Controlled polymerization of N-n-propylacrylamide was achieved by atom transfer radical polymerization(ATRP) in a N,N-dimethylformamide-water mixture(50 vol%)at room temperature with methyl 2-chloropropinonate as init...Controlled polymerization of N-n-propylacrylamide was achieved by atom transfer radical polymerization(ATRP) in a N,N-dimethylformamide-water mixture(50 vol%)at room temperature with methyl 2-chloropropinonate as initiator and CuCl/tris(2-dimethylaminoethyl)amine as the catalytic system in a ratio of 1:1:1.High molecular weight homopolymers(up to 3.7×10~4)with narrow molecular weight distribution(less than 1.2)were obtained.The living character of the polymerization was further demonstrated by self-blocking...展开更多
基金This work was supported by the National Natural Science Foundation of China through Young Investigator Award(No.20328407)Nankai University,and the Canada Research Chair program.
文摘Controlled polymerization of N-n-propylacrylamide was achieved by atom transfer radical polymerization(ATRP) in a N,N-dimethylformamide-water mixture(50 vol%)at room temperature with methyl 2-chloropropinonate as initiator and CuCl/tris(2-dimethylaminoethyl)amine as the catalytic system in a ratio of 1:1:1.High molecular weight homopolymers(up to 3.7×10~4)with narrow molecular weight distribution(less than 1.2)were obtained.The living character of the polymerization was further demonstrated by self-blocking...
