Highly active MCM-41 supported nickel phosphide catalysts for hydrodesulfurization （HDS） were synthesized by two different phosphorus sources, in which the surface of Ni2P catalysts were modified by air instead of b...Highly active MCM-41 supported nickel phosphide catalysts for hydrodesulfurization （HDS） were synthesized by two different phosphorus sources, in which the surface of Ni2P catalysts were modified by air instead of being passivated by O2/N2 mixture. In addition, the catalysts need not be activated with flowing H2 （30 ml·min^-1） at 500℃ for 2 h prior to reaction as traditional method. X-ray diffraction （XRD）, X-ray photoelectro spectroscopy （XPS）, N2-adsorption specific surface area measurements and CO chemisorption were used to characterize the resulting catalysts. The effect of modification with air on the surface of the catalysts for HDS performance was investigated. Results showed that the surface modification with air can promote the formation of smaller Ni2P particles and more active Ni sites on surface of catalysts. At 3.0 MPa and 613 K, the dibenzothiophene （DBT） conversion of the catalysts modified with air was 98.7%, which was 7.1% higher than that of catalyst passivated by O2/N2 mixture. The higher activities of Ni2P（x）/M41-O catalysts can be attributed to the smaller Ni2P particles sizes and the increased hydrogen dissociation activity due to the surface modification.展开更多
基金Supported by the National Natural Science Foundation of China(21276048)the Project of Education Department of Heilongjiang Province,China(12541060)the Graduate Innovation Project of Northeast Petroleum University,China(YJSCX2016-019NEPU)
文摘Highly active MCM-41 supported nickel phosphide catalysts for hydrodesulfurization （HDS） were synthesized by two different phosphorus sources, in which the surface of Ni2P catalysts were modified by air instead of being passivated by O2/N2 mixture. In addition, the catalysts need not be activated with flowing H2 （30 ml·min^-1） at 500℃ for 2 h prior to reaction as traditional method. X-ray diffraction （XRD）, X-ray photoelectro spectroscopy （XPS）, N2-adsorption specific surface area measurements and CO chemisorption were used to characterize the resulting catalysts. The effect of modification with air on the surface of the catalysts for HDS performance was investigated. Results showed that the surface modification with air can promote the formation of smaller Ni2P particles and more active Ni sites on surface of catalysts. At 3.0 MPa and 613 K, the dibenzothiophene （DBT） conversion of the catalysts modified with air was 98.7%, which was 7.1% higher than that of catalyst passivated by O2/N2 mixture. The higher activities of Ni2P（x）/M41-O catalysts can be attributed to the smaller Ni2P particles sizes and the increased hydrogen dissociation activity due to the surface modification.
