Dynamics of major picoplankton groups, Synechococcus (Syn), Prochlorococcus (Pro), picoeukaryotes (Euk) and heterotrophic bacteria (Bact) was investigated by flow cytometry for the first time in the Nansha Islands are...Dynamics of major picoplankton groups, Synechococcus (Syn), Prochlorococcus (Pro), picoeukaryotes (Euk) and heterotrophic bacteria (Bact) was investigated by flow cytometry for the first time in the Nansha Islands area in the South China Sea. Averaged over the whole investigation area, depth-weighted integrated cell abundance (DWA) of Syn, Pro, Euk and Bact was 1.6 (0.4-5.7)×103, 5.4 (0.1-7.3)×104, 0.7 (0.2-2.2)×103, and 2.3 (1.4-3.2)×105 cells/mL respectively. Picoautotrophic cell abundance was low in the northwest part of the Nansha Islands where surface water temperature was low and the upper mixed layer was shallow. Concurrently, a surface maximum vertical distribution pattern was observed in this area. While in the southeast and east zones where temperatures were relatively higher and nitraclines were deeper, picoplankton is abundant and a subsurface maximum around 50-75 m is observed. Coupling of horizontal and vertical distribution patterns of picoplankton abundance and hydrological status was found, suggesting a strong influence of currents and water column structure on picoplankton distribution in the investigation area. Contrary to that in the shelf water in the East China Sea, the relationship between Pro and Bact in the Nansha Islands area in the South China Sea was not significantly negative but weakly positive. Moreover, a similar distribution pattern of Syn and Pro was observed. Possible reasons for these differences in the two marine regimes were discussed.展开更多
The area of the southwestern Nansha Trough is one of the most productive areas of the southern South China Sea.It is a typical semi-deep sea area of transition from shoal to abyssal zone.To understand distributions an...The area of the southwestern Nansha Trough is one of the most productive areas of the southern South China Sea.It is a typical semi-deep sea area of transition from shoal to abyssal zone.To understand distributions and roles of nitrogen forms involved in biogeochemical cycling in this area,contents of nitrogen in four extractable forms:nitrogen in ion exchangeable form(IEF-N),nitrogen in weak acid extractable form(WAEF-N),nitrogen in strong alkali extractable form(SAEF-N) and nitrogen in strong oxidation extractable form(SOEF-N),as well as in total nitrogen content(TN) in surface sediments were determined from samples collected from the cruise in April-May 1999.The study area was divided into three regions(A,B and C) in terms of clay sediment(<4 μm) content at <40%,40%-60% and >60%,respectively.Generally,region C was the richest in the nitrogen of all forms and region A the poorest,indicating that the finer the grain size is,the richer the contents of various nitrogen are.The burial efficiency of total nitrogen in surface sediments was 28.79%,indicating that more than 70% of nitrogen had been released and participated in biogeochemical recycling through sediment-water interface.展开更多
Layer-block tectonics (LBT) concept, with the core of pluralistic geodynamic outlook and multilayer-sliding tectonic outlook, is one of new keys to study 3-dimensional solid and its 4-dimensional evolution history o...Layer-block tectonics (LBT) concept, with the core of pluralistic geodynamic outlook and multilayer-sliding tectonic outlook, is one of new keys to study 3-dimensional solid and its 4-dimensional evolution history of global tectonic system controlled by global geodynamics system. The LBT concept is applied to study the lithospheric tectonics of the southern South China Sea (SCS). Based on the analysis of about 30 000 km of geophysical and geological data, some layer-blocks in the Nansha micro-plate can be divided as Nansha ultra-crustal layer-block, Zengmu crustal layer-block, Nanwei (Rifleman bank)-Andu (Ardasier bank) and Liyue (Reed bank) North Palawan crustal layer-blocks, Andu-Bisheng and Liyue-Banyue basemental layer-blocks. The basic characteristics of the basemental layer-blocks have been dicussed, and three intra-plate basin groups are identified. The intra-plate basins within Nansha micro-plate can be divided into three basin groups of Nanwei- Andu, Feixin-Nanhua, and Liyue-North Palawan based on the different geodynamics. In the light of pluralistic geodynamic concept, the upheaving force induced by the mid-crust plastic layer is proposed as the main dynamical force which causes the formation of the intra-plate basins within the Nansha micro-plate. Finally, models of a face-to-face dip-slip detachment of basemental layerblock and a unilateral dip-slip-detachment of basemental layer-block are put forward for the forming mechanisms of the Nanwei Andu and Liyue-North Palawan intra-plate basin groups, respectively.展开更多
It is exceedingly important to estimate the stability of coral reefs. In recent years, growing construction projects have been carried out on the reef flat in the South China Sea. As a special marine geotechnical medi...It is exceedingly important to estimate the stability of coral reefs. In recent years, growing construction projects have been carried out on the reef flat in the South China Sea. As a special marine geotechnical medium, it is made of the reef debris underwent overwhelmingly long geological age. Reefs grow thickly on the carbonate platform after the Late Oligocene and have five to six main sedimentary facies. It can be used as a recorder to measure the occurrence time of recent earthquake. A model of reef body is presented to study the influence of earthquakes according to the geological structure characteristic of reefs in the Nansha Islands. Furthermore, Geo Studio is used to simulate stress and deformation situations within it under various earthquake intensities. A safety factor is calculated by the limit equilibrium method, and the possible scenarios of earthquake-induced landslides and sliding scale are defined with a Newmark sliding block method, as well as stress distribution and deformation behaviors. Therefore, the numerical results suggest that the connections between the coral reef and the earthquake are as follows:(1) the reef body has a good stability under self-gravity state;(2) after the earthquake, it may cause slope's instability and bring out slumping when the safety factor is smaller than 1(FS〈1);(3) the safety factor decreases with the increasing earthquake intensity, and fluctuates around a particular value after a while;and(4) as a new developed part of the reef, the smaller shallow landslide will be easily subject to collapse caused by the earthquake. It is concluded that it is feasible to provide a reference for evaluating the stability of coral reef using a geotechnical engineering simulation method. This can help the engineering constructions in the South China Sea.展开更多
There are rich natural gas resources in the northwestern South China Sea deepwater areas, with poor degree of exploration. Because of the unique tectonic, sedimentary background of the region, velocity model building ...There are rich natural gas resources in the northwestern South China Sea deepwater areas, with poor degree of exploration. Because of the unique tectonic, sedimentary background of the region, velocity model building and time-depth conversion have been an important and difficult problem for a long time. Recent researches in this direction have revealed three major problems for deepwater areas, i.e., the way to determine error correction for drilling velocity, the optimization of velocity modeling, and the understanding and analysis of velocity variations in the slope areas. The present contribution proposes technical solutions to the problems:(1) velocity correction version can be established by analyzing the geology, reservoir, water depths and velocity spectrum characteristics;(2) a unified method can be adopted to analyze the velocity variation patterns in drilled pale structural positions;and (3) across-layer velocity is analyzed to establish the velocity model individually for each of the layers. Such a solution is applicable, as shown in an example from the northwestern South China Sea deepwater areas, in which an improved prediction precision is obtained.展开更多
Concentrations of organic matter, iron and manganese in the deep sea surface sediments in the Nansha Islands sea area, South China Sea are measured. Horizontal and vertical distributions of iron and manganese are disc...Concentrations of organic matter, iron and manganese in the deep sea surface sediments in the Nansha Islands sea area, South China Sea are measured. Horizontal and vertical distributions of iron and manganese are discussed. The vertical distribution of iron and manganese in the sediments results from reduction, diffusion, and redeposition of manganese (or iron) oxide and hydroxide in the sediment. There are the maxima of iron and manganese in solid phase in the top of the sediment, which is caused by the penetration of O2 and the upward flux of Mn2+ ( or Fe2+ ). Manganese bacteria play a very important role in the cycle of solid-phase iron and manganese in the ocean environment. Manganese bacteria oxidize Mn2+ ( or Fe2+ ) in dissolved state to Mn4+ ( or Fe3+ ) in oxidized state under the aerobic condition, whereas they reduce iron and manganese in anaerobic conditions.展开更多
The diffusion attenuation coefficient for downwelling irradiance, Kd (490), is an important optical parameter of seawater. The optical property, Kd (490), around Nansha Islands in the South China Sea was analyzed base...The diffusion attenuation coefficient for downwelling irradiance, Kd (490), is an important optical parameter of seawater. The optical property, Kd (490), around Nansha Islands in the South China Sea was analyzed based on optical data profiles measured with SPMR ( SeaWiFS Profiling Multichannel Radiometer ) and SMSR ( SeaWiFS Multichannel Surface Reference ) instrument in April and May, 1999. The results show that Kd (490) is closely correlated with chlorophyll-a concentration, Cchl.a, and that the vertical distribution of Kd (490) shows the strong stratification of the water column in this area. Kd (490) has a similar vertical co-variation as KL (490), the diffusive attenuation coefficient for upwelling radiance. Both coefficients increase with depth in the upper layer, where KL (490) is greater than Kd (490); and after a depth, approximatively at the chlorophyll maximum, they decrease with depth, with the former being smaller than the latter.展开更多
The undrained shear strength of shallow strata is a critical parameter for safety design in deep-water operations.In situ piezocone penetration tests(CPTU) and laboratory experiments are performed at Site W18-19 in th...The undrained shear strength of shallow strata is a critical parameter for safety design in deep-water operations.In situ piezocone penetration tests(CPTU) and laboratory experiments are performed at Site W18-19 in the Shenhu area, northern South China Sea, where China's first marine hydrate exploitation operation is due to be located. The validation of the undrained shear strength prediction model based on CPTU parameters. Different laboratory tests, including pocket penetrometer, torvane, miniature vane and unconsolidated undrained triaxial tests, are employed to solve empirical cone coefficients by statistical and mathematical methods. Finally, an optimized model is proposed to describe the longitudinal distribution of undrained shear strength in calcareous clay strata in the Shenhu area. Research results reveal that average empirical cone coefficients based on total cone resistance, effective resistance, and excess-pore pressure are 13.8, 4.2 and 14.4, respectively. The undrained shear strength prediction model shows a good fit with the laboratory results only within specific intervals based on their compaction degree and gas-bearing conditions. The optimized prediction model in piecewise function format can be used to describe the longitudinal distribution of the undrained shear strength for calcareous clay within all depth intervals from the mud-line to the upper boundary of hydrate-bearing sediments(HBS). The optimized prediction result indicates that the effective cone resistance model is suitable for very soft to firm calcareous clays,the excess-pore pressure model can depict the undrained shear strength for firm to very stiff but gas-free clays,while the total cone resistance model is advantageous for evaluating the undrained shear strength for very stiff and gassy clays. The optimized model in piecewise function format can considerably improve the adaptability of empirical models for calcareous clay in the Shenhu area. These results are significant for safety evaluations of proposed hydrate exploitation projects.展开更多
The first marine gas hydrate expedition in China has been conducted by Guangzhou Marine Geological Survey in the Shenhu Area, northern continental slope of the South China Sea. Previous study has analyzed the P-T cond...The first marine gas hydrate expedition in China has been conducted by Guangzhou Marine Geological Survey in the Shenhu Area, northern continental slope of the South China Sea. Previous study has analyzed the P-T conditions, geophysical anomalies and saturation calculations of these gas hydrates, but has not documented in detail the migration of gas-bearing fluids in the study area. Based on the interpretations of 2D/3D seismic data, this work identified two types of migration pathways for gas-bearing fluids in the Shenhu area, i.e., vertical and lateral pathways. The vertical pathways(largescale faults, gas chimneys and mud diapirs) presented as steep seismic reflection anomalies, which could be traced downward to the Eocene source rocks and may penetrate into the Late Miocene strata. The deeper gases/fluids might be allowed migrating into the shallower strata through these vertical conduits. However, the distributions showed distinct differences between these pathways. Large-scale faults developed only in the north and northeast of the Shenhu area, while in the drilling area gas chimneys were the sole vertical migration pathways. Since the Pliocene, normal faults, detachment faults and favorable sediments have constituted the lateral pathways in the Shenhu gas hydrate drilling area. Although these lateral pathways were connected with gas chimneys, they exerted different effects on hydrate formation and accumulation. Gas-bearing fluids migrated upward along gas chimneys might further migrate laterally because of the normal faults, thereby enlarging the range of the chimneys. Linking gas chimneys with the seafloor, the detachment faults might act as conduits for escaping gases/fluids. Re-deposited sediments developed at the early stage of the Quaternary were located within the gas hydrate stability zone, so hydrates would be enriched in these favorable sediments. Compared with the migration pathways(large-scale faults and mud diapirs) in the LW3-1 deep-sea oil/gas field, the migration efficiency of the vertical pathways(composed of gas chimneys) in the gas hydrate drilling area might be relatively low. Description and qualitative discrimination of migration pathways in the Shenhu gas hydrate drilling area are helpful to further understand the relationship between good-quality deep source rocks and shallow, mainly biogenicallyproduced, hydrates. As the main source rocks of the Baiyun sag, lacustrine mudstones in the Wenchang and Enping Formations may provide thermogenic methane. Gas chimneys with relatively low migration efficiency created the vertical pathways. Caused by the Dongsha tectonic movement, the release of overpressured fluids might reduce the vertical migration rates of the thermogenic methane. The thick bathyal/abyssal fine-grained sediments since the Late Miocene provided migration media with low permeability. These preconditions may cause carbon isotopic fractionation ofthermogenic methane during long-distance vertical migrations. Therefore, although geochemical analyses indicate that the methane forming gas hydrate in the Shenhu area was mainly produced biogenically, or was mixed methane primarily of microbial origin, thermogenic methane still contribute significantly.展开更多
BSR (Bottom Simulating Reflector) occurs widely in the strata since the late Miocene in the deep-water area of the northern continental slope of South China Sea (SCS). It is an important seismic reference mark whi...BSR (Bottom Simulating Reflector) occurs widely in the strata since the late Miocene in the deep-water area of the northern continental slope of South China Sea (SCS). It is an important seismic reference mark which identifies the gas hydrate and its distribution influenced by the tectonic movements. Single-point basin modeling was conducted using 473 points in the study area. To discuss the relationships between the tectonic subsidence and BSR, the volume and rate of tectonic subsidence in each geological time have been simulated. The results show that there are three tectonic accelerate subsidence processes in the study area since the late Miocene, especially since 1.8Ma the tectonic subsidence accelerates more apparently. Since the Late Miocene to Pleistocene, the rate of tectonic subsidence in deep-water underwent a transformation from weak to strong. The ratio of tectonic subsidence to the total subsidence was relatively high (65-70%). Through the superposition of the BSR developed areas and the contours of tectonic subsidence in this area, it was discovered that more than 80% of BSR tend to be distributed at the slope break or depression-uplift structural transfer zone and the average tectonic subsidence rate ranges from 70 m/Ma to 125 m/Ma.展开更多
Shenhu Area is located in the Baiyun Sag of Pearl River Mouth Basin,which is on the northern continental slope of the South China Sea.Gas hydrates in this area have been intensively investigated,achieving a wide cover...Shenhu Area is located in the Baiyun Sag of Pearl River Mouth Basin,which is on the northern continental slope of the South China Sea.Gas hydrates in this area have been intensively investigated,achieving a wide coverage of the three-dimensional seismic survey,a large number of boreholes,and detailed data of the seismic survey,logging,and core analysis.In the beginning of 2020,China has successfully conducted the second offshore production test of gas hydrates in this area.In this paper,studies were made on the structure of the hydrate system for the production test,based on detailed logging data and core analysis of this area.As to the results of nuclear magnetic resonance(NMR)logging and sonic logging of Well GMGS6-SH02 drilled during the GMGS6 Expedition,the hydrate system on which the production well located can be divided into three layers:(1)207.8–253.4 mbsf,45.6 m thick,gas hydrate layer,with gas hydrate saturation of 0–54.5%(31%av.);(2)253.4–278 mbsf,24.6 m thick,mixing layer consisting of gas hydrates,free gas,and water,with gas hydrate saturation of 0–22%(10%av.)and free gas saturation of 0–32%(13%av.);(3)278–297 mbsf,19 m thick,with free gas saturation of less than 7%.Moreover,the pore water freshening identified in the sediment cores,taken from the depth below the theoretically calculated base of methane hydrate stability zone,indicates the occurrence of gas hydrate.All these data reveal that gas hydrates,free gas,and water coexist in the mixing layer from different aspects.展开更多
Bottom acoustic parameters play an important role in sound field prediction. Acoustic parameters in deep water are not well understood. Bottom acoustic parameters are sensitive to the transmission-loss (TL) data in ...Bottom acoustic parameters play an important role in sound field prediction. Acoustic parameters in deep water are not well understood. Bottom acoustic parameters are sensitive to the transmission-loss (TL) data in the shadow zone of deep water. We propose a multiple-step fill inversion method to invert sound speed, density and attenuation in deep water. Based on a uniform liquid hMf-space bottom model, sound speed of the bottom is inverted by using the long range TL at low frequency obtained in an acoustic propagation experiment conducted in the South China Sea (SCS) in summer 2014. Meanwhile, bottom density is estimated combining with the Hamilton sediment empirical relationship. Attenuation coefficients at different frequencies are then estimated from the TL data in the shadow zones by using the known sound speed and density as a constraint condition. The nonlinear relationship between attenuation coefficient and frequency is given in the end. Tile inverted bottom parameters can be used to forecast the transmission loss in the deep water area of SCS very we//.展开更多
The global carbon cycle has played a key role in mitigating global warming and climate change.Long-term natural and anthropogenic processes influence the composition,sources,burial rates,and fluxes of carbon in sedime...The global carbon cycle has played a key role in mitigating global warming and climate change.Long-term natural and anthropogenic processes influence the composition,sources,burial rates,and fluxes of carbon in sediments on the continental shelf of China.In this study,the rates,fluxes,and amounts of carbon storage at the centennial scale were estimated and demonstrated using the case study of three fine-grained sediment cores from the central South Yellow Sea area(SYSA) and Min-Zhe belt(MZB),East China Sea.Based on the high-resolution temporal sequences of total carbon(TC)and total organic carbon(TOC)contents,we reconstructed the annual variations of historical marine carbon storage,and explored the influence of terrestrial and marine sources on carbon burial at the centennial scale.The estimated TC storage over 100 years was 1.18×10~8 t in the SYSA and 1.45×10~9 t in the MZB.The corrected TOC storage fluxes at the centennial scale ranged from 17 to 28 t/(km^2·a)in the SYSA and from 56 to 148 t/(km^2·a)in the MZB.The decrease of terrestrial materials and the increase of marine primary production suggest that the TOC buried in the sediments in the SYSA and MZB was mainly derived from the marine autogenetic source.In the MZB,two depletion events occurred in TC and TOC storage from 1985 to 1987 and 2003 to 2006,which were coeval with the water impoundment in the Gezhouba and Three Gorges dams,respectively.The high-resolution records of the carbon storage rates and fluxes in the SYSA and MZB reflect the synchronous responses to human activities and provide an important reference for assessing the carbon sequestration capacity of the marginal seas of China.展开更多
Previous work has largely discussed the relations between sediment structures and accumulation of gas hydrates in the Shenhu area of South China Sea, but has not documented why the gas hydrates occurred at the seafloo...Previous work has largely discussed the relations between sediment structures and accumulation of gas hydrates in the Shenhu area of South China Sea, but has not documented why the gas hydrates occurred at the seafloor topographic highs. Many gas hydrate exploration examples abroad also indicate that the saturation of gas hydrates was higher at seafloor topographic highs. This work aims to understand why gas hydrates accumulated at topographic highs and why their saturation is higher.展开更多
The mechanism of slope failure associated with overpressure that is caused by hydrocarbon migration and accumulation remains unclear.High-resolution seismic data and gas hydrate drilling data collected from the Shenhu...The mechanism of slope failure associated with overpressure that is caused by hydrocarbon migration and accumulation remains unclear.High-resolution seismic data and gas hydrate drilling data collected from the Shenhu gas hydrate field(site SH5)offer a valuable opportunity to study the relations between submarine slope failure and hydrocarbon accumulation and flow that is associated with a~2 kmdiameter gas chimney developed beneath site SH5 where none gas hydrates had been recovered by drilling and sampling despite the presence of distinct bottom simulating reflectors(BSRs)and favorable gas hydrate indication.The mechanism of submarine slope failure resulted from buoyancy extrusion and seepage-derived deformation which were caused by overpressure from a~1100 m-high gas column in a gas chimney was studied via numerical simulation.The~9.55 MPa overpressure caused by hydrocarbons that migrated through the gas chimney and then accumulated beneath subsurface gas hydratebearing impermeable sediments.This may have resulted in a submarine slope failure,which disequilibrated the gas hydrate-bearing zone and completely decomposed the gas hydrate once precipitated at site SH5.Before the gas hydrate decomposition,the largely impermeable sediments overlying the gas chimney may have undergone a major upward deformation due to the buoyancy extrusion of the overpressure in the gas chimney,and slope failure was initiated from plastic strain of the sediments and reduced internal strength.Slope failure subsequently resulted in partial gas hydrate decomposition and sediment permeability increase.The pressurized gas in the gas chimney may have diffused into the overlying sediments controlled by seepage-derived deformation,causing an effective stress reduction at the base of the sediments and significant plastic deformation.This may have formed a new cycle of submarine slope failure and finally the total gas hydrate dissociation.The modeling results of buoyancy extrusion and seepage-derived deformation of the overpressure in the gas chimney would provide new understanding in the development of submarine slope failure and the link between slope failure and gas hydrate accumulation and dissociation.展开更多
Gas hydrate is one kind of potential energy resources that is buried under deep seafloor or frozen areas.The first trial offshore production from the silty reservoir was conducted in the South China Sea by the China G...Gas hydrate is one kind of potential energy resources that is buried under deep seafloor or frozen areas.The first trial offshore production from the silty reservoir was conducted in the South China Sea by the China Geological Survey(CGS).During this test,there were many unique characteristics different from the sand reservoir,which was believed to be related to the clayed silt physical properties.In this paper,simulation experiments,facilities analysis,and theoretical calculation were used to confirm the hydrate structure,reservoir thermo-physical property,and bond water movement rule.And the behavior of how they affected production efficiency was analyzed.The results showed that:It was reasonable to use the structure I rather than structure II methane hydrate phase equilibrium data to make the production plan;the dissociation heat absorbed by hydrate was large enough to cause hydrate self-protection or reformation depend on the reservoir thermal transfer and gas supply;clayed silt got better thermal conductivity compared to coarse grain,but poor thermal convection especially with hydrate;clayed silt sediment was easy to bond water,but the irreducible water can be exchanged to free water under high production pressure,and the most obvious pressure range of water increment was 1.9–4.9 MPa.展开更多
Submarine volcanism is widely developed in the South China Sea(SCS).However,the characteristics,distribution,and genesis of submarine volcanoes in the southern margin of the SCS remain obscure.In this study,we analyze...Submarine volcanism is widely developed in the South China Sea(SCS).However,the characteristics,distribution,and genesis of submarine volcanoes in the southern margin of the SCS remain obscure.In this study,we analyzed the characteristics of submarine volcanoes and identified a total of 43 submarine volcanoes in the southern margin of the SCS,based on a newly acquired 310-km seismic reflection profile,along with previous 45 multi-channel seismic(MCS)profiles,petrological results from volcanic rocks sampled by dredging and drilling,nearby ocean bottom seismometer(OBS)wide-angle seismic profiles,and gravity and magnetic data.The study ascertains that most of these volcanoes are located in fault-block belts and graben-horst zones with strong crustal stretching and thinning.These volcanoes exhibit positive high-amplitude external seismic reflections,weak and chaotic internal seismic reflections,and are accompanied by local deformation of the surrounding sedimentary strata.Meanwhile,they have higher positive gravity anomalies and higher magnetic anomalies than the background strata.The petrological dating results show that volcanic ages are primarily in the Pliocene-Pleistocene,with geochemical characteristics indicating dominance of oceanic island basalt(OIB)-type alkali-basalts.Extensional faults have obviously spatial correspondence with post-spreading volcanism,suggesting these faults may provide conduits for submarine volcanism.The high-velocity bodies(HVBs)in the lower crust and magma underplating exist in the southern SCS,which could provide a clue of genesis for submarine volcanism.The inference is that the intensity of post-spreading volcanism in the southern margin might be affected by stretching faults,crustal thinning and magma underplating.展开更多
Geochemical and detrital zircon U-Pb dating data for drilled sediments from the Baiyun deepwater area of the northern South China Sea demonstrate a change of sedimentary sources from the Oligocene to the Miocene.Zirco...Geochemical and detrital zircon U-Pb dating data for drilled sediments from the Baiyun deepwater area of the northern South China Sea demonstrate a change of sedimentary sources from the Oligocene to the Miocene.Zircon ages of the pre-rift Eocene sequences are dominated by Yanshanian ages with various peak values(110–115 Ma for U1435 and L21; 150 Ma for H1), indicating local sediment supply from the pre-existing Mesozoic magmatic belt. For the Oligocene sediments in the northern part of the basin, the rare earth elements show different distribution characteristics, indicating sediment supply from the paleo-Zhujiang River(Pearl River), as also confirmed by the multimodal zircon age spectra of the Lower Oligocene strata in Well X28. By contrast, a positive Eu anomaly characterizes sediments from the western and southern parts of the basin, indicating potential provenances from intermediate to basic volcanic rock materials. The Baiyun Movement at the end of the Oligocene contributed to a large-scale subsidence in the deepwater area and also a northward retreat of continental shelf break, leading to deepening depositional environment in the basin. As a result, all the detrital zircon ages of the Upper Oligocene strata from Wells X28, L13, and L21 share a similar distribution, implying the possible control of a common source like the Zhujiang River. During the Miocene, whereas sediments in the northern area were mainly sourced from the Zhujiang River Delta, and those in the southern deepwater area continued to be affected by basic volcanic activities, the Dongsha Uplift could have contributed as the main source to the eastern area.展开更多
Through the investigation on radioactive activities of water, sediment and some marine organismsin the Zhujiang Estuary, adjacent sea area and the distributary mouths of the Zhujiang River, activities of total α. rad...Through the investigation on radioactive activities of water, sediment and some marine organismsin the Zhujiang Estuary, adjacent sea area and the distributary mouths of the Zhujiang River, activities of total α. radioactivity, total β radioactivity, artificial radioactive 90Srand 157Cs, and factors inflencing the distribution and the content of U in seawater are studied.The mainly radioactive pollution substances and their sources in the sea area are studied by γ spectra obtained from sediment in the sea area. The results show that the main radioactivity substances are natural radioactivity U,Th series and 40K. which were produced by the modern industry and transported into the sea through the main current of the Zhujiang River.展开更多
To obtain the characteristics of the gas hydrate reservoirs at GMGS3-W19,extensive geophysical logging data and cores were analyzed to assess the reservoir properties.Sediment porosities were estimated from density,ne...To obtain the characteristics of the gas hydrate reservoirs at GMGS3-W19,extensive geophysical logging data and cores were analyzed to assess the reservoir properties.Sediment porosities were estimated from density,neutron,and nuclear magnetic resonance(NMR)logs.Both the resistivity and NMR logs were used to calculate gas hydrate saturations,the Simandoux model was employed to eliminate the effects of high clay content determined based on the ECS and core data.The density porosity was closely in agreement with the core-derived porosity,and the neutron porosity was higher while the NMR porosity was lower than the density porosity of sediments without hydrates.The resistivity log has higher vertical resolution than the NMR log and thus is more favorable for assessing gas hydrate saturation with strong heterogeneity.For the gas hydrate reservoirs at GMGS3-W19,the porosity,gas hydrate saturation and free gas saturation was 52.7%,42.7%and 10%,on average,respectively.The various logs provide different methods for the comprehensive evaluation of hydrate reservoir,which supports the selection of candidate site for gas hydrate production testing.展开更多
文摘Dynamics of major picoplankton groups, Synechococcus (Syn), Prochlorococcus (Pro), picoeukaryotes (Euk) and heterotrophic bacteria (Bact) was investigated by flow cytometry for the first time in the Nansha Islands area in the South China Sea. Averaged over the whole investigation area, depth-weighted integrated cell abundance (DWA) of Syn, Pro, Euk and Bact was 1.6 (0.4-5.7)×103, 5.4 (0.1-7.3)×104, 0.7 (0.2-2.2)×103, and 2.3 (1.4-3.2)×105 cells/mL respectively. Picoautotrophic cell abundance was low in the northwest part of the Nansha Islands where surface water temperature was low and the upper mixed layer was shallow. Concurrently, a surface maximum vertical distribution pattern was observed in this area. While in the southeast and east zones where temperatures were relatively higher and nitraclines were deeper, picoplankton is abundant and a subsurface maximum around 50-75 m is observed. Coupling of horizontal and vertical distribution patterns of picoplankton abundance and hydrological status was found, suggesting a strong influence of currents and water column structure on picoplankton distribution in the investigation area. Contrary to that in the shelf water in the East China Sea, the relationship between Pro and Bact in the Nansha Islands area in the South China Sea was not significantly negative but weakly positive. Moreover, a similar distribution pattern of Syn and Pro was observed. Possible reasons for these differences in the two marine regimes were discussed.
基金Supported by the National Basic Research Program of China (973 Program, No. 2007CB407305)Qingdao Special Project for Outstanding Scientists (No.05-2-JC-90)the 100 Talents Project of Chinese Academy of Sciences (No.2003-202)
文摘The area of the southwestern Nansha Trough is one of the most productive areas of the southern South China Sea.It is a typical semi-deep sea area of transition from shoal to abyssal zone.To understand distributions and roles of nitrogen forms involved in biogeochemical cycling in this area,contents of nitrogen in four extractable forms:nitrogen in ion exchangeable form(IEF-N),nitrogen in weak acid extractable form(WAEF-N),nitrogen in strong alkali extractable form(SAEF-N) and nitrogen in strong oxidation extractable form(SOEF-N),as well as in total nitrogen content(TN) in surface sediments were determined from samples collected from the cruise in April-May 1999.The study area was divided into three regions(A,B and C) in terms of clay sediment(<4 μm) content at <40%,40%-60% and >60%,respectively.Generally,region C was the richest in the nitrogen of all forms and region A the poorest,indicating that the finer the grain size is,the richer the contents of various nitrogen are.The burial efficiency of total nitrogen in surface sediments was 28.79%,indicating that more than 70% of nitrogen had been released and participated in biogeochemical recycling through sediment-water interface.
基金The National Basic Research Program of China ("973") under contract Nos 2009CB2194 and 2007CB411700the Major Knowledge Innovation Programs of the Chinese Academy of Sciences under contract No. kzcx2-yw-203-01+2 种基金the National Natural Science Foundation of China of China under contract No. 40676039the National Program of Sustaining Science and Technology of China under contract No. 2006BAB19B02the Program of the Ministry of Land and Natural Resources of China under contract No. GT-YQ-QQ-2008-1-02
文摘Layer-block tectonics (LBT) concept, with the core of pluralistic geodynamic outlook and multilayer-sliding tectonic outlook, is one of new keys to study 3-dimensional solid and its 4-dimensional evolution history of global tectonic system controlled by global geodynamics system. The LBT concept is applied to study the lithospheric tectonics of the southern South China Sea (SCS). Based on the analysis of about 30 000 km of geophysical and geological data, some layer-blocks in the Nansha micro-plate can be divided as Nansha ultra-crustal layer-block, Zengmu crustal layer-block, Nanwei (Rifleman bank)-Andu (Ardasier bank) and Liyue (Reed bank) North Palawan crustal layer-blocks, Andu-Bisheng and Liyue-Banyue basemental layer-blocks. The basic characteristics of the basemental layer-blocks have been dicussed, and three intra-plate basin groups are identified. The intra-plate basins within Nansha micro-plate can be divided into three basin groups of Nanwei- Andu, Feixin-Nanhua, and Liyue-North Palawan based on the different geodynamics. In the light of pluralistic geodynamic concept, the upheaving force induced by the mid-crust plastic layer is proposed as the main dynamical force which causes the formation of the intra-plate basins within the Nansha micro-plate. Finally, models of a face-to-face dip-slip detachment of basemental layerblock and a unilateral dip-slip-detachment of basemental layer-block are put forward for the forming mechanisms of the Nanwei Andu and Liyue-North Palawan intra-plate basin groups, respectively.
基金The National Basic Research Program(973 Program)of China under contract No.2013CB956104the National Natural Science Foundation of China under contract No.41376063the Strategic Priority Research Program of the Chinese Academy of Sciences under contract No.XDA13000000
文摘It is exceedingly important to estimate the stability of coral reefs. In recent years, growing construction projects have been carried out on the reef flat in the South China Sea. As a special marine geotechnical medium, it is made of the reef debris underwent overwhelmingly long geological age. Reefs grow thickly on the carbonate platform after the Late Oligocene and have five to six main sedimentary facies. It can be used as a recorder to measure the occurrence time of recent earthquake. A model of reef body is presented to study the influence of earthquakes according to the geological structure characteristic of reefs in the Nansha Islands. Furthermore, Geo Studio is used to simulate stress and deformation situations within it under various earthquake intensities. A safety factor is calculated by the limit equilibrium method, and the possible scenarios of earthquake-induced landslides and sliding scale are defined with a Newmark sliding block method, as well as stress distribution and deformation behaviors. Therefore, the numerical results suggest that the connections between the coral reef and the earthquake are as follows:(1) the reef body has a good stability under self-gravity state;(2) after the earthquake, it may cause slope's instability and bring out slumping when the safety factor is smaller than 1(FS〈1);(3) the safety factor decreases with the increasing earthquake intensity, and fluctuates around a particular value after a while;and(4) as a new developed part of the reef, the smaller shallow landslide will be easily subject to collapse caused by the earthquake. It is concluded that it is feasible to provide a reference for evaluating the stability of coral reef using a geotechnical engineering simulation method. This can help the engineering constructions in the South China Sea.
基金The National Twelfth Five Major Projects Subject--the deepwater area of northern South China Sea,rich hydrocarbon generation potential sag evaluation under contract No.2011ZX05025-002
文摘There are rich natural gas resources in the northwestern South China Sea deepwater areas, with poor degree of exploration. Because of the unique tectonic, sedimentary background of the region, velocity model building and time-depth conversion have been an important and difficult problem for a long time. Recent researches in this direction have revealed three major problems for deepwater areas, i.e., the way to determine error correction for drilling velocity, the optimization of velocity modeling, and the understanding and analysis of velocity variations in the slope areas. The present contribution proposes technical solutions to the problems:(1) velocity correction version can be established by analyzing the geology, reservoir, water depths and velocity spectrum characteristics;(2) a unified method can be adopted to analyze the velocity variation patterns in drilled pale structural positions;and (3) across-layer velocity is analyzed to establish the velocity model individually for each of the layers. Such a solution is applicable, as shown in an example from the northwestern South China Sea deepwater areas, in which an improved prediction precision is obtained.
基金supported by the National Natural Science Foundation of China(contract No.49706065)the Special Foundation of National Social Common Wealth Research(contract No.2001DIA50041)ZKCX2-SW-212 by Chinese Academy of Science
文摘Concentrations of organic matter, iron and manganese in the deep sea surface sediments in the Nansha Islands sea area, South China Sea are measured. Horizontal and vertical distributions of iron and manganese are discussed. The vertical distribution of iron and manganese in the sediments results from reduction, diffusion, and redeposition of manganese (or iron) oxide and hydroxide in the sediment. There are the maxima of iron and manganese in solid phase in the top of the sediment, which is caused by the penetration of O2 and the upward flux of Mn2+ ( or Fe2+ ). Manganese bacteria play a very important role in the cycle of solid-phase iron and manganese in the ocean environment. Manganese bacteria oxidize Mn2+ ( or Fe2+ ) in dissolved state to Mn4+ ( or Fe3+ ) in oxidized state under the aerobic condition, whereas they reduce iron and manganese in anaerobic conditions.
基金This work was jointly supported by project KZCX2-202 from CAS the project of 818-06-03 from national 863 program and project 97-926-07 of national special program for science and technology.
文摘The diffusion attenuation coefficient for downwelling irradiance, Kd (490), is an important optical parameter of seawater. The optical property, Kd (490), around Nansha Islands in the South China Sea was analyzed based on optical data profiles measured with SPMR ( SeaWiFS Profiling Multichannel Radiometer ) and SMSR ( SeaWiFS Multichannel Surface Reference ) instrument in April and May, 1999. The results show that Kd (490) is closely correlated with chlorophyll-a concentration, Cchl.a, and that the vertical distribution of Kd (490) shows the strong stratification of the water column in this area. Kd (490) has a similar vertical co-variation as KL (490), the diffusive attenuation coefficient for upwelling radiance. Both coefficients increase with depth in the upper layer, where KL (490) is greater than Kd (490); and after a depth, approximatively at the chlorophyll maximum, they decrease with depth, with the former being smaller than the latter.
基金The National Natural Science Foundation of China under contract No.41606078the Taishan Scholar Special Experts Project under contract No.ts201712079+1 种基金the National Key Research and Development Plan under contract No.2017YFC0307600the Open Fund of Qingdao National Laboratory for Marine Science and Technology of China under contract Nos QNLM2016ORP0203 and QNLM2016ORP0207
文摘The undrained shear strength of shallow strata is a critical parameter for safety design in deep-water operations.In situ piezocone penetration tests(CPTU) and laboratory experiments are performed at Site W18-19 in the Shenhu area, northern South China Sea, where China's first marine hydrate exploitation operation is due to be located. The validation of the undrained shear strength prediction model based on CPTU parameters. Different laboratory tests, including pocket penetrometer, torvane, miniature vane and unconsolidated undrained triaxial tests, are employed to solve empirical cone coefficients by statistical and mathematical methods. Finally, an optimized model is proposed to describe the longitudinal distribution of undrained shear strength in calcareous clay strata in the Shenhu area. Research results reveal that average empirical cone coefficients based on total cone resistance, effective resistance, and excess-pore pressure are 13.8, 4.2 and 14.4, respectively. The undrained shear strength prediction model shows a good fit with the laboratory results only within specific intervals based on their compaction degree and gas-bearing conditions. The optimized prediction model in piecewise function format can be used to describe the longitudinal distribution of the undrained shear strength for calcareous clay within all depth intervals from the mud-line to the upper boundary of hydrate-bearing sediments(HBS). The optimized prediction result indicates that the effective cone resistance model is suitable for very soft to firm calcareous clays,the excess-pore pressure model can depict the undrained shear strength for firm to very stiff but gas-free clays,while the total cone resistance model is advantageous for evaluating the undrained shear strength for very stiff and gassy clays. The optimized model in piecewise function format can considerably improve the adaptability of empirical models for calcareous clay in the Shenhu area. These results are significant for safety evaluations of proposed hydrate exploitation projects.
基金supported by the National Natural Science Foundation of China (grants No.41576048,41202080 and 41176052)the Open Fund of State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation (Chengdu University of Technology) (grant No.PLC201402)+1 种基金the Youth Innovation Promotion Association CAS (2016312)the Scientific Cooperative Project by CNPC and CAS (2015A-4813)
文摘The first marine gas hydrate expedition in China has been conducted by Guangzhou Marine Geological Survey in the Shenhu Area, northern continental slope of the South China Sea. Previous study has analyzed the P-T conditions, geophysical anomalies and saturation calculations of these gas hydrates, but has not documented in detail the migration of gas-bearing fluids in the study area. Based on the interpretations of 2D/3D seismic data, this work identified two types of migration pathways for gas-bearing fluids in the Shenhu area, i.e., vertical and lateral pathways. The vertical pathways(largescale faults, gas chimneys and mud diapirs) presented as steep seismic reflection anomalies, which could be traced downward to the Eocene source rocks and may penetrate into the Late Miocene strata. The deeper gases/fluids might be allowed migrating into the shallower strata through these vertical conduits. However, the distributions showed distinct differences between these pathways. Large-scale faults developed only in the north and northeast of the Shenhu area, while in the drilling area gas chimneys were the sole vertical migration pathways. Since the Pliocene, normal faults, detachment faults and favorable sediments have constituted the lateral pathways in the Shenhu gas hydrate drilling area. Although these lateral pathways were connected with gas chimneys, they exerted different effects on hydrate formation and accumulation. Gas-bearing fluids migrated upward along gas chimneys might further migrate laterally because of the normal faults, thereby enlarging the range of the chimneys. Linking gas chimneys with the seafloor, the detachment faults might act as conduits for escaping gases/fluids. Re-deposited sediments developed at the early stage of the Quaternary were located within the gas hydrate stability zone, so hydrates would be enriched in these favorable sediments. Compared with the migration pathways(large-scale faults and mud diapirs) in the LW3-1 deep-sea oil/gas field, the migration efficiency of the vertical pathways(composed of gas chimneys) in the gas hydrate drilling area might be relatively low. Description and qualitative discrimination of migration pathways in the Shenhu gas hydrate drilling area are helpful to further understand the relationship between good-quality deep source rocks and shallow, mainly biogenicallyproduced, hydrates. As the main source rocks of the Baiyun sag, lacustrine mudstones in the Wenchang and Enping Formations may provide thermogenic methane. Gas chimneys with relatively low migration efficiency created the vertical pathways. Caused by the Dongsha tectonic movement, the release of overpressured fluids might reduce the vertical migration rates of the thermogenic methane. The thick bathyal/abyssal fine-grained sediments since the Late Miocene provided migration media with low permeability. These preconditions may cause carbon isotopic fractionation ofthermogenic methane during long-distance vertical migrations. Therefore, although geochemical analyses indicate that the methane forming gas hydrate in the Shenhu area was mainly produced biogenically, or was mixed methane primarily of microbial origin, thermogenic methane still contribute significantly.
基金supported by the National 973 Basic Research Program (Grant No. 2009CB219502)National Natural Science Foundation of China (Grant No. 41072084)
文摘BSR (Bottom Simulating Reflector) occurs widely in the strata since the late Miocene in the deep-water area of the northern continental slope of South China Sea (SCS). It is an important seismic reference mark which identifies the gas hydrate and its distribution influenced by the tectonic movements. Single-point basin modeling was conducted using 473 points in the study area. To discuss the relationships between the tectonic subsidence and BSR, the volume and rate of tectonic subsidence in each geological time have been simulated. The results show that there are three tectonic accelerate subsidence processes in the study area since the late Miocene, especially since 1.8Ma the tectonic subsidence accelerates more apparently. Since the Late Miocene to Pleistocene, the rate of tectonic subsidence in deep-water underwent a transformation from weak to strong. The ratio of tectonic subsidence to the total subsidence was relatively high (65-70%). Through the superposition of the BSR developed areas and the contours of tectonic subsidence in this area, it was discovered that more than 80% of BSR tend to be distributed at the slope break or depression-uplift structural transfer zone and the average tectonic subsidence rate ranges from 70 m/Ma to 125 m/Ma.
基金Jointly funded by a major research plan of National Natural Science Foundation of China(51991365)titled“Multi-Field Spatial-Temporal Evolution Laws of Phase Transition and Seepage of Natural Gas Hydrate in Reservoirs”and a geological survey project initiated by China Geological Survey(DD20190226)titled“Implementation of Natural Gas Hydrate Production Test in Pilot Test Area in Shenhu Area”.
文摘Shenhu Area is located in the Baiyun Sag of Pearl River Mouth Basin,which is on the northern continental slope of the South China Sea.Gas hydrates in this area have been intensively investigated,achieving a wide coverage of the three-dimensional seismic survey,a large number of boreholes,and detailed data of the seismic survey,logging,and core analysis.In the beginning of 2020,China has successfully conducted the second offshore production test of gas hydrates in this area.In this paper,studies were made on the structure of the hydrate system for the production test,based on detailed logging data and core analysis of this area.As to the results of nuclear magnetic resonance(NMR)logging and sonic logging of Well GMGS6-SH02 drilled during the GMGS6 Expedition,the hydrate system on which the production well located can be divided into three layers:(1)207.8–253.4 mbsf,45.6 m thick,gas hydrate layer,with gas hydrate saturation of 0–54.5%(31%av.);(2)253.4–278 mbsf,24.6 m thick,mixing layer consisting of gas hydrates,free gas,and water,with gas hydrate saturation of 0–22%(10%av.)and free gas saturation of 0–32%(13%av.);(3)278–297 mbsf,19 m thick,with free gas saturation of less than 7%.Moreover,the pore water freshening identified in the sediment cores,taken from the depth below the theoretically calculated base of methane hydrate stability zone,indicates the occurrence of gas hydrate.All these data reveal that gas hydrates,free gas,and water coexist in the mixing layer from different aspects.
基金Supported by the National Natural Science Foundation of China under Grant Nos 11434012,41561144006,11174312 and 11404366
文摘Bottom acoustic parameters play an important role in sound field prediction. Acoustic parameters in deep water are not well understood. Bottom acoustic parameters are sensitive to the transmission-loss (TL) data in the shadow zone of deep water. We propose a multiple-step fill inversion method to invert sound speed, density and attenuation in deep water. Based on a uniform liquid hMf-space bottom model, sound speed of the bottom is inverted by using the long range TL at low frequency obtained in an acoustic propagation experiment conducted in the South China Sea (SCS) in summer 2014. Meanwhile, bottom density is estimated combining with the Hamilton sediment empirical relationship. Attenuation coefficients at different frequencies are then estimated from the TL data in the shadow zones by using the known sound speed and density as a constraint condition. The nonlinear relationship between attenuation coefficient and frequency is given in the end. Tile inverted bottom parameters can be used to forecast the transmission loss in the deep water area of SCS very we//.
基金Supported by the National Basic Research Program of China(973 Program)(No.2012CB956004)the Fundamental Research Funds for the Central Universities(No.16lgjc22)
文摘The global carbon cycle has played a key role in mitigating global warming and climate change.Long-term natural and anthropogenic processes influence the composition,sources,burial rates,and fluxes of carbon in sediments on the continental shelf of China.In this study,the rates,fluxes,and amounts of carbon storage at the centennial scale were estimated and demonstrated using the case study of three fine-grained sediment cores from the central South Yellow Sea area(SYSA) and Min-Zhe belt(MZB),East China Sea.Based on the high-resolution temporal sequences of total carbon(TC)and total organic carbon(TOC)contents,we reconstructed the annual variations of historical marine carbon storage,and explored the influence of terrestrial and marine sources on carbon burial at the centennial scale.The estimated TC storage over 100 years was 1.18×10~8 t in the SYSA and 1.45×10~9 t in the MZB.The corrected TOC storage fluxes at the centennial scale ranged from 17 to 28 t/(km^2·a)in the SYSA and from 56 to 148 t/(km^2·a)in the MZB.The decrease of terrestrial materials and the increase of marine primary production suggest that the TOC buried in the sediments in the SYSA and MZB was mainly derived from the marine autogenetic source.In the MZB,two depletion events occurred in TC and TOC storage from 1985 to 1987 and 2003 to 2006,which were coeval with the water impoundment in the Gezhouba and Three Gorges dams,respectively.The high-resolution records of the carbon storage rates and fluxes in the SYSA and MZB reflect the synchronous responses to human activities and provide an important reference for assessing the carbon sequestration capacity of the marginal seas of China.
基金funded by the National Natural Science Foundation of China(grants No.41406080,41273066 and 41106060)
文摘Previous work has largely discussed the relations between sediment structures and accumulation of gas hydrates in the Shenhu area of South China Sea, but has not documented why the gas hydrates occurred at the seafloor topographic highs. Many gas hydrate exploration examples abroad also indicate that the saturation of gas hydrates was higher at seafloor topographic highs. This work aims to understand why gas hydrates accumulated at topographic highs and why their saturation is higher.
基金supported by the National Natural Science Foundation of China(No.41776056)Open Found of Key Laboratory of Tectonics and Petroleum Resources(China University of Geosciences)+2 种基金Ministry of Education(No.TPR-2020-06)the China National Hydrate Project(DD20190217)China Postdoctoral Science Foundation(No.2017M622655)。
文摘The mechanism of slope failure associated with overpressure that is caused by hydrocarbon migration and accumulation remains unclear.High-resolution seismic data and gas hydrate drilling data collected from the Shenhu gas hydrate field(site SH5)offer a valuable opportunity to study the relations between submarine slope failure and hydrocarbon accumulation and flow that is associated with a~2 kmdiameter gas chimney developed beneath site SH5 where none gas hydrates had been recovered by drilling and sampling despite the presence of distinct bottom simulating reflectors(BSRs)and favorable gas hydrate indication.The mechanism of submarine slope failure resulted from buoyancy extrusion and seepage-derived deformation which were caused by overpressure from a~1100 m-high gas column in a gas chimney was studied via numerical simulation.The~9.55 MPa overpressure caused by hydrocarbons that migrated through the gas chimney and then accumulated beneath subsurface gas hydratebearing impermeable sediments.This may have resulted in a submarine slope failure,which disequilibrated the gas hydrate-bearing zone and completely decomposed the gas hydrate once precipitated at site SH5.Before the gas hydrate decomposition,the largely impermeable sediments overlying the gas chimney may have undergone a major upward deformation due to the buoyancy extrusion of the overpressure in the gas chimney,and slope failure was initiated from plastic strain of the sediments and reduced internal strength.Slope failure subsequently resulted in partial gas hydrate decomposition and sediment permeability increase.The pressurized gas in the gas chimney may have diffused into the overlying sediments controlled by seepage-derived deformation,causing an effective stress reduction at the base of the sediments and significant plastic deformation.This may have formed a new cycle of submarine slope failure and finally the total gas hydrate dissociation.The modeling results of buoyancy extrusion and seepage-derived deformation of the overpressure in the gas chimney would provide new understanding in the development of submarine slope failure and the link between slope failure and gas hydrate accumulation and dissociation.
基金funded by the National Key Research and Development Program of China(2017YFC0307600)the China Geological Survey Program(DD20190231).
文摘Gas hydrate is one kind of potential energy resources that is buried under deep seafloor or frozen areas.The first trial offshore production from the silty reservoir was conducted in the South China Sea by the China Geological Survey(CGS).During this test,there were many unique characteristics different from the sand reservoir,which was believed to be related to the clayed silt physical properties.In this paper,simulation experiments,facilities analysis,and theoretical calculation were used to confirm the hydrate structure,reservoir thermo-physical property,and bond water movement rule.And the behavior of how they affected production efficiency was analyzed.The results showed that:It was reasonable to use the structure I rather than structure II methane hydrate phase equilibrium data to make the production plan;the dissociation heat absorbed by hydrate was large enough to cause hydrate self-protection or reformation depend on the reservoir thermal transfer and gas supply;clayed silt got better thermal conductivity compared to coarse grain,but poor thermal convection especially with hydrate;clayed silt sediment was easy to bond water,but the irreducible water can be exchanged to free water under high production pressure,and the most obvious pressure range of water increment was 1.9–4.9 MPa.
基金Supported by the National Key Research and Development Program of China(No.2022YFC3102200)the Guangdong Research Foundation(No.2019BT02H594)+3 种基金the National Natural Science Foundation of China(No.42076071)the Key Special Project for Introduced Talents Team of the Southern Marine Science and Engineering Guangdong Laboratory(Guangzhou)(No.GML2019ZD0204)the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDA22020303)the Key Research Program of the Chinese Academy of Sciences(No.ZDRW-XH-2021-2-02)。
文摘Submarine volcanism is widely developed in the South China Sea(SCS).However,the characteristics,distribution,and genesis of submarine volcanoes in the southern margin of the SCS remain obscure.In this study,we analyzed the characteristics of submarine volcanoes and identified a total of 43 submarine volcanoes in the southern margin of the SCS,based on a newly acquired 310-km seismic reflection profile,along with previous 45 multi-channel seismic(MCS)profiles,petrological results from volcanic rocks sampled by dredging and drilling,nearby ocean bottom seismometer(OBS)wide-angle seismic profiles,and gravity and magnetic data.The study ascertains that most of these volcanoes are located in fault-block belts and graben-horst zones with strong crustal stretching and thinning.These volcanoes exhibit positive high-amplitude external seismic reflections,weak and chaotic internal seismic reflections,and are accompanied by local deformation of the surrounding sedimentary strata.Meanwhile,they have higher positive gravity anomalies and higher magnetic anomalies than the background strata.The petrological dating results show that volcanic ages are primarily in the Pliocene-Pleistocene,with geochemical characteristics indicating dominance of oceanic island basalt(OIB)-type alkali-basalts.Extensional faults have obviously spatial correspondence with post-spreading volcanism,suggesting these faults may provide conduits for submarine volcanism.The high-velocity bodies(HVBs)in the lower crust and magma underplating exist in the southern SCS,which could provide a clue of genesis for submarine volcanism.The inference is that the intensity of post-spreading volcanism in the southern margin might be affected by stretching faults,crustal thinning and magma underplating.
基金The National Natural Science Foundation of China under contract Nos 41576059,91128207 and 91528302the National Major Science and Technology Projects under contract No.2011ZX05025-006-02
文摘Geochemical and detrital zircon U-Pb dating data for drilled sediments from the Baiyun deepwater area of the northern South China Sea demonstrate a change of sedimentary sources from the Oligocene to the Miocene.Zircon ages of the pre-rift Eocene sequences are dominated by Yanshanian ages with various peak values(110–115 Ma for U1435 and L21; 150 Ma for H1), indicating local sediment supply from the pre-existing Mesozoic magmatic belt. For the Oligocene sediments in the northern part of the basin, the rare earth elements show different distribution characteristics, indicating sediment supply from the paleo-Zhujiang River(Pearl River), as also confirmed by the multimodal zircon age spectra of the Lower Oligocene strata in Well X28. By contrast, a positive Eu anomaly characterizes sediments from the western and southern parts of the basin, indicating potential provenances from intermediate to basic volcanic rock materials. The Baiyun Movement at the end of the Oligocene contributed to a large-scale subsidence in the deepwater area and also a northward retreat of continental shelf break, leading to deepening depositional environment in the basin. As a result, all the detrital zircon ages of the Upper Oligocene strata from Wells X28, L13, and L21 share a similar distribution, implying the possible control of a common source like the Zhujiang River. During the Miocene, whereas sediments in the northern area were mainly sourced from the Zhujiang River Delta, and those in the southern deepwater area continued to be affected by basic volcanic activities, the Dongsha Uplift could have contributed as the main source to the eastern area.
文摘Through the investigation on radioactive activities of water, sediment and some marine organismsin the Zhujiang Estuary, adjacent sea area and the distributary mouths of the Zhujiang River, activities of total α. radioactivity, total β radioactivity, artificial radioactive 90Srand 157Cs, and factors inflencing the distribution and the content of U in seawater are studied.The mainly radioactive pollution substances and their sources in the sea area are studied by γ spectra obtained from sediment in the sea area. The results show that the main radioactivity substances are natural radioactivity U,Th series and 40K. which were produced by the modern industry and transported into the sea through the main current of the Zhujiang River.
基金jointly supported by the Key Area Research and Development Program of Guangdong Province(2020B1111030003)the Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou)(GML2019ZD0102)the Project of China Geological Survey (DD20221700).
文摘To obtain the characteristics of the gas hydrate reservoirs at GMGS3-W19,extensive geophysical logging data and cores were analyzed to assess the reservoir properties.Sediment porosities were estimated from density,neutron,and nuclear magnetic resonance(NMR)logs.Both the resistivity and NMR logs were used to calculate gas hydrate saturations,the Simandoux model was employed to eliminate the effects of high clay content determined based on the ECS and core data.The density porosity was closely in agreement with the core-derived porosity,and the neutron porosity was higher while the NMR porosity was lower than the density porosity of sediments without hydrates.The resistivity log has higher vertical resolution than the NMR log and thus is more favorable for assessing gas hydrate saturation with strong heterogeneity.For the gas hydrate reservoirs at GMGS3-W19,the porosity,gas hydrate saturation and free gas saturation was 52.7%,42.7%and 10%,on average,respectively.The various logs provide different methods for the comprehensive evaluation of hydrate reservoir,which supports the selection of candidate site for gas hydrate production testing.