The women of the 1930s in the Chinese TV serials deduct inspiring stories.They play different roles in the big wealthy families such as mothers-in-law,daughters-in-law,and maidservants.There are unceasing conflicts be...The women of the 1930s in the Chinese TV serials deduct inspiring stories.They play different roles in the big wealthy families such as mothers-in-law,daughters-in-law,and maidservants.There are unceasing conflicts between these women,because of their struggle for men's love,wealth or social position.The theme of their stories is always about fertility,love,kindness and evil,with the ending being either comic or tragic.The stories of various kinds of women of the 1930s in the Chinese TV serials decorate and enrich the lives of many of us latecomers and their names are passed on from generation to generation.展开更多
A novel solid superacid catalyst S2O8^2-/ZrO2-CeO2 was prepared by a coprecipitation method and characterized by means of XRD FTIR, BET, TEM and DSC/TG analysis methods. The results indicated that incorporation of app...A novel solid superacid catalyst S2O8^2-/ZrO2-CeO2 was prepared by a coprecipitation method and characterized by means of XRD FTIR, BET, TEM and DSC/TG analysis methods. The results indicated that incorporation of appropriate amounts of Ce into the catalyst was beneficial to the formation of sole tetragonal ZrO2 and effectively prevented from the formation of monoclinic ZrO〉 and restrained the loss of sulfated species. XRD revealed the presence of tetragonal Ce0.16Zr0.84O2phase in the case of S2O8^2-/ZrO2-CeO2 calcined above 500 ℃. Catalytic activities of S2O8^2-/ZrO2-CeO2 for the esterification of lactic acid with n-butanol was studied. The results showed that the optimum conditions were as follows: calcination temperature of the catalyst 600 ℃, n(lactic acid):n(n-butyl alcohol)=1.0:3.0, w(S2O8^2-/ZrO2- CeO2)=12.0%, reaction temperature 145 ℃, and reaction time 2 h. The esterification efficiency of lactic acid was about 96.6%.展开更多
Y1.94-xMgxO2S:0.06Ti (0≤x≤0.10) phosphors with long afterglow were synthesized by solid state reaction route. The photoluminescence spectra, decay curves, thermoluminescent spectra and chromaticity coordinate curves...Y1.94-xMgxO2S:0.06Ti (0≤x≤0.10) phosphors with long afterglow were synthesized by solid state reaction route. The photoluminescence spectra, decay curves, thermoluminescent spectra and chromaticity coordinate curves were investigated. The results show that the luminescence intensity of Y1.94-xMgxO2S :0.06Ti (0≤x≤0. 10) phosphors decrease gradually with increasing Mg2+ ion content, and the shape of luminescence spectra and chromaticity coordinate change as well. Furthermore, two thermoluminescent peaks in single Ti-doped Y2O2S sample are found at 91.8 and 221.5℃, respectively. Nevertheless, significant different spectra were found for the Mg, Ti co-doped Y2O2S samples that three thermoluminescence peaks appear at 52.3, 141.7 and 226.8℃, respectively. These results indicate that the co-doped Mg ion changes the inherent trap depth of single Ti-doped Y2O2S: Ti phosphor, and induces simultaneously a new trap level in the Y1.94-xMgxO2S:0.06Ti phosphor. Based on the analysis of thermoluminescent spectra, photolumi-nescent spectra, decay curve and crystal structure defect, it was proposed that the varied structure defect and introduced new trap level by the doped Mg2+ ions should be responsible for reducing luminescence intensity and varying color in the Y1.94-x Mgx O2S : 0.06Ti phosphor.展开更多
The Jinman deposit is a Ag-bearing copper vein deposit located at the north marginof the Lanping-Simao back-arc basin in West Yunnan. Systematic studies of fluid inclusions andstable isotopes are presented in this pap...The Jinman deposit is a Ag-bearing copper vein deposit located at the north marginof the Lanping-Simao back-arc basin in West Yunnan. Systematic studies of fluid inclusions andstable isotopes are presented in this paper. The filling-replacement stage and the boiling-exhala-tive precipitation stage of mineralization took place at T1 = 140 - 280℃ and T2 = 94 - 204℃under pressure of (600 - 1200) ×105 Pa. The salinity of ore-forming solutions ranges from 5 wt%-20. 8 wt% (NaCl). Sulphide δ34S(CDT) values are in the rang of - 9.6‰ - + 11.03% witha range of 22. 66‰ showing an apparent "pagoda"-shaped distribution in histogram. Mean-while, the δ34S values of the various sulphides are consistent with the characters of isotope equi-librium fractionation, i. e., δ34SPy>δ34 SCp> δ34SBn. The TS/TOC ratios of the ores are widelyvariable between 0.16 and 5. 54 with no correlation of any kind can be established. Accirding to themodel of Ohmoto, the oxidation-reduction ratios of sulfur species in ore-forming solutions at the twomineralization stages were calculated to be R’1 = 2. 16×10(-17) and R’2 = 1. 55×104. δ13CCO2 (PDB)values obtained from fluid inclusions in calcite and quartz are between - 8.12‰ - - 3. 18‰, av-eraging - 5. 26‰, which are comparable with the isotopic composition of mantle-derived CO2.Inclusions in quartz yield δ13CCH4(PDB) between - 32. 11‰ and - 22. 04‰ (averaging- 26. 69‰),similar to that of methane in modern geothermal gases. For the ore-forming soutions, δ18OH2O(SMOW) values are between - 10. 57‰ and + 9. 77‰ and δDH2O(SMOW) are between - 51‰and - 135‰. Considering the effect of isotope exchange during waterrock reactions, most ofthe data are plotted along or close to the line defined by the reaction of meteoric water withclastic rocks, while a small part of the points fall near the reaction line of magmatic water withclastic rocks. In δ13C vs. δ18O diagram, the ore-forming soutions are plotted for the most partinto the mixing area between the meteoric fluid and the deep-seated fluid and partially on themixing line of P = 1.展开更多
Long-lasting phosphor Y2O2S : Eu^3+ , Mg^2+ , Ti^4+ was synthesized by a flux method and their luminescence properties were investigated. The result indicates that the unit cell parameter c is linearly increased w...Long-lasting phosphor Y2O2S : Eu^3+ , Mg^2+ , Ti^4+ was synthesized by a flux method and their luminescence properties were investigated. The result indicates that the unit cell parameter c is linearly increased with the increase of Eu2O3 content in Y2O2S: Eu^3+ (0.01 ≤ x ≤0.10). On the other hand, the change of unit cell parameter a is not linear dependence. In the Y2O2S: Eu^3 + crystal structure, Eu^3+ ions only replaced Y^3 + ions' places in which it posited center position of c axis. With the increase of Eu2O3 content, the position of the strongest emission peak changed from 540 nm (5D1→^ 7F2 transition) to 626 nm (^5Do→^7TF2 transition), and the maximum intensity was obtained when x = 0.09 in Y2O2S: Eu^3+ (0.01 ≤x ≤0.10). This is due to the environment of trivalent europium in the crystal structure of Y2O2S. Doping with Mg^2+ or Ti^4+. ions alone cannot get the good long-lasting afterglow effect, whereas co-doping with Mg^2 + and Ti^4 + ions and excited with 365 nm ultraviolet light, a strong thermoluminesence peak appeared, red and orange long-lasting phosphorescence (LLP) was also observed and the phosphorescence lasted nearly 3 h in the light perception of the dark-adapted human eye (0.32 mcd·m^-2). Thus the LLP mechanism was analyzed.展开更多
In this article, the synthesis and characterization of a novel fluoromonomer and its copolymer with acrylamide is reported. 2-perfluoroamyl-4-hydroxylquinoline 2 was synthesized from ethyl 2, 2-dihydroperfluoroheptano...In this article, the synthesis and characterization of a novel fluoromonomer and its copolymer with acrylamide is reported. 2-perfluoroamyl-4-hydroxylquinoline 2 was synthesized from ethyl 2, 2-dihydroperfluoroheptanoate in high yields. The monomer 4 was then synthesized from 2 in two steps readily in high yields. Synthesis and characterization of copolymers of acrylamide (AM) and the fluoromonomer were investigated. The composition and intrinsic viscosity of these copolymers were studied. It was found that the rheological properties of aqueous solutions of polyacrylamide were modified significantly when a small proportion of the fluoromonomer 4 was incorporated on investigating the viscosity-concentration profiles, pseudoplasticity of these solutions and the effect of the presence of surfactant. These results could be explained by the hydrophobic association of the fluorocarbon segments in the aqueous solutions of these copolymers.展开更多
Since the publication of the Good Earth in 1922, Pearl S, Buck published another two novels based on the same theme and they were called the House of Earth Trilogy. The House of Earth Trilogy used as a window to under...Since the publication of the Good Earth in 1922, Pearl S, Buck published another two novels based on the same theme and they were called the House of Earth Trilogy. The House of Earth Trilogy used as a window to understand China for the westerners at that time. And it had a great impact on the whole world. People gave two different views on her success of winning so many awards. Some thought that she wrote what she knew and her works were based on her own experiences. But others said that she was a foreigner and her values, her distinct aesthetic views would affect her writing. So, some of her depictions, to some extent, were untruthful and distorted. The aim of writing this thesis is to give an objective judgment on the Good Earth, and make it easier for us to communicate with the westerners on literature.展开更多
Y2O2S:Sm^3+, Mg^2+, Ti^4+ phosphor was synthesized by co-precipitation method. The crystalline structure of all synthesized phosphors was investigated by XRD. The result showed that all synthesized phosphors had a...Y2O2S:Sm^3+, Mg^2+, Ti^4+ phosphor was synthesized by co-precipitation method. The crystalline structure of all synthesized phosphors was investigated by XRD. The result showed that all synthesized phosphors had a hexagonal crystal structure, which was the same as Y2O2S. The emission spectrum and excitation spectrum were measured, and the effect of Sm^3 + molar ratio on the spectra was discussed. The emission spectra of the phosphors showed three emission peaks due to typical transitions of Sm^3 + (4G5/2→6HJ ,J = 5/2, 7/2, 9/2), and the emission peaks at 606 nm was stronger than others. With the increase of Sm^3 + molar ratio, the emission intensity was strengthened. The excitation peaks were ascribed to the representative energy transition 4f→4f of Ti^4+ phosphor prepared by co-precipitation method was Sm^3+ ions. The results indicated that the Y2O2S : Sm^3+ , Mg^2+ , an efficient long afterglow phosphor.展开更多
By processing S-wave data from the Fanshi-Huai’an-Taipusiqi DSS profile,which is a three-component,wide-angle reflection/refraction profile,and in the light of the results from P-wave interpretation,two-dimensional(2...By processing S-wave data from the Fanshi-Huai’an-Taipusiqi DSS profile,which is a three-component,wide-angle reflection/refraction profile,and in the light of the results from P-wave interpretation,two-dimensional(2-D)structures of the crust and upper mantle are presented,including S-wave velocity Vs and the physical parameter of medium-Poisson’s ratio a.Taking other geological and geophysical information into account,and with reference to the results from petrophysical experiments at home and abroad,we carried out interpretation and inference with respect to deep crustal structure,tectonics,and lithologic characters.It has been concluded that in the upper and middle crust,a values are mostly not greater than 0.25,and rocks,which generally assume brittle,are mainly composed of granite; the rocks in the lower layer of the upper crust between Yangyuan-Huai’an containing inorganic CO2 itself releases carbon; for the rocks in the lower crust and crust-mantle transitional zone,which are comparatively展开更多
The man-induced sediment disaster includes material erosion, transportation and accumulation by human activities. It possesses special attribute in sociology and disaster science. In accordance with human activities, ...The man-induced sediment disaster includes material erosion, transportation and accumulation by human activities. It possesses special attribute in sociology and disaster science. In accordance with human activities, geomorphologic location, behavior and particular, the man-induced sediment disaster can be divided into 4 types: the drainage network, slope and gully, channel and plain-estuary-coastline. Each type includes erosion, transportation, accumulation, complexity and cascading. Based on human activity, geomorphology, sediment mechanics and catastrophology, the man-induced sediment disaster is characterized as follows: (1) accelerating tendency with geographical zoning back-ground; (2) non-order characters by blind action without special technical training; (3) gradually and sharply changing with human environment vibration; and (4) complexity and non-linear figure, etc. One of the reasons leading to man-induced sediment disaster is human environment vibration.展开更多
After trace Sm^3+ ions and Gd^3+ ions doping, the emission intensity of red phosphors Y2O2S: Eu^3 + was enhanced and the voltage character (relation between emission intensity and excitation voltage) was improve...After trace Sm^3+ ions and Gd^3+ ions doping, the emission intensity of red phosphors Y2O2S: Eu^3 + was enhanced and the voltage character (relation between emission intensity and excitation voltage) was improved while the other properties of physics and chemistry were not changed. The origins of enhancement and improvement are discussed. Probably the distortion and the defect of crystals are decreased by the substitution of Gd^3+ for Y^3+ instead of Eu^3+ for Y^3+ , and thus the Eu^3+ crystal field is improved, and radiationless process and energy loss resulted from crystal defect are weakened, which leads to increased luminescence intensity and voltage character improvement. The overlapping fluorescent spectra of Y2O2S: Sm^3+ emission and Y2O2S:Eu^3+ excitation as well as Eu^3 + excitation spectra transitions spectra lead to energy transfer from Sm^3 + sensitization of Sm^3+ ions fectively. containing Sm^3+ excitation the possibility of resonance ions to Eu^3+ ions, and the to Eu^3+ ions is achieved effectively.展开更多
Design and synthesis of organic chelating agents containing nitrogen and sulfur as donor atoms and their metal complexes is an interesting field of research for their different types of activities. The bi-dentate N,N ...Design and synthesis of organic chelating agents containing nitrogen and sulfur as donor atoms and their metal complexes is an interesting field of research for their different types of activities. The bi-dentate N,N chelating agent such as 2,2-Bipyridal has been playing a vital role in synthetic and medicinal chemistry. 2,2-Bipyridal has been used to prepare many mixed-ligand complexes. Different ligand complexes prepared from 2,2-Bipyridyl are used in different areas such as molecular catalysis, solar energy conversion, calorimetric analysis, herbicides, molecular recognition, self-assembly, antineoplastic agents, and nucleic acid probes. Another important property of these types of compounds is the triplet state photosensitizing character of bipyridyl nucleus, which is shown in metal complexes. It is also found that compounds containing O,S,N atoms have received considerable attention because of their pharmacological studies like anticancer, antibacterial, and antitumour activities. Therefore, it has been decided to synthesize Schiff bases derived from 2,2’- bipyridyl-5,5’-dicarbaldehyde compounds with O,S,N and F-containing amines and study their antibacterial properties. Several new Schiff bases have been synthesized and fully characterized by spectral data. This paper presents the synthesis and characterization of newly designed Schiff bases.展开更多
Eight novel Schiff Bases, from 6,6′-diformyl-2,2′-bipyridyl (1a, 43%)with O, N, S and F containing amines: Thiosemicarbazide (2a, 70%), 4-Ethyl-3-thiosemicabazide (2b, 75%), 4,4-Dimethyl-3-thio-semicarbazide (2c, 75...Eight novel Schiff Bases, from 6,6′-diformyl-2,2′-bipyridyl (1a, 43%)with O, N, S and F containing amines: Thiosemicarbazide (2a, 70%), 4-Ethyl-3-thiosemicabazide (2b, 75%), 4,4-Dimethyl-3-thio-semicarbazide (2c, 75%), S-benzyldithiocarbazide, SBDTC (2d, 80%), (Trifluromethyl) phenylhy-drazine (2e, 80%), 4-Phenyl-3-thiosemcarbazide (2f, 80%), Thiocarbazide (2g, 70%), 2-Amino-thiophenol (2h, 65%), have been synthesized. The conventional method of synthesis of the Schiff bases involves refluxing the reaction mixture containing the diformyls and amines for 1 hour. The solid products that had formed were filtered off using suction filtration. In few reactions, 2 - 3 drops of conc. sulfuric acid were used to obtain high yield. The structures of all eight novel synthesized compounds have fully been characterized by spectroscopic (IR, NMR, MS) methods.展开更多
A new organic dye, trans-4-[4'-(N-hydroxyethyl-N-methylamino)styryl]-N-methylpyridinium p-toluene sulfonate (HMASPS) has been synthesized and its structure has been determined. Pumped with a 1064 nm, 50 ps laser p...A new organic dye, trans-4-[4'-(N-hydroxyethyl-N-methylamino)styryl]-N-methylpyridinium p-toluene sulfonate (HMASPS) has been synthesized and its structure has been determined. Pumped with a 1064 nm, 50 ps laser pulses, 0.05 mol/L HMASPS/DMF solution showed the two-photon pumped (TPP) output/input efficiency of 8.4% which is higher than that of trans-4-[p-(N-hydroxyethyl-N-methylamino) styryl]-N-methylpyridinium iodide (ASPI)(1) at the same pump level.展开更多
The electronic modification effect of various metal oxides over Pt-Al;O;catalyst andthe relationships between the polarizing force of cations(PFC)and the electrophiliccharacter(EC)and catalytic performances(CP)o...The electronic modification effect of various metal oxides over Pt-Al;O;catalyst andthe relationships between the polarizing force of cations(PFC)and the electrophiliccharacter(EC)and catalytic performances(CP)of promoted Pt catalyst have been studiecby competitive hydrogenation reaction method(CHRM)and test reaction,i.e.hydrogena-tion of benzene and hydrogenolysis of cyclopentane.展开更多
文摘The women of the 1930s in the Chinese TV serials deduct inspiring stories.They play different roles in the big wealthy families such as mothers-in-law,daughters-in-law,and maidservants.There are unceasing conflicts between these women,because of their struggle for men's love,wealth or social position.The theme of their stories is always about fertility,love,kindness and evil,with the ending being either comic or tragic.The stories of various kinds of women of the 1930s in the Chinese TV serials decorate and enrich the lives of many of us latecomers and their names are passed on from generation to generation.
基金supported by the Science and Technique Foundation of Shaaxi Province of China (2008K07-32)the Foundation of Shaanxi Educa- tional Committee of China (08JK228)the Graduate Innovation Fund of Shaanxi University of Science and Technology
文摘A novel solid superacid catalyst S2O8^2-/ZrO2-CeO2 was prepared by a coprecipitation method and characterized by means of XRD FTIR, BET, TEM and DSC/TG analysis methods. The results indicated that incorporation of appropriate amounts of Ce into the catalyst was beneficial to the formation of sole tetragonal ZrO2 and effectively prevented from the formation of monoclinic ZrO〉 and restrained the loss of sulfated species. XRD revealed the presence of tetragonal Ce0.16Zr0.84O2phase in the case of S2O8^2-/ZrO2-CeO2 calcined above 500 ℃. Catalytic activities of S2O8^2-/ZrO2-CeO2 for the esterification of lactic acid with n-butanol was studied. The results showed that the optimum conditions were as follows: calcination temperature of the catalyst 600 ℃, n(lactic acid):n(n-butyl alcohol)=1.0:3.0, w(S2O8^2-/ZrO2- CeO2)=12.0%, reaction temperature 145 ℃, and reaction time 2 h. The esterification efficiency of lactic acid was about 96.6%.
基金Project supported by SRF for ROCS, SEM (2003-14), and Science and Technology Department of Zhejiang Province (2005C31019)
文摘Y1.94-xMgxO2S:0.06Ti (0≤x≤0.10) phosphors with long afterglow were synthesized by solid state reaction route. The photoluminescence spectra, decay curves, thermoluminescent spectra and chromaticity coordinate curves were investigated. The results show that the luminescence intensity of Y1.94-xMgxO2S :0.06Ti (0≤x≤0. 10) phosphors decrease gradually with increasing Mg2+ ion content, and the shape of luminescence spectra and chromaticity coordinate change as well. Furthermore, two thermoluminescent peaks in single Ti-doped Y2O2S sample are found at 91.8 and 221.5℃, respectively. Nevertheless, significant different spectra were found for the Mg, Ti co-doped Y2O2S samples that three thermoluminescence peaks appear at 52.3, 141.7 and 226.8℃, respectively. These results indicate that the co-doped Mg ion changes the inherent trap depth of single Ti-doped Y2O2S: Ti phosphor, and induces simultaneously a new trap level in the Y1.94-xMgxO2S:0.06Ti phosphor. Based on the analysis of thermoluminescent spectra, photolumi-nescent spectra, decay curve and crystal structure defect, it was proposed that the varied structure defect and introduced new trap level by the doped Mg2+ ions should be responsible for reducing luminescence intensity and varying color in the Y1.94-x Mgx O2S : 0.06Ti phosphor.
文摘The Jinman deposit is a Ag-bearing copper vein deposit located at the north marginof the Lanping-Simao back-arc basin in West Yunnan. Systematic studies of fluid inclusions andstable isotopes are presented in this paper. The filling-replacement stage and the boiling-exhala-tive precipitation stage of mineralization took place at T1 = 140 - 280℃ and T2 = 94 - 204℃under pressure of (600 - 1200) ×105 Pa. The salinity of ore-forming solutions ranges from 5 wt%-20. 8 wt% (NaCl). Sulphide δ34S(CDT) values are in the rang of - 9.6‰ - + 11.03% witha range of 22. 66‰ showing an apparent "pagoda"-shaped distribution in histogram. Mean-while, the δ34S values of the various sulphides are consistent with the characters of isotope equi-librium fractionation, i. e., δ34SPy>δ34 SCp> δ34SBn. The TS/TOC ratios of the ores are widelyvariable between 0.16 and 5. 54 with no correlation of any kind can be established. Accirding to themodel of Ohmoto, the oxidation-reduction ratios of sulfur species in ore-forming solutions at the twomineralization stages were calculated to be R’1 = 2. 16×10(-17) and R’2 = 1. 55×104. δ13CCO2 (PDB)values obtained from fluid inclusions in calcite and quartz are between - 8.12‰ - - 3. 18‰, av-eraging - 5. 26‰, which are comparable with the isotopic composition of mantle-derived CO2.Inclusions in quartz yield δ13CCH4(PDB) between - 32. 11‰ and - 22. 04‰ (averaging- 26. 69‰),similar to that of methane in modern geothermal gases. For the ore-forming soutions, δ18OH2O(SMOW) values are between - 10. 57‰ and + 9. 77‰ and δDH2O(SMOW) are between - 51‰and - 135‰. Considering the effect of isotope exchange during waterrock reactions, most ofthe data are plotted along or close to the line defined by the reaction of meteoric water withclastic rocks, while a small part of the points fall near the reaction line of magmatic water withclastic rocks. In δ13C vs. δ18O diagram, the ore-forming soutions are plotted for the most partinto the mixing area between the meteoric fluid and the deep-seated fluid and partially on themixing line of P = 1.
文摘Long-lasting phosphor Y2O2S : Eu^3+ , Mg^2+ , Ti^4+ was synthesized by a flux method and their luminescence properties were investigated. The result indicates that the unit cell parameter c is linearly increased with the increase of Eu2O3 content in Y2O2S: Eu^3+ (0.01 ≤ x ≤0.10). On the other hand, the change of unit cell parameter a is not linear dependence. In the Y2O2S: Eu^3 + crystal structure, Eu^3+ ions only replaced Y^3 + ions' places in which it posited center position of c axis. With the increase of Eu2O3 content, the position of the strongest emission peak changed from 540 nm (5D1→^ 7F2 transition) to 626 nm (^5Do→^7TF2 transition), and the maximum intensity was obtained when x = 0.09 in Y2O2S: Eu^3+ (0.01 ≤x ≤0.10). This is due to the environment of trivalent europium in the crystal structure of Y2O2S. Doping with Mg^2+ or Ti^4+. ions alone cannot get the good long-lasting afterglow effect, whereas co-doping with Mg^2 + and Ti^4 + ions and excited with 365 nm ultraviolet light, a strong thermoluminesence peak appeared, red and orange long-lasting phosphorescence (LLP) was also observed and the phosphorescence lasted nearly 3 h in the light perception of the dark-adapted human eye (0.32 mcd·m^-2). Thus the LLP mechanism was analyzed.
基金Project supported by National Natural Science Foundation,Grant approval numbers 29472074 and 29632003
文摘In this article, the synthesis and characterization of a novel fluoromonomer and its copolymer with acrylamide is reported. 2-perfluoroamyl-4-hydroxylquinoline 2 was synthesized from ethyl 2, 2-dihydroperfluoroheptanoate in high yields. The monomer 4 was then synthesized from 2 in two steps readily in high yields. Synthesis and characterization of copolymers of acrylamide (AM) and the fluoromonomer were investigated. The composition and intrinsic viscosity of these copolymers were studied. It was found that the rheological properties of aqueous solutions of polyacrylamide were modified significantly when a small proportion of the fluoromonomer 4 was incorporated on investigating the viscosity-concentration profiles, pseudoplasticity of these solutions and the effect of the presence of surfactant. These results could be explained by the hydrophobic association of the fluorocarbon segments in the aqueous solutions of these copolymers.
文摘Since the publication of the Good Earth in 1922, Pearl S, Buck published another two novels based on the same theme and they were called the House of Earth Trilogy. The House of Earth Trilogy used as a window to understand China for the westerners at that time. And it had a great impact on the whole world. People gave two different views on her success of winning so many awards. Some thought that she wrote what she knew and her works were based on her own experiences. But others said that she was a foreigner and her values, her distinct aesthetic views would affect her writing. So, some of her depictions, to some extent, were untruthful and distorted. The aim of writing this thesis is to give an objective judgment on the Good Earth, and make it easier for us to communicate with the westerners on literature.
基金Project supported by the Hebei Developing Foundation of Science&Technology (51215103b)
文摘Y2O2S:Sm^3+, Mg^2+, Ti^4+ phosphor was synthesized by co-precipitation method. The crystalline structure of all synthesized phosphors was investigated by XRD. The result showed that all synthesized phosphors had a hexagonal crystal structure, which was the same as Y2O2S. The emission spectrum and excitation spectrum were measured, and the effect of Sm^3 + molar ratio on the spectra was discussed. The emission spectra of the phosphors showed three emission peaks due to typical transitions of Sm^3 + (4G5/2→6HJ ,J = 5/2, 7/2, 9/2), and the emission peaks at 606 nm was stronger than others. With the increase of Sm^3 + molar ratio, the emission intensity was strengthened. The excitation peaks were ascribed to the representative energy transition 4f→4f of Ti^4+ phosphor prepared by co-precipitation method was Sm^3+ ions. The results indicated that the Y2O2S : Sm^3+ , Mg^2+ , an efficient long afterglow phosphor.
文摘By processing S-wave data from the Fanshi-Huai’an-Taipusiqi DSS profile,which is a three-component,wide-angle reflection/refraction profile,and in the light of the results from P-wave interpretation,two-dimensional(2-D)structures of the crust and upper mantle are presented,including S-wave velocity Vs and the physical parameter of medium-Poisson’s ratio a.Taking other geological and geophysical information into account,and with reference to the results from petrophysical experiments at home and abroad,we carried out interpretation and inference with respect to deep crustal structure,tectonics,and lithologic characters.It has been concluded that in the upper and middle crust,a values are mostly not greater than 0.25,and rocks,which generally assume brittle,are mainly composed of granite; the rocks in the lower layer of the upper crust between Yangyuan-Huai’an containing inorganic CO2 itself releases carbon; for the rocks in the lower crust and crust-mantle transitional zone,which are comparatively
基金Joint project by National Natural Science Foundation of China and the Ministry of Water Resources,No.59890200National Natural Science Foundation of China, No.48870008
文摘The man-induced sediment disaster includes material erosion, transportation and accumulation by human activities. It possesses special attribute in sociology and disaster science. In accordance with human activities, geomorphologic location, behavior and particular, the man-induced sediment disaster can be divided into 4 types: the drainage network, slope and gully, channel and plain-estuary-coastline. Each type includes erosion, transportation, accumulation, complexity and cascading. Based on human activity, geomorphology, sediment mechanics and catastrophology, the man-induced sediment disaster is characterized as follows: (1) accelerating tendency with geographical zoning back-ground; (2) non-order characters by blind action without special technical training; (3) gradually and sharply changing with human environment vibration; and (4) complexity and non-linear figure, etc. One of the reasons leading to man-induced sediment disaster is human environment vibration.
文摘After trace Sm^3+ ions and Gd^3+ ions doping, the emission intensity of red phosphors Y2O2S: Eu^3 + was enhanced and the voltage character (relation between emission intensity and excitation voltage) was improved while the other properties of physics and chemistry were not changed. The origins of enhancement and improvement are discussed. Probably the distortion and the defect of crystals are decreased by the substitution of Gd^3+ for Y^3+ instead of Eu^3+ for Y^3+ , and thus the Eu^3+ crystal field is improved, and radiationless process and energy loss resulted from crystal defect are weakened, which leads to increased luminescence intensity and voltage character improvement. The overlapping fluorescent spectra of Y2O2S: Sm^3+ emission and Y2O2S:Eu^3+ excitation as well as Eu^3 + excitation spectra transitions spectra lead to energy transfer from Sm^3 + sensitization of Sm^3+ ions fectively. containing Sm^3+ excitation the possibility of resonance ions to Eu^3+ ions, and the to Eu^3+ ions is achieved effectively.
文摘Design and synthesis of organic chelating agents containing nitrogen and sulfur as donor atoms and their metal complexes is an interesting field of research for their different types of activities. The bi-dentate N,N chelating agent such as 2,2-Bipyridal has been playing a vital role in synthetic and medicinal chemistry. 2,2-Bipyridal has been used to prepare many mixed-ligand complexes. Different ligand complexes prepared from 2,2-Bipyridyl are used in different areas such as molecular catalysis, solar energy conversion, calorimetric analysis, herbicides, molecular recognition, self-assembly, antineoplastic agents, and nucleic acid probes. Another important property of these types of compounds is the triplet state photosensitizing character of bipyridyl nucleus, which is shown in metal complexes. It is also found that compounds containing O,S,N atoms have received considerable attention because of their pharmacological studies like anticancer, antibacterial, and antitumour activities. Therefore, it has been decided to synthesize Schiff bases derived from 2,2’- bipyridyl-5,5’-dicarbaldehyde compounds with O,S,N and F-containing amines and study their antibacterial properties. Several new Schiff bases have been synthesized and fully characterized by spectral data. This paper presents the synthesis and characterization of newly designed Schiff bases.
文摘Eight novel Schiff Bases, from 6,6′-diformyl-2,2′-bipyridyl (1a, 43%)with O, N, S and F containing amines: Thiosemicarbazide (2a, 70%), 4-Ethyl-3-thiosemicabazide (2b, 75%), 4,4-Dimethyl-3-thio-semicarbazide (2c, 75%), S-benzyldithiocarbazide, SBDTC (2d, 80%), (Trifluromethyl) phenylhy-drazine (2e, 80%), 4-Phenyl-3-thiosemcarbazide (2f, 80%), Thiocarbazide (2g, 70%), 2-Amino-thiophenol (2h, 65%), have been synthesized. The conventional method of synthesis of the Schiff bases involves refluxing the reaction mixture containing the diformyls and amines for 1 hour. The solid products that had formed were filtered off using suction filtration. In few reactions, 2 - 3 drops of conc. sulfuric acid were used to obtain high yield. The structures of all eight novel synthesized compounds have fully been characterized by spectroscopic (IR, NMR, MS) methods.
基金This tvork was supported by the grant for state key program of China by the National NaturalScience Foundation of China, al
文摘A new organic dye, trans-4-[4'-(N-hydroxyethyl-N-methylamino)styryl]-N-methylpyridinium p-toluene sulfonate (HMASPS) has been synthesized and its structure has been determined. Pumped with a 1064 nm, 50 ps laser pulses, 0.05 mol/L HMASPS/DMF solution showed the two-photon pumped (TPP) output/input efficiency of 8.4% which is higher than that of trans-4-[p-(N-hydroxyethyl-N-methylamino) styryl]-N-methylpyridinium iodide (ASPI)(1) at the same pump level.
文摘The electronic modification effect of various metal oxides over Pt-Al;O;catalyst andthe relationships between the polarizing force of cations(PFC)and the electrophiliccharacter(EC)and catalytic performances(CP)of promoted Pt catalyst have been studiecby competitive hydrogenation reaction method(CHRM)and test reaction,i.e.hydrogena-tion of benzene and hydrogenolysis of cyclopentane.