Water-Rock Interaction in Tarim Basin: Constraints from Oilfield Water Geochemistry

Oilfield waters from Cenozoic and Mesozoic terrestrial and Paleozoic marine environments in the Tarim Basin show no obvious difference in water chemistry except Br and isotopic compositions. The Paleozoic marine strata have higher Br concentrations than the terrestrial sediments, and the lack of obvious relationship between Br and Ⅰ suggests that Br is not, for the most part, derived from the degradation of organic matter. The oilfield waters are characterized by high TDS (total dissolved solids), ranging from 120000mg/L to 320000mg/L,relatively low Mg, high Ca, Sr, and CF relative to Br of evaporating seawater, suggestive of enhanced water-rock interaction. (Al (organic acid anions) concentrations are generally lower than 1500 mg/L with high values occurring over the temperature range from 95℃ to 140℃ ,in the Cambrian to Jurassic systems, and nearby unconformities. Organic acids are considered to be generated mainly from thermal maturation of kerogens during progressive burial of the Jurassic-Triassic and Cambrian-Ordovician systems, biodegradation of crude oils nearby unconformities, and thermochemical sulfate reduction in part of the Cambrian and Ordovician strata.High Al concentrations up to 3 mg/L to 5. 5 mg/L tend to occur in the waters of high OAA or petroleum- bearing intervals, suggesting the presence of organic complexing agents. Calculation by SOLMINEQ. 88 with updated database shows that AlAc2+ may account for more than 30%of the total Al. IsotoPic measurements (δD, δ18O) provide evidence for the following types of waters: diagenetically- modified connate meteoric water from the Jurassic and Triassic strata;diagenetically-modified connate marine water from the Cambrian and Ordovician strata; subaerially-evaporated water from the Cenozoic and Cretaceous strata; and mixed meteoric-evaporated or/and diagenetically modified connate water from the Carboniferous strata and reservoirs adjacent to the J/C and T/C unconformities. Those waters with very negativeδD values from -51. 30‰. to - 53. 80‰ (SMOW) and positive δ18 O values from 2. 99‰ to 4. 99‰(SMOW) in the continuous burial of the Cambrian-Ordovician system are explained to have resulted from hydrocarbon-water and water-rock interactions.

A PRELIMINARY EVALUATION MODEL FOR RESERVOIR HYDROCARBON-GENERATING POTENTIAL ESTABLISHED BASED ON DISSOLVED HYDROCARBONS IN OILFIELD WATER

A large number of oilfield water samples were analyzed in this work. Research on the relationship between the concentrations and distribution of dissolved hydrocarbons suggested that the contents and composition of dissolved hydrocarbons varied with the hydrocarbon-generating potential of reservoirs. The concentrations of dissolved hydrocarbons were low in dry layers, water layers and gas-water layers, but high in gas reservoirs and oil reservoirs, especially in gas reservoirs with condensed oil. Series of carbon-number alkanes were usually absent in oilfield water from dry layers, water layers and gas-water layers but abundant in oilfield water from oil-water reservoirs, gas reservoirs and oil reservoirs, whose carbon numbers varied most widely in oil reservoirs and least in gas reservoirs. A preliminary evaluation model for reservoir hydrocarbon-generating potential was established based on the characteristics of dissolved hydrocarbons in oilfield water to assist hydrocarbon exploration.

Geochemical Characteristics of Oilfield Waters fromthe Turpan Depression, Xinjiang and Their Petroleum Geological Significance

This paper, based on the fundamental inorganic chemical and organic geochemical characteristics of oilfield waters from the Turpan Depression, presents the contents of organic matter, the distribution of low-carbon fatty acids and the contents of aromatic hydrocarbons as well as their principal ultraviolet absorption spectral and fluorescence spectral characteristics in oilfield waters from different oil/gas-bearing areas. The oil/gas reservoirs in this depression are classified in terms of their conserving conditions. In addition, the paper also discusses the chemical characteristics of oilfield waters from different types of oil/gas reservoirs with an emphasis on the characteristics of their localization in the γ_Na/γCa-γNa/γ_Cl correction diagram. On this basis it is attempted to expound the fundamental geochemical characteristics of oilfield waters from the Turpan Depression and their geological significance.

Influences of water treatment agents on oil-water interfacial properties of oilfield produced water

The emulsion stability of oilfield produced water is related to the oil-water interfacial film strength and the zeta potential of the oil droplets. We investigated the effects of water treatment agents （corrosion inhibitor SL-2, scale inhibitor HEDP, germicide 1227, and flocculant polyaluminium chloride PAC） on the stability of oilfield produced water. The influence of these treatment agents on oil-water interfacial properties and the mechanism of these agents acting on the oilfield produced water were studied by measuring the interfacial shear viscosity, interfacial tension and zeta electric potential. The results indicated that the scale inhibitor HEDP could increase the oil-water interfacial film strength, and it could also increase the absolute value of the zeta potential of oil droplets. HEDP played an important role in the stability of the emulsion. Polyaluminum chloride （PAC） reduced the stability of the emulsion by considerably decreasing the absolute value of the zeta potential of oil droplets. Corrosion inhibitor SL-2 and germicide 1227 could decrease the oil-water interfacial tension, whereas they had little influence on oil-water interfacial shear viscosity and oil-water interfacial electricity properties.

Corrosion Behavior of Pipeline Steel in Oilfield Produced Water under Dynamic Corrosion System

In order to predict the corrosion trendency of X100 pipeline steel in flowing oilfield produced water,the effect of flow rate on the corrosion behavior of X100 pipeline steel was studied under general dynamic condition and simulated real working condition at the flow rate of 0.2,0.4,and 0.6 m·s^(-1).Potentiodynamic polarization curves and electrochemical impedance spectroscopy were used to study the corrosion behavior of X100 steel.Energy dispersive spectroscopy,X-ray diffraction and scanning electron microscopy were used to analyze corrosion product composition and micromorphology.The experimental results show that the corrosion is more serious under simulated real working conditions than that under the general dynamic conditions.In any case the corrosion current density increases with the increase of the flow rate,and the total impedance value decreases.The corrosion products include Fe_(3)O_(4),Fe_(2)O_(3),and FeOOH.The mass transfer and electrochemistry were simulated by flow coupled in COMSOL software.The multiphysical field coupling simulation results are closer to the engineering practice than the single flow field simulation,and similar results from the experiments were obtained.Both experimental and simulation results reveal that the higher flow rate is,the more serious corrosion appear and the more corrosion products accumulate.By combining experimental and COMSOL simulation data,the corrosion process model of X100 steel was proposed.

Simultaneous Detection of Phenols and Anilines in Oilfield Waste Water

ＳｉｍｕｌｔａｎｅｏｕｓＤｅｔｅｃｔｉｏｎｏｆＰｈｅｎｏｌｓａｎｄＡｎｉｌｉｎｅｓｉｎＯｉｌｆｉｅｌｄＷａｓｔｅＷａｔｅｒＹｕａｎＣｕｎｇｕａｎｇａｎｄＦｅｎｇＣｈｅｎｇｗｕ（ＣｈｅｍｉｃａｌＥｎｇｉｎｅｅｒｉｎｇＤｅｐａｒｔｍｅｎｔ，Ｕｎｉｖｅｒｓ...

Hydrogeochemical Simulation of Water-Rock Interaction Under Water Flood Recovery in Renqiu Oilfield, Hebei Province, China

Hydrogeochemical simulation is an effective method to study water-rock interaction. In this paper, PHREEQM was used for the simulation of water-rock interaction under water flooding in the Renqiu Oilfield. Calculated results revealed that when fresh water was injected into the reservoir, Cl\+- and Na\++ would decrease without involvement in water-rock interaction. Erosion to dolomite will lead to an increase in Ca\+\{2+\}, Mg\+\{2+\} and CaHCO\++\-3. Saturation index of calcite and aragonite decreased first and then increased. With fresh water accounting for up to 70%, mixed water has the strongest erosion ability. Deoiled water has erosion ability under high temperature and high partial pressure of CO\-2. Pyrite and gypsum were sensitive to deoiled water, which can cause the dissolution of pyrite and the precipitation of gypsum. Micrographs revealed a great deal of information about water-rock interaction.

The Status and Prospects of Enhancing Oil Recovery Technology for Waterflooding Oilfields in China

Oilfield,Recovery factor,Water Flooding,Evaluation,Prediction

Characteristics of Water Flooding in Thick Reservoirs of Shuanghe Oilfield and Adjustment in the Late Development Period with High Water Cut

The Heterogeneity of the Thick Glutenite Reservoirs and the Direction for Exploit-ing Potential at a Period of Very High Wa-ter Cut

油田采出水处理技术的研究进展

在油田开采中,采出水的直接排放会对环境造成影响,通常需要经过深度处理后再排放或者回用。而油田采出水含油量高且含有高浓度有机物和悬浮物,处理难度大。水质特性、处理技术以及处理设备等都会对处理效果产生直接影响,因此,有必要对上述问题进行深入研究。本文对现有研究中油田采出水的水质特性、新型的膜分离技术以及气浮工艺进行了总结,分析了各类处理技术研究现状,并对今后发展趋势进行了展望。

高含水老油田化学驱综合治理新方法及工程实践路径

针对胜利高含水老油田化学驱在科学、技术、管理、工程四个角度面临的开发矛盾,以渤76块为典型单元,在工程实践中进行具体对策分析,构建了“适、专、快、集”的老油田化学驱综合治理新方法。“适”指在老油田科学开发方式转化上,构建不同油藏类型老油田化学驱最佳介入时机模型,提出了在含水率相对较低的阶段,是适合化学驱的有利时机,高效开发方式需“适”介入。“专”指在老油田开发技术应用上,改变传统聚合物先溶解后注入的开发思路,研制可控相转化聚合物,使聚合物先注入后溶解,解决炮眼剪切降解的难题,提高油水流度控制能力,老油田开发矛盾需“专”治理。“快”指在老油田综合管理模式上,改变传统方式,即矿场提问题、研究院设计方案、化工厂生产驱油剂的“串联”管理模式,提出充分发挥矿场、研究院、生产厂三方优势的“并联”管理模式,形成针对单一油藏的产品工业化工艺包以及产业化落地方案,老油田开发技术实现“快”转化。“集”指在老油田工程应用实践上,打破老油田化学驱地面大规模建站的工程工艺模式,采用集约化撬装配注设备,实现老油田化学驱的集约快速配注,老油田工程工艺实现“集”应用。运用上述方法,在胜利油田渤76块综合含水率上升初期,实施由水驱转为可控相转化聚合物驱,实施后一年即见到明显的降水增油效果,单井日产油水平增加8.6t/d,综合含水率降低3.1%,验证了综合治理模式的可行性,为高含水老油田化学驱高效开发提供了有效路径。

基于PLC的油田注水全自动监控模型构建

油田注水全自动监控能够减少能耗,为实现油田注水全自动监控,构建一种基于PLC的油田注水全自动监控模型。首先设定监测目标,将注水量、供水量、注水井压力和注水井总流量作为约束条件,并建立基于油压、套压、注水水质、注水量、注水温度等预警指标,采用PID与PLC结合的方法实现油田注水全自动监控。实验结果表明,所提油田注水全自动监控模型在注水量监控、缓存罐液位监测、回水管路液体压力、油压监测等方面具有较高的准确性,能够满足方法设计需求,具有一定应用价值。

Method of moderate water injection and its application in ultra-low permeability oil reservoirs of Yanchang Oilfield, NW China

To explore the method of improving development effect and solving the problem of water breakthrough and water out for ultralow permeability fractured reservoirs, an indoor evaluation method of dynamic imbibition for fracture-matrix system was established taking the Chang 8 reservoir in southern Yanchang Oilfield as a research target. Key factors for the imbibition effect were obtained, an imbibition's rate expression was obtained, a model considering the double effects of imbibition-displacement was built and optimal injection and production parameters for the research area were obtained as well. The results show that an optimum displacement rate that maximizes the oil displacement efficiency exists in the water displacing oil process, and the optimal displacing rate becomes smaller as the permeability decreases. The imbibition displacement efficiency increases as the reservoir quality index and water wettability index of rock become bigger. But the larger the initial water saturation or oil-water viscosity ratio is, the smaller the imbibition displacement efficiency is. The optimal injection-production ratio for the Chang 8 reservoir of southern Yanchang Oilfield is 0.95, and the predicted recovery is 17.2% when the water cut is 95%, it is 2.9% higher than the recovery of conventional injection-production ratio 1.2. By using the moderate water injection technique based on the double effects of imbibition-displacement mechanism, the water injection development effect for the ultra-low permeability fractured reservoirs can be improved significantly.

Sandbody architecture of the bar finger within shoal water delta front:Insights from the Lower Member of Minghuazhen Formation,Neogene,Bohai BZ25 Oilfield,Bohai Bay Basin,East China

Core, well logging and seismic data were used to investigate sandbody architectural characteristics within Lower Member of Minghuazhen Formation in Neogene, Bohai BZ25 Oilfield, and to analyze the sedimentary microfacies, distribution and internal architecture characteristics of the bar finger within shoal water delta front. The branched sand body within shoal water delta front is the bar finger, consisting of the mouth bar, distributary channel over bar, and levee. The distributary channel cuts through the mouth bar, and the thin levee covers the mouth bar which is located at both sides of distributary channel. The bar finger is commonly sinuous and its sinuosity increases basinward. The distributary channel changes from deeply incising the mouth bar to shallowly incising top of the mouth bar.The aspect ratio ranges from 25 to 50 and there is a double logarithmic linear positive relationship between the width and thickness for the bar finger, which is controlled by base-level changing in study area. For the bar finger, injection and production in the same distributary channel should be avoided during water flooding development. In addition, middle–upper distributary channel and undrilled mouth bar are focus of tapping remaining oil.

同位素注入剖面测井解释智能化批量处理技术的实现与应用

同位素注入剖面测井是水驱油田了解各小层吸水状况的主要监测手段,该测井方法在中国油田的年测井工作量在3万井次左右,在注水油藏动态监测中占主导地位。传统的同位素注水剖面测井结果依赖人工解释,工作效率低、工作量大且多解性强,容易受到不同分析员人为因素影响,已经无法满足日益增长的生产需求。运用大数据监测和机器学习等技术,解决了基础数据录入、原始数据解编、深度匹配、工具识别、曲线叠合、综合评价等关键环节技术难题,形成了智能化批量处理技术。通过在CIFLog测井解释平台上的集成运行,单井处理时间从30~60min缩短到30s,人工干预率低于12%,验证了该处理流程及算法的有效性。

塔里木盆地塔河油田逆冲背斜区奥陶系古暗河系统发育特征

塔里木盆地塔河油田古暗河系统研究尚处于初始阶段,主要从暗河的深浅分布、结构样式等特征开展暗河洞穴的划分,较少从构造、断裂、古地貌、地下水位等地质方面综合分析复杂暗河系统的空间发育规律,致使暗河的主次从属关系、空间叠置样式、原始连通关系难以厘清,从而制约了塔河油田开发后期的综合治理研究。为了明确塔河油田主体区逆冲背斜区奥陶系古暗河系统发育特征,利用构造断裂解析、古地貌恢复、地震属性刻画、纵断剖面解读等方法进行了S67井区古暗河的类型识别、系统划分和地质成因研究,尤其首次识别并剖析了潜流回流暗河。结果表明,S67井区处于塔河主体区岩溶台原南缘的低地势区,发育幅差较小的峰丛洼地、溶丘洼地,地表水系下切深度较浅;逆冲背斜为低角度逆冲推覆构造样式,逆冲背斜之上的网格状断裂为多层状暗河系统提供有利溶蚀通道。研究区奥陶系发育相对独立的、树枝状结构的地下水位暗河系统和潜流带暗河系统,地下水位型暗河可分为主干型、支流型和废弃型,潜流回流暗河可分为上升型、对称型。控制逆冲背斜区古暗河发育的主要因素有古地貌、地下水位、逆冲背斜构造和次级断裂网络等。

酮醛胺缩合物缓蚀剂/水性聚氨酯复合膜的性能研究

针对油田注水用Q235钢管的腐蚀问题,用酮醛胺缩合物缓蚀剂改性水性聚氨酯(WPU)乳液,使其复合膜(涂层)对侵蚀离子具有缓蚀和阻隔双重作用,采用红外光谱仪、热重分析仪、电化学工作站等手段进行了有关分析表征。结果表明:缓蚀剂的加入与水性聚氨酯之间形成大量的氢键和分子间作用力;大量苯环的存在能够提高复合膜的热稳定性;与纯的WPU膜相比,WPU-3和WPU-5复合膜的硬度能够达到2H;当缓蚀剂的添加量为3%时,接触角由原来未改性的59.69°增加到74.74°,疏水性提高,膜层阻抗达到最大值,此时复合膜的电化学性能最佳,防腐蚀效果最好。

油田采出水过滤器滤料高效清洗剂的研制与应用

以脂肪醇聚氧乙烯醚羧酸钠和十六烷基三甲基氯化铵为原料制备了一种滤料清洗剂,利用接触角测试、界面张力测试等方法评价了该滤料清洗剂的性能,并在东部某油田注水站进行了现场试验。实验结果表明,该滤料清洗剂具有良好的润湿性调控性能,可将被原油污染的基材表面恢复至亲水;有效含量为1~5 g/L时可将油水界面张力降至10^(-3)m N/m数量级,具有高界面性能;对原油具有良好的乳化增溶能力;对被污染的滤料进行动态清洗,洗油效率约99%。现场试验结果显示,经该滤料清洗剂处理后过滤罐的前后压差明显降低,后端滤出水含油量不大于5 mg/L,达到良好的恢复滤料性能的效果。

大庆油田裸眼井测井技术进展与展望

为了提高大庆油田裸眼井测井技术支撑能力和研究成果领先水平,全面回顾了大庆油田测井采集系列及解释技术的创新发展历程,系统总结了特高含水期剩余油解释、火山岩等复杂岩性测井评价、碎屑岩储量参数解释、非常规油气“甜点”分类、缝洞型碳酸盐岩储层测井评价等油田勘探开发测井评价技术。在客观分析大庆油田勘探开发测井解释评价需求和面临瓶颈问题的基础上,结合当前油田测井评价对象规模小、物性差、埋藏深、地层结构复杂、非均质性强的特点。指明了测井解释评价核心技术主攻方向。围绕新阶段测井采集及解释评价技术体系完善与建立,对高分辨率和成像测井采集、后油藏时期和非常规测井解释评价、新一代智能解释技术体系等未来发展进行了展望。