Evaluation of Non Crystalline Phase in AZS Refractories by XRD Methods

The relation between the atomic structure and the macroscopic properties and behaviors of a material constitute one of the objectives of the materials science, particularly in the design and development of ceramic materials.Crystalline and non crystalline phases together with pores, grain boundaries, etc. affect mechanical and fracture properties as well as chemical resistance and electric properties. These aspects will be bonded to the raw materials chosen and the whole processing route.In glass industry, although there are other electrofused refractories such as the alumina ones used in the feeding of the fusion kilns, probably the most used refractories in contact with the melted glass are electrofused materials that belong to the Al2O3-SiO2-ZrO2 system commonly named AZS.Exceptionally for refractory materials the amount of the glassy phase in a AZS material is important and appreciable;and makes them particularly adequate for containing fussed glass. The glass proportion will define much of their properties and behaviors.In the present work the results of the non crystalline phase quantification of two samples of commercial AZS materials are presented and compared. These were obtained by three different methods using in the X ray powder diffraction (XRD) techniques. The first method consists in the linear interpolation of the base lines of the diffractograms compared to the amorphous silica and the fully crystalline quartz. The other two methods are based in the application of the Rietveld method. One is the internal standard method with quartz as fully crystalline standard and the other one consist in the inclusion of the glassy phase to the refinement with a structural model that can be understood as the widening of the peaks consequence of an extreme decrease in the crystallite size of a quartz phase.The three methods showed equivalent results (with differences less than 3%) for the two samples and demonstrated that are adequate for the quantification of the non crystalline phase in this kind of materials.

Consistency and Validity of the Mathematical Models and the Solution Methods for BVPs and IVPs Based on Energy Methods and Principle of Virtual Work for Homogeneous Isotropic and Non-Homogeneous Non-Isotropic Solid Continua

Energy methods and the principle of virtual work are commonly used for obtaining solutions of boundary value problems (BVPs) and initial value problems (IVPs) associated with homogeneous, isotropic and non-homogeneous, non-isotropic matter without using (or in the absence of) the mathematical models of the BVPs and the IVPs. These methods are also used for deriving mathematical models for BVPs and IVPs associated with isotropic, homogeneous as well as non-homogeneous, non-isotropic continuous matter. In energy methods when applied to IVPs, one constructs energy functional (I) consisting of kinetic energy, strain energy and the potential energy of loads. The first variation of this energy functional (δI) set to zero is a necessary condition for an extremum of I. In this approach one could use δI = 0 directly in constructing computational processes such as the finite element method or could derive Euler’s equations (differential or partial differential equations) from δI = 0, which is also satisfied by a solution obtained from δI = 0. The Euler’s equations obtained from δI = 0 indeed are the mathematical model associated with the energy functional I. In case of BVPs we follow the same approach except in this case, the energy functional I consists of strain energy and the potential energy of loads. In using the principle of virtual work for BVPs and the IVPs, we can also accomplish the same as described above using energy methods. In this paper we investigate consistency and validity of the mathematical models for isotropic, homogeneous and non-isotropic, non-homogeneous continuous matter for BVPs that are derived using energy functional consisting of strain energy and the potential energy of loads. Similar investigation is also presented for IVPs using energy functional consisting of kinetic energy, strain energy and the potential energy of loads. The computational approaches for BVPs and the IVPs designed using energy functional and principle of virtual work, their consistency and validity are also investigated. Classical continuum mechanics (CCM) principles i.e. conservation and balance laws of CCM with consistent constitutive theories and the elements of calculus of variations are employed in the investigations presented in this paper.

Almost Sure Convergence of Proximal Stochastic Accelerated Gradient Methods

Proximal gradient descent and its accelerated version are resultful methods for solving the sum of smooth and non-smooth problems. When the smooth function can be represented as a sum of multiple functions, the stochastic proximal gradient method performs well. However, research on its accelerated version remains unclear. This paper proposes a proximal stochastic accelerated gradient (PSAG) method to address problems involving a combination of smooth and non-smooth components, where the smooth part corresponds to the average of multiple block sums. Simultaneously, most of convergence analyses hold in expectation. To this end, under some mind conditions, we present an almost sure convergence of unbiased gradient estimation in the non-smooth setting. Moreover, we establish that the minimum of the squared gradient mapping norm arbitrarily converges to zero with probability one.

Determination of Bonding Failures in Transparent Materials with Non-Destructive Methods—Evaluation of Climatically Stressed Glued and Laminated Glass Compounds

As part of an international research project—funded by the European Union—capillary glasses for facades are being developed exploiting storage energy by means of fluids flowing through the capillaries. To meet highest visual demands, acrylate adhesives and EVA films are tested as possible bonding materials for the glass setup. Especially non-destructive methods (visual analysis, analysis of birefringent properties and computed tomographic data) are applied to evaluate failure patterns as well as the long-term behavior considering climatic influences. The experimental investigations are presented after different loading periods, providing information of failure developments. In addition, detailed information and scientific findings on the application of computed tomographic analyses are presented.

Variational Methods to Nonlinear Differential Equations with Non-instantaneous Impulses

The author aimed to investigate the solvability for nonlinear differential equations with not instantaneous impulses.Variational approach was adopted to obtain the existence of weak solutions as critical points. The findings of this study may serve as a reference for multiplicity of impulsive problems.

ANALYSIS OF NONLINEAR PIEZOELECTRIC CIRCULAR SHALLOW SPHERICAL SHELLS BY DIFFERENTIAL QUADRATURE ELEMENT METHOD

The static behavior of piezoelectric circular spherical shallow shells under both electrical and mechanical loads is studied by using the differential quadrature element method (DQEM). Geometrical nonlinearity effect is considered. Detailed formulations and procedures are given for the first time. Several examples are analyzed and accurate results are obtained by the DQEM. Based on the results in this paper, one may conclude that the DQEM is a useful tool for obtaining solutions of structural elements. It can be seen that the shell shape may be theore tically controlled and snap through may occur when the applied voltage reaches a critical value even without mechanical load for certain geometric configurations.

GLOBAL CONVERGENCE RESULTS OF A THREE TERM MEMORY GRADIENT METHOD WITH A NON-MONOTONE LINE SEARCH TECHNIQUE

In this paper, a new class of three term memory gradient method with non-monotone line search technique for unconstrained optimization is presented. Global convergence properties of the new methods are discussed. Combining the quasi-Newton method with the new method, the former is modified to have global convergence property. Numerical results show that the new algorithm is efficient.

Estimation of non-point source pollution loads with flux method in Danjiangkou Reservoir area,China

The estimation of non-point source pollution loads into the Danjiangkou Reservoir is highly significant to environmental protection in the watershed. In order to overcome the drawbacks of traditional watershed numerical models, a base flow separation method was established coupled with a digital filtering method and a flux method. The digital filtering method has been used to separate the base flows of the Hanjiang,Tianhe, Duhe, Danjiang, Laoguan, and Qihe rivers. Based on daily discharge, base flow, and pollutant concentration data, the flux method was used to calculate the point source pollution load and non-point source pollution load. The results show that:(1) In the year 2013, the total inflow of the six rivers mentioned above accounted for 95.9% of the total inflow to the Danjiangkou Reservoir. The total pollution loads of chemical oxygen demand(CODMn) and total phosphorus(TP) from the six rivers were 58.20 103 t and 1.863 10~3 t, respectively, and the non-point source pollution loads were 39.82 10~3 t and 1.544 10~3 t, respectively, indicating that the non-point source pollution is a major factor(with a contribution rate of 68.4% for CODMnand 82.9% for TP).(2) The Hanjiang River is the most significant contributor of pollution loads to the Danjiangkou Reservoir, and its CODMnand TP contribution rates reached 79.3% and 83.2%, respectively. The Duhe River took the second place.(3) Non-point source pollution mainly occurred in the wet season in 2013, accounting for 80.8% and 90.9% of the total pollution loads of CODMnand TP, respectively. It is concluded that the emphasis of pollution control should be placed on non-point source pollution.

On the field method in non-holonomic mechanics

This paper deals with the generalization of the fieldmethod to non-holonomic systems whose motion is subject toeither non-linear constraints or those of a higher order,whiletheir motion is modeled by the generalized Lagrange equa-tions of the second kind.Two examples are given to illustratethe theory.

An Analytical Method for Predicting Chaos in Perturbed Planar Non-Hamiltonian System

An analytical method for predicting chaos in perturbed planar non Hamiltonian integrable systems with slowly varying parameters was developed. Based on the analysis of the geometric structure of unperturbed systems, the condition of transversely homoclinic intersection was given. The generalized Melnikov function of the perturbed system was found by applying the theorem on the differentiability of ordinary differential equation solutions with respect to parameters.

Free vibration of non-uniform axially functionally graded beams using the asymptotic development method

The asymptotic development method is applied to analyze the free vibration of non-uniform axially functionally graded(AFG) beams, of which the governing equations are differential equations with variable coefficients. By decomposing the variable flexural stiffness and mass per unit length into reference invariant and variant parts, the perturbation theory is introduced to obtain an approximate analytical formula of the natural frequencies of the non-uniform AFG beams with different boundary conditions.Furthermore, assuming polynomial distributions of Young's modulus and the mass density, the numerical results of the AFG beams with various taper ratios are obtained and compared with the published literature results. The discussion results illustrate that the proposed method yields an effective estimate of the first three order natural frequencies for the AFG tapered beams. However, the errors increase with the increase in the mode orders especially for the cases with variable heights. In brief, the asymptotic development method is verified to be simple and efficient to analytically study the free vibration of non-uniform AFG beams, and it could be used to analyze any tapered beams with an arbitrary varying cross width.

GLOBAL COVERGENCE OF THE NON-QUASI-NEWTON METHOD FOR UNCONSTRAINED OPTIMIZATION PROBLEMS

In this paper, the non-quasi-Newton＇s family with inexact line search applied to unconstrained optimization problems is studied. A new update formula for non-quasi-Newton＇s family is proposed. It is proved that the constituted algorithm with either Wolfe-type or Armijotype line search converges globally and Q-superlinearly if the function to be minimized has Lipschitz continuous gradient.

A NOVEL SEMI-ANALYTICAL METHOD FOR SOLVING ACOUSTIC RADIATION FROM LONGITUDINALLY STIFFENED INFINITE NON-CIRCULAR CYLINDRICAL SHELLS IN WATER

Based on the extended homogeneous capacity high precision integration method and the spectrum method of virtual boundary with a complex radius vector, a novel semi-analytical method, which has satisfactory computation efectiveness and precision, is presented for solving the acoustic radiation from a submerged infnite non-circular cylindrical shell stifened by longitudinal ribs by means of the Fourier integral transformation and stationary phase method. In this work, besides the normal interacting force, which is commonly adopted by some researchers, the other interacting forces and moments between the longitudinal ribs and the non-circular cylindrical shell are considered at the same time. The efects of the number and the size of the cross-section of longitudinal ribs on the characteristics of acoustic radiation are investigated. Numerical results show that the method proposed is more efcient than the existing mixed FE-BE method.

An efficient synthesis of benzofuran derivatives under conventional/non-conventional method

l-Methyl-3-ethyl imidazolium bromide[meim]Br/basic alumina（Al2O3） has been found to promote the cyclocondensation of chloroacetone/chloroethyl acetate with salicylaldehydes under conventional as well as microwave irradiation to yield benzofuran derivatives.

GENERALIZED VARIATIONAL DATA ASSIMILATION METHOD AND NUMERICAL EXPERIMENT FOR NON-DIFFERENTIAL SYSTEM

The generalized variational data assimilation for non-differential dynamical systems is studied.There is no tangent linear model for non-differential systems and thus the general adjoint model can not be derived in the traditional way.The weak form of the original system was introduced, and then the generalized adjoint model was derived. The generalized variational data assimilation methods were developed for non-differential low dimensional system and non-differential high dimensional system with global and local observations. Furthermore, ideas in inverse problems are introduced to 4DVAR (Four-dimensional variational) of non-differential partial differential system with local observations.

Free-surface Simulations of Newtonian and Non-Newtonian Fluids with the Lattice Boltzmann Method

This paper describes the application of a three-dimensional lattice Boltzmann method （LBM） to Newtonian and non-Newtonian （Bingham fluid in this work） flows with free surfaces. A mass tracking algorithm was incorporated to capture the free surface, whereas Papanastasiou＇s modified model was used for Bingham fluids. The lattice Boltzmann method was first validated using two benchmarks： Newtonian flow through a square cross-section tube and Bingham flow through a circular cross-section tube. Afterward, the dam-break problem for the Newtonian fluid and the slump test for Bingham fluid were simulated to validate the free-surface-capturing algorithm. The numerical results were in good agreement with analytical results, as well as other simulations, thereby proving the validity and correctness of the current method. The proposed method is a promising substitute for time-consuming and costly physical experiments to solve problems encountered in geotechnical and geological engineering, such as the surge and debris flow induced by a landslide or earthquake.

Thermoelastic Analysis of Non-uniform Pressurized Functionally Graded Cylinder with Variable Thickness Using First Order Shear Deformation Theory(FSDT) and Perturbation Method

Recently application of functionally graded materials（FGMs） have attracted a great deal of interest. These materials are composed of various materials with different micro-structures which can vary spatially in FGMs. Such composites with varying thickness and non-uniform pressure can be used in the aerospace engineering. Therefore, analysis of such composite is of high importance in engineering problems. Thermoelastic analysis of functionally graded cylinder with variable thickness under non-uniform pressure is considered. First order shear deformation theory and total potential energy approach is applied to obtain the governing equations of non-homogeneous cylinder. Considering the inner and outer solutions, perturbation series are applied to solve the governing equations. Outer solution for out of boundaries and more sensitive variable in inner solution at the boundaries are considered. Combining of inner and outer solution for near and far points from boundaries leads to high accurate displacement field distribution. The main aim of this paper is to show the capability of matched asymptotic solution for different non-homogeneous cylinders with different shapes and different non-uniform pressures. The results can be used to design the optimum thickness of the cylinder and also some properties such as high temperature residence by applying non-homogeneous material.

Stability analysis method considering non-parallelism:EPSE method and its application

The e-N method is widely used in transition prediction. The amplitude growth rate used in the e-N method is usually provided by the linear stability theory （LST） based on the local parallel hypothesis. Considering the non-parallelism effect, the parabolized stability equation （PSE） method lacks local characteristic of stability analysis. In this paper, a local stability analysis method considering non-parallelism is proposed, termed as EPSE since it may be considered as an expansion of the PSE method. The EPSE considers variation of the shape function in the streamwise direction. Its local characteristic is convenient for stability analysis. This paper uses the EPSE in a strong non-parallel flow and mode exchange problem. The results agree well with the PSE and the direct numerical simulation （DNS）. In addition, it is found that the growth rate is related to the normalized method in the non-parallel flow. Different results can be obtained using different normalized methods. Therefore, the normalized method must be consistent.

Numerical simulation of non-Archie electrophysical property of saturated rock with lattice Boltzmann method

The electrophysical property of saturated rocks is very important for reservoir identification and evaluation. In this paper, the lattice Boltzmann method （LBM） was used to study the electrophysical property of rock saturated with fluid because of its advantages over conventional numerical approaches in handling complex pore geometry and boundary conditions. The digital core model was constructed through the accumulation of matrix grains based on their radius distribution obtained by the measurements of core samples. The flow of electrical current through the core model saturated with oil and water was simulated on the mesoscopic scale to reveal the non-Archie relationship between resistivity index and water saturation （I-Sw）. The results from LBM simulation and laboratory measurements demonstrated that the I-Sw relation in the range of low water saturation was generally not a straight line in the log-log coordinates as described by the Archie equation. We thus developed a new equation based on numerical simulation and physical experiments. This new equation was used to fit the data from laboratory core measurements and previously published data. Determination of fluid saturation and reservoir evaluation could be significantly improved by using the new equation.