A novel Nd（Ⅲ） compound,[Nd3（OH）7（O2CC6H4SO3）（H2O）]n·nH2O 1,has been synthesized by the hydrothermal reaction of Nd2O3 and 3-sulfobenzoic acid monosodium salt. It was characterized by IR spectroscopy,elem...A novel Nd（Ⅲ） compound,[Nd3（OH）7（O2CC6H4SO3）（H2O）]n·nH2O 1,has been synthesized by the hydrothermal reaction of Nd2O3 and 3-sulfobenzoic acid monosodium salt. It was characterized by IR spectroscopy,elemental analysis,thermogravimetric analysis and single-crystal X-ray diffraction. It crystallizes in monoclinic,space group P21/c with a = 13.024（3）,b = 10.961（2）,c = 12.792（3） ,β = 91.271（3）°,V = 1825.6（7） 3,Z = 4,Mr = 787.97,Dc = 2.867 g/cm3,μ = 8.584 mm-1,F（000） = 1460,S = 1.035,R = 0.0442 and wR = 0.1166 （I 〉 2σ（I））. In this compound,the cross-linkage of Nd atoms by bridging hydroxy groups results in a Nd-O inorganic 〈200〉 layer,and such layers are linked by the 3-O3S-C6H4-CO2 dianions into a pillar-layered structure. The lattice water molecules are located in the cavity.展开更多
The divalent state of Ln（III） ions has attracted much interest because of their ability to serve isomorphously in many biological system of divalent Ca（II） ion. Therefore, present paper deals with the study of div...The divalent state of Ln（III） ions has attracted much interest because of their ability to serve isomorphously in many biological system of divalent Ca（II） ion. Therefore, present paper deals with the study of divalent state of Eu（III） and Nd（III） ions in non-aqueous medium. In present study, cyclic voltammetry and chronopotentiometry were utilized to establish the divalent state of Eu（III） and Nd（III） ions. The cyclic voltammetric technique showed two-step reduction process at cathode for both Ln（III） ions under specified experimental conditions and chronopotentiometric method also showed two different transition times （r）. Looking to the shape of cyclic voltammogram we calculated het- erogeneous forward rate constant （K^fh, cm/s） and diffusion coefficient （D, cm2/s） for both ions, which suggested that sweep rate had great ef- fect on the shape of cyclic voltammogram of Eu（III） and Nd（III） ions. The result of chronopotentiometry also suggested that stable divalent states of Eu（III） and Nd（III） ions existed with chronopotentiogram with two distinct transition times. The diffusion coefficients （D, cm2/s） were calculated from Sand equation. The diffusion coefficients of both techniques were compared and the results suggested that the system at electrode surface was changing from being reversible to irreversible.展开更多
基金supported by the Natural Science Foundation for Youths in Jiangxi Province (No. 2008GQH0002)
文摘A novel Nd（Ⅲ） compound,[Nd3（OH）7（O2CC6H4SO3）（H2O）]n·nH2O 1,has been synthesized by the hydrothermal reaction of Nd2O3 and 3-sulfobenzoic acid monosodium salt. It was characterized by IR spectroscopy,elemental analysis,thermogravimetric analysis and single-crystal X-ray diffraction. It crystallizes in monoclinic,space group P21/c with a = 13.024（3）,b = 10.961（2）,c = 12.792（3） ,β = 91.271（3）°,V = 1825.6（7） 3,Z = 4,Mr = 787.97,Dc = 2.867 g/cm3,μ = 8.584 mm-1,F（000） = 1460,S = 1.035,R = 0.0442 and wR = 0.1166 （I 〉 2σ（I））. In this compound,the cross-linkage of Nd atoms by bridging hydroxy groups results in a Nd-O inorganic 〈200〉 layer,and such layers are linked by the 3-O3S-C6H4-CO2 dianions into a pillar-layered structure. The lattice water molecules are located in the cavity.
文摘The divalent state of Ln（III） ions has attracted much interest because of their ability to serve isomorphously in many biological system of divalent Ca（II） ion. Therefore, present paper deals with the study of divalent state of Eu（III） and Nd（III） ions in non-aqueous medium. In present study, cyclic voltammetry and chronopotentiometry were utilized to establish the divalent state of Eu（III） and Nd（III） ions. The cyclic voltammetric technique showed two-step reduction process at cathode for both Ln（III） ions under specified experimental conditions and chronopotentiometric method also showed two different transition times （r）. Looking to the shape of cyclic voltammogram we calculated het- erogeneous forward rate constant （K^fh, cm/s） and diffusion coefficient （D, cm2/s） for both ions, which suggested that sweep rate had great ef- fect on the shape of cyclic voltammogram of Eu（III） and Nd（III） ions. The result of chronopotentiometry also suggested that stable divalent states of Eu（III） and Nd（III） ions existed with chronopotentiogram with two distinct transition times. The diffusion coefficients （D, cm2/s） were calculated from Sand equation. The diffusion coefficients of both techniques were compared and the results suggested that the system at electrode surface was changing from being reversible to irreversible.
