating method.The results of X-ray diffraction(XRD),Fourier transform infrared spectroscopy(FT-IR),thermogravimetric analysis(TG-DTG),scanning electron microscopy(SEM)and N_(2)adsorption/desorption isotherms indicate that all of the bis-N-heterocyclic quaternary ammonium salts have been successfully inserted into the vermiculite layers,leading to the organic monolayer.The results of capillary rise tests combined with Lipophilic to Hydrophilic Ratio(LHR)values unveil the wettability alteration of the organo-Vts.As the layer charge decreases,the hydrophilicity of the organo-Vts gradually increases,which is probably caused by the decline in binding sites.As the result of the change in spacer length of modifier,the wetting properties of morpholinium-based organo-Vts change in order of BMMD-Vts>BMMH-Vts>BMMB-Vts,and difference in N-heterocyclic headgroups leads to the sequence of wettability:BMPMH-Vts>BPMH-Vts>BMMH-Vts.Layer charge of Vt,spacer length and the type of the N-heterocyclic headgroup of modifier have the synergistic effect on the regulation of the wettability. 展开更多
关键词 VERMICULITE bis-N-heterocyclic quaternary ammonium salts Organo-vermiculite Layer charge Wettability alteration
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Influence of Climate and Tectonics on the Crystallization of Carnallite and Related Salts in the Congolese Atlantic Basin during the Lower Cretaceous, Republic of Congo
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作者 Daphne Steimer Garcia Nkokani Milandou Hilaire Elenga +1 位作者 Maurice Dieudonné Malounguila Nganga Mathurin Enama Mengong 《Open Journal of Geology》 CAS 2023年第1期51-71,共21页
Lithological, petrographic, and morphoscopic studies were conducted on cuttings and cores from three boreholes drilled in the Loemé salt, Kanga site, Republic of the Congo, to determine 1) the preferential condit... Lithological, petrographic, and morphoscopic studies were conducted on cuttings and cores from three boreholes drilled in the Loemé salt, Kanga site, Republic of the Congo, to determine 1) the preferential conditions for crystallization of carnallite and associated salts and 2) to reconstruct paleoenvironmental and paleoclimatic conditions at the time of sedimentation. Sequential analysis of logs, sedimentary structures, carnallitite facies and associated salts concluded to the existence of a potassic carnallitite lagoon basin with low water cover, on a very wide and extensive plateau, affected by coastal waves and swells resulting from successive collapses. This basin evolved in two phases: confined and then open. The regular stratifications of halite, the rhythmicity of the halite-carnallitite elementary sequences are characteristic of salts that precipitated in relatively stable brines. These salts are therefore tectonosedimentary. The brecciated facies of the carnallitites sometimes associated with tachyhydrite result from the evolution of these deposits into salt crusts reworked by the surges into subaquatic allochemical gravelly cords under water. These crusts mark stages of partial and complete drying of the basin in a very hot and arid climate. Prolonged exposure of halite brines as well as their homogenization by surges accelerated evaporation and their abrupt evolution into carnallite brines obstructing the fossilization of sylvite. The precipitation of tachyhydrite marks the final stage of the successive complete drying of the basin. 展开更多
关键词 Potassium Lagoon SURGES Stable Brines RHYTHMICITY Elementary Sequences salt Crusts Arid Climate Republic of the Congo
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A Review:Pre-lithiation Strategies Based on Cathode Sacrificial Lithium Salts for Lithium-Ion Capacitors
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作者 Kailimai Su Yan Wang +4 位作者 Bao Yang Xu Zhang Wei Wu Junwei Lang Xingbin Yan 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2023年第6期10-32,共23页
Similar to lithium-ion batteries(LIBs),during the first charge/discharge process of lithium-ion capacitors(LICs),lithium-intercalated anodes(e.g.,silicon,graphite,and hard carbon)also exhibit irreversible lithium inte... Similar to lithium-ion batteries(LIBs),during the first charge/discharge process of lithium-ion capacitors(LICs),lithium-intercalated anodes(e.g.,silicon,graphite,and hard carbon)also exhibit irreversible lithium intercalation behaviors,such as the formation of a solid electrolyte interface(SEI),which will consume Li^(+)in the electrolyte and significantly reduce the electrochemical performance of the system.Therefore,pre-lithiation is an indispensable procedure for LICs.At present,commercial LICs mostly use lithium metal as the lithium source to compensate for the irreversible capacity loss,which has the demerits of operational complexity and danger.However,the pre-lithiation strategy based on cathode sacrificial lithium salts(CSLSs)has been proposed,which has the advantages of low cost,simple operation,environmental protection,and safety.Therefore,there is an urgent need for a timely and comprehensive summary of the application of CSLSs to LICs.In this review,the important roles of pre-lithiation in LICs are detailed,and different pre-lithiation methods are reviewed and compared systematically and comprehensively.After that,we systematically discuss the pre-lithiation strategies based on CSLSs and mainly introduce the lithium extraction mechanism of CSLSs and the influence of intrinsic characteristics and doping amount of CSLSs on LICs performance.In addition,a summary and outlook are conducted,aiming to provide the essential basic knowledge and guidance for developing a new pre-lithiation technology. 展开更多
关键词 cathode sacrificial lithium salts lithium-ion battery capacitors lithium-ion capacitors perspectives pre-lithiation strategies
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Lacunary silicotungstic heteropoly salts as high-performance catalysts in oxidation of cyclopentene
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作者 Peiyin Chen Yanxiong Fang +5 位作者 Kaihong Xie Yao Chen Yang Liu Hongliang Zuo Weijian Lu Baoyu Liu 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第4期152-159,共8页
The development of polyoxometalates for olefin oxidation is critical to achieving the green chemical process of the C5 fraction further processing.Di-lacunary silicotungstic anions were easily obtained by continuously... The development of polyoxometalates for olefin oxidation is critical to achieving the green chemical process of the C5 fraction further processing.Di-lacunary silicotungstic anions were easily obtained by continuously adjusting the p H instead of the traditional step-by-step method,which exhibited excellent performance in the catalytic oxidation of cyclopentene(CPE)to aldehydes or alcohols.The 93.69%CPE conversion and 97.15%total product selectivity(41.38%for glutaraldehyde(GA)and 55.77%for 1,2-cyclopentanediol(1,2-diol)were achieved by using H_(2)O_(2)as the oxidant and acetonitrile as the solvent.Through complementary characterization,it was found that the optimized di-lacunary silicotungstic polyoxometalate retained a complete Keggin structure,and exhibited better catalytic activity and stability than the mono-lacunary or saturated silicodecatungstate because it exposed more catalytic active centers.Furthermore,in situ FT-IR spectra was utilized to monitor the reaction process,revealing the formation of the active species W(O_(2))on the di-lacunary silicotungstic polyoxometalate and the intermediate epoxycyclopentane during the catalytic oxidation of cyclopentene. 展开更多
关键词 Lacunary silicotungstic heteropoly salts Cyclopentene(CPE) Catalytic oxidation Glutaraldehyde(GA) 1 2-Cyclopentanediol(1 2-diol)
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Research progress on protective coatings against molten nitrate salts for thermal energy storage in concentrating solar power plants
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作者 HOU Wenjie Maria Elena Navarro Rivero +4 位作者 PAN Jin ZOU Boyang Benjamin Grégoire Anabel Palacios DING Yulong 《Baosteel Technical Research》 CAS 2023年第4期1-16,共16页
Concentrating solar power(CSP) has garnered considerable global attention as a reliable means of generating bulk electricity, effectively addressing the intermittent nature of solar resources.The integration of molten... Concentrating solar power(CSP) has garnered considerable global attention as a reliable means of generating bulk electricity, effectively addressing the intermittent nature of solar resources.The integration of molten salt technology for thermal energy storage(TES) has further contributed to the growth of CSP plants;however, the corrosive nature of molten salts poses challenges to the durability of container materials, necessitating innovative corrosion mitigation strategies.This review summarizes scientific advancements in high-temperature anticorrosion coatings for molten nitrate salts, highlighting the key challenges and future trends.It also explores various coating types, including metallic, ceramic, and carbon-based coatings, and compares different coating deposition methods.This review emphasizes the need for durable coatings that meet long-term performance requirements and regulatory limitations, with an emphasis on carbon-based coatings and emerging nanomaterials.A combination of multiple coatings is required to achieve desirable anticorrosion properties while addressing material compatibility and cost considerations.The overall goal is to advance the manufacturing, assembly, and performance of CSP systems for increased efficiency, reliability, and durability in various applications. 展开更多
关键词 anticorrosive coating high temperature molten salt concentrated solar power thermal energy storage
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The source of lithium in Lakkor Co Salt Lake on Qinghai-Tibet Plateau,China:evidence from hydrochemical characteristics and boron isotope
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作者 Zheng Yan Li Bin Kai Li +2 位作者 Mao-Yong He Xue Qin Wen Jiang Di Zhou 《Acta Geochimica》 EI CAS CSCD 2024年第5期933-946,共14页
The availability of lithium resources is of great significance for the development of modern technologies,as well as for civil and military industries.The Qinghai-Tibet Plateau is a region known for its abundance of l... The availability of lithium resources is of great significance for the development of modern technologies,as well as for civil and military industries.The Qinghai-Tibet Plateau is a region known for its abundance of lithium-rich salt lakes.However,the specific origin of lithium in these lakes is still unknown,which hinders the advancement of the lithium resource business in this region.To research this issue,this study involved the collection of 20 samples from Lakkor Co Salt Lake on Qinghai-Tibet Plateau,encompassing samples of surface brine,cold springs,fresh lakes,and recharge rivers.The composition of anions and cations in these samples was determined.Furthermore,the analysis extensivelyutilizedthePiperthree-linediagram,Gibbs model,and ion proportion coefficient.The findings of this study indicate that as the moves from the recharge water system to salt lake,there is a transition in water type from strong carbonate to moderate carbonate and weak carbonate,as well as Na sulfate.This research based on a similar source of both lithium and boron,utilized ion correlation analysis and boron isotope study in the Lakkor Co area,and analyzed the source and transporting process of lithium.The main origin of lithium in Lakkor Co is the dissolution of lithiumrich rocks,recharge water systems,and deep hydrothermal fluids.These findings are highly significant in enhancing the foundational data of lithium-rich brine resources in the Qinghai-Tibet Plateau and are beneficial for assessing the future development of such deposits. 展开更多
关键词 LITHIUM Hydrochemical Li-rich salt lake Boron isotope
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Growth kinetics of titanium carbide coating by molten salt synthesis process on graphite sheet surface
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作者 Xiaoyu Shi Chongxiao Guo +4 位作者 Jiamiao Ni Songsong Yao Liqiang Wang Yue Liu Tongxiang Fan 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第8期1858-1864,共7页
The synthesis of carbide coatings on graphite substrates using molten salt synthesis(MSS),has garnered significant interest due to its cost-effective nature.This study investigates the reaction process and growth kine... The synthesis of carbide coatings on graphite substrates using molten salt synthesis(MSS),has garnered significant interest due to its cost-effective nature.This study investigates the reaction process and growth kinetics involved in MSS,shedding light on key aspects of the process.The involvement of Ti powder through liquid-phase mass transfer is revealed,where the diffusion distance and quantity of Ti powder play a crucial role in determining the reaction rate by influencing the C content gradient on both sides of the carbide.Furthermore,the growth kinetics of the carbide coating are predominantly governed by the diffusion behavior of C within the carbide layer,rather than the chemical reaction rate.To analyze the kinetics,the thickness of the carbide layer is measured with respect to heat treatment time and temperature,unveiling a parabolic relationship within the temperature range of 700-1300℃.The estimated activation energy for the reaction is determined to be 179283 J·mol^(-1).These findings offer valuable insights into the synthesis of carbide coatings via MSS,facilitating their optimization and enhancing our understanding of their growth mechanisms and properties for various applications. 展开更多
关键词 titanium carbide GRAPHITE molten salt kinetic analysis
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The transcription factor ZmNAC84 increases maize salt tolerance by regulating ZmCAT1 expression
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作者 Yitian Pan Tong Han +2 位作者 Yang Xiang Caifen Wang Aying Zhang 《The Crop Journal》 SCIE CSCD 2024年第5期1344-1356,共13页
Salt stress severely affects plant growth and yield.The transcription factor NAC plays a variety of important roles in plant abiotic stress,but we know relatively little about the specific molecular mechanisms of NAC ... Salt stress severely affects plant growth and yield.The transcription factor NAC plays a variety of important roles in plant abiotic stress,but we know relatively little about the specific molecular mechanisms of NAC in antioxidant defense.Here,our genetic studies reveal the positive regulation of salt tolerance in maize by the transcription factor ZmNAC84.Under salt stress,overexpression of ZmNAC84 in maize increased the expression of ZmCAT1,enhanced CAT activity,and consequently reduced H_(2)O_(2) accumulation,thereby improving salt stress tolerance in maize.Whereas RNA interference-mediated knockdown of ZmNAC84 produced the opposite effect.Subsequently,we found that ZmNAC84 directly binds to and regulates the expression of the ZmCAT1 promoter,and the hybridized material also demonstrated that ZmCAT1 is a downstream target gene of ZmNAC84.In addition,phenotypic and biochemical analyses indicated that ZmCAT1 positively regulated salt tolerance by regulating H_(2)O_(2) accumulation under salt stress.Taken together,these results reveal the function of ZmNAC84 in regulating ZmCAT1-mediated antioxidant defense in response to salt stress in plants. 展开更多
关键词 MAIZE ZmNAC84 ZmCAT1 salt stress
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Wild soybean(Glycine soja)transcription factor GsWRKY40 plays positive roles in plant salt tolerance
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作者 Minglong Li Man Xue +7 位作者 Huiying Ma Peng Feng Tong Chen Xiaohuan Sun Qiang Li Xiaodong Ding Shuzhen Zhang Jialei Xiao 《The Crop Journal》 SCIE CSCD 2024年第3期766-775,共10页
Wild soybean(Glycine soja),a relative of cultivated soybean,shows high adaptability to adverse environmental conditions.We identified and characterized a wild soybean transcription factor gene,GsWRKY40,that promotes p... Wild soybean(Glycine soja),a relative of cultivated soybean,shows high adaptability to adverse environmental conditions.We identified and characterized a wild soybean transcription factor gene,GsWRKY40,that promotes plant salt stress.GsWRKY40 was highly expressed in wild soybean roots and was up-regulated by salt treatment.GsWRKY40 was localized in nucleus and demonstrated DNA-binding activities but without transcriptional activation.Mutation and overexpression of GsWRKY40 altered salt tolerance of Arabidopsis plants.To understand the molecular mechanism of GsWRKY40 in regulating plant salt resistance,we screened a cDNA library and identified a GsWRKY40 interacting protein GsbHLH92 by using yeast two-hybrid approach.The physical interaction of GsWRKY40 and GsbHLH92 was confirmed by co-immunoprecipitation(co-IP),GST pull-down,and bimolecular fluorescence complementation(BiFC)techniques.Intriguingly,co-overexpression of GsWRKY40 and GsbHLH92 resulted in higher salt tolerance and lower ROS levels than overexpression of GsWRKY40 or GsbHLH92 in composite soybean plants,suggesting that GsWRKY40 and GsbHLH92 may synergistically regulate plant salt resistance through inhibiting ROS production.qRT-PCR data indicated that the expression level of GmSPOD1 gene encoding peroxidase was cooperatively regulated by GsWRKY40 and GsbHLH92,which was confirmed by using a dual luciferase report system and yeast one-hybrid experiment.Our study reveals a pathway that GsWRKY40 and GsbHLH92 collaboratively up-regulate plant salt resistance through impeding GmSPOD1 expression and reducing ROS levels,providing a novel perspective on the regulatory mechanisms underlying plant tolerance to abiotic stresses. 展开更多
关键词 Wild soybean Transcription factor salt stress ROS
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Different Approaches to Reduce Salinity in Salt-Affected Soils and Enhancing Salt Stress Tolerance in Plants
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作者 Amra Bratovcic 《Agricultural Sciences》 2024年第8期830-847,共18页
Salt stress is one of the most harmful environmental stresses in recent times and represents a significant threat to food security. Soil salinization is caused by spontaneous natural processes of mineral dissolution a... Salt stress is one of the most harmful environmental stresses in recent times and represents a significant threat to food security. Soil salinization is caused by spontaneous natural processes of mineral dissolution and human activities such as inappropriate irrigation practices. Natural geological progressions like weathering of rocks, arid climate, and higher evaporation, as well as anthropogenic activities, including the use of brackish water for irrigation, and poor tillage operations, are the foremost causes of soil salinization. Typical characteristics of saline soils are salt stress, high pH, and lack of organic carbon, as well as low availability of nutrients. Disruption of precipitation patterns as well as high average annual temperatures due to climate change additionally negatively affects the process of soil salinization. Productivity and ability to support crop growth are reduced on saline soil. Salinity-induced stress reduces plant growth by modulating the antioxidative system and nutrient orchestration. The aim of this work is to show that the mentioned problems can be alleviated in several ways such as the addition of biochar, exogenous application of several elicitors, seed priming, etc. Research has shown that the addition of biochar can significantly improve the recovery of saline soil. The addition of biochar has no significant effect on soil pH, while the cation exchange capacity of the soil increased by 17%, and the electrical conductivity of the saturated paste extract decreased by 13.2% (depends on the initial salinity and the type of biochar raw material). Moreover, biochar enriched with silicon increases the resistance of bananas to salt stress. In addition, exogenous application of several elicitors helps plants to alleviate stress by inducing stress-related physicochemical and molecular changes (selenium, sulfur, silicon, salicylic acid). Finally, seed priming showed positive effects on metabolomics, proteomics and growth of plants subjected to abiotic stress. Priming usually involves immersing the seed in a solution for a period of time to induce physiological and metabolic progression prior to germination. 展开更多
关键词 salt-Affected Soils salt Stress BIOCHAR ELICITORS Seed Priming
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