To solve the problem of only surface carbonation and realize high-efficiency carbonation of recycled coarse aggregate,the method of carbonated recycled coarse aggregate with nano materials pre-soaking was first put fo...To solve the problem of only surface carbonation and realize high-efficiency carbonation of recycled coarse aggregate,the method of carbonated recycled coarse aggregate with nano materials pre-soaking was first put forward.The carbonation effect of modified recycled coarse aggregate with three different carbonation methods was evaluated,and water absorption,apparent density and crush index of modified recycled coarse aggregate were measured.Combined with XRD,SEM,and MIP microscopic analysis,the high-efficiency carbonation strengthening mechanism of modified recycled coarse aggregate was revealed.The experimental results show that,compared with the non-carbonated recycled coarse aggregate,the physical and microscopic properties of carbonated recycled coarse aggregate are improved.The method of carbonation with nano-SiO_(2) pre-soaking can realize the high-efficiency carbonation of recycled coarse aggregate,for modified recycled coarse aggregate with the method,water absorption is reduced by 23.03%,porosity is reduced by 44.06%,and the average pore diameter is 21.82 nm.The high-efficiency carbonation strengthening mechanism show that the pre-socked nano-SiO_(2) is bound to the hydration product Ca(OH)_(2) of the old mortar with nano-scale C-S-H,which can improve the CO_(2) absorption rate,accelerate the carbonation reaction,generate more stable CaCO_(3) and nano-scale silica gel,and bond to the dense three-dimensional network structure to realize the bidirectional enhancement of nano-materials and pressurized carbonation.It is concluded that the method of carbonation with nano-SiO_(2) pre-soaking is a novel high-efficiency carbonation modification of recycled coarse aggregate.展开更多
In order to understand the melting processes that occur within recycled oceanic crust and mantle in a heterogeneous plume (e.g., that beneath the Hawaiian Islands), a series of high-pressure-high-temperature layered e...In order to understand the melting processes that occur within recycled oceanic crust and mantle in a heterogeneous plume (e.g., that beneath the Hawaiian Islands), a series of high-pressure-high-temperature layered experiments were performed at 2.9 GPa, 5 GPa, and 8 GPa, from 1300°C to 1650°C, using a fertile peridotite KLB-1 and N-MORB. Our experiments at conditions below the dry peridotite solidus produced melt compositions that ranged from basaltic andesite to tholeiite. An Opx reaction band formed between eclogite and peridotite layers, likely via chemical reaction between a silica-rich eclogite-derived partial melt and olivine in the peridotite matrix. At temperatures at or above the dry peridotite solidus, substantial melting occurred in both basalt and peridotite layers, and fully molten basalt melt and melt pockets from the peridotite layer combined. In our layered experiments, major and minor element contents in reacted melts closely matched those of Hawaiian tholeiite and picrite, except for Fe. Partial melts of anhydrous run products had ~55 - 57 wt% SiO2 at low temperature (i.e., were andesitic) and had ~50 - 53 wt% SiO2 at high temperatures, slightly below the dry peridotite solidus (i.e., were tholeiitic, and similar to those that occur during the Hawaii shield-building stage). Based on the Fe- and LREE-enriched signature in Hawaiian tholeiites, we propose that recycled components in the Hawaiian plume are not modern N-MORB, but are Fe-rich tholeiite;a lithology that was common in the Archaean and early Proterozoic. We have demonstrated that the entire compositional spectrum of Hawaiian tholeiites (basalt to picrite) can be formed by basalt-peridotite reactive melting near the dry solidus of peridotite. Based on these results, we propose that the potential temperature of the sub-Hawaiian plume may be much lower than previously estimated.展开更多
In order to study the axial compression performances of short columns made of recycled aggregate concrete,four samples were designed with different recycled aggregate replacement rates and carbon fibre reinforced plas...In order to study the axial compression performances of short columns made of recycled aggregate concrete,four samples were designed with different recycled aggregate replacement rates and carbon fibre reinforced plastics(CFRP)sheets.Then,monotonic loading was implemented to assess the variation trends of their axial compression properties.The ABAQUS finite element software was also used to determined the compression performances.Good agreement between experimental and numerical results has been found for the different parameters being considered.As shown by the results,recycled coarse aggregates result in improved ductility and better deformation performance of the specimens.The failure of specimens caused by pre damage can be compensated by using CFRP sheets,by which both the resistance to deformation and the axial carrying capacity of columns can be increased.展开更多
Microwave heating,which is used for pre-treatment of concrete before it is comminuted,stands as a strong candidate for selective liberation of multiphase materials like concrete.This paper is concerned with the select...Microwave heating,which is used for pre-treatment of concrete before it is comminuted,stands as a strong candidate for selective liberation of multiphase materials like concrete.This paper is concerned with the selective liberation of concrete's raw constituents(particularly aggregate)for recycling by considering the water content of concrete as a parameter of microwave heating for the first time.The deterioration law of the concrete's performance was characterized by the variation in the splitting tensile strength and relative dynamic modulus after heating by microwave at different water contents.Besides,tests were conducted to evaluate the performance of the interface transition zone(ITZ)between aggregate and mortar as well as to investigate the reasons for the stripping behavior of aggregate-mortar,which included the interface tensile strength test,temperature measurement,and porosity test.The deterioration law of splitting tensile strength and relative dynamic modulus revealed that the performance of concrete was subject to different degrees of damage depending on the water content.Furthermore,experimental results showed that interface bonding strength between aggregate and mortar was dramatically impaired,and a large temperature difference was generated between the aggregate and mortar during microwave heating.Meanwhile,the permeable pores increased considerably even when the specimens were dried.In the presence of water,the intactness of ITZ between aggregate and mortar was destroyed by microwave heating,and its performance was significantly lowered,which led to the occurrence of stripping behavior between aggregate and mortar.This was reaffirmed by the microstructure presented by scanning electron microscopy.Thus,the newly developed microwave pretreatment improved by providing appropriate water contents for concrete corresponding to different strength grades is a promising method for recycling aggregate from waste concrete.展开更多
A new ambient ion source was developed and its application to real samples has been demonstrated.This ion source is based on a previously build ion source using chemical ionization under atmospheric pressure and extra...A new ambient ion source was developed and its application to real samples has been demonstrated.This ion source is based on a previously build ion source using chemical ionization under atmospheric pressure and extractive electrospray ionization(DIP-APCI/EESI).To enhance the range of analytes,we added to this ion source a photoionization lamp to enable also photoionization,which allows the possibility to analyze polar(EESI),middle(APCI)and non-polar(APPI)analytes with the same source and with no or only a small change of the setup.In comparison with DIP-APCI,this ion source reaches similar analytical limits but shows better sensitivity for some aromatic and non-polar analytes.The analysis of bisphenol A from extracts of recycled paper demonstrates the use of this ion source for real samples.Quantification was possible by the use of a deuterated internal standard that was added to the papers before extraction.Here atmospheric pressure chemical ionization leads to bad results due to ion suppression,whereas atmospheric pressure photoionization shows results that fit to literature values.展开更多
基金Funded by Joint Funds of the National Natural Science Foundation of China(No.U1904188)the Jiangxi Provincial Department of Education Science and Technology Project(Nos.GJJ171079,GJJ181023,and GJJ181022)。
文摘To solve the problem of only surface carbonation and realize high-efficiency carbonation of recycled coarse aggregate,the method of carbonated recycled coarse aggregate with nano materials pre-soaking was first put forward.The carbonation effect of modified recycled coarse aggregate with three different carbonation methods was evaluated,and water absorption,apparent density and crush index of modified recycled coarse aggregate were measured.Combined with XRD,SEM,and MIP microscopic analysis,the high-efficiency carbonation strengthening mechanism of modified recycled coarse aggregate was revealed.The experimental results show that,compared with the non-carbonated recycled coarse aggregate,the physical and microscopic properties of carbonated recycled coarse aggregate are improved.The method of carbonation with nano-SiO_(2) pre-soaking can realize the high-efficiency carbonation of recycled coarse aggregate,for modified recycled coarse aggregate with the method,water absorption is reduced by 23.03%,porosity is reduced by 44.06%,and the average pore diameter is 21.82 nm.The high-efficiency carbonation strengthening mechanism show that the pre-socked nano-SiO_(2) is bound to the hydration product Ca(OH)_(2) of the old mortar with nano-scale C-S-H,which can improve the CO_(2) absorption rate,accelerate the carbonation reaction,generate more stable CaCO_(3) and nano-scale silica gel,and bond to the dense three-dimensional network structure to realize the bidirectional enhancement of nano-materials and pressurized carbonation.It is concluded that the method of carbonation with nano-SiO_(2) pre-soaking is a novel high-efficiency carbonation modification of recycled coarse aggregate.
文摘In order to understand the melting processes that occur within recycled oceanic crust and mantle in a heterogeneous plume (e.g., that beneath the Hawaiian Islands), a series of high-pressure-high-temperature layered experiments were performed at 2.9 GPa, 5 GPa, and 8 GPa, from 1300°C to 1650°C, using a fertile peridotite KLB-1 and N-MORB. Our experiments at conditions below the dry peridotite solidus produced melt compositions that ranged from basaltic andesite to tholeiite. An Opx reaction band formed between eclogite and peridotite layers, likely via chemical reaction between a silica-rich eclogite-derived partial melt and olivine in the peridotite matrix. At temperatures at or above the dry peridotite solidus, substantial melting occurred in both basalt and peridotite layers, and fully molten basalt melt and melt pockets from the peridotite layer combined. In our layered experiments, major and minor element contents in reacted melts closely matched those of Hawaiian tholeiite and picrite, except for Fe. Partial melts of anhydrous run products had ~55 - 57 wt% SiO2 at low temperature (i.e., were andesitic) and had ~50 - 53 wt% SiO2 at high temperatures, slightly below the dry peridotite solidus (i.e., were tholeiitic, and similar to those that occur during the Hawaii shield-building stage). Based on the Fe- and LREE-enriched signature in Hawaiian tholeiites, we propose that recycled components in the Hawaiian plume are not modern N-MORB, but are Fe-rich tholeiite;a lithology that was common in the Archaean and early Proterozoic. We have demonstrated that the entire compositional spectrum of Hawaiian tholeiites (basalt to picrite) can be formed by basalt-peridotite reactive melting near the dry solidus of peridotite. Based on these results, we propose that the potential temperature of the sub-Hawaiian plume may be much lower than previously estimated.
文摘In order to study the axial compression performances of short columns made of recycled aggregate concrete,four samples were designed with different recycled aggregate replacement rates and carbon fibre reinforced plastics(CFRP)sheets.Then,monotonic loading was implemented to assess the variation trends of their axial compression properties.The ABAQUS finite element software was also used to determined the compression performances.Good agreement between experimental and numerical results has been found for the different parameters being considered.As shown by the results,recycled coarse aggregates result in improved ductility and better deformation performance of the specimens.The failure of specimens caused by pre damage can be compensated by using CFRP sheets,by which both the resistance to deformation and the axial carrying capacity of columns can be increased.
基金the financial support from the open project funds for National Major Science and Technology Infrastructure of Materials Service Safety Assessment Facilities,China(MSAF-2020-106)the National Natural Science Foundation of China(No.51808051)。
文摘Microwave heating,which is used for pre-treatment of concrete before it is comminuted,stands as a strong candidate for selective liberation of multiphase materials like concrete.This paper is concerned with the selective liberation of concrete's raw constituents(particularly aggregate)for recycling by considering the water content of concrete as a parameter of microwave heating for the first time.The deterioration law of the concrete's performance was characterized by the variation in the splitting tensile strength and relative dynamic modulus after heating by microwave at different water contents.Besides,tests were conducted to evaluate the performance of the interface transition zone(ITZ)between aggregate and mortar as well as to investigate the reasons for the stripping behavior of aggregate-mortar,which included the interface tensile strength test,temperature measurement,and porosity test.The deterioration law of splitting tensile strength and relative dynamic modulus revealed that the performance of concrete was subject to different degrees of damage depending on the water content.Furthermore,experimental results showed that interface bonding strength between aggregate and mortar was dramatically impaired,and a large temperature difference was generated between the aggregate and mortar during microwave heating.Meanwhile,the permeable pores increased considerably even when the specimens were dried.In the presence of water,the intactness of ITZ between aggregate and mortar was destroyed by microwave heating,and its performance was significantly lowered,which led to the occurrence of stripping behavior between aggregate and mortar.This was reaffirmed by the microstructure presented by scanning electron microscopy.Thus,the newly developed microwave pretreatment improved by providing appropriate water contents for concrete corresponding to different strength grades is a promising method for recycling aggregate from waste concrete.
基金We are thankful to iGenTrax UG and SIM GmbH for technical supportFurthermore,we acknowledge AIF for financial support due to project number KF2210314NT3.
文摘A new ambient ion source was developed and its application to real samples has been demonstrated.This ion source is based on a previously build ion source using chemical ionization under atmospheric pressure and extractive electrospray ionization(DIP-APCI/EESI).To enhance the range of analytes,we added to this ion source a photoionization lamp to enable also photoionization,which allows the possibility to analyze polar(EESI),middle(APCI)and non-polar(APPI)analytes with the same source and with no or only a small change of the setup.In comparison with DIP-APCI,this ion source reaches similar analytical limits but shows better sensitivity for some aromatic and non-polar analytes.The analysis of bisphenol A from extracts of recycled paper demonstrates the use of this ion source for real samples.Quantification was possible by the use of a deuterated internal standard that was added to the papers before extraction.Here atmospheric pressure chemical ionization leads to bad results due to ion suppression,whereas atmospheric pressure photoionization shows results that fit to literature values.
