The Baimazhai Ni-Cu- (PGE) sulphide deposit in southeast Yunnan Province is hosted in mafic-ultramafic intrusions associated with the Permian Emeishan large igneous province. The deposit, one of several in the provinc...The Baimazhai Ni-Cu- (PGE) sulphide deposit in southeast Yunnan Province is hosted in mafic-ultramafic intrusions associated with the Permian Emeishan large igneous province. The deposit, one of several in the province, exhibits field and petrographic features suggestive of post-magmatic modification. The mafic-ultramafic intrusions that host the Baimazhai sulphide ores show near-pervasive to pervasive hydrothermal alteration, with the sulphides be- ing spatially associated with hydrothermal minerals such as biotite, amphibole and chlorite. This intimate association suggests that the sulphide ores were subjected to deformational and hydrothermal redistribution and textural changes resulting in disseminated and brecciated ores. Geochemically the Baimazhai sulphide ores are enriched in Cu, Pd and Au which, according to published studies, reflects the action of hydrothermal fluids. Interestingly, Ar-Ar age data yielded plateau ages of about 160-170 Ma, which also supports the modification features of the sulfide ores.展开更多
Magmatic Ni-Cu-(PGE) sulfide and Fe-Ti oxide deposits in plume-related large igneous provinces(LIPs)are commonly related to low-Ti and high-Ti series magmas, respectively, but the major factors that control such a rel...Magmatic Ni-Cu-(PGE) sulfide and Fe-Ti oxide deposits in plume-related large igneous provinces(LIPs)are commonly related to low-Ti and high-Ti series magmas, respectively, but the major factors that control such a relationship of metallogenic types and magma compositions are unclear. Magma fOcontrols sulfur status and relative timing of Fe-Ti oxide saturation in mafic magmas, which may help clarify this issue. Taking the Emeishan LIP as a case, we calculated the magma fOof the high-Ti and low-Ti picrites based on the olivine-spinel oxygen barometer, and the partitioning of V in olivine. The obtained fOof the high-Ti series magma(FMQ + 1.1 to FMQ + 2.6) is higher than that of the low-Ti series magma(FMQ-0.5to FMQ + 0.5). The magma fOof the high-Ti and low-Ti picrites containing Fo > 90 olivine reveals that the mantle source of the high-Ti series is likely more oxidized than that of the low-Ti series. The results using the ’lambda REE’ approach show that the high-Ti series may have been derived from relatively oxidized mantle with garnet pyroxenite component. The S contents at sulfide saturation(SCSS) of the two series magmas were calculated based on liquid compositions obtained from the alpha Melts modeling, and the results show that the low-Ti series magma could easily attain the sulfide saturation as it has low fOwith S being dominantly as S. In contrast, the oxidized high-Ti series magma is difficult to attain the sulfide saturation, but could crystallize Fe-Ti oxides at magma MgO content of ~7.0 wt.%. Thus, contrasting magma fOof low-Ti and high-Ti series in plume-related LIPs may play an important role in producing two different styles of metallogeny.展开更多
基金Projects 2002GH11 supported by the International Coorperation Project of Yunnan Province and 2003D0039Q by The Natural Science Fund of Yunnan Province
文摘The Baimazhai Ni-Cu- (PGE) sulphide deposit in southeast Yunnan Province is hosted in mafic-ultramafic intrusions associated with the Permian Emeishan large igneous province. The deposit, one of several in the province, exhibits field and petrographic features suggestive of post-magmatic modification. The mafic-ultramafic intrusions that host the Baimazhai sulphide ores show near-pervasive to pervasive hydrothermal alteration, with the sulphides be- ing spatially associated with hydrothermal minerals such as biotite, amphibole and chlorite. This intimate association suggests that the sulphide ores were subjected to deformational and hydrothermal redistribution and textural changes resulting in disseminated and brecciated ores. Geochemically the Baimazhai sulphide ores are enriched in Cu, Pd and Au which, according to published studies, reflects the action of hydrothermal fluids. Interestingly, Ar-Ar age data yielded plateau ages of about 160-170 Ma, which also supports the modification features of the sulfide ores.
基金supported by grants from the National Natural Science Foundation of China (Nos. 41902077, 41730423 and 41921003)China Postdoctoral Science Foundation Grant (No. 2019M653103)Science and Technology Planning of Guangdong Province, China (2020B1212060055)。
文摘Magmatic Ni-Cu-(PGE) sulfide and Fe-Ti oxide deposits in plume-related large igneous provinces(LIPs)are commonly related to low-Ti and high-Ti series magmas, respectively, but the major factors that control such a relationship of metallogenic types and magma compositions are unclear. Magma fOcontrols sulfur status and relative timing of Fe-Ti oxide saturation in mafic magmas, which may help clarify this issue. Taking the Emeishan LIP as a case, we calculated the magma fOof the high-Ti and low-Ti picrites based on the olivine-spinel oxygen barometer, and the partitioning of V in olivine. The obtained fOof the high-Ti series magma(FMQ + 1.1 to FMQ + 2.6) is higher than that of the low-Ti series magma(FMQ-0.5to FMQ + 0.5). The magma fOof the high-Ti and low-Ti picrites containing Fo > 90 olivine reveals that the mantle source of the high-Ti series is likely more oxidized than that of the low-Ti series. The results using the ’lambda REE’ approach show that the high-Ti series may have been derived from relatively oxidized mantle with garnet pyroxenite component. The S contents at sulfide saturation(SCSS) of the two series magmas were calculated based on liquid compositions obtained from the alpha Melts modeling, and the results show that the low-Ti series magma could easily attain the sulfide saturation as it has low fOwith S being dominantly as S. In contrast, the oxidized high-Ti series magma is difficult to attain the sulfide saturation, but could crystallize Fe-Ti oxides at magma MgO content of ~7.0 wt.%. Thus, contrasting magma fOof low-Ti and high-Ti series in plume-related LIPs may play an important role in producing two different styles of metallogeny.