A volcano-platform carbonate sequence ,from Carboniferous to Permian , is widely trapped in the deep water deposits in Changning- Menglian belt .Three components can be roughly recognized in ascending order as :the la...A volcano-platform carbonate sequence ,from Carboniferous to Permian , is widely trapped in the deep water deposits in Changning- Menglian belt .Three components can be roughly recognized in ascending order as :the lava .the volcaniclastic and carbonate rocks .In most cases, the sequence is incomplete due to faulting resulted from the strong orogenic compression. But (he stratigraphic succession is continuous except for the two interruptions of paleokarsts . which extended from middle Late Carboniferous to Late Permian and from late Early Permian to Late Permian respectively .A preliminary study indicates that the stratigraphy, petrology , sedimentation , vokanism geochemistry and fossils in the sequence are quite similar to mat in modern and ancient oceanic islands and there may be the relics of ancient oceanic islands in the paleo-Tethys .The differences among these sequences probably suggest a complex configuration of the islands or island chain These islands were formed under infra oceanic environments of the paleo-Tethys ,far from continent and accreted to Simao continental margin in Late Permian .The occurrence of large number of ancient oceanic islands in orogenic belts , including the paleo Tethys, Cordillera , etc ..suggests mat some ancient oceans .such as the paleo Tethys and proto-Pacific ,were full of archipelagoes as their modem counterparts . It is possible that more oceanic islands will be recongnized when sufficient research is done in orogenic belts over the world .展开更多
Recently, we focused on the Darbut and Karamay ophiolitic m41anges in West Junggar of the Central Asian Orogenic Belt (CAOB, SengOr et al., 1993; Windley et al., 2007; Xiao and Santosh, 2014), and made much progress...Recently, we focused on the Darbut and Karamay ophiolitic m41anges in West Junggar of the Central Asian Orogenic Belt (CAOB, SengOr et al., 1993; Windley et al., 2007; Xiao and Santosh, 2014), and made much progress. This study was supported by the National Nature Science Foundation of China (No. 41303027) and Special Fund for Basic Scientific Research of Central Colleges Project (No. 2014G1271058). The achievements are illustrated as follows.展开更多
The major elements, rare earth elements (REE) and trace elements of four basalt samples from central and western Pacific ferro- manganese crust provinces have been analyzed using chemical methods and ICP - MS, respe...The major elements, rare earth elements (REE) and trace elements of four basalt samples from central and western Pacific ferro- manganese crust provinces have been analyzed using chemical methods and ICP - MS, respectively. The results indicate that the samples have been extensively altered and that the contents of their major elements have changed significantly. However, the similarity of REE partition patterns and trace element contents of basalt samples to those of fresh oceanic island basalts (OIB) indicate that the basalt samples originated as OIB. Because of low-temperature alteration, the contents of A1203 , Fe203 , MnO, K20 and P205 increased, while MgO and FeO decreased. Active components, such as magnesium and iron, were leached from OIB resulting in the relative enrichment of SiO2. The leaching of active components can cause the relative enrichment of REE, while the precipitation of LREE-rich ferromanganese oxides in vesicles and fissures not only causes an increase of REE contents, but also induces "fractionation" of LREE and HREE. Based on the enrichment mechanism of REE contents, the theoretical quantities of precipitated ferromanganese oxides and the depleted quantities of active components are calculated : the depleted quantities of active components for the unit mass of fresh basalts vary in the range of 0.15 ~ 0. 657, and the precipitated quantities of ferromanganese oxides for the unit mass of fresh basahs vary in the range of 0. 006 ~ 0. 042. Of the major elements, the two most depleted are iron, and magnesium, with 18.28% ~ 70.95% of iron and 44.50% ~ 93.94% of magnesium in the fresh basalts was leached out. Theoretical calculation and geochemistry results both indicate that low-temperature alteration of basalts can supply abundant amount of metals to seawater, and may play an important role in ocean metal circulation.展开更多
Interactions between basaltic melt and orthopyroxenite(Opx)were investigated to gain a better understanding of the consequences of the residence and transport of ocean island basalts(OIBs)within the mantle.The experim...Interactions between basaltic melt and orthopyroxenite(Opx)were investigated to gain a better understanding of the consequences of the residence and transport of ocean island basalts(OIBs)within the mantle.The experiments were conducted using a DS-3600 six-anvil apparatus at 3.0–4.5 GPa and 1300–1450℃.The basaltic melt and Opx coexisted at local equilibrium at these pressures and temperatures;the initial melts dissolved Opx,which modified their chemical composition,and clinopyroxene(Cpx)precipitated with or without garnet(Grt).The trace-element contents of Grt,Cpx,and melt were measured and the mineral–melt distribution coefficients(D)of Cpx–melt and Grt–melt were calculated,which can be used to assess the distribution of trace elements between basalt and minerals in the mantle.Two types of reaction rim were found in the experimental products,Cpx,and Cpx+Grt;this result indicates that residual rocks within the mantle should be pyroxenite or garnet pyroxenite.Both rock types are found in mantle xenoliths from Hawaii,and the rare-earth-element(REE)pattern of Cpx in these mantle pyroxenites matches those of Cpx in the experimental reaction rims.Furthermore,residual melts in the experimental products plot in similar positions to Hawaiian high-SiO_(2)OIBs on major-element Harker diagrams,and their trace-element patterns show the signature of residual Grt,particularly in runs at1350℃ and 4.0–4.5 GPa.Trace-element concentrations of the experimental residual melts plot in similar positions to the Hawaiian OIBs on commonly used discrimination diagrams(Ti vs.Zr,Cr vs.Y,Cr vs.V,Zr/Y vs.Zr,and Ti/Y vs.Nb/Y).These results indicate that reaction between basaltic melt and pyroxenite might contribute to the generation of Hawaiian high-SiO2 OIBs and account for their chemical variability.展开更多
Seamount accretion is one of the most significant accretionary orogenic processes in the Central Asian Orogenic Belt,but there are few paleo-seamounts reported from and debate on the tectonic evolution of the Junggar ...Seamount accretion is one of the most significant accretionary orogenic processes in the Central Asian Orogenic Belt,but there are few paleo-seamounts reported from and debate on the tectonic evolution of the Junggar Ocean still exists.In this study,we present geochronological,mineralogical,geochemical and isotopic data for basalts from the Chagantaolegai ophiolitic mélanges in Junggar.Zircon U-Pb dating on one basalt yielded a weighted mean^(206)Pb/^(238)U age of 469±7 Ma,which suggests that it formed in the Middle Ordovician.All rock samples belong to alkaline basalt and show similar geochemical characteristics,displaying high TiO_(2)(~3 wt%),(La/Yb)N(17.6–19.0),ΣREE(232–289 ppm)and enrichment in Nb and Ta,which implies an ocean island basalt(OIB)affinity.Based upon positiveεN d(t)(+4.16 to+4.23),ΔNb(0.20–0.22)and low initial^(87)Sr/^(86)Sr(0.70425 to 0.70452)and Zr/Nb(3.35–3.57),we suggest that the Chagantaolegai OIB samples were likely derived from a fertile mantle source related to plume.The OIB rock assemblage,chert and marble in the southern part of the Chagantaolegai ophiolitic mélange indicates that a Middle Ordovician seamount was accreted to the Boshchekul-Chingiz arc due to the northward subduction of the Junggar-Balkhash Ocean.展开更多
The compositional variability of ocean island basalts(OIBs)is thought to reflect partial melting of a lithologicallyheterogeneous mantle source dominated by either pyroxenite or peridotite.The Pohnpei Island in Micron...The compositional variability of ocean island basalts(OIBs)is thought to reflect partial melting of a lithologicallyheterogeneous mantle source dominated by either pyroxenite or peridotite.The Pohnpei Island in Micronesia,which is associated with the Caroline hotspot,is suggested to have been generated from partial melting of a pyroxenite-rich mantle.To examine this hypothesis,we present new major-and trace-element compositions of olivine phenocrysts in basalts from the island.The olivines exhibit large systematic inter-and intra-crystalline compositional variability.In Sample DS1,olivines record compositional zonation,in which cores have relatively high Fo(77–85),Ni(550×10^(-6 )–2392×10^(-6 )),and Fe/Mn ratios(66–82),whereas rims have lower Fo(71–78),Ni(526×10^(-6 )–1537×10^(-6 )),and Fe/Mn ratios(51–62).By contrast,olivines within other samples preserve no clear compositional zonation,exhibiting similar or slightly lower Fo values(66–78),Ni contents(401×10^(-6 )–1268×10^(-6 )),and Fe/Mn ratios(53–69)as the rims of zoned crystals.The distinct chemical contrast between the two different types of olivine suggests they formed in magma chambers at different depths.Analysis using forward petrological modeling and multi-element indicators(Fe/Mn,Zn/Fe,FC3MS(FeO^(T)/CaO-(3×MgO/SiO^(2))),Mn/Zn,and Ni/(Mg/Fe))of whole-rock samples and high-Fo olivines is inconsistent with a pyroxenite-rich mantle source.We suggest these inconsistencies reflect an influence on the partition coefficients of Ni and Mn between olivine and liquid during melting at variable pressures and temperatures.In addition,magma recharge and mixing within the magmatic plumbing system can change the composition of olivine.We suggest that identification of the mantle source of OIBs in volcanic islands such as the Pohnpei Island using olivine geochemistry should be treated with caution.展开更多
The alkaline oceanic island basalts(OIBs)with under-saturated SiO2 and high contents of CaO and alkaline are usually attributed to mantle sources different from typical tholeiitic OIBs.Based on the results of high pre...The alkaline oceanic island basalts(OIBs)with under-saturated SiO2 and high contents of CaO and alkaline are usually attributed to mantle sources different from typical tholeiitic OIBs.Based on the results of high pressure and temperature experiment study,the genesis of silica under-saturated alkaline basaltic melts could be explained by the role of CO2,thus,the genetic relationship of alkaline basalts with CO2 has become a topic of relevance because it is closely related to the deep carbon cycle.The Magellan Seamount chain in the West Pacific Seamount Province has wide distribution of alkali basalts.For the first time,we collected alkaline basalt samples from the Kocebu Seamount of the Magellan Seamount chain and found that magmatic apatites widely occur in the less evolved volcanic rock samples,and the high contents of phosphorus should be a feature of the alkaline OIBs of the Magellan Seamounts.Compared with typical OIBs,these alkaline volcanic rocks have higher CaO and P2O5,lower SiO2 content,negative anomaly of high field strength elements(HFSEs),more distinctly negative anomaly of potassium(K)and the ubiquity of titanaugite,indicating a CO2-rich mantle source.Based on the relatively high K2O and TiO2 contents and La/Yb ratio and low MgO content of these alkaline rocks,we suggest that the volcanic rocks of the Magellan Seamounts are originated from carbonated eclogites derived possibly from ancient subducted altered oceanic crust.展开更多
The evolution and final closure of the Neo-Tethys Ocean are one of the most important geological events that have occurred on Earth since the Mesozoic.However,the evolution of the Neo-Tethys is not well constrained,in...The evolution and final closure of the Neo-Tethys Ocean are one of the most important geological events that have occurred on Earth since the Mesozoic.However,the evolution of the Neo-Tethys is not well constrained,in particular whether its opening occurred in the Permian or the Triassic and whether a plume was involved with its opening or not.In this study,we present geochronological and geochemical data for mafic igneous rocks in mélanges along the Yarlung Zangbo suture zone(YZSZ)in southern Tibet to constrain the timing and mechanism of opening the Neo-Tethys Ocean.Based on field observations,the YZSZ mélanges can be divided into three segments.The western(west of Zhongba)and eastern(Sangsang-Renbu)segments are composed of ocean plate stratigraphy representing accretionary complexes that formed during subduction of Neo-Tethyan oceanic lithosphere beneath the southern margin of the Asian continent.Mélanges in the central segment(Zhongba-eastern Saga)typically have a siliciclastic matrix,and represent Tethyan Himalayan strata that were structurally mixed with the southern margin of the Asian continent.Based on our and previously published geochemical data,the mafic rocks in the YZSZ mélanges are ocean island basalt(OIB)-like,with ages in the Late Permian-Middle Triassic,the Middle-Late Jurassic,and the Early Cretaceous,respectively.An OIB-like block with an age of ca.253 Ma is identified from the Zhongba mélanges in the western segment,and it is the oldest OIB lithology yet identified in the YZSZ mélanges related to the evolution of the Neo-Tethys Ocean.Geochemical features indicate that this OIB-like block is distinct from typical OIBs and would be formed during continental rifting to incipient seafloor spreading.In the framework of plate divergent-convergent coupling systems and based on literature data for early Middle Triassic seamounts,radiolarian cherts,and normal mid-ocean ridge basalt-like oceanic crust,we conclude that opening of the Yarlung Zangbo Neo-Tethys Ocean would mainly occur at~250–243 Ma in the Early Triassic,not later than the early phase of Middle Triassic.In addition,a mantle plume was not involved in opening the Yarlung Zangbo Neo-Tethys Ocean.On the other hand,we have also identified a suite of ca.160 Ma OIB-like basaltic sills from the Bainang mélanges in the eastern segment,which is the same age as the OIB lithologies previously reported in the Zhongba mélanges.Based on the sill-like occurrence and absence of plume-related rock associations in this region,the Bainang OIB-like rocks might result from Middle-Late Jurassic continental rifting in northern Gondwana.Magmatism related to this tectonic event is preserved in both the YZSZ mélanges and Himalayan strata,but its tectonic significance requires further investigation.Based on this study of the YZSZ mélanges and the previous studies of YZSZ ophiolites,Gangdese belt igneous rocks,and sedimentary rocks,we have reconstructed the entire Wilson Cycle of the Yarlung Zangbo Neo-Tethys Ocean,mainly involving continental rifting and ocean opening,subduction initiation,ultraslow-spreading ridge-trench conversion,subduction re-initiation,and oceanic closure and initial India-Asia collision for the tectonic emplacement of ophiolites.These processes were associated not only with magmatic flare-ups and lulls in the Gangdese belt but also with two stages of ophiolite obduction.Our data therefore provide new insights into the evolution of the Yarlung Zangbo Neo-Tethys Ocean and related Tethyan geodynamics.展开更多
Early Cretaceous magmatism suggested to be related with the Kerguelen mantle plume has been reported in both the eastern and western Tethyan Himalayan terrane.Coeval magmatism(133-138 Ma)recorded by hypabyssal intrusi...Early Cretaceous magmatism suggested to be related with the Kerguelen mantle plume has been reported in both the eastern and western Tethyan Himalayan terrane.Coeval magmatism(133-138 Ma)recorded by hypabyssal intrusive rocks have been recently discovered in the central Tethyan Himalaya(TH).The hypabyssal intrusions are dominated by OIB-like basaltic rocks intruded by later porphyritic/ophitic intermediate rocks and are characterized by strongly light rare earth element enrichment and prominent Na-Ta depletion and Pb enrichment.The basaltic rocks have low 143Nd/144Nd ratios ranging from 0.512365 to 0.512476 but relatively high 87Sr/86Sr ratios ranging from 0.708185 to 0.708966.TheεNd(t)ratios of the basaltic rocks are between-4.33 and-2.20 and initial 87Sr/86Sr ratios are 0.707807 to 0.708557.Geochemical data demonstrate that these rocks have experienced combined crustal assimilation and fractional crystallization processes.Magmatic zircons from the hypabyssal rocks exclusively have negativeεHf(t)values ranging from-0.7 to-12.7,suggestive of assimilation of crustal material.Zircons from these hypabyssal rocks have UPb ages ranging from 130 to 147 Ma.Inherited zircons have UPb ages from 397 to 2495 Ma.All the zircons are characterized by negativeεHf(t)values.The Jiding ocean island basalt(OIB)-like magmatism is geochemically and geochronologically comparable with that in the western and eastern Tethyan Himalaya,indicating widespread OIB-like magmatism in the northern margin of Greater India during the Cretaceous.Collectively,these rocks can be correlated with other early Cretaceous magmatism in western Australia and northern Antarctica.Considering the similarities,we suggest that the Jiding hypabyssal rocks are also genetically related to Kerguelen plume.Within the Yarlung Zangbo Suture Zone(YZSZ),there are also numerous occurrences of OIB-like rocks derived from mantle sources different from those of N-MORB-like magmas.The OIB-like magmatism in the YZSZ is nearly coeval with that in the TH,and the two are geochemically similar.We suggest that the OIB-like magmatism in the Neo-Tethyan ocean and the northern margin of Greater India may represent the dispersed fingerprints of the Kerguelen plume preserved in southern Tibet,China.展开更多
Aims Plant-pollinator interaction networks are dynamic entities,and seasonal variation in plant phenology can reshape their structure on both short and long timescales.However,such seasonal dynamics are rarely conside...Aims Plant-pollinator interaction networks are dynamic entities,and seasonal variation in plant phenology can reshape their structure on both short and long timescales.However,such seasonal dynamics are rarely considered,especially for oceanic island pollination networks.Here,we assess changes in the temporal dynamics of plant-pollinator interactions in response to seasonal variation in floral resource richness in oceanic island communities.Methods We evaluated seasonal variations of pollination networks in the Yongxing Island community.Four temporal qualitative pollination networks were analyzed using plant-pollinator interaction data of the four seasons.We collected data on plant-pollinator interactions during two consecutive months in each of the four seasons.Four network-level indices were calculated to characterize the overall structure of the networks.Statistical analyses of community dissimilarity were used to compare this community across four seasons to explore the underlying factors driving these patterns.We also evaluated the temporal variation in two species-level indices of plant and pollinator functional groups.Important Findings Both network-level specialization and modularity showed a significantly opposite trend compared with plant species richness across four seasons.Increased numbers of plant species might promote greater competition among pollinators,leading to increased niche overlap and causing decreased specialization and modularity and vice versa.Further analyses suggested that the season-to-season turnover of interactions was dominated by interaction rewiring.Thus,the seasonal changes in niche overlap among pollinators lead to interaction rewiring,which drives interaction turnover in this community.Hawkmoths had higher values of specialization and Apidae had higher values of species strength compared with other pollinator functional groups.These findings should be considered when exploring plant-pollinator interactions in ecosystems of isolated oceanic islands and in other ecosystems.展开更多
The tectonic environment of granitoids has always been a concern of the academic community.The Nb vs.Y and Rb vs.Nb+Y diagrams have had a substantial impact.The present work uses more than 110,000 granitoid samples(Si...The tectonic environment of granitoids has always been a concern of the academic community.The Nb vs.Y and Rb vs.Nb+Y diagrams have had a substantial impact.The present work uses more than 110,000 granitoid samples(SiO_(2)≥56%)from the globally shared database to discuss the validity and also explain why these diagrams used for discrimination between the different tectonic settings of granitoid rocks.The amount of data from the spreading center is sparse and the data are highly scattered and so,the present study focuses mainly on granites from the ocean islands and convergent margins tectonic environments.On the TAS diagram most of the ocean island data are alkaline series and trachybasalt series,and some are bimodal.In contrast,the granitoids on the convergent margin are mainly sub-alkaline.This work shows that the tectonic discrimination diagrams of granitoids remain valid,and only the boundaries need to be slightly adjusted.展开更多
Accretionary wedge is the typical product of subduction-zone processes at shallow depths. Determining the location, composition and mechanism of accretionary wedge has important implications for understanding the tect...Accretionary wedge is the typical product of subduction-zone processes at shallow depths. Determining the location, composition and mechanism of accretionary wedge has important implications for understanding the tectonism of plate subduction. The Central Asian Orogenic Belt (CAOB) is one of the world's largest accretionary orogenic belts, and records the bulk evolution of Paleo-Asian Ocean from opening to closure, with multi-stages and multi-types of crust-mantle interaction in the Paleozoic. West Junggar (western part of Junggar Basin), located in the core area of CAOB, is characterized by a multiple intra-oceanic subduction system during the Paleozoic. In its eastem part crop out Devonian-Carboniferous marine sedimentary rocks, Darbut and Karamay ophiolitic m61anges, alkali oceanic island basalts, island arc volcanic rocks and thrusted nappe structure. Such lithotectonic associations indicate the occurrence of accretionary wedge at Karamay. In order to decipher its formation mechanism, this paper presents a synthesis of petrography, structural geology and geochemistry of volcanic rocks. In combination with oceanic subduction channel processes, it is suggested that the accretionary wedge is a composite melange with multiple stages of formation. The application of oceanic subduction channel model to the Karamay accretionary wedge provides new insights into the accretion and orogenesis of CAOB.展开更多
The Galápagos are considered a model oceanic archipelago,with unique flora and fauna currently threatened by alien invasive species.Seed dispersal is an important ecosystem function with consequences for plant po...The Galápagos are considered a model oceanic archipelago,with unique flora and fauna currently threatened by alien invasive species.Seed dispersal is an important ecosystem function with consequences for plant population dynamics and vegetation structure.Hence,understanding the seed dispersal abilities of the assemblages of frugivores will inform scientists and managers of the dynamics of plant invasions and improve management planning.Here we provide the first comprehensive review of published information on frugivory and animal seed dispersal in the Galápagos.We collected data from a variety of sources,including notes of the first naturalist expeditions,gray literature available only in Galápagos collections,and peer-reviewed journal articles.Plant–animal frugivorous interactions were retrieved from 43 studies and compiled into an interaction matrix describing 366 unique interactions.Most studies focused on fruit consumption as a driving force for natural selection,but seed fate was seldom considered.Although most(71%)of the interactions involved native plants,more than one-quarter(28%)involved introduced species.Interactions involving birds are considerably more common than those of reptiles and mammals,probably reflecting a research bias towards birds.Despite the historical importance of the archipelago as the laboratory for evolutionary and ecological research,understanding of its seed dispersal systems is limited.We end the review by suggesting 3 priority areas of research on frugivory and seed dispersal in the Galápagos:(i)target research to close knowledge gaps;(ii)the use of a network approach to frame seed dispersal at the community level;and(iii)evaluation of the effect of seed dispersal as a selective pressure acting upon plants and frugivores.Finally,the output of this research has to be properly delivered to the Galápagos National Park Services to help increase management effectiveness.展开更多
基金The research is supported by National Nature Science Foundation of China No.49172101the State Education Committee Funds for Doctoral Supervisors
文摘A volcano-platform carbonate sequence ,from Carboniferous to Permian , is widely trapped in the deep water deposits in Changning- Menglian belt .Three components can be roughly recognized in ascending order as :the lava .the volcaniclastic and carbonate rocks .In most cases, the sequence is incomplete due to faulting resulted from the strong orogenic compression. But (he stratigraphic succession is continuous except for the two interruptions of paleokarsts . which extended from middle Late Carboniferous to Late Permian and from late Early Permian to Late Permian respectively .A preliminary study indicates that the stratigraphy, petrology , sedimentation , vokanism geochemistry and fossils in the sequence are quite similar to mat in modern and ancient oceanic islands and there may be the relics of ancient oceanic islands in the paleo-Tethys .The differences among these sequences probably suggest a complex configuration of the islands or island chain These islands were formed under infra oceanic environments of the paleo-Tethys ,far from continent and accreted to Simao continental margin in Late Permian .The occurrence of large number of ancient oceanic islands in orogenic belts , including the paleo Tethys, Cordillera , etc ..suggests mat some ancient oceans .such as the paleo Tethys and proto-Pacific ,were full of archipelagoes as their modem counterparts . It is possible that more oceanic islands will be recongnized when sufficient research is done in orogenic belts over the world .
基金supported by the National Nature Science Foundation of China(No.41303027)Special Fund for Basic Scientific Research of Central Colleges Project(No.2014G1271058)
文摘Recently, we focused on the Darbut and Karamay ophiolitic m41anges in West Junggar of the Central Asian Orogenic Belt (CAOB, SengOr et al., 1993; Windley et al., 2007; Xiao and Santosh, 2014), and made much progress. This study was supported by the National Nature Science Foundation of China (No. 41303027) and Special Fund for Basic Scientific Research of Central Colleges Project (No. 2014G1271058). The achievements are illustrated as follows.
基金The National Natural Science Foundation of China (NSFC) under contract No 40706028the China Oceanic Mineral Resources Re-search and Development Association (COMRA) under contract No DYXM115-01-2-01
文摘The major elements, rare earth elements (REE) and trace elements of four basalt samples from central and western Pacific ferro- manganese crust provinces have been analyzed using chemical methods and ICP - MS, respectively. The results indicate that the samples have been extensively altered and that the contents of their major elements have changed significantly. However, the similarity of REE partition patterns and trace element contents of basalt samples to those of fresh oceanic island basalts (OIB) indicate that the basalt samples originated as OIB. Because of low-temperature alteration, the contents of A1203 , Fe203 , MnO, K20 and P205 increased, while MgO and FeO decreased. Active components, such as magnesium and iron, were leached from OIB resulting in the relative enrichment of SiO2. The leaching of active components can cause the relative enrichment of REE, while the precipitation of LREE-rich ferromanganese oxides in vesicles and fissures not only causes an increase of REE contents, but also induces "fractionation" of LREE and HREE. Based on the enrichment mechanism of REE contents, the theoretical quantities of precipitated ferromanganese oxides and the depleted quantities of active components are calculated : the depleted quantities of active components for the unit mass of fresh basalts vary in the range of 0.15 ~ 0. 657, and the precipitated quantities of ferromanganese oxides for the unit mass of fresh basahs vary in the range of 0. 006 ~ 0. 042. Of the major elements, the two most depleted are iron, and magnesium, with 18.28% ~ 70.95% of iron and 44.50% ~ 93.94% of magnesium in the fresh basalts was leached out. Theoretical calculation and geochemistry results both indicate that low-temperature alteration of basalts can supply abundant amount of metals to seawater, and may play an important role in ocean metal circulation.
基金Natural Science Foundations of China(Grant Nos.41502057 and 41472065)Foundations of Suzhou University(Nos.2019ZD46,2015jb01 and 2015jb07).
文摘Interactions between basaltic melt and orthopyroxenite(Opx)were investigated to gain a better understanding of the consequences of the residence and transport of ocean island basalts(OIBs)within the mantle.The experiments were conducted using a DS-3600 six-anvil apparatus at 3.0–4.5 GPa and 1300–1450℃.The basaltic melt and Opx coexisted at local equilibrium at these pressures and temperatures;the initial melts dissolved Opx,which modified their chemical composition,and clinopyroxene(Cpx)precipitated with or without garnet(Grt).The trace-element contents of Grt,Cpx,and melt were measured and the mineral–melt distribution coefficients(D)of Cpx–melt and Grt–melt were calculated,which can be used to assess the distribution of trace elements between basalt and minerals in the mantle.Two types of reaction rim were found in the experimental products,Cpx,and Cpx+Grt;this result indicates that residual rocks within the mantle should be pyroxenite or garnet pyroxenite.Both rock types are found in mantle xenoliths from Hawaii,and the rare-earth-element(REE)pattern of Cpx in these mantle pyroxenites matches those of Cpx in the experimental reaction rims.Furthermore,residual melts in the experimental products plot in similar positions to Hawaiian high-SiO_(2)OIBs on major-element Harker diagrams,and their trace-element patterns show the signature of residual Grt,particularly in runs at1350℃ and 4.0–4.5 GPa.Trace-element concentrations of the experimental residual melts plot in similar positions to the Hawaiian OIBs on commonly used discrimination diagrams(Ti vs.Zr,Cr vs.Y,Cr vs.V,Zr/Y vs.Zr,and Ti/Y vs.Nb/Y).These results indicate that reaction between basaltic melt and pyroxenite might contribute to the generation of Hawaiian high-SiO2 OIBs and account for their chemical variability.
基金supported by the National Science Foundation of China(Grant No.41672217)the Fundamental Research Funds for the Central Universities(Grant No.N170104022)the State Scholarship Fund(Grant No.201806085034)。
文摘Seamount accretion is one of the most significant accretionary orogenic processes in the Central Asian Orogenic Belt,but there are few paleo-seamounts reported from and debate on the tectonic evolution of the Junggar Ocean still exists.In this study,we present geochronological,mineralogical,geochemical and isotopic data for basalts from the Chagantaolegai ophiolitic mélanges in Junggar.Zircon U-Pb dating on one basalt yielded a weighted mean^(206)Pb/^(238)U age of 469±7 Ma,which suggests that it formed in the Middle Ordovician.All rock samples belong to alkaline basalt and show similar geochemical characteristics,displaying high TiO_(2)(~3 wt%),(La/Yb)N(17.6–19.0),ΣREE(232–289 ppm)and enrichment in Nb and Ta,which implies an ocean island basalt(OIB)affinity.Based upon positiveεN d(t)(+4.16 to+4.23),ΔNb(0.20–0.22)and low initial^(87)Sr/^(86)Sr(0.70425 to 0.70452)and Zr/Nb(3.35–3.57),we suggest that the Chagantaolegai OIB samples were likely derived from a fertile mantle source related to plume.The OIB rock assemblage,chert and marble in the southern part of the Chagantaolegai ophiolitic mélange indicates that a Middle Ordovician seamount was accreted to the Boshchekul-Chingiz arc due to the northward subduction of the Junggar-Balkhash Ocean.
基金The Resources and Environment Projects of China Ocean Mineral R&D Association under contract No.DY135-E2-2-01the Natural Science Foundation of Shandong Province under contract No.ZR2020QD076
文摘The compositional variability of ocean island basalts(OIBs)is thought to reflect partial melting of a lithologicallyheterogeneous mantle source dominated by either pyroxenite or peridotite.The Pohnpei Island in Micronesia,which is associated with the Caroline hotspot,is suggested to have been generated from partial melting of a pyroxenite-rich mantle.To examine this hypothesis,we present new major-and trace-element compositions of olivine phenocrysts in basalts from the island.The olivines exhibit large systematic inter-and intra-crystalline compositional variability.In Sample DS1,olivines record compositional zonation,in which cores have relatively high Fo(77–85),Ni(550×10^(-6 )–2392×10^(-6 )),and Fe/Mn ratios(66–82),whereas rims have lower Fo(71–78),Ni(526×10^(-6 )–1537×10^(-6 )),and Fe/Mn ratios(51–62).By contrast,olivines within other samples preserve no clear compositional zonation,exhibiting similar or slightly lower Fo values(66–78),Ni contents(401×10^(-6 )–1268×10^(-6 )),and Fe/Mn ratios(53–69)as the rims of zoned crystals.The distinct chemical contrast between the two different types of olivine suggests they formed in magma chambers at different depths.Analysis using forward petrological modeling and multi-element indicators(Fe/Mn,Zn/Fe,FC3MS(FeO^(T)/CaO-(3×MgO/SiO^(2))),Mn/Zn,and Ni/(Mg/Fe))of whole-rock samples and high-Fo olivines is inconsistent with a pyroxenite-rich mantle source.We suggest these inconsistencies reflect an influence on the partition coefficients of Ni and Mn between olivine and liquid during melting at variable pressures and temperatures.In addition,magma recharge and mixing within the magmatic plumbing system can change the composition of olivine.We suggest that identification of the mantle source of OIBs in volcanic islands such as the Pohnpei Island using olivine geochemistry should be treated with caution.
基金the National Natural Science Foundation of China(Nos.91858206,41876040)the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDA22050101,XDB42020302)+1 种基金the Taishan Scholars Program of Shandong Province(No.tsqn201909157),Senior User Project of R/V Kexue(No.KEXUE2018G09)the Laboratory for Marine Geology,Qingdao National Laboratory for Marine Science and Technology(No.MGQNLMTD201806)。
文摘The alkaline oceanic island basalts(OIBs)with under-saturated SiO2 and high contents of CaO and alkaline are usually attributed to mantle sources different from typical tholeiitic OIBs.Based on the results of high pressure and temperature experiment study,the genesis of silica under-saturated alkaline basaltic melts could be explained by the role of CO2,thus,the genetic relationship of alkaline basalts with CO2 has become a topic of relevance because it is closely related to the deep carbon cycle.The Magellan Seamount chain in the West Pacific Seamount Province has wide distribution of alkali basalts.For the first time,we collected alkaline basalt samples from the Kocebu Seamount of the Magellan Seamount chain and found that magmatic apatites widely occur in the less evolved volcanic rock samples,and the high contents of phosphorus should be a feature of the alkaline OIBs of the Magellan Seamounts.Compared with typical OIBs,these alkaline volcanic rocks have higher CaO and P2O5,lower SiO2 content,negative anomaly of high field strength elements(HFSEs),more distinctly negative anomaly of potassium(K)and the ubiquity of titanaugite,indicating a CO2-rich mantle source.Based on the relatively high K2O and TiO2 contents and La/Yb ratio and low MgO content of these alkaline rocks,we suggest that the volcanic rocks of the Magellan Seamounts are originated from carbonated eclogites derived possibly from ancient subducted altered oceanic crust.
基金supported by the National Natural Science Foundation of China (Grant Nos.42025201,92155001,41802062,41888101)the Second Tibetan Plateau Scientific Expedition and Research Program (Grant No.2019QZKK0801)。
文摘The evolution and final closure of the Neo-Tethys Ocean are one of the most important geological events that have occurred on Earth since the Mesozoic.However,the evolution of the Neo-Tethys is not well constrained,in particular whether its opening occurred in the Permian or the Triassic and whether a plume was involved with its opening or not.In this study,we present geochronological and geochemical data for mafic igneous rocks in mélanges along the Yarlung Zangbo suture zone(YZSZ)in southern Tibet to constrain the timing and mechanism of opening the Neo-Tethys Ocean.Based on field observations,the YZSZ mélanges can be divided into three segments.The western(west of Zhongba)and eastern(Sangsang-Renbu)segments are composed of ocean plate stratigraphy representing accretionary complexes that formed during subduction of Neo-Tethyan oceanic lithosphere beneath the southern margin of the Asian continent.Mélanges in the central segment(Zhongba-eastern Saga)typically have a siliciclastic matrix,and represent Tethyan Himalayan strata that were structurally mixed with the southern margin of the Asian continent.Based on our and previously published geochemical data,the mafic rocks in the YZSZ mélanges are ocean island basalt(OIB)-like,with ages in the Late Permian-Middle Triassic,the Middle-Late Jurassic,and the Early Cretaceous,respectively.An OIB-like block with an age of ca.253 Ma is identified from the Zhongba mélanges in the western segment,and it is the oldest OIB lithology yet identified in the YZSZ mélanges related to the evolution of the Neo-Tethys Ocean.Geochemical features indicate that this OIB-like block is distinct from typical OIBs and would be formed during continental rifting to incipient seafloor spreading.In the framework of plate divergent-convergent coupling systems and based on literature data for early Middle Triassic seamounts,radiolarian cherts,and normal mid-ocean ridge basalt-like oceanic crust,we conclude that opening of the Yarlung Zangbo Neo-Tethys Ocean would mainly occur at~250–243 Ma in the Early Triassic,not later than the early phase of Middle Triassic.In addition,a mantle plume was not involved in opening the Yarlung Zangbo Neo-Tethys Ocean.On the other hand,we have also identified a suite of ca.160 Ma OIB-like basaltic sills from the Bainang mélanges in the eastern segment,which is the same age as the OIB lithologies previously reported in the Zhongba mélanges.Based on the sill-like occurrence and absence of plume-related rock associations in this region,the Bainang OIB-like rocks might result from Middle-Late Jurassic continental rifting in northern Gondwana.Magmatism related to this tectonic event is preserved in both the YZSZ mélanges and Himalayan strata,but its tectonic significance requires further investigation.Based on this study of the YZSZ mélanges and the previous studies of YZSZ ophiolites,Gangdese belt igneous rocks,and sedimentary rocks,we have reconstructed the entire Wilson Cycle of the Yarlung Zangbo Neo-Tethys Ocean,mainly involving continental rifting and ocean opening,subduction initiation,ultraslow-spreading ridge-trench conversion,subduction re-initiation,and oceanic closure and initial India-Asia collision for the tectonic emplacement of ophiolites.These processes were associated not only with magmatic flare-ups and lulls in the Gangdese belt but also with two stages of ophiolite obduction.Our data therefore provide new insights into the evolution of the Yarlung Zangbo Neo-Tethys Ocean and related Tethyan geodynamics.
基金supported by the National Natural Science Foundation of China(41802034,41720104009,41802055)the Natural Science Foundation of Jiangsu Province(BK20180349)the fund from the Key Laboratory of Deep-Earth Dynamics of Ministry of Natural Resources
文摘Early Cretaceous magmatism suggested to be related with the Kerguelen mantle plume has been reported in both the eastern and western Tethyan Himalayan terrane.Coeval magmatism(133-138 Ma)recorded by hypabyssal intrusive rocks have been recently discovered in the central Tethyan Himalaya(TH).The hypabyssal intrusions are dominated by OIB-like basaltic rocks intruded by later porphyritic/ophitic intermediate rocks and are characterized by strongly light rare earth element enrichment and prominent Na-Ta depletion and Pb enrichment.The basaltic rocks have low 143Nd/144Nd ratios ranging from 0.512365 to 0.512476 but relatively high 87Sr/86Sr ratios ranging from 0.708185 to 0.708966.TheεNd(t)ratios of the basaltic rocks are between-4.33 and-2.20 and initial 87Sr/86Sr ratios are 0.707807 to 0.708557.Geochemical data demonstrate that these rocks have experienced combined crustal assimilation and fractional crystallization processes.Magmatic zircons from the hypabyssal rocks exclusively have negativeεHf(t)values ranging from-0.7 to-12.7,suggestive of assimilation of crustal material.Zircons from these hypabyssal rocks have UPb ages ranging from 130 to 147 Ma.Inherited zircons have UPb ages from 397 to 2495 Ma.All the zircons are characterized by negativeεHf(t)values.The Jiding ocean island basalt(OIB)-like magmatism is geochemically and geochronologically comparable with that in the western and eastern Tethyan Himalaya,indicating widespread OIB-like magmatism in the northern margin of Greater India during the Cretaceous.Collectively,these rocks can be correlated with other early Cretaceous magmatism in western Australia and northern Antarctica.Considering the similarities,we suggest that the Jiding hypabyssal rocks are also genetically related to Kerguelen plume.Within the Yarlung Zangbo Suture Zone(YZSZ),there are also numerous occurrences of OIB-like rocks derived from mantle sources different from those of N-MORB-like magmas.The OIB-like magmatism in the YZSZ is nearly coeval with that in the TH,and the two are geochemically similar.We suggest that the OIB-like magmatism in the Neo-Tethyan ocean and the northern margin of Greater India may represent the dispersed fingerprints of the Kerguelen plume preserved in southern Tibet,China.
基金supported by the National Natural Science Foundation of China(grant no.31800447)the Chinese Academy of Sciences(grant no.XDA13020504)+1 种基金the Natural Science Foundation of Guangdong Province(grant no.2018A030310385)the National Natural Science Foundation of China(grant no.U1701246).
文摘Aims Plant-pollinator interaction networks are dynamic entities,and seasonal variation in plant phenology can reshape their structure on both short and long timescales.However,such seasonal dynamics are rarely considered,especially for oceanic island pollination networks.Here,we assess changes in the temporal dynamics of plant-pollinator interactions in response to seasonal variation in floral resource richness in oceanic island communities.Methods We evaluated seasonal variations of pollination networks in the Yongxing Island community.Four temporal qualitative pollination networks were analyzed using plant-pollinator interaction data of the four seasons.We collected data on plant-pollinator interactions during two consecutive months in each of the four seasons.Four network-level indices were calculated to characterize the overall structure of the networks.Statistical analyses of community dissimilarity were used to compare this community across four seasons to explore the underlying factors driving these patterns.We also evaluated the temporal variation in two species-level indices of plant and pollinator functional groups.Important Findings Both network-level specialization and modularity showed a significantly opposite trend compared with plant species richness across four seasons.Increased numbers of plant species might promote greater competition among pollinators,leading to increased niche overlap and causing decreased specialization and modularity and vice versa.Further analyses suggested that the season-to-season turnover of interactions was dominated by interaction rewiring.Thus,the seasonal changes in niche overlap among pollinators lead to interaction rewiring,which drives interaction turnover in this community.Hawkmoths had higher values of specialization and Apidae had higher values of species strength compared with other pollinator functional groups.These findings should be considered when exploring plant-pollinator interactions in ecosystems of isolated oceanic islands and in other ecosystems.
文摘The tectonic environment of granitoids has always been a concern of the academic community.The Nb vs.Y and Rb vs.Nb+Y diagrams have had a substantial impact.The present work uses more than 110,000 granitoid samples(SiO_(2)≥56%)from the globally shared database to discuss the validity and also explain why these diagrams used for discrimination between the different tectonic settings of granitoid rocks.The amount of data from the spreading center is sparse and the data are highly scattered and so,the present study focuses mainly on granites from the ocean islands and convergent margins tectonic environments.On the TAS diagram most of the ocean island data are alkaline series and trachybasalt series,and some are bimodal.In contrast,the granitoids on the convergent margin are mainly sub-alkaline.This work shows that the tectonic discrimination diagrams of granitoids remain valid,and only the boundaries need to be slightly adjusted.
基金supported by the National Natural Science Foundation of China(Grant No.41303027)the Young Star of Science and Technology Plan Projects in Shaanxi Province,China(Grant No.2016KJXX-71)the Special Fund for Basic Scientific Research of Central Colleges,Chang'an University(Grant Nos.310827153506&310827153407)
文摘Accretionary wedge is the typical product of subduction-zone processes at shallow depths. Determining the location, composition and mechanism of accretionary wedge has important implications for understanding the tectonism of plate subduction. The Central Asian Orogenic Belt (CAOB) is one of the world's largest accretionary orogenic belts, and records the bulk evolution of Paleo-Asian Ocean from opening to closure, with multi-stages and multi-types of crust-mantle interaction in the Paleozoic. West Junggar (western part of Junggar Basin), located in the core area of CAOB, is characterized by a multiple intra-oceanic subduction system during the Paleozoic. In its eastem part crop out Devonian-Carboniferous marine sedimentary rocks, Darbut and Karamay ophiolitic m61anges, alkali oceanic island basalts, island arc volcanic rocks and thrusted nappe structure. Such lithotectonic associations indicate the occurrence of accretionary wedge at Karamay. In order to decipher its formation mechanism, this paper presents a synthesis of petrography, structural geology and geochemistry of volcanic rocks. In combination with oceanic subduction channel processes, it is suggested that the accretionary wedge is a composite melange with multiple stages of formation. The application of oceanic subduction channel model to the Karamay accretionary wedge provides new insights into the accretion and orogenesis of CAOB.
基金The present study was part of a biodiversity project funded by the BBVA Foundation(Spain).
文摘The Galápagos are considered a model oceanic archipelago,with unique flora and fauna currently threatened by alien invasive species.Seed dispersal is an important ecosystem function with consequences for plant population dynamics and vegetation structure.Hence,understanding the seed dispersal abilities of the assemblages of frugivores will inform scientists and managers of the dynamics of plant invasions and improve management planning.Here we provide the first comprehensive review of published information on frugivory and animal seed dispersal in the Galápagos.We collected data from a variety of sources,including notes of the first naturalist expeditions,gray literature available only in Galápagos collections,and peer-reviewed journal articles.Plant–animal frugivorous interactions were retrieved from 43 studies and compiled into an interaction matrix describing 366 unique interactions.Most studies focused on fruit consumption as a driving force for natural selection,but seed fate was seldom considered.Although most(71%)of the interactions involved native plants,more than one-quarter(28%)involved introduced species.Interactions involving birds are considerably more common than those of reptiles and mammals,probably reflecting a research bias towards birds.Despite the historical importance of the archipelago as the laboratory for evolutionary and ecological research,understanding of its seed dispersal systems is limited.We end the review by suggesting 3 priority areas of research on frugivory and seed dispersal in the Galápagos:(i)target research to close knowledge gaps;(ii)the use of a network approach to frame seed dispersal at the community level;and(iii)evaluation of the effect of seed dispersal as a selective pressure acting upon plants and frugivores.Finally,the output of this research has to be properly delivered to the Galápagos National Park Services to help increase management effectiveness.