The variations of ocean environmental parameters invariably result in variations of local modal wave numbers of a sound pressure field. The asymptotic Hankel transform with a short sliding window is applied to the com...The variations of ocean environmental parameters invariably result in variations of local modal wave numbers of a sound pressure field. The asymptotic Hankel transform with a short sliding window is applied to the complex sound pressure field in the water containing a mesoscale eddy to examine the variation of local modal wave numbers in such a range-dependent environment. The numerical simulation results show that modal wave number spectra obtained by this method can reflect the location and strength of a mesoscale eddy, therefore it can be used to monitor the strength and spatial scale of ocean mesoscale eddies.展开更多
As we know, there are three structures-sⅠ, sⅡ, and sH, with hydrocarbonate gas hydrate.Because of those special structures characteristics and potentail large fossil energy resource, gas hydrate play an important ro...As we know, there are three structures-sⅠ, sⅡ, and sH, with hydrocarbonate gas hydrate.Because of those special structures characteristics and potentail large fossil energy resource, gas hydrate play an important role in natural carbonate cycle system. In this paper, CH4, CO2, C3H8, and CH4 +CO2 system have been experimental performed in order to model hydrate formation and discomposition and to obtain hydrate stability conditions of tempreature and pressure. The results from laboratory using Raman spectra show that Raman spectrascopy is a effective tool to identify hydrate structure. Raman spectra of clathrate hydrate guest molecules are presented for two structure (sⅠ and sⅡ) in the following systems: CH4, CO2, C3 H8. Relatively occupancy of CH4 in the large and small cavities of sⅠ were determined by deconvoluting the v1 symmetric bands, resulting in hydration numbers of 6.04±0.03. The freqyuency of the v1 bands for CH4 in structures Ⅰ and Ⅱ differ statistically. The large cavities were measured to be almost fully occupied by CH4 and CO2, whereas only a small fraction of the small cavities are occupied by CH4. No CO2 was found in the small cavities.展开更多
In this paper, we give out the formula of number of primes no more than any given n (n ∈ Z<sup>+</sup>, n > 2). At the same time, we also show the principle, derivation process of the formula and appli...In this paper, we give out the formula of number of primes no more than any given n (n ∈ Z<sup>+</sup>, n > 2). At the same time, we also show the principle, derivation process of the formula and application examples, it is usually marked with π(n), which is: that is: where “[ ]” denotes taking integer. r = 1,2,3,4,5,6;s<sub>x</sub> = s<sub>1</sub>,s<sub>2</sub>,...,s<sub>j</sub>,s<sub>h</sub>;s1</sub>,s2</sub>,...,s<sub>j</sub>,,s<sub>h </sub><sub>= 0,1,2,3,....</sub>As i ≥ 2, 2 ≤ s<sub>x </sub>≤ i-1 (x=1,2,...,j,h).展开更多
The full-spectrum least-squares(FSLS) method is introduced to perform quantitative energy-dispersive X-ray fluorescence analysis for unknown solid samples.Based on the conventional least-squares principle, this spectr...The full-spectrum least-squares(FSLS) method is introduced to perform quantitative energy-dispersive X-ray fluorescence analysis for unknown solid samples.Based on the conventional least-squares principle, this spectrum evaluation method is able to obtain the background-corrected and interference-free net peaks, which is significant for quantization analyses. A variety of analytical parameters and functions to describe the features of the fluorescence spectra of pure elements are used and established, such as the mass absorption coefficient, the Gi factor, and fundamental fluorescence formulas. The FSLS iterative program was compiled in the C language. The content of each component should reach the convergence criterion at the end of the calculations. After a basic theory analysis and experimental preparation, 13 national standard soil samples were detected using a spectrometer to test the feasibility of using the algorithm. The results show that the calculated contents of Ti, Fe, Ni, Cu, and Zn have the same changing tendency as the corresponding standard content in the 13 reference samples. Accuracies of 0.35% and 14.03% are obtained, respectively, for Fe and Ti, whose standard concentrations are 8.82% and 0.578%, respectively. However, the calculated results of trace elements (only tens of lg/g) deviate from the standard values. This may be because of measurement accuracy and mutual effects between the elements.展开更多
文摘The variations of ocean environmental parameters invariably result in variations of local modal wave numbers of a sound pressure field. The asymptotic Hankel transform with a short sliding window is applied to the complex sound pressure field in the water containing a mesoscale eddy to examine the variation of local modal wave numbers in such a range-dependent environment. The numerical simulation results show that modal wave number spectra obtained by this method can reflect the location and strength of a mesoscale eddy, therefore it can be used to monitor the strength and spatial scale of ocean mesoscale eddies.
基金Supported by the National Natural Science Foundation of China (No. 49973024, 40272066)211 Projects of Xiamen University.
文摘As we know, there are three structures-sⅠ, sⅡ, and sH, with hydrocarbonate gas hydrate.Because of those special structures characteristics and potentail large fossil energy resource, gas hydrate play an important role in natural carbonate cycle system. In this paper, CH4, CO2, C3H8, and CH4 +CO2 system have been experimental performed in order to model hydrate formation and discomposition and to obtain hydrate stability conditions of tempreature and pressure. The results from laboratory using Raman spectra show that Raman spectrascopy is a effective tool to identify hydrate structure. Raman spectra of clathrate hydrate guest molecules are presented for two structure (sⅠ and sⅡ) in the following systems: CH4, CO2, C3 H8. Relatively occupancy of CH4 in the large and small cavities of sⅠ were determined by deconvoluting the v1 symmetric bands, resulting in hydration numbers of 6.04±0.03. The freqyuency of the v1 bands for CH4 in structures Ⅰ and Ⅱ differ statistically. The large cavities were measured to be almost fully occupied by CH4 and CO2, whereas only a small fraction of the small cavities are occupied by CH4. No CO2 was found in the small cavities.
文摘In this paper, we give out the formula of number of primes no more than any given n (n ∈ Z<sup>+</sup>, n > 2). At the same time, we also show the principle, derivation process of the formula and application examples, it is usually marked with π(n), which is: that is: where “[ ]” denotes taking integer. r = 1,2,3,4,5,6;s<sub>x</sub> = s<sub>1</sub>,s<sub>2</sub>,...,s<sub>j</sub>,s<sub>h</sub>;s1</sub>,s2</sub>,...,s<sub>j</sub>,,s<sub>h </sub><sub>= 0,1,2,3,....</sub>As i ≥ 2, 2 ≤ s<sub>x </sub>≤ i-1 (x=1,2,...,j,h).
基金supported by the National Key R&D Project of China(No.2017YFC0602100)the National Natural Science Foundation of China(No.41774147)Sichuan Science and Technology Support Program(No.2015GZ0272)
文摘The full-spectrum least-squares(FSLS) method is introduced to perform quantitative energy-dispersive X-ray fluorescence analysis for unknown solid samples.Based on the conventional least-squares principle, this spectrum evaluation method is able to obtain the background-corrected and interference-free net peaks, which is significant for quantization analyses. A variety of analytical parameters and functions to describe the features of the fluorescence spectra of pure elements are used and established, such as the mass absorption coefficient, the Gi factor, and fundamental fluorescence formulas. The FSLS iterative program was compiled in the C language. The content of each component should reach the convergence criterion at the end of the calculations. After a basic theory analysis and experimental preparation, 13 national standard soil samples were detected using a spectrometer to test the feasibility of using the algorithm. The results show that the calculated contents of Ti, Fe, Ni, Cu, and Zn have the same changing tendency as the corresponding standard content in the 13 reference samples. Accuracies of 0.35% and 14.03% are obtained, respectively, for Fe and Ti, whose standard concentrations are 8.82% and 0.578%, respectively. However, the calculated results of trace elements (only tens of lg/g) deviate from the standard values. This may be because of measurement accuracy and mutual effects between the elements.
