介绍了基于有机场效应晶体管(organic field effect transistor,OFET)技术的柔性半导体器件的工作原理和发展概况,综述了基于OFET的生物力学监测设备、文身生物监测设备、细胞检测设备等可穿戴柔性监测设备的研究现状,分析了基于OFET的...介绍了基于有机场效应晶体管(organic field effect transistor,OFET)技术的柔性半导体器件的工作原理和发展概况,综述了基于OFET的生物力学监测设备、文身生物监测设备、细胞检测设备等可穿戴柔性监测设备的研究现状,分析了基于OFET的可穿戴柔性监测设备存在的不足,指出了微型化、个性化、多元化等是未来基于OFET的可穿戴柔性监测设备的发展方向。展开更多
A comprehensive understanding of the organic semiconductor material pentacene is meaningful for organic fieldeffect transistors （OFETs）. Thin films of pentacene are the most mobile molecular films known to date. Thi...A comprehensive understanding of the organic semiconductor material pentacene is meaningful for organic fieldeffect transistors （OFETs）. Thin films of pentacene are the most mobile molecular films known to date. This paper reported that the pentacene sample was successfully synthesized. The purity of pentacene is up to 95%. The results of a joint experimental investigation based on a combination of infrared absorption spectra, mass spectra （MS）, element analysis, x-ray diffraction （XRD） and atom force microscopy （AFM）. The authors fabricated OFET with the synthesized pentacene. Its field effect mobility is about 1.23 cm^2/（V·s） and on-off ratio is above 10^6.展开更多
Pentacene organic field-effect transistors （OFETs） based on single- or double-layer biocompatible dielectrics of poly（methyl methacrylate） （PMMA） and/or silk fibroin （SF） are fabricated. Compared with those de...Pentacene organic field-effect transistors （OFETs） based on single- or double-layer biocompatible dielectrics of poly（methyl methacrylate） （PMMA） and/or silk fibroin （SF） are fabricated. Compared with those devices based on sin- gle PMMA or SF dielectric or SF/PMMA bilayer dielectric, the OFETs with biocompatible PMMA/SF bilayer dielectric exhibit optimal performance with a high field-effect mobility of 0.21 cm2/Vs and a current on/off ratio of 1.5 × 104. By investigating the surface morphology of the pentacene active layer through atom force microscopy and analyzing the elec- trical properties, the performance enhancement is mainly attributed to the crystallization improvement of the pentacene and the smaller interface trap density at the dielectric/organic interface. Meanwhile, a low contact resistance also indicates that a good electrode/organic contact is formed, thereby assisting the performance improvement of the OFET.展开更多
The rapid development of electronic devices such as organic field-effect transistors(OFETs)and solar cells makes the research and development of electronic transport materials imminent.The acceptor-acceptortype(Aà...The rapid development of electronic devices such as organic field-effect transistors(OFETs)and solar cells makes the research and development of electronic transport materials imminent.The acceptor-acceptortype(AàA-type)conjugated n-type polymer semiconductors have caught much attention due to the outstanding advantages on excellent electron-accepting capabilities,the precise adjustment of energy levels and the mass production at low fabrication cost.This article systematically reviews the polymerization methods of AàA-type polymers and the recent advancements applied in OFETs and polymer solar cells(PSCs).The analyses of the synthesis and the relationship between device performances and polymer molecular structures may provide a constructive guidance for the further development of highperformance n-type polymer materials.展开更多
A top-contact organic field-effect transistor （OFET） is fabricated by adopting a pentacene/1,11-bis（di-4- tolylaminophenyl） cyclohexane （TAPC） heterojunction structure and inserting an MoO3 buffer layer between ...A top-contact organic field-effect transistor （OFET） is fabricated by adopting a pentacene/1,11-bis（di-4- tolylaminophenyl） cyclohexane （TAPC） heterojunction structure and inserting an MoO3 buffer layer between the TAPC organic semiconductor layer and the source/drain electrode. The performances of the heterojunction OFET, including output current, field-effect mobility, and threshed voltage~ are all significantly improved by introducing the MoO3 thin buffer layer. The performance improvement of the modified heterojunction OFET is attributed to a better contact formed at the Au/TAPC interface due to the MoO3 thin buffer layer, thereby leading to a remarkable reduction of the contact resistance at the metal/organic interface.展开更多
The addition of substituents at the 6,13-position improved the solubility and stability of pentacene, making it possible to use the derivatives in spin coating of organic field-effect transistors(OFETs). Three pentace...The addition of substituents at the 6,13-position improved the solubility and stability of pentacene, making it possible to use the derivatives in spin coating of organic field-effect transistors(OFETs). Three pentacene derivatives, 6,13-bis(m-tolyl)pentacene(MP), 6,13-bis(4-butylphenyl)pentacene(BP), and 6,13-bis((4-butylphenyl)ethynyl)pentacene(BPEP) were synthesized, and their properties were investigated. 6,13-Pentacenequinone and organolithium were used in the preparation of 6,13-dihydropentacene at 0 ℃, and pentacene derivatives were synthesized with SnCl_2/HCl as reducing agent, to reduce 6,13-dihydropentacene at room temperature. The structure of the derivatives was characterized using NMR. The thermal stability, photochemical properties, and electronic structure of the three compounds were investigated using TGA, cyclic voltammetry, and UV–Vis. BPEP was also characterized using X-ray diffraction and atom force microscopy. BPEP was used to fabricate an OFET device using spin coating. The device showed a mobility of 0.07 cm^2 V s^(-1) at V_(th) =-10 V and I_(ON)/I _(OFF) = 10~2.展开更多
文摘介绍了基于有机场效应晶体管(organic field effect transistor,OFET)技术的柔性半导体器件的工作原理和发展概况,综述了基于OFET的生物力学监测设备、文身生物监测设备、细胞检测设备等可穿戴柔性监测设备的研究现状,分析了基于OFET的可穿戴柔性监测设备存在的不足,指出了微型化、个性化、多元化等是未来基于OFET的可穿戴柔性监测设备的发展方向。
基金Project supported by the National Natural Science Foundation of China (Grant No 60676033)
文摘A comprehensive understanding of the organic semiconductor material pentacene is meaningful for organic fieldeffect transistors （OFETs）. Thin films of pentacene are the most mobile molecular films known to date. This paper reported that the pentacene sample was successfully synthesized. The purity of pentacene is up to 95%. The results of a joint experimental investigation based on a combination of infrared absorption spectra, mass spectra （MS）, element analysis, x-ray diffraction （XRD） and atom force microscopy （AFM）. The authors fabricated OFET with the synthesized pentacene. Its field effect mobility is about 1.23 cm^2/（V·s） and on-off ratio is above 10^6.
基金Project supported by the National Natural Science Foundation of China(Grant No.61177032)the Foundation for Innovation Groups of the National Natural Science Foundation of China(Grant No.61021061)+1 种基金the Fundamental Research Funds for the Central Universities,China(Grant No.ZYGX2010Z004)the Scientific Research Staring Foundation for the Returned Overseas Chinese Scholars of the Education Ministry of China(Grant No.GGRYJJ08-05)
文摘Pentacene organic field-effect transistors （OFETs） based on single- or double-layer biocompatible dielectrics of poly（methyl methacrylate） （PMMA） and/or silk fibroin （SF） are fabricated. Compared with those devices based on sin- gle PMMA or SF dielectric or SF/PMMA bilayer dielectric, the OFETs with biocompatible PMMA/SF bilayer dielectric exhibit optimal performance with a high field-effect mobility of 0.21 cm2/Vs and a current on/off ratio of 1.5 × 104. By investigating the surface morphology of the pentacene active layer through atom force microscopy and analyzing the elec- trical properties, the performance enhancement is mainly attributed to the crystallization improvement of the pentacene and the smaller interface trap density at the dielectric/organic interface. Meanwhile, a low contact resistance also indicates that a good electrode/organic contact is formed, thereby assisting the performance improvement of the OFET.
基金the financial support from the Natural Science Foundation of Beijing Municipality(2192059)the National Natural Science Foundation of China(21673059,21774130 and 51925306)+4 种基金the National Key R&D Program of China(2018FYA0305800)the Key Research Program of Frontier Sciences,CAS(QYZDB-SSW-JSC046)the Key Research Program of the Chinese Academy of Sciences(XDPB08-2)the Strategic Priority Research Program of Chinese Academy of Sciences(XDB28000000)the International Partnership Program of Chinese Academy of Sciences(211211KYSB20170014)。
文摘The rapid development of electronic devices such as organic field-effect transistors(OFETs)and solar cells makes the research and development of electronic transport materials imminent.The acceptor-acceptortype(AàA-type)conjugated n-type polymer semiconductors have caught much attention due to the outstanding advantages on excellent electron-accepting capabilities,the precise adjustment of energy levels and the mass production at low fabrication cost.This article systematically reviews the polymerization methods of AàA-type polymers and the recent advancements applied in OFETs and polymer solar cells(PSCs).The analyses of the synthesis and the relationship between device performances and polymer molecular structures may provide a constructive guidance for the further development of highperformance n-type polymer materials.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 61071026 and 61177032)the Science Fund for Creative Research Groups of the National Natural Science Foundation of China (Grant No.61021061)+1 种基金the Fundamental Research Fund for the Central Universities of Misistry of Education of China (Grant No.ZYGX2010Z004)the Specialized Research Fund for the Doctoral Program of Higher Education of China (Grant No. 20090185110020)
文摘A top-contact organic field-effect transistor （OFET） is fabricated by adopting a pentacene/1,11-bis（di-4- tolylaminophenyl） cyclohexane （TAPC） heterojunction structure and inserting an MoO3 buffer layer between the TAPC organic semiconductor layer and the source/drain electrode. The performances of the heterojunction OFET, including output current, field-effect mobility, and threshed voltage~ are all significantly improved by introducing the MoO3 thin buffer layer. The performance improvement of the modified heterojunction OFET is attributed to a better contact formed at the Au/TAPC interface due to the MoO3 thin buffer layer, thereby leading to a remarkable reduction of the contact resistance at the metal/organic interface.
基金supported by the National Natural Science Foundation of China (No. 21102099)
文摘The addition of substituents at the 6,13-position improved the solubility and stability of pentacene, making it possible to use the derivatives in spin coating of organic field-effect transistors(OFETs). Three pentacene derivatives, 6,13-bis(m-tolyl)pentacene(MP), 6,13-bis(4-butylphenyl)pentacene(BP), and 6,13-bis((4-butylphenyl)ethynyl)pentacene(BPEP) were synthesized, and their properties were investigated. 6,13-Pentacenequinone and organolithium were used in the preparation of 6,13-dihydropentacene at 0 ℃, and pentacene derivatives were synthesized with SnCl_2/HCl as reducing agent, to reduce 6,13-dihydropentacene at room temperature. The structure of the derivatives was characterized using NMR. The thermal stability, photochemical properties, and electronic structure of the three compounds were investigated using TGA, cyclic voltammetry, and UV–Vis. BPEP was also characterized using X-ray diffraction and atom force microscopy. BPEP was used to fabricate an OFET device using spin coating. The device showed a mobility of 0.07 cm^2 V s^(-1) at V_(th) =-10 V and I_(ON)/I _(OFF) = 10~2.
