To determine the nucleation region location of Si nano-crystal grains, pulsed laser ablation of Si target is performed in Ar gas of 10 Pa at room temperature with laser fluence of 4 J/cm2, the substrates are located h...To determine the nucleation region location of Si nano-crystal grains, pulsed laser ablation of Si target is performed in Ar gas of 10 Pa at room temperature with laser fluence of 4 J/cm2, the substrates are located horizontal under ablation spot with different vertical distance. Characteristics of deposited grains are described by scanning electron microscopy, Raman scattering and X-ray diffraction spectra, the results indicate that deposition position on substrates in a certain range is relative to target surface, which changes according to different vertical distance of substrates to ablation spot. Grain size increased?at first and then decreased with addition of lateral distances to target in the range, but the integral distribution rule was independent of position of substrates. Combining with hydrodynamics model, nucleation division model, thermokinetic equation and flat parabolic motion, spatial nucleation region location of grains is obtained through numerical calculations, which is 2.7 mm-43.2 mm to target surface along the plume axis.展开更多
A low temperature preparation of nano TiO2 using sol-gel method was proposed. The antibacterial properties of the treatment solution and the treated cotton fabrics obtained via a dip-padding process were evaluated. XR...A low temperature preparation of nano TiO2 using sol-gel method was proposed. The antibacterial properties of the treatment solution and the treated cotton fabrics obtained via a dip-padding process were evaluated. XRD pattern shows that the nano TiO2 produced is an anatase phase. Aqueous nano-dispersion of the nano TiO2 exhibites positive results as an antibacterial finishing agent for cotton fabrics. The treatment solution possesses antibacterial rates of over 92% and 88.9% against Escherichia coli and Bacillus subtilis,respectively. The treated fabrics are slightly downgraded but still maintained over 89% and 83% of reduction towards the same bacteria. After washing for 50 times,the antibacterial performances of the treated fabric still remains at a relatively high level,indicating the durable characteristic of nano TiO2 treatment.展开更多
Grain evolution of nano-crystals ZnO under high temperature and pressure is studied using a cubic high pressure apparatus. The structure, grain sizes and morphology of the samples are characterized by X-ray diffractio...Grain evolution of nano-crystals ZnO under high temperature and pressure is studied using a cubic high pressure apparatus. The structure, grain sizes and morphology of the samples are characterized by X-ray diffraction and field emission scanning electron microscopy. The results show that the grain sizes of ZnO grow rapidly at temperature 200℃ under pressure. At temperature lower than 300 ℃ (including 300 ℃), the grain sizes of the samples first increase with the pressure increasing from 1 to 3 GPa and later de- crease from 4 to 6 GPa. The activation volume from 1 to 3 GPa and from 4 to 6 GPa is calculated respectively using the phenomenological kinetic grain growth equation at temperature 300 ℃. At temperature higher than 400℃ (including 400 ℃), the grain sizes of the samples increase with the pressure increasing from 1 to 6 GPa. ZnO nano-bulks with good quality can be obtained under the specific conditions.展开更多
文摘To determine the nucleation region location of Si nano-crystal grains, pulsed laser ablation of Si target is performed in Ar gas of 10 Pa at room temperature with laser fluence of 4 J/cm2, the substrates are located horizontal under ablation spot with different vertical distance. Characteristics of deposited grains are described by scanning electron microscopy, Raman scattering and X-ray diffraction spectra, the results indicate that deposition position on substrates in a certain range is relative to target surface, which changes according to different vertical distance of substrates to ablation spot. Grain size increased?at first and then decreased with addition of lateral distances to target in the range, but the integral distribution rule was independent of position of substrates. Combining with hydrodynamics model, nucleation division model, thermokinetic equation and flat parabolic motion, spatial nucleation region location of grains is obtained through numerical calculations, which is 2.7 mm-43.2 mm to target surface along the plume axis.
基金Project (06YFJMJC02700) supported by Municipal Natural Science Foundation of Tianjin, China
文摘A low temperature preparation of nano TiO2 using sol-gel method was proposed. The antibacterial properties of the treatment solution and the treated cotton fabrics obtained via a dip-padding process were evaluated. XRD pattern shows that the nano TiO2 produced is an anatase phase. Aqueous nano-dispersion of the nano TiO2 exhibites positive results as an antibacterial finishing agent for cotton fabrics. The treatment solution possesses antibacterial rates of over 92% and 88.9% against Escherichia coli and Bacillus subtilis,respectively. The treated fabrics are slightly downgraded but still maintained over 89% and 83% of reduction towards the same bacteria. After washing for 50 times,the antibacterial performances of the treated fabric still remains at a relatively high level,indicating the durable characteristic of nano TiO2 treatment.
基金This work was supported by the National Natural Science Foundation of China(Grant No.50171059)Hebei Provincial Fund(Grant No.B2004000189) Hebei Education Fund(Grant No.2005309).
文摘Grain evolution of nano-crystals ZnO under high temperature and pressure is studied using a cubic high pressure apparatus. The structure, grain sizes and morphology of the samples are characterized by X-ray diffraction and field emission scanning electron microscopy. The results show that the grain sizes of ZnO grow rapidly at temperature 200℃ under pressure. At temperature lower than 300 ℃ (including 300 ℃), the grain sizes of the samples first increase with the pressure increasing from 1 to 3 GPa and later de- crease from 4 to 6 GPa. The activation volume from 1 to 3 GPa and from 4 to 6 GPa is calculated respectively using the phenomenological kinetic grain growth equation at temperature 300 ℃. At temperature higher than 400℃ (including 400 ℃), the grain sizes of the samples increase with the pressure increasing from 1 to 6 GPa. ZnO nano-bulks with good quality can be obtained under the specific conditions.
