A novel three dimensional fluorinated gallium phosphate has been hydrothermally synthesized by using diethylenetriamine as an organic structure directing agent. X ray single crystal structure analysis indicates this c...A novel three dimensional fluorinated gallium phosphate has been hydrothermally synthesized by using diethylenetriamine as an organic structure directing agent. X ray single crystal structure analysis indicates this compound crystallizes in the orthorhombic space group Pbca, a =1.605 6(7) nm, b = 1 011 4 (4) nm, c =1.854 6(5) nm, V =3.011 6(19) nm 3, Z =4. The three dimensional framework based on linkage of corner sharing polyhedron PO 4, GaO 4F and GaO 4F 2 delimit ten ring channels along b axis in which the triply protonated amines are located serving as charge compensating guests and supporters.展开更多
文摘以固体A l2(SO4)3.nH2O为催化剂,在微波辐射下,以α-萘乙酸和甲醇为原料合成了α-萘乙酸甲酯。考察了催化剂的用量、微波功率、微波辐射时间、醇酸比对酯产率的影响。实验结果表明,最佳实验条件为:催化剂用量6%,微波功率600 W,微波辐射时间28 m in,醇酸摩尔比12∶1,酯产率72.45%。
文摘A novel three dimensional fluorinated gallium phosphate has been hydrothermally synthesized by using diethylenetriamine as an organic structure directing agent. X ray single crystal structure analysis indicates this compound crystallizes in the orthorhombic space group Pbca, a =1.605 6(7) nm, b = 1 011 4 (4) nm, c =1.854 6(5) nm, V =3.011 6(19) nm 3, Z =4. The three dimensional framework based on linkage of corner sharing polyhedron PO 4, GaO 4F and GaO 4F 2 delimit ten ring channels along b axis in which the triply protonated amines are located serving as charge compensating guests and supporters.
基金Postdoctoral Science Foundation of China(2012M520605)Research Foundation of Taiyuan University of Technology(tyut-rc201369a,2013Z040)+1 种基金Open Foundation of State Key Laboratory of Coal Conversion(09-102)Natural Science Foundation of Shanxi Province(2013011042-1)
