Bis diphenyl 22 and 11 Membered Ring N pivot lariat Crown Ethers were prepared by one step reaction of 2,2' dihydroxy diphenyl with N tosyl diethanolamine ditoskylate in DMF at refluxing tem perature unde...Bis diphenyl 22 and 11 Membered Ring N pivot lariat Crown Ethers were prepared by one step reaction of 2,2' dihydroxy diphenyl with N tosyl diethanolamine ditoskylate in DMF at refluxing tem perature under N z,Using anhydrous potassium carbonate as condensing agent,respectirely.The tosyl group of(1,2) were removed by treatment with 40%HBr in AcoH in the presence gf a large amount of phenol to give correspondence crown ether compounds(3,4).New N pirot lariat crown thers(5,6)were prepared by one step reaction of(3)with RBr(R=-CH 2CH=CH 2,-CH 2(CH 2) 14 CH 3) in CH 3CN at refluxing temperature under N 2,Using anhydrous K 2CO 3 as condensing agent.New N pivot lariat croon ether(7) were prepared by one step reaction (4)with n bromohexadecane in CH 3CN at refluxing temperature under N 2, Using anhydrous potassium carbonate as condensing agent.New compounds(1,3,5,6,7)were characterized by IR,, 1H NMR,Ms and elemental analysis.展开更多
Diaza Crown ethers are versatile complexing reagents, their complexing abilities are dramatically modified by the electron donating atoms on substituents attached to the nitrogen if they can give a three-dimensional c...Diaza Crown ethers are versatile complexing reagents, their complexing abilities are dramatically modified by the electron donating atoms on substituents attached to the nitrogen if they can give a three-dimensional cavity as in cryptates. Hence the synthesis and characterization of bibracchial lariat ethers (BIBLES) have received much attention. In the preparation of new BIBLES, a complex Ⅱ was unexpectedly obtained.展开更多
文摘Bis diphenyl 22 and 11 Membered Ring N pivot lariat Crown Ethers were prepared by one step reaction of 2,2' dihydroxy diphenyl with N tosyl diethanolamine ditoskylate in DMF at refluxing tem perature under N z,Using anhydrous potassium carbonate as condensing agent,respectirely.The tosyl group of(1,2) were removed by treatment with 40%HBr in AcoH in the presence gf a large amount of phenol to give correspondence crown ether compounds(3,4).New N pirot lariat crown thers(5,6)were prepared by one step reaction of(3)with RBr(R=-CH 2CH=CH 2,-CH 2(CH 2) 14 CH 3) in CH 3CN at refluxing temperature under N 2,Using anhydrous K 2CO 3 as condensing agent.New N pivot lariat croon ether(7) were prepared by one step reaction (4)with n bromohexadecane in CH 3CN at refluxing temperature under N 2, Using anhydrous potassium carbonate as condensing agent.New compounds(1,3,5,6,7)were characterized by IR,, 1H NMR,Ms and elemental analysis.
基金Supported by the National Natural Science foundation of China Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics, Academic Soinica, Wuhan
文摘Diaza Crown ethers are versatile complexing reagents, their complexing abilities are dramatically modified by the electron donating atoms on substituents attached to the nitrogen if they can give a three-dimensional cavity as in cryptates. Hence the synthesis and characterization of bibracchial lariat ethers (BIBLES) have received much attention. In the preparation of new BIBLES, a complex Ⅱ was unexpectedly obtained.
