Among sensitizing systems, the combination of benzophenone(BP) and tertiary amines(TA) has been deeply studied. Since the structure of O-acyl-oximes is similar to that of BP and their triplet state energies are nearly...Among sensitizing systems, the combination of benzophenone(BP) and tertiary amines(TA) has been deeply studied. Since the structure of O-acyl-oximes is similar to that of BP and their triplet state energies are nearly equal, we want to know whether the behavior of the photopolymerization initiated with O-acyl-oximes—TA system is the same as that of photopolymerization initiated with展开更多
O-Acyl ketoximes has been proven to be versatile building blocks for practical construction of Nheterocycles.In the last few years,diverse catalytic systems have been discovered to enable efficient transformations of ...O-Acyl ketoximes has been proven to be versatile building blocks for practical construction of Nheterocycles.In the last few years,diverse catalytic systems have been discovered to enable efficient transformations of O-acyl ketoximes to a range of nitrogen-heterocycles.Herein,we summarized our recent examples of novel nitrogen-heterocycle formation with new function findings of O-acyl ketoximes through facile aerobic copper catalysis,metal-free N–O bond activation,multi-component assembly,and bis-annulations.From the green chemistry perspective,these works represent efficient methods with high atom economy,high selectivity,and minimized chemical waste.These findings also complement well to the previous mainly copper-based catalytic systems and more importantly enrich the oxime chemistry in organic synthesis.展开更多
A convenient copper-catalyzed approach has been developed for the synthesis of substituted spiro-fused pyrazolin-5-ones from readily available cyclopropyl O-acyl ketoximes via an intramolecular N-N bond formation reac...A convenient copper-catalyzed approach has been developed for the synthesis of substituted spiro-fused pyrazolin-5-ones from readily available cyclopropyl O-acyl ketoximes via an intramolecular N-N bond formation reaction. These catalytic reactions proceed in excellent yields with a broad scope.展开更多
文摘Among sensitizing systems, the combination of benzophenone(BP) and tertiary amines(TA) has been deeply studied. Since the structure of O-acyl-oximes is similar to that of BP and their triplet state energies are nearly equal, we want to know whether the behavior of the photopolymerization initiated with O-acyl-oximes—TA system is the same as that of photopolymerization initiated with
基金Financial support by the National Natural Science Foundation of China(No.22071211)the Science and Technology Planning Project of Hunan Province(No.2019RS2039)+2 种基金Hunan Provincial Natural Science Foundation of China(No.2020JJ3032)Scientific Research Fund of Education Department of Hunan Province(No.21A0079)Open Research Fund of School of Chemistry and Chemical Engineering of Henan Normal University(No.2022C02)。
文摘O-Acyl ketoximes has been proven to be versatile building blocks for practical construction of Nheterocycles.In the last few years,diverse catalytic systems have been discovered to enable efficient transformations of O-acyl ketoximes to a range of nitrogen-heterocycles.Herein,we summarized our recent examples of novel nitrogen-heterocycle formation with new function findings of O-acyl ketoximes through facile aerobic copper catalysis,metal-free N–O bond activation,multi-component assembly,and bis-annulations.From the green chemistry perspective,these works represent efficient methods with high atom economy,high selectivity,and minimized chemical waste.These findings also complement well to the previous mainly copper-based catalytic systems and more importantly enrich the oxime chemistry in organic synthesis.
文摘A convenient copper-catalyzed approach has been developed for the synthesis of substituted spiro-fused pyrazolin-5-ones from readily available cyclopropyl O-acyl ketoximes via an intramolecular N-N bond formation reaction. These catalytic reactions proceed in excellent yields with a broad scope.
