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Method to measure tree-ring width,density,elemental composition,and stable carbon and oxygen isotopes using one sample 被引量:1
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作者 Chenxi Xu Yaru Zhao +4 位作者 Wenling An Qingyu Zhao Yucheng Liu Masaki Sano Takeshi Nakatsuka 《Journal of Forestry Research》 SCIE EI CAS CSCD 2024年第3期167-174,共8页
Tree-ring width(RW),density,elemental com-position,and stable carbon and oxygen isotope(δ^(13)C,δ^(18)O)are widely used as proxies to assess climate change,ecology,and environmental pollution;however,a specific pret... Tree-ring width(RW),density,elemental com-position,and stable carbon and oxygen isotope(δ^(13)C,δ^(18)O)are widely used as proxies to assess climate change,ecology,and environmental pollution;however,a specific pretreat-ment has been needed for each proxy.Here,we developed a method by which each proxy can be measured in the same sample.First,the sample is polished for ring width meas-urement.After obtaining the ring width data,the sample is cut to form a 1-mm-thick wood plate.The sample is then mounted in a vertical sample holder,and gradually scanned by an X-ray beam.Simultaneously,the count rates of the fluorescent photons of elements(for chemical characteriza-tion)and a radiographic grayscale image(for wood density)are obtained,i.e.the density and the element content are obtained.Then,cellulose is isolated from the 1-mm wood plate by removal of lignin,and hemicellulose.After producing this cellulose plate,cellulose subsamples are separated by knife under the microscope for inter-annual and intra-annual stable carbon and oxygen isotope(δ^(13)C,δ^(18)O)analysis.Based on this method,RW,density,elemental composition,δ^(13)C,and δ^(18)O can be measured from the same sample,which reduces sample amount and treatment time,and is helpful for multi-proxy comparison and combination research. 展开更多
关键词 Tree-ring width Tree-ring density Tree-ring elemental composition Tree-ring stable carbon and oxygenisotopes
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Effects of desert plant communities on soil enzyme activities and soil organic carbon in the proluvial fan in the eastern foothills of the Helan Mountain in Ningxia,China
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作者 SHEN Aihong SHI Yun +8 位作者 MI Wenbao YUE Shaoli SHE Jie ZHANG Fenghong GUO Rui HE Hongyuan WU Tao LI Hongxia ZHAO Na 《Journal of Arid Land》 SCIE CSCD 2024年第5期725-737,共13页
It is of great significance to study the effects of desert plants on soil enzyme activities and soil organic carbon(SOC)for maintaining the stability of the desert ecosystem.In this study,we studied the responses of s... It is of great significance to study the effects of desert plants on soil enzyme activities and soil organic carbon(SOC)for maintaining the stability of the desert ecosystem.In this study,we studied the responses of soil enzyme activities and SOC fractions(particulate organic carbon(POC)and mineral-associated organic carbon(MAOC))to five typical desert plant communities(Convolvulus tragacanthoides,Ephedra rhytidosperma,Stipa breviflora,Stipa tianschanica var.gobica,and Salsola laricifolia communities)in the proluvial fan in the eastern foothills of the Helan Mountain in Ningxia Hui Autonomous Region,China.We recorded the plant community information mainly including the plant coverage and herb and shrub species,and obtained the aboveground biomass and plant species diversity through sample surveys in late July 2023.Soil samples were also collected at depths of 0–10 cm(topsoil)and 10–20 cm(subsoil)to determine the soil physicochemical properties and enzyme activities.The results showed that the plant coverage and aboveground biomass of S.laricifolia community were significantly higher than those of C.tragacanthoides,S.breviflora,and S.tianschanica var.gobica communities(P<0.05).Soil enzyme activities varied among different plant communities.In the topsoil,the enzyme activities of alkaline phosphatase(ALP)andβ-1,4-glucosidas(βG)were significantly higher in E.rhytidosperma and S.tianschanica var.gobica communities than in other plant communities(P<0.05).The topsoil had higher POC and MAOC contents than the subsoil.Specifically,the content of POC in the topsoil was 18.17%–42.73%higher than that in the subsoil.The structural equation model(SEM)indicated that plant species diversity,soil pH,and soil water content(SWC)were the main factors influencing POC and MAOC.The soil pH inhibited the formation of POC and promoted the formation of MAOC.Conversely,SWC stimulated POC production and hindered MAOC formation.Our study aimed to gain insight into the effects of desert plant communities on soil enzyme activities and SOC fractions,as well as the drivers of SOC fractions in the proluvial fan in the eastern foothills of the Helan Mountain and other desert ecosystems. 展开更多
关键词 proluvial fan desert plant community soil enzyme activity particulate organic carbon mineral-associated organic carbon Helan Mountain
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One memristor–one electrolyte-gated transistor-based high energy-efficient dropout neuronal units
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作者 李亚霖 时凯璐 +4 位作者 朱一新 方晓 崔航源 万青 万昌锦 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第6期569-573,共5页
Artificial neural networks(ANN) have been extensively researched due to their significant energy-saving benefits.Hardware implementations of ANN with dropout function would be able to avoid the overfitting problem. Th... Artificial neural networks(ANN) have been extensively researched due to their significant energy-saving benefits.Hardware implementations of ANN with dropout function would be able to avoid the overfitting problem. This letter reports a dropout neuronal unit(1R1T-DNU) based on one memristor–one electrolyte-gated transistor with an ultralow energy consumption of 25 p J/spike. A dropout neural network is constructed based on such a device and has been verified by MNIST dataset, demonstrating high recognition accuracies(> 90%) within a large range of dropout probabilities up to40%. The running time can be reduced by increasing dropout probability without a significant loss in accuracy. Our results indicate the great potential of introducing such 1R1T-DNUs in full-hardware neural networks to enhance energy efficiency and to solve the overfitting problem. 展开更多
关键词 dropout neuronal unit synaptic transistors MEMRISTOR artificial neural network
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Polyetherketoneketone/carbon fiber composites with an amorphous interface prepared by solution impregnation
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作者 ZHANG Feng LI Bo-lan +5 位作者 JIAO Meng-xiao LI Yan-bo WANG Xin YANG Yu YANG Yu-qiu ZHANG Xiao-hua 《新型炭材料(中英文)》 SCIE EI CAS CSCD 北大核心 2024年第4期692-702,共11页
Interfacial adhesion between carbon fibers(CF)and polyetherketoneketone(PEKK)is a key factor that affects the mechanical performances of their composites.It is therefore of great importance to impregnate the CF bundle... Interfacial adhesion between carbon fibers(CF)and polyetherketoneketone(PEKK)is a key factor that affects the mechanical performances of their composites.It is therefore of great importance to impregnate the CF bundles with PEKK as effi-ciently as possible.We report that PEKK with a good dispersion in a mixed solution of 4-chlorophenol and 1,2-dichloroethane can be introduced onto CF surfaces by solution impregnation and curing at 280,320,340 and 360℃.The excellent wettability or infiltra-tion of the PEKK solution guarantees a full covering and its tight binding to CFs,making it possible to evaluate the interfacial shear strength(IFSS)with the microdroplet method.The interior of the CF bundles is completely and uniformly filled with PEKK by solu-tion impregnation,leading to a high interlaminar shear strength(ILSS).The maximum IFSS and ILSS reached 107.8 and 99.3 MPa,respectively.Such superior shear properties are ascribed to the formation of amorphous PEKK in the small spaces between CFs. 展开更多
关键词 Polyetherketoneketone carbon fiber WETTABILITY Amorphous adhesion Interfacial strength
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Hounsfield units in assessing bone mineral density in ankylosing spondylitis patients with cervical fracture-dislocation
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作者 Zhong-Ya Gao Wei-Lin Peng +1 位作者 Yang Li Xu-Hua Lu 《World Journal of Clinical Cases》 SCIE 2024年第23期5329-5337,共9页
BACKGROUND Cervical spine fracture-dislocations in patients with ankylosing spondylitis(AS)are mostly unstable and require surgery.However,osteoporosis,one of the comorbidities for AS,could lead to detrimental prognos... BACKGROUND Cervical spine fracture-dislocations in patients with ankylosing spondylitis(AS)are mostly unstable and require surgery.However,osteoporosis,one of the comorbidities for AS,could lead to detrimental prognoses.There are few accurate assessments of bone mineral density in AS patients.AIM To analyze Hounsfield units(HUs)for assessing bone mineral density in AS patients with cervical fracture-dislocation.METHODS The HUs from C2 to C7 of 51 patients obtained from computed tomography(CT)scans and three-dimensional reconstruction of the cervical spine were independently assessed by two trained spinal surgeons and statistically analyzed.Inter-reader reliability and agreement were assessed by interclass correlation coefficient.RESULTS The HUs decreased gradually from C2 to C7.The mean values of the left and right levels were significantly higher than those in the middle.Among the 51 patients,25 patients(49.02%)may be diagnosed with osteoporosis,and 16 patients(31.37%)may be diagnosed with osteopenia.CONCLUSION The HUs obtained by cervical spine CT are feasible for assessing bone mineral density with excellent agreement in AS patients with cervical fracture-dislocation. 展开更多
关键词 Hounsfield unit Ankylosing spondylitis FRACTURE-DISLOCATION Cervical spine OSTEOPOROSIS
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Correlation and Pathway Analysis of the Carbon,Nitrogen,and Phosphorus in Soil-Microorganism-Plant with Main Quality Components of Tea(Camellia sinensis)
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作者 Chun Mao Ji He +3 位作者 Xuefeng Wen Yangzhou Xiang Jihong Feng Yingge Shu 《Phyton-International Journal of Experimental Botany》 SCIE 2024年第3期487-502,共16页
The contents of carbon(C),nitrogen(N),and phosphorus(P)in soil-microorganisms-plant significantly affect tea quality by altering the main quality components of tea,such as tea polyphenols,amino acids,and caffeine.Howev... The contents of carbon(C),nitrogen(N),and phosphorus(P)in soil-microorganisms-plant significantly affect tea quality by altering the main quality components of tea,such as tea polyphenols,amino acids,and caffeine.However,few studies have quantified the effects of these factors on the main quality components of tea.The study aimed to explore the interactions of C,N,and P in soil-microorganisms-plants and the effects of these factors on the main quality components of tea by using the path analysis method.The results indicated that(1)The contents of C,N,and P in soil,microorganisms,and tea plants were highly correlated and collinear,and showed significant correlations with the main quality components of tea.(2)Optimal regression equations were established to esti-mate tea polyphenol,amino acid,catechin,caffeine,and water extract content based on C,N,and P contents in soil,microorganisms,and tea plants(R^(2)=0.923,0.726,0.954,0.848,and 0.883,respectively).(3)Pathway analysis showed that microbial biomass phosphorus(MBP),root phosphorus,branch nitrogen,and microbial biomass carbon(MBC)were the largest direct impact factors on tea polyphenol,catechin,water extracts,amino acid,and caffeine content,respectively.Leaf carbon,root phosphorus,and leaf nitrogen were the largest indirect impact factors on tea polyphenol,catechin,and water extract content,respectively.Leaf carbon indirectly affected tea polyphenol content mainly by altering MBP content.Root phosphorus indirectly affected catechin content mainly by altering soil organic carbon content.Leaf nitrogen indirectly affected water extract content mainly by altering branch nitrogen content.The research results provide the scientific basis for reasonable fertilization in tea gardens and tea quality improvement. 展开更多
关键词 Soil-microorganisms-plant system carbon NITROGEN PHOSPHORUS tea quality path analysis
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Experimental investigation on the origin of carbonaceous materials in the fault zone of the Wenchuan earthquake
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作者 Deyang Shi Yaowei Liu Jin Shi 《Earthquake Science》 2024年第3期189-199,共11页
Carbonaceous materials in seismic fault zones may considerably influence seismic fault slip;however,the formation mechanism of carbonaceous materials remains unclear.In this study,we proposed a novel hypothesis for th... Carbonaceous materials in seismic fault zones may considerably influence seismic fault slip;however,the formation mechanism of carbonaceous materials remains unclear.In this study,we proposed a novel hypothesis for the formation of carbonaceous materials in fault gouge.Thus,we conducted a CO_(2) hydrogenation experiment in a high-temperature reactor at a co-seismic temperature,with fault gouge formed during the Wenchuan earthquake as the catalyst.Our experimental results demonstrate that carbonaceous materials in fault zones are formed on the fault gouge during the chemical reaction process,suggesting that the carbonaceous materials are possibly generated from the catalytic hydrogenation of CO_(2),followed by thermal cracking of its products.The results of this study provide a theoretical basis for understanding fault behavior and earthquake physics. 展开更多
关键词 carbon dioxide hydrogenation carbonaceous mineral formation co-seismic temperature fault weakening fault gouge
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Topological Structure-Modulated Collagen Carbon as Two-in-One Energy Storage Configuration toward Ultrahigh Power and Energy Density
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作者 Li Yuan Wenlong Cai +4 位作者 Yunhong Wei Yiran Pu Can Liu Yun Zhang Hao Wu 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第2期18-29,共12页
Efficient energy storage devices with suitable electrode materials,that integrate high power and high energy,are the crucial requisites of the renewable power source,which have unwrapped new possibilities in the susta... Efficient energy storage devices with suitable electrode materials,that integrate high power and high energy,are the crucial requisites of the renewable power source,which have unwrapped new possibilities in the sustainable development of energy and the environment.Herein,a facile collagen microstructure modulation strategy is proposed to construct a nitrogen/oxygen dual-doped hierarchically porous carbon fiber with ultrahigh specific surface area(2788 m^(2)g^(-1))and large pore volume(4.56 cm^(3)g^(-1))via local microfibrous breakage/disassembly of natural structured proteins.Combining operando spectroscopy and density functional theory unveil that the dual-heteroatom doping could effectively regulate the electronic structure of carbon atom framework with enhanced electric conductivity and electronegativity as well as decreased diffusion resistance in favor of rapid pseudocapacitive-dominated Li^(+)-storage(353 mAh g^(-1)at 10 A g^(-1)).Theoretical calculations reveal that the tailored micro-/mesoporous structures favor the rapid charge transfer and ion storage,synergistically realizing high capacity and superior rate performance for NPCF-H cathode(75.0 mAh g^(-1)at 30 A g^(-1)).The assembled device with NPCF-H as both anode and cathode achieves extremely high energy density(200 Wh kg^(-1))with maximum power density(42600 W kg^(-1))and ultralong lifespan(80%capacity retention over 10000 cycles). 展开更多
关键词 collagen carbon energy storage device theoretical calculations topological structure modulation ultrahigh power and energy density
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Research Progress of Carbon-Silicone Composite Materials
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作者 Beibei Liu Rongjie Kan 《Expert Review of Chinese Chemical》 2024年第2期1-7,共7页
Silicone is a kind of polymer material with high cross-linked structure,which is com-posed by Si-O-Si main chain.Due to the special molecular chain structure,silicone mate-rials are characterized by oxidation resistan... Silicone is a kind of polymer material with high cross-linked structure,which is com-posed by Si-O-Si main chain.Due to the special molecular chain structure,silicone mate-rials are characterized by oxidation resistance,aging resistance,high and low temperature resistance and chemical corrosion resistance.Moreover,silicone materials have process-able properties,simple forming process,good mechanical property,non-toxic and pollution-free.Therefore,silicone has been widely concerned by researchers at home and abroad.In this paper,the main research progress and application directions of carbon-silicone composite at home and abroad in recent years are reviewed. 展开更多
关键词 carbon materials GRAPHEME SILICone composite materials
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Status and Opportunities of Zinc Ion Hybrid Capacitors: Focus on Carbon Materials, Current Collectors, and Separators 被引量:5
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作者 Yanyan Wang Shirong Sun +2 位作者 Xiaoliang Wu Hanfeng Liang Wenli Zhang 《Nano-Micro Letters》 SCIE EI CAS CSCD 2023年第6期73-111,共39页
Zinc ion hybrid capacitors(ZIHCs), which integrate the features of the high power of supercapacitors and the high energy of zinc ion batteries, are promising competitors in future electrochemical energy storage applic... Zinc ion hybrid capacitors(ZIHCs), which integrate the features of the high power of supercapacitors and the high energy of zinc ion batteries, are promising competitors in future electrochemical energy storage applications. Carbon-based materials are deemed the competitive candidates for cathodes of ZIHC due to their cost-effectiveness, high electronic conductivity, chemical inertness, controllable surface states, and tunable pore architectures. In recent years, great research efforts have been devoted to further improving the energy density and cycling stability of ZIHCs. Reasonable modification and optimization of carbon-based materials offer a remedy for these challenges. In this review, the structural design, and electrochemical properties of carbon-based cathode materials with different dimensions, as well as the selection of compatible, robust current collectors and separators for ZIHCs are discussed. The challenges and prospects of ZIHCs are showcased to guide the innovative development of carbon-based cathode materials and the development of novel ZIHCs. 展开更多
关键词 Zinc ion hybrid capacitors carbon materials carbon cathode Current collectors SEPARATORS
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Prospects for the transformation and development of carbon storage in abandoned mines of coal enterprises from the perspective ofcarbon neutrality 被引量:2
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作者 Xin Lyu Tong Zhang +1 位作者 Liang Yuan Juejing Fang 《International Journal of Coal Science & Technology》 EI CAS CSCD 2023年第3期24-40,共17页
Under the carbon neutrality goal,coal enterprises must seek breakthroughs from abandoned mines,develop new resources in the new era,turn problems into countermeasures,and participate in the carbon emissions market,for... Under the carbon neutrality goal,coal enterprises must seek breakthroughs from abandoned mines,develop new resources in the new era,turn problems into countermeasures,and participate in the carbon emissions market,for contributing to the accomplishment of the national strategic goal of carbon neutrality.To this end,we investigated the relevant national policies and regulations to clarify the boundaries disclosed by the carbon information of enterprises,understood the development direction of carbon storage in abandoned mines,and clarified the transformation and development of carbon storage in aban-doned mines.We made a few suggestions:(1)China should learn from its past experience and other countries to develop the energy industry with Chinese characteristics and reform the economic system.(2)Coal enterprises must actively respond to the national carbon information disclosure policy,clarify their own responsibilities and carbon emission boundaries.(3)It is necessary to proactively obtain advanced knowledge and plan carbon storage pathways for abandoned mines.(4)Devel-opment problems of coal enterprises should be deduced using cases.The'dual carbon'goals should be achieved steadily step-by-step.(5)Three measures,i.e.improving the existing resource structure,coordinating the information of abandoned mines,and promoting the cultivation of scientific and technological talents. 展开更多
关键词 Mining engineering Abandoned mines carbon neutrality carbon emission rights carbon tax
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Inclusion of peanut in wheat–maize rotation increases wheat yield and net return and improves soil organic carbon pool by optimizing bacterial community 被引量:2
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作者 ZOU Xiao-xia HUANG Ming-ming +5 位作者 LIU Yan SI Tong ZHANG Xiao-jun YU Xiao-na GUO Feng WAN Shu-bo 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2023年第11期3430-3443,共14页
Improving soil quality while achieving higher productivity is the major challenge in the agricultural industry. Wheat(Triticum aestivum L.)–maize(Zea mays L.)(W–M) rotation is the dominant planting pattern in the Hu... Improving soil quality while achieving higher productivity is the major challenge in the agricultural industry. Wheat(Triticum aestivum L.)–maize(Zea mays L.)(W–M) rotation is the dominant planting pattern in the Huang-HuaiHai Plain and is important for food security in China. However, the soil quality is deteriorating due to the W–M rotation’s long-term, intensive, and continuous cultivation. Introducing legumes into the W–M rotation system may be an effective way to improve soil quality. In this study, we aimed to verify this hypothesis by exploring efficient planting systems(wheat–peanut(Arachis hypogaea L.)(W–P) rotation and wheat rotated with maize and peanut intercropping(W–M/P)) to achieve higher agricultural production in the Huang-Huai-Hai Plain. Using traditional W–M rotation as the control, we evaluated crop productivity, net returns, soil microorganisms(SMs), and soil organic carbon(SOC) fractions for three consecutive years. The results indicated that wheat yields were significantly increased under W–P and W–M/P(382.5–579.0 and 179.8–513.1 kg ha-1, respectively) compared with W–M. W–P and W–M/P provided significantly higher net returns(58.2 and 70.4%, respectively) than W–M. W–M/P and W–M retained the SOC stock more efficiently than W–P, increasing by 25.46–31.03 and 14.47–27.64%, respectively, in the 0–20 cm soil layer. Compared with W–M, W–M/P improved labile carbon fractions;the sensitivity index of potentially mineralizable carbon, microbial biomass carbon(MBC), and dissolved organic carbon was 31.5, 96.5–157.2, and 17.8% in 20–40, 10–40, and 10–20 cm soil layers, respectively. The bacterial community composition and bacteria function were altered as per the soil depth and planting pattern. W–M/P and W–M exhibited similar bacterial community composition and function in 0–20 and 20–40 cm soil layers. Compared with W–P, a higher abundance of functional genes, namely, contains mobile elements and stress-tolerant, and a lower abundance of genes, namely,potentially pathogenic, were observed in the 10–20 cm soil layer of W–M and the 0–20 cm soil layer of W–M/P. SOC and MBC were the main factors affecting soil bacterial communities, positively correlated with Sphingomonadales and Gemmatimonadales and negatively correlated with Blastocatellales. Organic input was the main factor affecting SOC and SMs, which exhibited feedback effects on crop productivity. In summary, W–M/P improved productivity, net returns, and SOC pool compared with traditional W–M rotation systems, and it is recommended that plant–soil–microbial interactions be considered while designing high-yield cropping systems. 展开更多
关键词 composite planting carbon sequestration labile carbon fraction bacterial community structure bacterial functions
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"Three-in-One" Multi-Scale Structural Design of Carbon Fiber-Based Composites for Personal Electromagnetic Protection and Thermal Management 被引量:6
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作者 Ming Zhou Shujuan Tan +3 位作者 Jingwen Wang Yue Wu Leilei Liang Guangbin Ji 《Nano-Micro Letters》 SCIE EI CAS CSCD 2023年第10期317-333,共17页
Wearable devices with efficient thermal management and electromagnetic interference(EMI) shielding are highly desirable for improving human comfort and safety. Herein, a multifunctional wearable carbon fibers(CF) @ po... Wearable devices with efficient thermal management and electromagnetic interference(EMI) shielding are highly desirable for improving human comfort and safety. Herein, a multifunctional wearable carbon fibers(CF) @ polyaniline(PANI)/silver nanowires(Ag NWs) composites with a “branch-trunk” interlocked micro/nanostructure were achieved through "three-in-one" multi-scale design. The reasonable assembly of the three kinds of one-dimensional(1D) materials can fully exert their excellent properties i.e., the superior flexibility of CF, the robustness of PANI, and the splendid conductivity of Ag NWs. Consequently, the constructed flexible composite demonstrates enhanced mechanical properties with a tensile stress of 1.2 MPa, which was almost 6 times that of the original material. This is mainly attributed to the fact that the PNAI(branch) was firmly attached to the CF(trunk) through polydopamine(PDA), forming a robust interlocked structure. Meanwhile, the composite possesses excellent thermal insulation and heat preservation capacity owing to the synergistically low thermal conductivity and emissivity. More importantly, the conductive path of the composite established by the three 1D materials greatly improved its EMI shielding property and Joule heating performance at low applied voltage. This work paves the way for rational utilization of the intrinsic properties of 1D materials, as well as provides a promising strategy for designing wearable electromagnetic protection and thermal energy management devices. 展开更多
关键词 Electromagnetic shielding Multi-scale design one-dimensional materials carbon fiber Thermal management
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Preface:Deep Carbon Cycle and Abiotic Methane in the Subduction Zone 被引量:1
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作者 ZHANG Lifei 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2023年第1期286-287,共2页
Two kinds of carbon cycle on Earth have been recognized:surface short-term and deep long-term carbon cycles(Berner,2003;Zhang et al.,2017).Over the years,the surface short-term carbon cycle has been attracted extensiv... Two kinds of carbon cycle on Earth have been recognized:surface short-term and deep long-term carbon cycles(Berner,2003;Zhang et al.,2017).Over the years,the surface short-term carbon cycle has been attracted extensive attention because of their significance implications in the study of environmental changes of human beings.Recently,scientists found more than 98%carbon is stored in the solid Earth which takes great role on the surface carbon cycle(DePaolo,2015;Kelemen and Manning,2015;Plank and Manning,2019;Mao and Mao,2020).Therefore,the research of deep carbon cycle is very significant to the study of the formation and evolution,multi-layered interaction and habitability of the Earth.On the other hand,recent petrological study combined with high pressure-temperature experimental simulation shows that abiotic methane can be formed by the metamorphic reduction of carbonates during the subduction metamorphism(Tao et al.,2018;Wang et al.,2022;Zhang et al.,2023). 展开更多
关键词 CYCLE carbon DEEP
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Oxidative exfoliation of spent cathode carbon:A two-in-one strategy for its decontamination and high-valued application 被引量:2
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作者 Runze Chen Yuran Chen +8 位作者 Xuemin Liang Yapeng Kong Yangyang Fan Quan Liu Zhenyu Yang Feiying Tang Johnny Muya Chabu Maru Dessie Walle Liqiang Wang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第7期262-269,共8页
Spent cathode carbon(SCC)from aluminum electrolysis is a potential graphite resource.However,full use of the SCC remains a challenge,since it contains many hazardous substances(e.g.,fluoride salts,cyanides),encapsulat... Spent cathode carbon(SCC)from aluminum electrolysis is a potential graphite resource.However,full use of the SCC remains a challenge,since it contains many hazardous substances(e.g.,fluoride salts,cyanides),encapsulated within the thick carbon layers and thus posing serious environmental concerns.This work presents a chemical oxidative exfoliation route to achieve the recycling of SCC and the decontaminated SCC with high-valued graphene oxide(GO)-like carbon structures(SCC-GO)is applied as an excellent adsorbent for organic pollutants.Specifically,after the oxidative exfoliation,the embedded hazardous constituents are fully exposed,facilitating their subsequent removal by aqueous leaching.Moreover,benefiting from the enhanced specific surface areas along with abundant O-containing functional groups,the as-produced SCC-GO,shows an adsorption capacity as high as 347 mg·g^(-1)when considering methylene blue as a pollutant model,which exceeds most of the recently reported carbon-based adsorbents.Our study provides a feasible solution for the efficient recycling of hazardous carbonaceous wastes. 展开更多
关键词 Waste treatment Spent cathode carbon Oxidative exfoliation Purification Recovery Adsorption
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Adsorption behavior of activated carbon for the elimination of zearalenone during bleaching process of corn oil 被引量:2
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作者 Yuyuan Hu Chuanguo Ma +3 位作者 Weifeng Huang Shujing Guo Tong Wang Jun Liu 《Grain & Oil Science and Technology》 2023年第1期24-33,共10页
Zearalenone is a mycotoxin produced by Fusarium species.It frequently contaminates cereals used for foods or animal feeds,especially deposited in crude corn oil.Certain amounts of zearalenone can be removed during ref... Zearalenone is a mycotoxin produced by Fusarium species.It frequently contaminates cereals used for foods or animal feeds,especially deposited in crude corn oil.Certain amounts of zearalenone can be removed during refining processes.In this study,we studied the influence of activated carbon and six industial absorbents(zeolite,diatomite,attapulgite,perlite,montmorillonite and activated clay)on the elimination of zearalenone during bleaching process of corn oil and explored the absorption mechanism of activated carbon.Results showed that activated carbon had an excellent adsorption capacity of zearalenone compared with the other six industrial adsorbents.For activated carbon,a high removal rate of zearalenone(exceeding 83%)from heavily zearalenone-polluted corn oil was achieved and the removal rate of zearalenone was kept above 60%after five regeneration cycles.The research on the adsorption mechanism of activated carbon showed that Freundlich adsorption isotherm model and pseudo-second-order kinetic model could well described the adsorption process.The thermodynamic study demonstrated that adsorption process was spontaneous and exothermic.Fourier transform infrared spectroscopy and Raman spectroscopy further revealed that activated carbon was effectively combined with zearalenone viaπ-πinteraction.Thus,activated carbon is an efficient and suitable adsorbent to control the levels of zearalenone during bleaching process of corn oil.This study not only proposed a systematic research scheme for the mechanism study of activated carbon for the elimination of zearalenone in corn oil,but also provided the scientific basis for developing effective methods to eliminate zearalenone in refined vegetable oils. 展开更多
关键词 ZEARALENone Adsorbents Activated carbon Adsorption kinetics Corn oil
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One-step floating conversion of biomass into highly graphitized and continuous carbon nanotube yarns 被引量:1
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作者 Gongxun Zhai Qianqian Wang +5 位作者 Fuyao Liu Zexu Hu Chao Jia Dengxin Li Hengxue Xiang Meifang Zhu 《Green Energy & Environment》 SCIE EI CAS CSCD 2023年第6期1711-1718,共8页
The rapid growth of the demand for carbon nanotubes(CNTs) has greatly promoted their large-scale synthesis and development. However,the continuous production of CNT fibers by floating catalyst chemical vapor depositio... The rapid growth of the demand for carbon nanotubes(CNTs) has greatly promoted their large-scale synthesis and development. However,the continuous production of CNT fibers by floating catalyst chemical vapor deposition(FCCVD) requires a large amount of non-renewable carbon sources. Here, the continuous production of highly graphitized CNT yarns from biomass tannic acid(TA) is reported. The chelation of TA and catalyst promotes the rapid cracking of biomass into carbon source gas, and the pyrolysis cracking produces the reducing gas, which solves the problems of the continuous production of CNT yarns using biomass. Through simple twisting, the mechanical strength of CNT yarn can reach 886 ± 46 MPa, and the electrical conductivity and graphitization(IG/ID) can reach 2 × 10^(5)S m^(-1)and 6.3, respectively. This work presents a promising solution for the continuous preparation of CNT yarns based on green raw material. 展开更多
关键词 carbon nanotube Tannic acid BIOMASS Pyrolysis Floating catalyst chemical vapor deposition
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Minimizing Carbon Content with Three-in-One Functionalized Nano Conductive Ceramics:Toward More Practical and Safer S Cathodes of Li-S Cells 被引量:1
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作者 Ning Li Chang Sun +5 位作者 Jianhui Zhu Shun Li Yanlong Wang Maowen Xu Changming Li Jian Jiang 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2023年第3期31-39,共9页
Using porous carbon hosts in cathodes of Li-S cells can disperse S actives and offset their poor electrical conductivity.However,such reservoirs would in turn absorb excess electrolyte solvents to S-unfilled regions,c... Using porous carbon hosts in cathodes of Li-S cells can disperse S actives and offset their poor electrical conductivity.However,such reservoirs would in turn absorb excess electrolyte solvents to S-unfilled regions,causing the electrolyte overconsumption,specific energy decline,and even safety hazards for battery devices.To build better cathodes,we propose to substitute carbons by In-doped SnO_(2)(ITO)nano ceramics that own three-in-one functionalities:1)using conductive ITO enables minimizing the total carbon content to an extremely low mass ratio(~3%)in cathodes,elevating the electrode tap density and averting the electrolyte overuse;2)polar ITO nanoclusters can serve as robust anchors toward Li polysulfide(LiPS)by electrostatic adsorption or chemical bond interactions;3)they offer catalysis centers for liquid–solid phase conversions of S-based actives.Also,such ceramics are intrinsically nonflammable,preventing S cathodes away from thermal runaway or explosion.These merits entail our configured cathodes with high tap density(1.54 g cm^(−3)),less electrolyte usage,good security for flame retardance,and decent Li-storage behaviors.With lean and LiNO_(3)-free electrolyte,packed full cells exhibit excellent redox kinetics,suppressed LiPS shuttling,and excellent cyclability.This may trigger great research enthusiasm in rational design of low-carbon and safer S cathodes. 展开更多
关键词 flame retardance Li-S cells minimized carbon ratio nano conductive ceramics three-in-one functionality
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Facile synthesis of the Mn_(3)O_(4)polyhedron grown on N-doped honeycomb carbon as high-performance negative material for lithium-ion batteries 被引量:1
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作者 Dan Zhang Chunyan Zhang +7 位作者 Xuan Zheng Yizhuo Zhao Xinyu Shi Baomin Luo Yuzhu Li Guangyin Liu Xiaodi Liu Chuang Yu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2023年第6期1152-1161,共10页
Because of their large volume variation and inferior electrical conductivity,Mn_(3)O_(4)-based oxide anode materials have short cyclic lives and poor rate capability,which obstructs their development.In this study,we ... Because of their large volume variation and inferior electrical conductivity,Mn_(3)O_(4)-based oxide anode materials have short cyclic lives and poor rate capability,which obstructs their development.In this study,we successfully prepared a Mn_(3)O_(4)/N-doped honeycomb carbon composite using a smart and facile synthetic method.The Mn_(3)O_(4)nanopolyhedra are grown on N-doped honeycomb carbon,which evidently mitigates the volume change in the charging and discharging processes but also improves the electrochemical reaction kinetics.More importantly,the Mn-O-C bond in the Mn_(3)O_(4)/N-doped honeycomb carbon composite benefits electrochemical reversibility.These features of the Mn_(3)O_(4)/N-doped honeycomb carbon(NHC)composite are responsible for its superior electrochemical performance.When used for Li-ion batteries,the Mn_(3)O_(4)/N-doped honeycomb carbon anode exhibits a high reversible capacity of 598 mAh·g^(−1)after 350 cycles at 1 A·g^(−1).Even at 2 A·g^(−1),the Mn_(3)O_(4)/NHC anode still delivers a high capacity of 472 mAh·g^(−1).This work provides a new prospect for synthesizing and developing manganese-based oxide materials for energy storage. 展开更多
关键词 Mn_(3)O_(4) POLYHEDRON nitrogen-doped honeycomb carbon anode lithium-ion battery
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The fate of carbon resulting from pore water exchange in a mangrove and Spartina alterniflora ecozone
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作者 Weizhen Jiang Guizhi Wang +4 位作者 Qing Li Manab Kumar Dutta Shilei Jin Guiyuan Dai Yi Xu 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2023年第8期61-76,共16页
Mangrove and salt-marsh wetlands are important coastal carbon sinks.In order to quantify carbon export via pore water exchange and to evaluate subsequent fate of the exported carbon,we carried out continuous observati... Mangrove and salt-marsh wetlands are important coastal carbon sinks.In order to quantify carbon export via pore water exchange and to evaluate subsequent fate of the exported carbon,we carried out continuous observations in a mangrove-Spartina alterniflora ecozone in the Zhangjiang River Estuary,China.The carbon fluxes via pore water exchange were estimated using^(222)Rn and^(228)Ra as tracers to be(2.15±0.63)mol/(m^(2)∙d)for dissolved inorganic carbon(DIC)and(-0.008±0.07)mol/(m^(2)∙d)for dissolved organic carbon(DOC)in the wet season and(3.02±0.65)mol/(m^(2)∙d)for DIC and(-0.15±0.007)mol/(m^(2)∙d)for DOC in the dry season in the mangrove-dominated creek(M-creek),while(2.52±0.82)mol/(m^(2)∙d)for DIC and(0.02±0.09)mol/(m^(2)∙d)for DOC in the dry season in the S.alterniflora-dominated creek(SA-creek).The negative value means that pore water was a sink of DOC in the creek.The total carbon via pore water exchange in the tidal creeks in the mangroves accounted for 41%-55%of the net carbon fixed by mangrove vegetation and was 3-4 times as much as the soil carbon accretion in the mangroves.The exported carbon in the form of DIC contributed all of the carbon outwelling from the M-creek and 79%of the carbon outwelling from the SA-creek,implying effective fixation of carbon by the wetland ecosystem.Moreover,it resulted in 54%in the dry season,75%in the wet season of the carbon dioxide released from the M-creek to the atmosphere,and 84%of the release from the SA-creek.Therefore,quantification of pore water exchange and related soil carbon loss is essential to trace the fate of carbon fixed in intertidal wetlands. 展开更多
关键词 MANGROVE SALT-MARSH carbon dioxide carbon accretion carbon outwelling pore water exchange
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