Improvement of the Open Circuit Voltage of CZTSe Thin-Film Solar Cells by Surface Sulfurization Using SnS

The objective of this study is to find an effective method to improve Voc without Jsc loss for Cu2ZnSnSe4 （CZTSe） thin film solar cells, which have been fabricated by the one step co-evaporation technique. Surface sulfurization of CZTSe thin films is carried out by using one technique that does not utilize toxic H2S gas; a sequential evaporation of SnS after CZTSe deposition and the annealing of CZTSe thin films in selenium vapor. A Cu2ZnSn（S, Se）4 （CZTSSe） thin layer is grown on the surface of the CZTSe thin film after the annealing. The conversion efficiency of the completed device is improved due to the enhancement of Voc, which could be attributed to the formation of a hole-recombination barrier at the surface or the passivation of the surface and grain boundary by S incorporation.

TOOL ORIENTATION PLANNING FOR FIVE-AXIS CNC MACHINING OF OPEN FREE-FORM SURFACES

For the geometry characteristics of open free-form surfaces,it is hard to consider global interference during the planning of feasible domains.Therefore,the optimal kinematic orientation of tool axis will no longer be confined to the boundary of feasible domains.In this paper,according to the principle demanding that the tool should be fitted to a surface as close as possible and relevant processing parameters,a feasible domain of tool orientation for each cutter contact is planned in the local feed coordinates system.Then,these feasible domains of the tool orientation are transformed into the same coordinates system of the machine tool by the inverse kinematics transformation.The linear equations based feasible domain method and Rosen gradient projection algorithm are used to improve the optimization process in precision and efficiency of the algorithm.It constructs the variation of tool orientation optimization model and ensures the smoothness of tool orientation globally.Simulation and analysis of examples show that the proposed method has good kinematics performance and greatly improves the efficiency.

Analytic derivation of Monin-Obukhov similarity function for open atmospheric surface layer

The Monin-Obukhov(MO)similarity functionφm of the atmospheric surface layer(ASL)describing the deviation from the log law of the canonical turbulent boundary layer because of thermal stratification has been traditionally determined empirically.This study presents a unified analytic expression derived from a symmetry-based theory of wall turbulence,called structural ensemble dynamics(SED),which postulates a generalized dilation symmetry principle expressing the effect of the wall on turbulence,leading to an analytic multi-regimes expression for the mixing length.For ASL in unstable and stable conditions(i.e.,UC and SC),a unified two-regime formula of the mixing length is proposed,leading to aφm,similar to the Businger-Dyer(BD)formula;with a simplified model energy balance equation,φm is completely specified with no free parameter.Furthermore,the theory allows the study of the open ASL’s underlying additional physical processes such as bottom-up or top-down flux due to pressure variations Tp.Assuming that Tp is decomposed into shear-like and buoyancy-like components,we propose new explanations for two important features of typical ASL:a significantly smaller Karman constant of 0.36 and a varyingφm for SC mean speed profiles.The theory is validated by the data obtained at Kansas and also at Qingtu Lake Observation Array in Northern China for a variety of heat flux conditions.In conclusion,due to pressure variations,we assert that ASL is intrinsically open and that the current theory offers a new basis for its quantification.

APPLICATION OF SINTAP TO THE SAFETY ASSESSMENT OF X65 PIPELINE STEEL

The recently developed European flaw assessment procedure, structural integrity assessment procedure（SiNTAP） is applied to assessment for welded joints of the API 5L X65 pipeline steel with an assumed embedded flaw and surface flaw at the weld toe. As one of the basic input data, fracture toughness crack tip opening displacement （CTOD） tests are conducted at 0℃ and performed according to the requirements of the standard of BS7448. For the heat affected zone （HAZ） specimens, the microstructure observation is performed to insure that the tip of the crack is located in the coarse grain zone. The result explains the dispersity of the test values. In structural integrity assessment procedure-fracture assessment diagram（SINTAP FAD） method, the failure curves of welded joints at level 1 and 3 are derived from the tensile test results. The results of the assessment show that all assessment points are located within the failure lines of analysis level 1 and 3. So the welded joint of the pipeline is safe. This study laid the foundation of application of SINTAP to pipeline structure assessment.

Area-Preserving Parameterization with Tutte Regularization

Area-preserving parameterization is now widely applied,such as for remeshing and medical image processing.We propose an efficient and stable approach to compute area-preserving parameterization on simply connected open surfaces.From an initial parameterization,we construct an objective function of energy.This consists of an area distortion measure and a new regularization,termed as the Tutte regularization,combined into an optimization problem with sliding boundary constraints.The original area-preserving problem is decomposed into a series of subproblems to linearize the boundary constraints.We design an iteration framework based on the augmented Lagrange method to solve each linear constrained subproblem.Our method generates a high-quality parameterization with area-preserving on facets.The experimental results demonstrate the efficacy of the designed framework and the Tutte regularization for achieving a fine parameterization.