Natural mordenite （NMOR）, modified by acid treatment and ion-exchange, was employed for NO adsorption in the present study. The NO storage capacity of modified NMOR was greatly improved compared with its original co...Natural mordenite （NMOR）, modified by acid treatment and ion-exchange, was employed for NO adsorption in the present study. The NO storage capacity of modified NMOR was greatly improved compared with its original correspondents, mainly due to the preservation of crystalline structure and the improvement of surface area of NMOR. Among all the modified NMOR, Ni-NMOR exhibited the highest adsorption capacity for NO （1.20 mmol-g^ 1） in the presence of 10% 02 at 308 K. The influence of the main ingredients in flue gas on the storage capacity of NMOR for NO had also been investigated. In general, H2O, CO2 and SO2 all displayed negative impact on NO adsorption due to their competitive adsorption on the surface of NMOR with NO, while the presence of 02 greatly improved the adsorption of NO because of the formation of NO2 and N203. Moreover, Ni-NMOR exhibited high efficiency for NOx removal through the NOx adsorption-plasma discharge process.展开更多
An experimental and model-based study of the effect of rich air/fuel ratios(AFRs) and temperature on the NOx slip of a lean NOx trap(LNT) was conducted in a lean-burn gasoline engine with an LNT after-treatment system...An experimental and model-based study of the effect of rich air/fuel ratios(AFRs) and temperature on the NOx slip of a lean NOx trap(LNT) was conducted in a lean-burn gasoline engine with an LNT after-treatment system. The emissions of the engine test bench and the inlet temperature of the LNT were used as the major inlet boundary conditions of the LNT. The engine periodically operated between a constant lean AFR of 23 with alterable rich AFRs of 10, 11, 12, 13, and 14. A decrease in the rich AFR of the engine strengthened the desorption atmosphere in the LNT, an effect closely related to the number of reductants, and further heightened the NOx desorption of the LNT, but with a penalty in fuel consumption. To eliminate that penalty, the inlet boundary conditions of the LNT were varied by adjusting the inlet temperature within a range between 200℃ and 400℃. An increase in inlet temperature heightened the NOx desorption of the LNT, and a NOx breakthrough occurred after the inlet temperature exceeded 390℃. To control NOx breakthrough, the inlet temperature can be adjusted to offset the strong desorption atmosphere in the LNT commonly created by a rich AFR.展开更多
基金Supporting information for this article is available on the WWW under http：//dx.doi.org/10.1002/cjoc.201200102 or from the authorAcknowledgement This work was financially supported by the Major Project of Zhejiang Province （No. 2009Cl1141）, the National Natural Science Foundation of China （No. 20977080） and the Natural Science Foundation of Zhejiang Province （No. J20091504）. We are also grateful to the assistance from Xiamen University for the situ-FI-IR test.
文摘Natural mordenite （NMOR）, modified by acid treatment and ion-exchange, was employed for NO adsorption in the present study. The NO storage capacity of modified NMOR was greatly improved compared with its original correspondents, mainly due to the preservation of crystalline structure and the improvement of surface area of NMOR. Among all the modified NMOR, Ni-NMOR exhibited the highest adsorption capacity for NO （1.20 mmol-g^ 1） in the presence of 10% 02 at 308 K. The influence of the main ingredients in flue gas on the storage capacity of NMOR for NO had also been investigated. In general, H2O, CO2 and SO2 all displayed negative impact on NO adsorption due to their competitive adsorption on the surface of NMOR with NO, while the presence of 02 greatly improved the adsorption of NO because of the formation of NO2 and N203. Moreover, Ni-NMOR exhibited high efficiency for NOx removal through the NOx adsorption-plasma discharge process.
基金Project supported by the National Natural Science Foundation of China(Nos.50276042,50776062,and 51276128)the National High Technology R&D Program (863) of China(No.2008AA06Z322)the Tianjin Research Program of Application Foundation and Advanced Technology(No.11JCZDJC23200),China
文摘An experimental and model-based study of the effect of rich air/fuel ratios(AFRs) and temperature on the NOx slip of a lean NOx trap(LNT) was conducted in a lean-burn gasoline engine with an LNT after-treatment system. The emissions of the engine test bench and the inlet temperature of the LNT were used as the major inlet boundary conditions of the LNT. The engine periodically operated between a constant lean AFR of 23 with alterable rich AFRs of 10, 11, 12, 13, and 14. A decrease in the rich AFR of the engine strengthened the desorption atmosphere in the LNT, an effect closely related to the number of reductants, and further heightened the NOx desorption of the LNT, but with a penalty in fuel consumption. To eliminate that penalty, the inlet boundary conditions of the LNT were varied by adjusting the inlet temperature within a range between 200℃ and 400℃. An increase in inlet temperature heightened the NOx desorption of the LNT, and a NOx breakthrough occurred after the inlet temperature exceeded 390℃. To control NOx breakthrough, the inlet temperature can be adjusted to offset the strong desorption atmosphere in the LNT commonly created by a rich AFR.
