The crystal structure of di-hydroxyisobutyrate)diaquo neodymium nitrate Nd(C_4H_7O_3)_2NO_32H_2O was determined by X-ray diffraction analysis. It belongs to monoclinic,space group C2/C,with cell dimensionsa=8.996(1), ...The crystal structure of di-hydroxyisobutyrate)diaquo neodymium nitrate Nd(C_4H_7O_3)_2NO_32H_2O was determined by X-ray diffraction analysis. It belongs to monoclinic,space group C2/C,with cell dimensionsa=8.996(1), b=8.601(1),c=21.111(3),β=92.38°,V=1632.O,Z=4,D_c=1.83g/cm^3.Crystal structure has been refined by full-matrix least-square techniques giving a final R value of 0.036.The neodymium atom is coordinated to eight oxygen atoms.The nitrate group in complex is not bonded to neodymium,each two neodymium atoms are linked by bridging carboxyl group forming a chain polymeric molecule.展开更多
(CH_3OCH_2CH_2C_5H_4)_2LnI(Ln=La,Nd)complexes have been synthesized by the reaction between NaI and[(CH_3OCH_2CH_2C_5H_4)_2LnCl]2 in THF;A single crystal X-ray study has shown that the lanthanum complex is an unsolvat...(CH_3OCH_2CH_2C_5H_4)_2LnI(Ln=La,Nd)complexes have been synthesized by the reaction between NaI and[(CH_3OCH_2CH_2C_5H_4)_2LnCl]2 in THF;A single crystal X-ray study has shown that the lanthanum complex is an unsolvated monomer with lanthanum(Ⅲ)in a trigonal bipyramidal coordination geometry if the cyclopentadienyl ring is regarded as occupying a single polyhedral vertex.展开更多
proach change of CGRP with time in periodontal ligaments of rats in magnetic field, maxillae of 28 Wistar rats of 6 7 weeks were placed in magnetic fields of permanent magnets Nd 2 Fe 4 B. Changes of CGRP w...proach change of CGRP with time in periodontal ligaments of rats in magnetic field, maxillae of 28 Wistar rats of 6 7 weeks were placed in magnetic fields of permanent magnets Nd 2 Fe 4 B. Changes of CGRP with t ime in maxillary periodontal ligaments of the rats were studied by immunohistochemistry. The result showed that: magnetic field had dynamic effect and some promotional effect on recove?E F F E C T O F M A G N E T I C F I E L D O N C A L C I T O N I N G E N E- R E L A T E D P E P T I D E I N P E R I O D O N T A L L I G A M E N T S O F R A T S X. Chang , K. Qin and Y. L. Lu Orthodontic Department of Stomatology College , China Medical University , Shenyang 110001 , China Manuscript received 24 June 1999 In order to approach change of C G R P with tim e in periodontal liga m ents of rats in m agneticfield , m axillae of 28 Wistar rats of 6 7 weeks w ere placed in m agnetic fields of per m anentm agnets Nd 2 Fe4 B. Changes of C G R P with tim e in m axillary periodontal liga ments of therats were stu died by i m m unohistoche mistry . The result sho wed that : m agnetic field had dy na m ic effect an d so m e pro motional effect on recovering and reconstruction of the periodontaltissues in it . This provided a better theoretical evidence for clinical use of per m anent m agnets .展开更多
The output characteristics of neodymium-doped gadolinium vanadate(Nd:GdVO4) crystals laser with dual c-axis orthogonal gains end-pumped by two fiber-coupled diode lasers are investigated. With two 1 W semiconductor di...The output characteristics of neodymium-doped gadolinium vanadate(Nd:GdVO4) crystals laser with dual c-axis orthogonal gains end-pumped by two fiber-coupled diode lasers are investigated. With two 1 W semiconductor diode lasers pumping, the output power of TEM00 laser is 920 m W, and the optical conversion efficiency is close to 46%. By changing the relative orientations of both Nd:Gd VO4 crystals, the polarization characteristics of laser are varied. In particular, by keeping the c-axes of two Nd:Gd VO4 crystals orthogonal to each other and adjusting two diode pump lasers to operate at the same power level, the completely unpolarized light is obtained.展开更多
Reactions of lanthanoid trichlorides with sodium cyclopentylcyclopentadienyl in THF afford bis(cyclopentylcyclopentadienyl) lanthanoid chloride complexes (C_5H_9C_5H_4)_2LnCl(THF)_n (Ln= Nd, Sm, n=1; Ln= Er, Yb, n= 0)...Reactions of lanthanoid trichlorides with sodium cyclopentylcyclopentadienyl in THF afford bis(cyclopentylcyclopentadienyl) lanthanoid chloride complexes (C_5H_9C_5H_4)_2LnCl(THF)_n (Ln= Nd, Sm, n=1; Ln= Er, Yb, n= 0). The compound [CP'_2SmCl(THF)]_2 (2) (Cp' =cyclopentylcy- clopentadienyl) crystallizes from mixed solvent of hexane and THF in monoclinic space group P_2_1/c with a = 11.583 (3), b = 23.019(6), c = 8.227 (2)(?), β= 90.26 (2)°, V= 2194 (1)(?)~3, D_c= 1.59 g/cm^3. μ= 28.6 cm^(-1), F(000) = 1060, Z= 2 (dimers). Its crystal molecule is a dimer with a crystallographic symmetry center. The central metal atom Sm is coordinated to two Cp' rings, two bridging chlorine atoms and one THF forming a distorted trigonal bipyramid. The crystal of [Cp'_2ErCl]_2 (3) belongs to the triclinic space group P(?) with a = 11.264 (2), b= 13.296(5), c = 14.296(6)(?), a = 96.99 (3), β= 112.47(2), γ= 102.78(2)°, V= 1865(1)(?)~3, D_c= 1.67 g /cm^3, μ= 48.0 cm^(-1), F(000) = 924, Z = 2 (dimers). The molecule is a dimer consisting of two Cp'_2 ErCl species bridged by two Cl atoms. The central metal atom Er is coordinated to two Cp' rings and two bridging chlorine atoms forming a pseudo- tetrahedron. All these complexes are soluble in THF, DME, Et_2O, toluene and hexane.展开更多
文摘The crystal structure of di-hydroxyisobutyrate)diaquo neodymium nitrate Nd(C_4H_7O_3)_2NO_32H_2O was determined by X-ray diffraction analysis. It belongs to monoclinic,space group C2/C,with cell dimensionsa=8.996(1), b=8.601(1),c=21.111(3),β=92.38°,V=1632.O,Z=4,D_c=1.83g/cm^3.Crystal structure has been refined by full-matrix least-square techniques giving a final R value of 0.036.The neodymium atom is coordinated to eight oxygen atoms.The nitrate group in complex is not bonded to neodymium,each two neodymium atoms are linked by bridging carboxyl group forming a chain polymeric molecule.
文摘(CH_3OCH_2CH_2C_5H_4)_2LnI(Ln=La,Nd)complexes have been synthesized by the reaction between NaI and[(CH_3OCH_2CH_2C_5H_4)_2LnCl]2 in THF;A single crystal X-ray study has shown that the lanthanum complex is an unsolvated monomer with lanthanum(Ⅲ)in a trigonal bipyramidal coordination geometry if the cyclopentadienyl ring is regarded as occupying a single polyhedral vertex.
文摘proach change of CGRP with time in periodontal ligaments of rats in magnetic field, maxillae of 28 Wistar rats of 6 7 weeks were placed in magnetic fields of permanent magnets Nd 2 Fe 4 B. Changes of CGRP with t ime in maxillary periodontal ligaments of the rats were studied by immunohistochemistry. The result showed that: magnetic field had dynamic effect and some promotional effect on recove?E F F E C T O F M A G N E T I C F I E L D O N C A L C I T O N I N G E N E- R E L A T E D P E P T I D E I N P E R I O D O N T A L L I G A M E N T S O F R A T S X. Chang , K. Qin and Y. L. Lu Orthodontic Department of Stomatology College , China Medical University , Shenyang 110001 , China Manuscript received 24 June 1999 In order to approach change of C G R P with tim e in periodontal liga m ents of rats in m agneticfield , m axillae of 28 Wistar rats of 6 7 weeks w ere placed in m agnetic fields of per m anentm agnets Nd 2 Fe4 B. Changes of C G R P with tim e in m axillary periodontal liga ments of therats were stu died by i m m unohistoche mistry . The result sho wed that : m agnetic field had dy na m ic effect an d so m e pro motional effect on recovering and reconstruction of the periodontaltissues in it . This provided a better theoretical evidence for clinical use of per m anent m agnets .
基金supported by the National Natural Science Foundation of China(No.11104234)
文摘The output characteristics of neodymium-doped gadolinium vanadate(Nd:GdVO4) crystals laser with dual c-axis orthogonal gains end-pumped by two fiber-coupled diode lasers are investigated. With two 1 W semiconductor diode lasers pumping, the output power of TEM00 laser is 920 m W, and the optical conversion efficiency is close to 46%. By changing the relative orientations of both Nd:Gd VO4 crystals, the polarization characteristics of laser are varied. In particular, by keeping the c-axes of two Nd:Gd VO4 crystals orthogonal to each other and adjusting two diode pump lasers to operate at the same power level, the completely unpolarized light is obtained.
文摘Reactions of lanthanoid trichlorides with sodium cyclopentylcyclopentadienyl in THF afford bis(cyclopentylcyclopentadienyl) lanthanoid chloride complexes (C_5H_9C_5H_4)_2LnCl(THF)_n (Ln= Nd, Sm, n=1; Ln= Er, Yb, n= 0). The compound [CP'_2SmCl(THF)]_2 (2) (Cp' =cyclopentylcy- clopentadienyl) crystallizes from mixed solvent of hexane and THF in monoclinic space group P_2_1/c with a = 11.583 (3), b = 23.019(6), c = 8.227 (2)(?), β= 90.26 (2)°, V= 2194 (1)(?)~3, D_c= 1.59 g/cm^3. μ= 28.6 cm^(-1), F(000) = 1060, Z= 2 (dimers). Its crystal molecule is a dimer with a crystallographic symmetry center. The central metal atom Sm is coordinated to two Cp' rings, two bridging chlorine atoms and one THF forming a distorted trigonal bipyramid. The crystal of [Cp'_2ErCl]_2 (3) belongs to the triclinic space group P(?) with a = 11.264 (2), b= 13.296(5), c = 14.296(6)(?), a = 96.99 (3), β= 112.47(2), γ= 102.78(2)°, V= 1865(1)(?)~3, D_c= 1.67 g /cm^3, μ= 48.0 cm^(-1), F(000) = 924, Z = 2 (dimers). The molecule is a dimer consisting of two Cp'_2 ErCl species bridged by two Cl atoms. The central metal atom Er is coordinated to two Cp' rings and two bridging chlorine atoms forming a pseudo- tetrahedron. All these complexes are soluble in THF, DME, Et_2O, toluene and hexane.
