Natural fractures are critical for shale oil and gas enrichment and development. Due to the extremely high heterogeneity of shale, the factors controlling the formation of internal fractures, especially horizontal fra...Natural fractures are critical for shale oil and gas enrichment and development. Due to the extremely high heterogeneity of shale, the factors controlling the formation of internal fractures, especially horizontal fractures, remain controversial. In this study, we integrate thin section analysis and microcomputed tomography(CT) data from several lacustrine shale samples from the third member(Es3) of the Shahejie Formation, Qikou Sag, Bohai Bay Basin, to assess the fractures in detail. The goal is to reveal the development characteristics, controlling factors, and geological significance for evaluating sweet spots in a shale oil play. The fractures in the Es3contain high-angle structural and horizontal bed-parallel fractures that are mostly shear and extensional. Various factors influence fracture development,including lithofacies, mineral composition, organic matter content, and the number of laminae. Structural fractures occur predominantly in siltstone, whereas bed-parallel fractures are abundant in laminated shale and layered mudstone. A higher quartz content results in higher shale brittleness, causing fractures, whereas the transformation between clay minerals contributes to the development of bedparallel fractures. Excess pore pressure due to hydrocarbon generation and expulsion during thermal advance can cause the formation of bed-parallel fractures. The density of the bed-parallel and structural fractures increases with the lamina density, and the bed-parallel fractures are more sensitive to the number of laminae. The fractures are critical storage spaces and flow conduits and are indicative of sweet spots. The laminated shale in the Es3with a high organic matter content contains natural fractures and is an organic-rich, liquid-rich, self-sourced shale play. Conversely, the siltstone, massive mudstone, and argillaceous carbonate lithofacies contain lower amounts of organic matter and do not have bed-parallel fractures. However, good reservoirs can form in these areas when structural fractures are present and the source, and storage spaces are separated.展开更多
The occurrence characteristics of shale oil are of great significance to the movability of shale oil.In this study,the occurrence characteristics of oil in the shale matrix at Funing Formation shale in Subei Basin wer...The occurrence characteristics of shale oil are of great significance to the movability of shale oil.In this study,the occurrence characteristics of oil in the shale matrix at Funing Formation shale in Subei Basin were quantitatively evaluated by organic geochemistry and microscopic pore structure characterization experiments.The Multiple Isothermal Stages Pyrolysis(MIS)experiment results show that the content of total oil,adsorbed oil,and free oil in the shales are 3.15-11.25 mg/g,1.41-4.95 mg/g,and 1.74-6.51 mg/g,respectively.among which the silicon-rich shale has the best oil-bearing.The relative content of free oil shows an increasing trend in pores with pore diameters greater than 3 nm.When the relative content of free oil reaches 100%,the pore size of silicon-rich shale is about 200 nm,while that of calcium-rich shale,clay-rich shale,and siliceous mixed shale is about 10 nm.The occurrence law of adsorbed oil is opposite to that of free oil,which indicates that shale oil will occur in the pores and fractures in a free state in a more extensive pore size range(>200 nm).This study also enables us to further understand the occurrence characteristics of shale oil under the interaction of occurrence state and occurrence space.展开更多
In the present work, the pool boiling critical heat flux, transient heat transfer characteristics, and bonding strength of thin Ni-Cr wire with aqua based reduced graphene oxide(r GO) nanofluids are experimentally stu...In the present work, the pool boiling critical heat flux, transient heat transfer characteristics, and bonding strength of thin Ni-Cr wire with aqua based reduced graphene oxide(r GO) nanofluids are experimentally studied. Results indicate:(i) the critical heat flux(CHF) of 0.01, 0.05, 0.1, 0.2, and 0.3 g·L^(-1) concentrations of r GO-water nanofluids varies from 1.42 to 2.40 MW·m^(-2);(ii) the CHF remains same for the tested samples during transient heat transfer studies and(iii) a constant value of CHF upto 10 tests when the nanocoated Ni-Cr wire is tested with DI water and deterioration occurs beyond this which implies a chance of peel off of r GO layer below the critical coating thickness.展开更多
The Dongsha fault- uplifted massif (for convenience . Dongsha massif from here on) is located in the northern continental shelf-slope of the South China Sea, where the water depth is 100-400m. The massif is considered...The Dongsha fault- uplifted massif (for convenience . Dongsha massif from here on) is located in the northern continental shelf-slope of the South China Sea, where the water depth is 100-400m. The massif is considered to be a part of the large-scale fault-uplifted zone directed NE and separating the Pearl River Mouth Basin into northern and southern graben areas. The sedimentary cover of the Pearl River Mouth Graben consists mainly of a 7000-10000m thick Tertiary system. A large-scale uplift occurred in the Dongsha fault-uplifted zone during Paleocene-Eocene when the lower structural layer (lower Tertiary) existed only in the small depressions of the fault-uplifted zone. The formation and evolution of the Dongsha fault-uplifted zone could be divided into: 1) the basement formation stage (J2-K1); 2) the slowly uplifted stage (K2-E22); 3) the weathering and erosion stage (E23-E31); 4) the integrated subsidence stage (E32-N12) and 5) the last uplifted stage (N13-Q). The formation of the oil and gas pools展开更多
Based on the analysis of the hydrocarbon geochemical characteristics in the Kuqa petroleum system of the Tarim Basin, this study discusses the causes and controlling factors of the phase diversities and their differen...Based on the analysis of the hydrocarbon geochemical characteristics in the Kuqa petroleum system of the Tarim Basin, this study discusses the causes and controlling factors of the phase diversities and their differences in geochemical features. According to the characteristics and differences in oil and gas phase, the petroleum system can be divided into five categories: oil reservoir, wet gas reservoir, condensate gas-rich reservoir, condensate gas-poor reservoir and dry gas reservoir. The causes for the diversities in oil and gas phases include diversities of the sources of parent material, maturity of natural gas and the process of hydrocarbon accumulation of different hydrocarbon phases. On the whole, the Jurassic and Triassic terrestrial source rocks are the main sources for the hydrocarbon in the Kuqa Depression. The small differences in parent material may cause diversities in oil and gas amount, but the impact is small. The differences in oil and gas phase are mainly affected by maturity and the accumulation process, which closely relates with each other. Oil and gas at different thermal evolution stage can be captured in different accumulation process.展开更多
Coal and oil shale are two common sedimentary energy sources which are often symbiotically developed in M esozoic- Cenozoic continental fault basins. However, the mechanisms and characteristics of the symbiotic develo...Coal and oil shale are two common sedimentary energy sources which are often symbiotically developed in M esozoic- Cenozoic continental fault basins. However, the mechanisms and characteristics of the symbiotic development are not yet clearly known. In this research study, the typical continental fault basins of eastern China were chosen as examples for the purpose of conducting an examination of the coal and oil shale symbiotic assemblage types, genetic environmental differences, and transformation mechanisms, as well as the development and occurrence characteristics o f different assemblage types. Through a large number of investigations, systematic experimental testing, and sequence stratigraphy studies, the following conclusions were obtained:(1) There were five types of coal and oil shale symbiotic assemblages observed in the continental fault basins,(2) The development of coal and oil shale deposits requires a warm and humid climate, stable structure, abundant organic matter supply, a certain water depth, and a lower terrestrial source debris supply. The observed differences were that the water depth conditions were diversified in the study area, as well as the sources, types, and content of the organic matter.(3) The rapid transformations of the coal and oil shale genetic environments were mainly controlled by the tectonic settings and climatic conditions, which were determined to control the changes in the water depths, salinity,redox conditions, and lake productivity of the genetic environments. Also, in the symbiotic assemblages, genetic environment changes had induced the development of oil shale deposits, which gradually evolved into coal genetic environments.(4) In the isochronous sequence stratigraphic framework of the coal and oil shale symbiotic assemblages, the lake expansion system tracts (EST) were determined to be the most beneficial to the growth o f all the types of assemblages and were characterized by more assemblage development phases and smaller bed thicknesses. From the early to the late stages of the EST, and from the lakesides to lake centers, the thicknesses of the coal seams in the symbiotic assemblages showed trends of thinning, while the thicknesses of the oil shale deposits exhibited increasing trends. The early stages of high stand system tracts were found to be beneficial to the development of the symbiotic assemblages of coal seams overlying the oil shale. This tract type generally presented large bed thicknesses and distribution ranges. The low stand system tract and the late high stand system tract were determined to be unconducive to the development of the symbiotic assemblages.展开更多
Rational determination and reduction of local energy loss of oil flow at pipe junctions are of important significance to improve hydraulic pipeline's work efficiency, especially for complex hydraulic pipeline connect...Rational determination and reduction of local energy loss of oil flow at pipe junctions are of important significance to improve hydraulic pipeline's work efficiency, especially for complex hydraulic pipeline connected by isodiametric T-type ducts with sharp comers to get combined and divided flow. From this point of view, the formulae of resistance loss for combined flow and divided flow through isodiametric T-type duct with sharp comers as well as the correlations of resistance loss coefficients in the branches of the duct are derived using energy method. On this basis, resistance characteristics of hydraulic oil in the duct are obtained by numerical simulation of different flow modes, which are commonly applied in hydraulic pipelines, using computational fluid dynamics (CFD) method, and the reasons for the resistance loss are analyzed based on the pressure change mechanism in the flow field. A part of simulation results was validated with the reference data. The research shows that for combined flows the resistance loss of symmetrical is lower than that of unsymmetrical to obtain low speed in common branch, but to gain high speed is quite the contrary, for divided flows, the symmetrical is always a reasonable choice to reduce resistance loss. These conclusions can be applied to optimize the design of hydraulic pipeline.展开更多
Subtle traps or oil pools have become an important exploration play in the Dongying Depression, Bohai Bay Basin, east China. Despite recent successes in exploration, the formation mechanisms of subtle traps are still ...Subtle traps or oil pools have become an important exploration play in the Dongying Depression, Bohai Bay Basin, east China. Despite recent successes in exploration, the formation mechanisms of subtle traps are still not well understood. The majority of subtle oil pools in the Dongying Depression are developed in the middle interval of the Es3 Member of the Paleogene Shahejie Formation with the subtle traps being primarily of lenticular basin-floor turbidite sands encompassed in mudstones. Oil in the subtle traps was previously thought to have migrated directly from the surrounding source rocks of the same formation (Es3). Detailed geochemical investigation of 41 oils and 41 rock samples from the depression now indicates that the oils from the subtle traps cannot be correlated well with the surrounding Es3 source rocks, which are characterized by high Pr/ Ph (〉1), low Gammacerane/C30hopane, representing a freshwater lacustrine setting. In contrast the oils features low Pr/Ph (〈1) and relatively high Gammacerane content, showing a genetic affinity with the underlying Es4 source rocks, which also have the same qualities, indicating a brackish lacustrine setting. Oils in the Es3 subtle traps are probably derived from mixed sources with the contribution from the upper Es4 source rocks predominating. Therefore unconventional oil migration and accumulation mechanisms need to be invoked to explain the pooling of oils from the ES4 source rocks, which probably came through a thick low interval of the Es3 source rocks with no apparent structural or stratigraphic pathways. We suggest that the subtle oil migration pathway probably plays an important role here. This finding may have significant implications for future exploration and the remaining resource evaluation in the Dongying Depression.展开更多
The double bonds in the vegetable oils can be conjungated and Diels-Alder react when they are heated in the existence of the catalyst. The percent of the double bond will decrease and the oxidative stability of the ve...The double bonds in the vegetable oils can be conjungated and Diels-Alder react when they are heated in the existence of the catalyst. The percent of the double bond will decrease and the oxidative stability of the vegetable oils can be ameliorated. Dimmer acid can react with different carbon chain length of alcohols to form dimmer acid esters. A series of dimmer acid esters were synthesized and their rheological characteristics (viscosity, viscosity index, pour point) and tribological characteristics (the coefficient of friction at different load, the characteristic of extreine pressure ( PB ), the wear scare diameter ( D30min^196N ) were evaluated and analyzed. The results showed that the characteristics of Di-iso-octanol dimmer acid ester were the best among the synthesized dimmer esters. It' s a lubricant with good properties(the viscosity is 94.5 mm^2/s, the viscosity index is high up to 141 and the pour point is - 49℃ ). It is a kind of newly interesthing ester type lubricant. Its rheological and tribological characteristics are even better than those of the slap-up synthesized lubricant--pentaerythritol esters (C7-9 acidate). The FT-IR spectrophotometer was used to analyze the structure of the synthetic esters. Their IR spectra are the same as the typical IR spectrum of ester. The test indicated that Di-iso-octanol dimmer acid ester could be used as a kind of base lubricant with excellent quantity.展开更多
Based on the comprehensive study of core samples, well testing data, and reservoir fluid properties, the construction and the distribution of the abnormal pressure systems of the Huatugou oil field in Qaidam Basin are...Based on the comprehensive study of core samples, well testing data, and reservoir fluid properties, the construction and the distribution of the abnormal pressure systems of the Huatugou oil field in Qaidam Basin are discussed. The correlation between the pressure systems and hydrocarbon accumulation is addressed by analyzing the corresponding fluid characteristics. The results show that the Huatugou oil field as a whole has low formation pressure and low fluid energy; therefore, the hydrocarbons are hard to migrate, which facilitates the forming of primary reservoirs. The study reservoirs, located at the Xiayoushashan Formation (N1/2) and the Shangganchaigou Formation (N1) are relatively shallow and have medium porosity and low permeability. They are abnormal low-pressure reservoirs with an average formation pressure coefficient of 0.61 and 0.72 respectively. According to the pressure coefficient and geothermal anomaly, the N1 and N1/2 Formations belong to two independent temperature-pressure systems, and the former has slightly higher energy. The low-pressure compartments consist of a distal bar as the main body, prodelta mud as the top boundary, and shore and shallow lake mud or algal mound as the bottom boundary. They are vertically overlapped and horizontally paralleled. The formation water is abundant in the Cl^- ion and can be categorized as CaCl2 type with high safinity, which indicates that the abnormal low-pressure compartments are in good sealing condition and beneficial for oil and gas accumulation and preservation.展开更多
Marine oil spills have caused major threats to marine environment over the past few years.The early detection of the oil spill is of great significance for the prevention and control of marine disasters.At present,rem...Marine oil spills have caused major threats to marine environment over the past few years.The early detection of the oil spill is of great significance for the prevention and control of marine disasters.At present,remote sensing is one of the major approaches for monitoring the oil spill.Full polarization synthetic aperture radarc SAR data are employed to extract polarization decomposition parameters including entropy(H) and reflection entropy(A).The characteristic spectrum of the entropy and reflection entropy combination has analyzed and the polarization characteristic spectrum of the oil spill has developed to support remote sensing of the oil spill.The findings show that the information extracted from(1-A)×(1-H) and(1-H)×A parameters is relatively evident effects.The results of extraction of the oil spill information based on H×A parameter are relatively not good.The combination of the two has something to do with H and A values.In general,when H〉0.7,A value is relatively small.Here,the extraction of the oil spill information using(1-A)×(1-H) and(1-H)×A parameters obtains evident effects.Whichever combined parameter is adopted,oil well data would cause certain false alarm to the extraction of the oil spill information.In particular the false alarm of the extracted oil spill information based on(1-A)×(1-H) is relatively high,while the false alarm based on(1-A)×H and(1-H)×A parameters is relatively small,but an image noise is relatively big.The oil spill detection employing polarization characteristic spectrum support vector machine can effectively identify the oil spill information with more accuracy than that of the detection method based on single polarization feature.展开更多
Thermo-gravimetric-analysis(TGA) was used to analyze the combustion characteristics of an oil shale and semi-cokes prepared from it.The effect of prior pyrolysis and TGA heating rate on the combustion process was stud...Thermo-gravimetric-analysis(TGA) was used to analyze the combustion characteristics of an oil shale and semi-cokes prepared from it.The effect of prior pyrolysis and TGA heating rate on the combustion process was studied.Prior pyrolysis affects the initial temperature of mass loss and the ignition temperature.The ignition temperature increases as the volatile content of the sample decreases.TG/DTG curves obtained at different heating rates show that heating rate has little effect on ignition temperature.But the peak of combustion shifts to higher temperatures as the heating rate is increased.The Coats-Redfern integration method was employed to find the combustion-reaction kinetic parameters for the burning of oil shale and oil shale semi-coke.展开更多
Conventional geochemical approaches were utilized in the quantitative prediction of the proportions of mixed-source crude oils derived from the Es3 and ES4 members of the Paleogene Shahejie Formation. The mixed-source...Conventional geochemical approaches were utilized in the quantitative prediction of the proportions of mixed-source crude oils derived from the Es3 and ES4 members of the Paleogene Shahejie Formation. The mixed-source oils are accumulated in the middle interval of the Es3 member (Es3 M) in the Niuzhuang Sag, which is one of the sags where subtle traps are primarily of lenticular basin-floor turbidite sands within mudstones mostly developed in the Dongying Depression, Bohai Bay Basin. The result showed that about 18-92% of the mixed-source oils were derived from the Es4 source rocks with an average of 55-60%). Reservoirs associated with deep faults appear to have much more Es4 genetic affinity oils. A high proportion of the Es4-derived oils discovered in the Es3 M subtle lithological traps in the Niuzhuang Sag have long migration distances. This suggests that surrounding source rocks might not necessarily control the hydrocarbon supply for subtle traps. Subtle migration pathway may play an important role in the vertical oil migration. The traditional concept of hydrocarbons accumulation in these tenticular turbidite sandstone traps within a short migration distance from the surrounding source rocks is not supported by this study. The present result is also consistent with our previous findings that immature oils in the Bamianhe Oilfield in the south slope of the Niuzhuang Sag were actually mixed-source oils mostly sourced from the Es4 in the depocenter of the Niuzhuang Sag, and the petroleum potential of the ES4 member in the Dongying Depression should therefore be re-evaluated.展开更多
It is of a vital importance to reduce the frictional losses in marine diesel engines. Advanced surface textures have provided an e ective solution to friction performance of rubbing pairs due to the rapid development ...It is of a vital importance to reduce the frictional losses in marine diesel engines. Advanced surface textures have provided an e ective solution to friction performance of rubbing pairs due to the rapid development of surface engineering techniques. However,the mechanisms through which textured patterns and texturing methods prove beneficial remains unclear. To address this issue,the tribological system of the cylinder liner?piston ring(CLPR) is investigated in this work. Two types of surface textures(Micro concave,Micro V?groove) are processed on the cylinder specimen using di erent processing methods. Comparative study on the friction coe cients,worn surface texture features and oil film characteristics are performed. The results demonstrate that the processing method of surface texture a ect the performance of the CLPR pairs under the specific testing conditions. In addition the micro V?groove processed by CNCPM is more favorable for improving the wear performances at the low load,while the micro?con?cave processed by CE is more favorable for improving the wear performances at the high load. These findings are in helping to understand the e ect of surface texture on wear performance of CLPR.展开更多
In this study, the effect of extraction processes on the physicochemical characteristics and antioxidant potential of baobab (Adansonia digitata L.) seed oil was evaluated. The oils were extracted, on the one hand, by...In this study, the effect of extraction processes on the physicochemical characteristics and antioxidant potential of baobab (Adansonia digitata L.) seed oil was evaluated. The oils were extracted, on the one hand, by cold pressing, and on the other hand, with three types of organic solvents (acetone, chloroform, n-hexane). The recorded results indicated that the extraction yield of baobab oil was significantly impacted by both the extraction method and the polarity of the solvent used. In addition, chloroform provides the best extraction yield (40.12 ± 0.607). However, extraction by cold pressure preserves at best the physicochemical and bioactive properties of the extracted oils. Indeed, the pressing oil contains a content of phenolic compounds (0.047 ± 0.0024 mgEAG/g of oil) and a very high radical scavenging activity (DPPH) (31.71% ± 0.61%). For the various oils extracted, the minimum and maximum values were 0.50 and 3.17 mEq?kg-1;56.26 and 99.113 mgI2?100 g-1;1.457 and 1.465;205.37 and 233.587 mgKOH/g respectively for the peroxide, iodine, refractive and saponification values. The color parameters (L*, a* and b*) of the oils also differ depending on the nature of the organic solvent used. Principal component analysis (PCA) and correlation analysis were performed on the physicochemical properties and the antioxidant potential of the extracted oils. Therefore, the results suggest the mixed use of acetone and hexane to obtain oil comparable to that extracted by cold pressing.展开更多
The Cenozoic continental strata of the Bohai Bay Basin are rich in shale oil resources, and they contain various types of reservoir spaces that are controlled by complex factors. Using field emission scanning electron...The Cenozoic continental strata of the Bohai Bay Basin are rich in shale oil resources, and they contain various types of reservoir spaces that are controlled by complex factors. Using field emission scanning electron microscopy(FESEM), automatic mineral identification and characterization system(AMICS), CO2 and N2 gas adsorption, and focused ion beam scanning electron microscopy(FIB-SEM), the types of shale reservoir spaces in the Bohai Bay Basin are summarized, the spatial distribution and connectivity of the various types of pores are described in detail, the microscopic pore structures are characterized, and the key geological mechanisms affecting the formation and evolution of the reservoir spaces are determined. Three conclusions can be drawn in the present study. First, the shale reservoir spaces in the Bohai Bay Basin can be divided into three broad categories, including mineral matrix pores, organic matter pores, and micro fractures. Those spaces can be subdivided into seven categories and fourteen sub-categories based on the distribution and formation mechanisms of the pores. Second, the complex pore-throat structures of the shale reservoir can be divided into two types based on the shape of the adsorption hysteresis loop. The pore structures mainly include wedge-shaped, flat slit-shaped, and ink bottle-shaped pores. The mesopores and micropores are the main contributors to pore volume and specific surface area, respectively. The macropores provide a portion of the pore volume, but they do not significantly contribute to the specific surface area. Third, the factors controlling the development of microscopic pores in the shale are complex. The sedimentary environment determines the composition and structure of the shale and provides the material basis for pore development. Diagenesis controls the types and characteristics of the pores. In addition, the thermal evolution of the organic matter is closely related to inorganic diagenesis and drives the formation and evolution of the pores.展开更多
Ni-matrix composite coating containing AI2O3 nano-particles is prepared by brush plating. The effects of the nano-particles on the microstructure, microhardness and tribological properties of the composite coating und...Ni-matrix composite coating containing AI2O3 nano-particles is prepared by brush plating. The effects of the nano-particles on the microstructure, microhardness and tribological properties of the composite coating under the lubrication of a diesel oil containing sand are investigated. The results show that the microstructure of the composite coating is finer than that of the pure nickel coating due to the codeposition of the nano-particles. When the nano-particle concentration in the electroplating bath reaches 20 g/L, the microhardness, and wear resistance of the composite coating is as much as 1.6 times and 1.3-2.5 times of those of the pure nickel coating respectively. The main hardening mechanism of the composite coating is superfine crystal grain strengthening and dispersion strengthening. The composite coating is characterized by scuffing as it slides against Si3N4 under the present test conditions.展开更多
The geochemical characteristics of crude oils from Zao\|Ⅴ oil measures in the Shenjiapu oilfield are systematically described in terms of the fractional composition of crude oils, GC characteristics of saturated hydr...The geochemical characteristics of crude oils from Zao\|Ⅴ oil measures in the Shenjiapu oilfield are systematically described in terms of the fractional composition of crude oils, GC characteristics of saturated hydrocarbon fraction of crude oils and the characteristics of their biomarkers. The depositional environment, type and evolution of the biological source are also discussed. All pieces of evidence such as low saturated hydrocarbon fraction, high resin and asphalt, high isoprenoid alkane, weak odd\|carbon number predominance (CPI ranging from \{1.23\} to \{1.29\}, OEP ranging from \{1.14\} to \{1.16\}) and low sterane and terpane maturity parameters show these crude oils are immature oils. Low Pr/Ph ratios (\{0.66\}-\{0.88\}) and high gammacerance/C\-\{31\} hopane ratios (\{0.59\}-\{0.86\}) indicate the source rocks were formed in a slightly saline to brackish reducing lake depositional environment. Gas chromatographic characteristics of the saturated hydrocarbon fraction and the predominance of C\-\{30\} hopane in terpane series and C\-\{29\} sterane in sterane series indicate the biological source of the crude oils is composed mainly of bacterial and algal organic matter, and some algae are perhaps the main contributor of organic matter to the source rocks.展开更多
Exploration potential is huge and the oil resources are rich in the Ordovician reservoirs of the Tarim Basin.However,the mechanism of hydrocarbon accumulation is complex and not yet fully understood.In the Tuoputai ar...Exploration potential is huge and the oil resources are rich in the Ordovician reservoirs of the Tarim Basin.However,the mechanism of hydrocarbon accumulation is complex and not yet fully understood.In the Tuoputai area,the hydrocarbon migration pathways and characteristics of deep hydrocarbon accumulation are revealed through analyses of the physical data of rich oil and gas,the geochemical parameters of oil,and fluid inclusions.The results show that the Ordovician oils in the Tuoputai area have the same geochemical characteristics as the mixed oil from the Lower Cambrian source rock and the Middle–Upper Ordovician source rock.The Ordovician reservoirs have been charged three times:in the late Caledonian,late Hercynian,and Himalayan stages.Oil charging occurred in the Hercynian stage,in particular,as it is the main filling period of hydrocarbon.The north-northeast(NNE)-trending TP12 CX major fault,active in in these times and is dominant migration channel of hydrocarbon,but there is segmentation affected by the difference of activities.Oil maturity is higher in the south than in the north and is abnormally high near the major fault.Parameters related to migration indicate that oil migrated northeastward along the NNE-trending TP12 CX major fault and adjusted laterally along the secondary faults and weathering crust,forming the present characteristics of oil and gas distribution.展开更多
The Chaoyanggou oil field is a fractured low-permeability reservoir, where the distribution of oil and gas is controlled by the distribution and development of fractures.Based on outcrop, drilling core, thin section a...The Chaoyanggou oil field is a fractured low-permeability reservoir, where the distribution of oil and gas is controlled by the distribution and development of fractures.Based on outcrop, drilling core, thin section and log data, the development characteristics of fractures in this area are described.On this basis, the degree of fracture development was predicted by quantitative analysis of fracture strength and numerical simulation.The result shows that four groups of structural fractures, i.e., in near NS, and EW directions and in due NW and NE directions, were developed in the reservoir, with the nearly NS and EW fractures dominant, which are the along bedding decollement fractures formed by compressive folding action, while low angle shear fractures are related to thrusts.These fractures are mainly formed in the reversed tectonic stage at the end of the Mingshui formation during the Cretaceous period.The degree of fracture development is controlled by such factors as lithology, stratum thickness, faults, folds and depth.The fractures are developed with a clear zonation and are best developed in the northern zone, moderately developed towards the south and poorly developed in the middle zone.These prediction results are in good agreement with interpretation results from logs.展开更多
基金financially supported by the CNPC Prospective Basic Science and Technology Special Project(2023ZZ08)the Science and Technology Cooperation Project of the CNPC-SWPU Innovation Alliance(2020CX050103)。
文摘Natural fractures are critical for shale oil and gas enrichment and development. Due to the extremely high heterogeneity of shale, the factors controlling the formation of internal fractures, especially horizontal fractures, remain controversial. In this study, we integrate thin section analysis and microcomputed tomography(CT) data from several lacustrine shale samples from the third member(Es3) of the Shahejie Formation, Qikou Sag, Bohai Bay Basin, to assess the fractures in detail. The goal is to reveal the development characteristics, controlling factors, and geological significance for evaluating sweet spots in a shale oil play. The fractures in the Es3contain high-angle structural and horizontal bed-parallel fractures that are mostly shear and extensional. Various factors influence fracture development,including lithofacies, mineral composition, organic matter content, and the number of laminae. Structural fractures occur predominantly in siltstone, whereas bed-parallel fractures are abundant in laminated shale and layered mudstone. A higher quartz content results in higher shale brittleness, causing fractures, whereas the transformation between clay minerals contributes to the development of bedparallel fractures. Excess pore pressure due to hydrocarbon generation and expulsion during thermal advance can cause the formation of bed-parallel fractures. The density of the bed-parallel and structural fractures increases with the lamina density, and the bed-parallel fractures are more sensitive to the number of laminae. The fractures are critical storage spaces and flow conduits and are indicative of sweet spots. The laminated shale in the Es3with a high organic matter content contains natural fractures and is an organic-rich, liquid-rich, self-sourced shale play. Conversely, the siltstone, massive mudstone, and argillaceous carbonate lithofacies contain lower amounts of organic matter and do not have bed-parallel fractures. However, good reservoirs can form in these areas when structural fractures are present and the source, and storage spaces are separated.
基金This work was financially supported by the National Natural Science Foundation of China(41972123,41922015)the Natural Science Foundation of Shandong Province(ZR2020QD036).
文摘The occurrence characteristics of shale oil are of great significance to the movability of shale oil.In this study,the occurrence characteristics of oil in the shale matrix at Funing Formation shale in Subei Basin were quantitatively evaluated by organic geochemistry and microscopic pore structure characterization experiments.The Multiple Isothermal Stages Pyrolysis(MIS)experiment results show that the content of total oil,adsorbed oil,and free oil in the shales are 3.15-11.25 mg/g,1.41-4.95 mg/g,and 1.74-6.51 mg/g,respectively.among which the silicon-rich shale has the best oil-bearing.The relative content of free oil shows an increasing trend in pores with pore diameters greater than 3 nm.When the relative content of free oil reaches 100%,the pore size of silicon-rich shale is about 200 nm,while that of calcium-rich shale,clay-rich shale,and siliceous mixed shale is about 10 nm.The occurrence law of adsorbed oil is opposite to that of free oil,which indicates that shale oil will occur in the pores and fractures in a free state in a more extensive pore size range(>200 nm).This study also enables us to further understand the occurrence characteristics of shale oil under the interaction of occurrence state and occurrence space.
文摘In the present work, the pool boiling critical heat flux, transient heat transfer characteristics, and bonding strength of thin Ni-Cr wire with aqua based reduced graphene oxide(r GO) nanofluids are experimentally studied. Results indicate:(i) the critical heat flux(CHF) of 0.01, 0.05, 0.1, 0.2, and 0.3 g·L^(-1) concentrations of r GO-water nanofluids varies from 1.42 to 2.40 MW·m^(-2);(ii) the CHF remains same for the tested samples during transient heat transfer studies and(iii) a constant value of CHF upto 10 tests when the nanocoated Ni-Cr wire is tested with DI water and deterioration occurs beyond this which implies a chance of peel off of r GO layer below the critical coating thickness.
文摘The Dongsha fault- uplifted massif (for convenience . Dongsha massif from here on) is located in the northern continental shelf-slope of the South China Sea, where the water depth is 100-400m. The massif is considered to be a part of the large-scale fault-uplifted zone directed NE and separating the Pearl River Mouth Basin into northern and southern graben areas. The sedimentary cover of the Pearl River Mouth Graben consists mainly of a 7000-10000m thick Tertiary system. A large-scale uplift occurred in the Dongsha fault-uplifted zone during Paleocene-Eocene when the lower structural layer (lower Tertiary) existed only in the small depressions of the fault-uplifted zone. The formation and evolution of the Dongsha fault-uplifted zone could be divided into: 1) the basement formation stage (J2-K1); 2) the slowly uplifted stage (K2-E22); 3) the weathering and erosion stage (E23-E31); 4) the integrated subsidence stage (E32-N12) and 5) the last uplifted stage (N13-Q). The formation of the oil and gas pools
基金supported by the Tarim Oil Field Research InstituteNational Natural Science Foundation (sanctified number:40602016)National Key Basic Research and Development Projects (Itemnumber:113404GJ0003)
文摘Based on the analysis of the hydrocarbon geochemical characteristics in the Kuqa petroleum system of the Tarim Basin, this study discusses the causes and controlling factors of the phase diversities and their differences in geochemical features. According to the characteristics and differences in oil and gas phase, the petroleum system can be divided into five categories: oil reservoir, wet gas reservoir, condensate gas-rich reservoir, condensate gas-poor reservoir and dry gas reservoir. The causes for the diversities in oil and gas phases include diversities of the sources of parent material, maturity of natural gas and the process of hydrocarbon accumulation of different hydrocarbon phases. On the whole, the Jurassic and Triassic terrestrial source rocks are the main sources for the hydrocarbon in the Kuqa Depression. The small differences in parent material may cause diversities in oil and gas amount, but the impact is small. The differences in oil and gas phase are mainly affected by maturity and the accumulation process, which closely relates with each other. Oil and gas at different thermal evolution stage can be captured in different accumulation process.
基金supported by the National Key Research and Development Plan (2017YFC0601400)SDUST Research Fund (2018TDJH101)the National Natural Science Foundation of China (41402086, 272172)
文摘Coal and oil shale are two common sedimentary energy sources which are often symbiotically developed in M esozoic- Cenozoic continental fault basins. However, the mechanisms and characteristics of the symbiotic development are not yet clearly known. In this research study, the typical continental fault basins of eastern China were chosen as examples for the purpose of conducting an examination of the coal and oil shale symbiotic assemblage types, genetic environmental differences, and transformation mechanisms, as well as the development and occurrence characteristics o f different assemblage types. Through a large number of investigations, systematic experimental testing, and sequence stratigraphy studies, the following conclusions were obtained:(1) There were five types of coal and oil shale symbiotic assemblages observed in the continental fault basins,(2) The development of coal and oil shale deposits requires a warm and humid climate, stable structure, abundant organic matter supply, a certain water depth, and a lower terrestrial source debris supply. The observed differences were that the water depth conditions were diversified in the study area, as well as the sources, types, and content of the organic matter.(3) The rapid transformations of the coal and oil shale genetic environments were mainly controlled by the tectonic settings and climatic conditions, which were determined to control the changes in the water depths, salinity,redox conditions, and lake productivity of the genetic environments. Also, in the symbiotic assemblages, genetic environment changes had induced the development of oil shale deposits, which gradually evolved into coal genetic environments.(4) In the isochronous sequence stratigraphic framework of the coal and oil shale symbiotic assemblages, the lake expansion system tracts (EST) were determined to be the most beneficial to the growth o f all the types of assemblages and were characterized by more assemblage development phases and smaller bed thicknesses. From the early to the late stages of the EST, and from the lakesides to lake centers, the thicknesses of the coal seams in the symbiotic assemblages showed trends of thinning, while the thicknesses of the oil shale deposits exhibited increasing trends. The early stages of high stand system tracts were found to be beneficial to the development of the symbiotic assemblages of coal seams overlying the oil shale. This tract type generally presented large bed thicknesses and distribution ranges. The low stand system tract and the late high stand system tract were determined to be unconducive to the development of the symbiotic assemblages.
基金supported by Hebei Provincial Natural Science Foundation of China (Grant No. 503292)
文摘Rational determination and reduction of local energy loss of oil flow at pipe junctions are of important significance to improve hydraulic pipeline's work efficiency, especially for complex hydraulic pipeline connected by isodiametric T-type ducts with sharp comers to get combined and divided flow. From this point of view, the formulae of resistance loss for combined flow and divided flow through isodiametric T-type duct with sharp comers as well as the correlations of resistance loss coefficients in the branches of the duct are derived using energy method. On this basis, resistance characteristics of hydraulic oil in the duct are obtained by numerical simulation of different flow modes, which are commonly applied in hydraulic pipelines, using computational fluid dynamics (CFD) method, and the reasons for the resistance loss are analyzed based on the pressure change mechanism in the flow field. A part of simulation results was validated with the reference data. The research shows that for combined flows the resistance loss of symmetrical is lower than that of unsymmetrical to obtain low speed in common branch, but to gain high speed is quite the contrary, for divided flows, the symmetrical is always a reasonable choice to reduce resistance loss. These conclusions can be applied to optimize the design of hydraulic pipeline.
基金provided by National Natural Science Foundation of China(Grant No.#40772077/D0206)an opening project of the Key Laboratory for Hydrocarbon Accumulation,Ministry of Education(China University of Petroleum)(2001-2).
文摘Subtle traps or oil pools have become an important exploration play in the Dongying Depression, Bohai Bay Basin, east China. Despite recent successes in exploration, the formation mechanisms of subtle traps are still not well understood. The majority of subtle oil pools in the Dongying Depression are developed in the middle interval of the Es3 Member of the Paleogene Shahejie Formation with the subtle traps being primarily of lenticular basin-floor turbidite sands encompassed in mudstones. Oil in the subtle traps was previously thought to have migrated directly from the surrounding source rocks of the same formation (Es3). Detailed geochemical investigation of 41 oils and 41 rock samples from the depression now indicates that the oils from the subtle traps cannot be correlated well with the surrounding Es3 source rocks, which are characterized by high Pr/ Ph (〉1), low Gammacerane/C30hopane, representing a freshwater lacustrine setting. In contrast the oils features low Pr/Ph (〈1) and relatively high Gammacerane content, showing a genetic affinity with the underlying Es4 source rocks, which also have the same qualities, indicating a brackish lacustrine setting. Oils in the Es3 subtle traps are probably derived from mixed sources with the contribution from the upper Es4 source rocks predominating. Therefore unconventional oil migration and accumulation mechanisms need to be invoked to explain the pooling of oils from the ES4 source rocks, which probably came through a thick low interval of the Es3 source rocks with no apparent structural or stratigraphic pathways. We suggest that the subtle oil migration pathway probably plays an important role here. This finding may have significant implications for future exploration and the remaining resource evaluation in the Dongying Depression.
文摘The double bonds in the vegetable oils can be conjungated and Diels-Alder react when they are heated in the existence of the catalyst. The percent of the double bond will decrease and the oxidative stability of the vegetable oils can be ameliorated. Dimmer acid can react with different carbon chain length of alcohols to form dimmer acid esters. A series of dimmer acid esters were synthesized and their rheological characteristics (viscosity, viscosity index, pour point) and tribological characteristics (the coefficient of friction at different load, the characteristic of extreine pressure ( PB ), the wear scare diameter ( D30min^196N ) were evaluated and analyzed. The results showed that the characteristics of Di-iso-octanol dimmer acid ester were the best among the synthesized dimmer esters. It' s a lubricant with good properties(the viscosity is 94.5 mm^2/s, the viscosity index is high up to 141 and the pour point is - 49℃ ). It is a kind of newly interesthing ester type lubricant. Its rheological and tribological characteristics are even better than those of the slap-up synthesized lubricant--pentaerythritol esters (C7-9 acidate). The FT-IR spectrophotometer was used to analyze the structure of the synthetic esters. Their IR spectra are the same as the typical IR spectrum of ester. The test indicated that Di-iso-octanol dimmer acid ester could be used as a kind of base lubricant with excellent quantity.
基金fmancially supported by the National Natural Science Foundation of China(No.40802027)the PetroChina Innovation Fund(No.0706d01040102)
文摘Based on the comprehensive study of core samples, well testing data, and reservoir fluid properties, the construction and the distribution of the abnormal pressure systems of the Huatugou oil field in Qaidam Basin are discussed. The correlation between the pressure systems and hydrocarbon accumulation is addressed by analyzing the corresponding fluid characteristics. The results show that the Huatugou oil field as a whole has low formation pressure and low fluid energy; therefore, the hydrocarbons are hard to migrate, which facilitates the forming of primary reservoirs. The study reservoirs, located at the Xiayoushashan Formation (N1/2) and the Shangganchaigou Formation (N1) are relatively shallow and have medium porosity and low permeability. They are abnormal low-pressure reservoirs with an average formation pressure coefficient of 0.61 and 0.72 respectively. According to the pressure coefficient and geothermal anomaly, the N1 and N1/2 Formations belong to two independent temperature-pressure systems, and the former has slightly higher energy. The low-pressure compartments consist of a distal bar as the main body, prodelta mud as the top boundary, and shore and shallow lake mud or algal mound as the bottom boundary. They are vertically overlapped and horizontally paralleled. The formation water is abundant in the Cl^- ion and can be categorized as CaCl2 type with high safinity, which indicates that the abnormal low-pressure compartments are in good sealing condition and beneficial for oil and gas accumulation and preservation.
基金The National Natural Science Foundation of China under contract No.41376183the Oceanography Public Welfare Scientific Research Project "Marine oil spill risk assessment and key technologies of emergency response integration and demonstration" under contract No.201205012
文摘Marine oil spills have caused major threats to marine environment over the past few years.The early detection of the oil spill is of great significance for the prevention and control of marine disasters.At present,remote sensing is one of the major approaches for monitoring the oil spill.Full polarization synthetic aperture radarc SAR data are employed to extract polarization decomposition parameters including entropy(H) and reflection entropy(A).The characteristic spectrum of the entropy and reflection entropy combination has analyzed and the polarization characteristic spectrum of the oil spill has developed to support remote sensing of the oil spill.The findings show that the information extracted from(1-A)×(1-H) and(1-H)×A parameters is relatively evident effects.The results of extraction of the oil spill information based on H×A parameter are relatively not good.The combination of the two has something to do with H and A values.In general,when H〉0.7,A value is relatively small.Here,the extraction of the oil spill information using(1-A)×(1-H) and(1-H)×A parameters obtains evident effects.Whichever combined parameter is adopted,oil well data would cause certain false alarm to the extraction of the oil spill information.In particular the false alarm of the extracted oil spill information based on(1-A)×(1-H) is relatively high,while the false alarm based on(1-A)×H and(1-H)×A parameters is relatively small,but an image noise is relatively big.The oil spill detection employing polarization characteristic spectrum support vector machine can effectively identify the oil spill information with more accuracy than that of the detection method based on single polarization feature.
基金Project CPEUKF08-04 support by the Key Laboratory of Coal Processing and Efficient Utilization, Ministry of Education of China
文摘Thermo-gravimetric-analysis(TGA) was used to analyze the combustion characteristics of an oil shale and semi-cokes prepared from it.The effect of prior pyrolysis and TGA heating rate on the combustion process was studied.Prior pyrolysis affects the initial temperature of mass loss and the ignition temperature.The ignition temperature increases as the volatile content of the sample decreases.TG/DTG curves obtained at different heating rates show that heating rate has little effect on ignition temperature.But the peak of combustion shifts to higher temperatures as the heating rate is increased.The Coats-Redfern integration method was employed to find the combustion-reaction kinetic parameters for the burning of oil shale and oil shale semi-coke.
基金the National Natural Science Foundation of China (Grant No.#40772077/D0206)a complimentary research project from the Key Laboratory for Hydrocarbon Accumulation Mechanism of the Ministry of Education (China University of Petroleum) (2001-2).
文摘Conventional geochemical approaches were utilized in the quantitative prediction of the proportions of mixed-source crude oils derived from the Es3 and ES4 members of the Paleogene Shahejie Formation. The mixed-source oils are accumulated in the middle interval of the Es3 member (Es3 M) in the Niuzhuang Sag, which is one of the sags where subtle traps are primarily of lenticular basin-floor turbidite sands within mudstones mostly developed in the Dongying Depression, Bohai Bay Basin. The result showed that about 18-92% of the mixed-source oils were derived from the Es4 source rocks with an average of 55-60%). Reservoirs associated with deep faults appear to have much more Es4 genetic affinity oils. A high proportion of the Es4-derived oils discovered in the Es3 M subtle lithological traps in the Niuzhuang Sag have long migration distances. This suggests that surrounding source rocks might not necessarily control the hydrocarbon supply for subtle traps. Subtle migration pathway may play an important role in the vertical oil migration. The traditional concept of hydrocarbons accumulation in these tenticular turbidite sandstone traps within a short migration distance from the surrounding source rocks is not supported by this study. The present result is also consistent with our previous findings that immature oils in the Bamianhe Oilfield in the south slope of the Niuzhuang Sag were actually mixed-source oils mostly sourced from the Es4 in the depocenter of the Niuzhuang Sag, and the petroleum potential of the ES4 member in the Dongying Depression should therefore be re-evaluated.
基金Supported by National Natural Science Foundation of China(Grant No.51422507)Hubei Provincial Natural Science Foundation of China(Grant No.2015CFB372)+1 种基金Fundamental Research Funds for the Central Universities of China(Grant No.2015IVA010)Tribology Science Fund of State Key Laboratory of Tribology of China(Grant No.SKLTKF14B03)
文摘It is of a vital importance to reduce the frictional losses in marine diesel engines. Advanced surface textures have provided an e ective solution to friction performance of rubbing pairs due to the rapid development of surface engineering techniques. However,the mechanisms through which textured patterns and texturing methods prove beneficial remains unclear. To address this issue,the tribological system of the cylinder liner?piston ring(CLPR) is investigated in this work. Two types of surface textures(Micro concave,Micro V?groove) are processed on the cylinder specimen using di erent processing methods. Comparative study on the friction coe cients,worn surface texture features and oil film characteristics are performed. The results demonstrate that the processing method of surface texture a ect the performance of the CLPR pairs under the specific testing conditions. In addition the micro V?groove processed by CNCPM is more favorable for improving the wear performances at the low load,while the micro?con?cave processed by CE is more favorable for improving the wear performances at the high load. These findings are in helping to understand the e ect of surface texture on wear performance of CLPR.
文摘In this study, the effect of extraction processes on the physicochemical characteristics and antioxidant potential of baobab (Adansonia digitata L.) seed oil was evaluated. The oils were extracted, on the one hand, by cold pressing, and on the other hand, with three types of organic solvents (acetone, chloroform, n-hexane). The recorded results indicated that the extraction yield of baobab oil was significantly impacted by both the extraction method and the polarity of the solvent used. In addition, chloroform provides the best extraction yield (40.12 ± 0.607). However, extraction by cold pressure preserves at best the physicochemical and bioactive properties of the extracted oils. Indeed, the pressing oil contains a content of phenolic compounds (0.047 ± 0.0024 mgEAG/g of oil) and a very high radical scavenging activity (DPPH) (31.71% ± 0.61%). For the various oils extracted, the minimum and maximum values were 0.50 and 3.17 mEq?kg-1;56.26 and 99.113 mgI2?100 g-1;1.457 and 1.465;205.37 and 233.587 mgKOH/g respectively for the peroxide, iodine, refractive and saponification values. The color parameters (L*, a* and b*) of the oils also differ depending on the nature of the organic solvent used. Principal component analysis (PCA) and correlation analysis were performed on the physicochemical properties and the antioxidant potential of the extracted oils. Therefore, the results suggest the mixed use of acetone and hexane to obtain oil comparable to that extracted by cold pressing.
基金the National Natural Science Foundation of China(Grant No.41572087)。
文摘The Cenozoic continental strata of the Bohai Bay Basin are rich in shale oil resources, and they contain various types of reservoir spaces that are controlled by complex factors. Using field emission scanning electron microscopy(FESEM), automatic mineral identification and characterization system(AMICS), CO2 and N2 gas adsorption, and focused ion beam scanning electron microscopy(FIB-SEM), the types of shale reservoir spaces in the Bohai Bay Basin are summarized, the spatial distribution and connectivity of the various types of pores are described in detail, the microscopic pore structures are characterized, and the key geological mechanisms affecting the formation and evolution of the reservoir spaces are determined. Three conclusions can be drawn in the present study. First, the shale reservoir spaces in the Bohai Bay Basin can be divided into three broad categories, including mineral matrix pores, organic matter pores, and micro fractures. Those spaces can be subdivided into seven categories and fourteen sub-categories based on the distribution and formation mechanisms of the pores. Second, the complex pore-throat structures of the shale reservoir can be divided into two types based on the shape of the adsorption hysteresis loop. The pore structures mainly include wedge-shaped, flat slit-shaped, and ink bottle-shaped pores. The mesopores and micropores are the main contributors to pore volume and specific surface area, respectively. The macropores provide a portion of the pore volume, but they do not significantly contribute to the specific surface area. Third, the factors controlling the development of microscopic pores in the shale are complex. The sedimentary environment determines the composition and structure of the shale and provides the material basis for pore development. Diagenesis controls the types and characteristics of the pores. In addition, the thermal evolution of the organic matter is closely related to inorganic diagenesis and drives the formation and evolution of the pores.
基金This research was financially supported by the Major Project of National Natural Science Foundation of China(No.50235030)the National 973 Planning Project(No.G1999065009)+1 种基金the Science and Technology Cooperation Project between China and Poland Governments in 2002(No.2002M3)their supports are gratefully acknowledged.
文摘Ni-matrix composite coating containing AI2O3 nano-particles is prepared by brush plating. The effects of the nano-particles on the microstructure, microhardness and tribological properties of the composite coating under the lubrication of a diesel oil containing sand are investigated. The results show that the microstructure of the composite coating is finer than that of the pure nickel coating due to the codeposition of the nano-particles. When the nano-particle concentration in the electroplating bath reaches 20 g/L, the microhardness, and wear resistance of the composite coating is as much as 1.6 times and 1.3-2.5 times of those of the pure nickel coating respectively. The main hardening mechanism of the composite coating is superfine crystal grain strengthening and dispersion strengthening. The composite coating is characterized by scuffing as it slides against Si3N4 under the present test conditions.
文摘The geochemical characteristics of crude oils from Zao\|Ⅴ oil measures in the Shenjiapu oilfield are systematically described in terms of the fractional composition of crude oils, GC characteristics of saturated hydrocarbon fraction of crude oils and the characteristics of their biomarkers. The depositional environment, type and evolution of the biological source are also discussed. All pieces of evidence such as low saturated hydrocarbon fraction, high resin and asphalt, high isoprenoid alkane, weak odd\|carbon number predominance (CPI ranging from \{1.23\} to \{1.29\}, OEP ranging from \{1.14\} to \{1.16\}) and low sterane and terpane maturity parameters show these crude oils are immature oils. Low Pr/Ph ratios (\{0.66\}-\{0.88\}) and high gammacerance/C\-\{31\} hopane ratios (\{0.59\}-\{0.86\}) indicate the source rocks were formed in a slightly saline to brackish reducing lake depositional environment. Gas chromatographic characteristics of the saturated hydrocarbon fraction and the predominance of C\-\{30\} hopane in terpane series and C\-\{29\} sterane in sterane series indicate the biological source of the crude oils is composed mainly of bacterial and algal organic matter, and some algae are perhaps the main contributor of organic matter to the source rocks.
基金funding by the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDA14010305)the National Key Research and Development Program of China(Grant No.2019YFC0605502)+1 种基金the National Natural Science Foundation(Grant No.41821002)Fundamental Research Funds for the Central Universities(Grant No.18CX05019A)。
文摘Exploration potential is huge and the oil resources are rich in the Ordovician reservoirs of the Tarim Basin.However,the mechanism of hydrocarbon accumulation is complex and not yet fully understood.In the Tuoputai area,the hydrocarbon migration pathways and characteristics of deep hydrocarbon accumulation are revealed through analyses of the physical data of rich oil and gas,the geochemical parameters of oil,and fluid inclusions.The results show that the Ordovician oils in the Tuoputai area have the same geochemical characteristics as the mixed oil from the Lower Cambrian source rock and the Middle–Upper Ordovician source rock.The Ordovician reservoirs have been charged three times:in the late Caledonian,late Hercynian,and Himalayan stages.Oil charging occurred in the Hercynian stage,in particular,as it is the main filling period of hydrocarbon.The north-northeast(NNE)-trending TP12 CX major fault,active in in these times and is dominant migration channel of hydrocarbon,but there is segmentation affected by the difference of activities.Oil maturity is higher in the south than in the north and is abnormally high near the major fault.Parameters related to migration indicate that oil migrated northeastward along the NNE-trending TP12 CX major fault and adjusted laterally along the secondary faults and weathering crust,forming the present characteristics of oil and gas distribution.
基金Project 40772086 supported by the National Natural Science Foundation of China
文摘The Chaoyanggou oil field is a fractured low-permeability reservoir, where the distribution of oil and gas is controlled by the distribution and development of fractures.Based on outcrop, drilling core, thin section and log data, the development characteristics of fractures in this area are described.On this basis, the degree of fracture development was predicted by quantitative analysis of fracture strength and numerical simulation.The result shows that four groups of structural fractures, i.e., in near NS, and EW directions and in due NW and NE directions, were developed in the reservoir, with the nearly NS and EW fractures dominant, which are the along bedding decollement fractures formed by compressive folding action, while low angle shear fractures are related to thrusts.These fractures are mainly formed in the reversed tectonic stage at the end of the Mingshui formation during the Cretaceous period.The degree of fracture development is controlled by such factors as lithology, stratum thickness, faults, folds and depth.The fractures are developed with a clear zonation and are best developed in the northern zone, moderately developed towards the south and poorly developed in the middle zone.These prediction results are in good agreement with interpretation results from logs.