Effect of nitrogen pressure on optical properties and microstructure of diamond-like carbon films grown by pulsed laser deposition

The effect of nitrogen pressure on optical properties of hydrogen-free diamond-like carbon (DLC) films deposited by pulsed laser ablation graphite in different background pressures of nitrogen is reported. By varying nitrogen pressures from 0.05 to 15.00 Pa, the photoluminescence is gradually increased and optical transmittance is gradually decreased. Atomic force microscopy (AFM) is used to observe the surface morphology of the DLC films. The results indicate that the surface becomes unsmoothed and there are some globose particles on the films surface with the rise of nitrogen pressures. The microstructure of the films is characterized using Raman spectroscopy.

Modeling, analysis, and screening of cyclic pressure pulsing with nitrogen in hydraulically fractured wells

Cyclic pressure pulsing with nitrogen is studied for hydraulically fractured wells in depleted reservoirs.A compositional simulation model is constructed to represent the hydraulic fractures through local-grid refinement.The process is analyzed from both operational and reservoir/hydraulic-fracture perspectives.Key sensitivity parameters for the operational component are chosen as the injection rate,lengths of injection and soaking periods and the economic rate limit to shut-in the well.For the reservoir/hydraulic fracturing components,reservoir permeability,hydraulic fracture permeability,effective thickness and half-length are used.These parameters are varied at five levels.A full-factorial experimental design is utilized to run 1250 cases.The study shows that within the ranges studied,the gas-injection process is applied successfully for a 20-year project period with net present values based on the incremental recoveries greater than zero.It is observed that the cycle rate limit,injection and soaking periods must be optimized to maximize the efficiency.The simulation results are used to develop a neural network based proxy model that can be used as a screening tool for the process.The proxy model is validated with blind-cases with a correlation coefficient of 0.96.

Producing ultra-high-speed nitrogen jets by arc heating in a low-pressure chamber

Pure nitrogen gas was heated with direct current arc, at input powers from several hundred Watt to over 5 kW, and then injected through a nozzle into a chamber at 1 or 10 Pa pressure, with the purpose of accelerating the gas to very high speed around 7 km/s. Various structures of the arc generator and gas expansion nozzle were examined. Results show that bypass exhausting of the boundary layer before it enters the nozzle divergent section can greatly increase flow speed of the jet, thus it might be possible to use nitrogen as a working gas in high speed gas dynamic test facilities.

THE EFFECTS OF PULSE BIAS VOLTAGE AND N_2 PARTIAL PRESSURE ON TiAlN FILMS OF ARC ION PLATING (AIP)

Owing to the characteristics of arc ion plating(AIP) technique, the structure and composition of TiAlN films can be tailored by controlling of various parameters such as compositions of target materials, N2 partial pressure, substrate bias and so on. In this study, several titanium aluminum nitride films were deposited on 1Cr11Ni2W2MoV steel for compressor blade of areo-engine under different d.c pulse bias voltage and nitrogen partial pressure. The effects of substrate pulse bias and nitrogen partial pressure on the deposition rate, droplet formation, microstruture and elemental component of the films were investigated.

Determination of 16 Species of OCPs in Water by Liquid-liquid Extraction-GC

[Objective] The research aimed to study the determination of 16 kinds of OCPs in water by liquid-liquid extraction -GC. [Method] The new method for determining 16 kinds of OCPs in water by liquid-liquid extraction -GC was established, and the influencing factors such as nitrogen pressure and water bath temperature were discussed. [ Result] Detection limit of the method was from 3.2 to 14.1 ng/L, the relative standard deviation was between 4.0% and 9.6%, and the average recovery ranged from 80.8% to 106.0%. By optimizing nitrogen pressure and water bath temperature in the sample pretreatment process, when nitrogen pressure was ＋0.087 kPa, and water bath temperature was ±36 ℃, recovery effect of this method was better. [ Conclusion] The determination method had accurate qualitative and quantitative results, and met detection requirement of 16 kinds of OCPs in water.