A new method for the determination of atrazine, simazine and prometryn in water samples by on-line sweeping concentration technique in micellar electrokinetic chromatography （MEKC） was developed. Various parameters ...A new method for the determination of atrazine, simazine and prometryn in water samples by on-line sweeping concentration technique in micellar electrokinetic chromatography （MEKC） was developed. Various parameters affecting sample enrichment and separation efficiency were systematically studied. Compared with the conventional MEKC method, up to 60-200-fold improvement in concentration sensitivity was achieved in terms of peak height by using this sweeping injection technique. The compound strychnine was used as the internal standard for the improvement of the experimental reproducibility. The limits of detection （S/ N = 3：1） for atrazine, simazine and prometryn were 9, 10 and 0.5 ng mL-1, respectively. This method has been successfully applied to the analysis of atrazine, simazine and prometryn in lake, steam and ground water.展开更多
A sensitive and simple micellar electrokinetic chromatography （MEKC） method was developed for the determination of antiepileptic drug, carbamazepine （CBZ）, using sweeping on-line concentration method with photodio...A sensitive and simple micellar electrokinetic chromatography （MEKC） method was developed for the determination of antiepileptic drug, carbamazepine （CBZ）, using sweeping on-line concentration method with photodiode array detection. Under the optimal conditions, the calibration curve was linear over a range of 0.5-40μg·mL^-1 for CBZ with a correlation coefficient of 0.998. The detection limit （S/N = 3：1） of CBZ was 0.10 μg·mL^-1. The sweeping-MEKC method has been successfully applied to the analysis of CBZ in human serum.展开更多
To take advantage of micelle to solvent stacking (MSS) to achieve more sensitivity enhancement with enough selectivity, the application of capillary electrophoretic online sequential concentration based on the MSS was...To take advantage of micelle to solvent stacking (MSS) to achieve more sensitivity enhancement with enough selectivity, the application of capillary electrophoretic online sequential concentration based on the MSS was reviewed. MSS has been coupled to sweeping FASS, FASI and normal EKI. Furthermore, multiple stacking by coupling MSS with more than one stacking method has also been reported. It is more sensitive and selective than solely used of one or two stacking methods and is very suitable for complex and trace sample analysis.展开更多
Reagents are optimized for the simultaneous determination of trace amounts of Cu^(2+), Cd^(2+) and Co^(2+) in zinc sulfate solution, which contains an extremely large excess of Zn^(2+). First, the reagents and their d...Reagents are optimized for the simultaneous determination of trace amounts of Cu^(2+), Cd^(2+) and Co^(2+) in zinc sulfate solution, which contains an extremely large excess of Zn^(2+). First, the reagents and their doses for the experiment are selected according to the characteristics of the zinc sulfate solution. Then, the reagent doses are optimized by analyzing the influence of reagent dose on the polarographic parameters(i.e. half-wave potential E_(1/2) and limiting diffusion current I_p). Finally, the optimization results are verified by simultaneously determining trace amounts of Cu^(2+), Cd^(2+) and Co^(2+) in the presence of an extremely large excess of Zn^(2+). The determination results indicate that the optimized reagents exhibit wide linearity, low detection limits, high accuracy and good precision for the simultaneous determination of trace amounts of Cu^(2+), Cd^(2+) and Co^(2+) in the presence of an extremely large excess of Zn^(2+).展开更多
With the development of distribution automation system, the centralized meter reading system has been adopted more and more extensively, which provides real-time electricity consumption data of end-users, and conseque...With the development of distribution automation system, the centralized meter reading system has been adopted more and more extensively, which provides real-time electricity consumption data of end-users, and consequently lays foundation for operating condition on-line analysis of distribution network. In this paper, a modified back/forward sweep method, which directly uses real-time electricity consumption data acquired from the centralized meter reading system, is proposedto realize voltage analysis based on 24-hour electricity consumption data of a typical transformer district. Furthermore, the calculated line losses are verified through data collected from the energy metering of the distribution transformer, illustrating that the proposed method can be applied in analyzing voltage level and discovering unknown energy losses, which will lay foundation for on-line analysis, calculation and monitoring of power distribution network.展开更多
In this paper, several {actors that could lead to the appearance of false peak were investigated by using on-line sample sweeping technique under different experimental conditions. The tested analytes were buflomedil ...In this paper, several {actors that could lead to the appearance of false peak were investigated by using on-line sample sweeping technique under different experimental conditions. The tested analytes were buflomedil hydrochloride, ephedrine hydrochloride, benzyl alcohol, vanillin, p-hydroxybenzaldehyde and m-methylphenol. Results showed mat among the six compounds, three of them, i.e., buflomedil hydrochloride, ephedrine hydrochloride and benzyl alcohol will cause false peaks to appear when sample injection time is long, sodium dodecyl sulfate (SDS) concentration is high and there is pH gradient between cathode and anode. In order to avoid the appearance of false peak, the pH gradient should be avoided.展开更多
In this paper, it is discussed that an on-line ultrasonic hydrochloric acid concentration meter according to the relationship between the concentration, temperature and ultrasonic velocity of hydrochloric acid solutio...In this paper, it is discussed that an on-line ultrasonic hydrochloric acid concentration meter according to the relationship between the concentration, temperature and ultrasonic velocity of hydrochloric acid solution. In the experiments, it is measured that the ultrasonic velocities of hydrochloric acid solution of the different concentrations and temperatures. And it is also calculated that the velocity-concentration coefficients and velocity-temperaturecoefficients of hydrochloric acid solution.展开更多
基金sponsored by the Natural Science Foundation of Hebei (Nos.B2006000413,B2008000210).
文摘A new method for the determination of atrazine, simazine and prometryn in water samples by on-line sweeping concentration technique in micellar electrokinetic chromatography （MEKC） was developed. Various parameters affecting sample enrichment and separation efficiency were systematically studied. Compared with the conventional MEKC method, up to 60-200-fold improvement in concentration sensitivity was achieved in terms of peak height by using this sweeping injection technique. The compound strychnine was used as the internal standard for the improvement of the experimental reproducibility. The limits of detection （S/ N = 3：1） for atrazine, simazine and prometryn were 9, 10 and 0.5 ng mL-1, respectively. This method has been successfully applied to the analysis of atrazine, simazine and prometryn in lake, steam and ground water.
文摘A sensitive and simple micellar electrokinetic chromatography （MEKC） method was developed for the determination of antiepileptic drug, carbamazepine （CBZ）, using sweeping on-line concentration method with photodiode array detection. Under the optimal conditions, the calibration curve was linear over a range of 0.5-40μg·mL^-1 for CBZ with a correlation coefficient of 0.998. The detection limit （S/N = 3：1） of CBZ was 0.10 μg·mL^-1. The sweeping-MEKC method has been successfully applied to the analysis of CBZ in human serum.
文摘To take advantage of micelle to solvent stacking (MSS) to achieve more sensitivity enhancement with enough selectivity, the application of capillary electrophoretic online sequential concentration based on the MSS was reviewed. MSS has been coupled to sweeping FASS, FASI and normal EKI. Furthermore, multiple stacking by coupling MSS with more than one stacking method has also been reported. It is more sensitive and selective than solely used of one or two stacking methods and is very suitable for complex and trace sample analysis.
基金Projects(61533021,61321003,61273185)supported by the National Natural Science Foundation of ChinaProject(2015CX007)supported by the Innovation-driven Plan in Central South University,ChinaProject(13JJ8003)supported by the Joint Fund of Hunan Provincial Natural Science Foundation of China
文摘Reagents are optimized for the simultaneous determination of trace amounts of Cu^(2+), Cd^(2+) and Co^(2+) in zinc sulfate solution, which contains an extremely large excess of Zn^(2+). First, the reagents and their doses for the experiment are selected according to the characteristics of the zinc sulfate solution. Then, the reagent doses are optimized by analyzing the influence of reagent dose on the polarographic parameters(i.e. half-wave potential E_(1/2) and limiting diffusion current I_p). Finally, the optimization results are verified by simultaneously determining trace amounts of Cu^(2+), Cd^(2+) and Co^(2+) in the presence of an extremely large excess of Zn^(2+). The determination results indicate that the optimized reagents exhibit wide linearity, low detection limits, high accuracy and good precision for the simultaneous determination of trace amounts of Cu^(2+), Cd^(2+) and Co^(2+) in the presence of an extremely large excess of Zn^(2+).
文摘With the development of distribution automation system, the centralized meter reading system has been adopted more and more extensively, which provides real-time electricity consumption data of end-users, and consequently lays foundation for operating condition on-line analysis of distribution network. In this paper, a modified back/forward sweep method, which directly uses real-time electricity consumption data acquired from the centralized meter reading system, is proposedto realize voltage analysis based on 24-hour electricity consumption data of a typical transformer district. Furthermore, the calculated line losses are verified through data collected from the energy metering of the distribution transformer, illustrating that the proposed method can be applied in analyzing voltage level and discovering unknown energy losses, which will lay foundation for on-line analysis, calculation and monitoring of power distribution network.
基金theNaturalScienceFoundationofHebeiProvince (No .2 0 0 077)andtheNationalNaturalScienceFoundationofChina (No .2 0 0 75 0 0 5 )
文摘In this paper, several {actors that could lead to the appearance of false peak were investigated by using on-line sample sweeping technique under different experimental conditions. The tested analytes were buflomedil hydrochloride, ephedrine hydrochloride, benzyl alcohol, vanillin, p-hydroxybenzaldehyde and m-methylphenol. Results showed mat among the six compounds, three of them, i.e., buflomedil hydrochloride, ephedrine hydrochloride and benzyl alcohol will cause false peaks to appear when sample injection time is long, sodium dodecyl sulfate (SDS) concentration is high and there is pH gradient between cathode and anode. In order to avoid the appearance of false peak, the pH gradient should be avoided.
文摘In this paper, it is discussed that an on-line ultrasonic hydrochloric acid concentration meter according to the relationship between the concentration, temperature and ultrasonic velocity of hydrochloric acid solution. In the experiments, it is measured that the ultrasonic velocities of hydrochloric acid solution of the different concentrations and temperatures. And it is also calculated that the velocity-concentration coefficients and velocity-temperaturecoefficients of hydrochloric acid solution.
