基于CAPE-OPEN标准的简捷炼油过程建模及常减压蒸馏流程在线模拟

简捷炼油过程模型广泛应用于运行监测、在线计算、实时优化等领域,但大多数模型只是将输入、输出变量进行关联,无法计算出各组分流量组成,难以集成在模拟软件中进行全流程模拟。本研究简化了炼油分离过程,开发了基于CAPE-OPEN标准的简捷炼油塔模型。首先,将炼油过程简化为连续的分离单元,根据实际产品数据校正模型参数,实现某一实际工况流程模拟;其次,将模型参数与实际工况操作变量数据相结合,采用径向基函数插值确定操作变量对模型参数的影响关系,实现多种工况流程模拟;最后,通过常减压蒸馏工业装置实例的3种工况进行验证。结果表明:各工况模拟结果与Aspen计算结果相比,初馏塔塔顶油馏出温度点偏差大多在2%以内,常减压蒸馏塔各侧线油的馏出温度点平均偏差在3%以内;与实际结果相比,平均误差都在5%以内,符合工程允许误差范围要求。所建模型的计算速度快,各塔均在0.2 s左右完成计算,适用于在线生产、调度等。

Exploring the moderating role of financial development in environmental Kuznets curve for South Africa:fresh evidence from the novel dynamic ARDL simulations approach

The extant literature has produced mixed evidence on the relationship between finan-cial development and ecological sustainability.This work addresses this conundrum by investigating financial development’s direct and indirect consequences on ecologi-cal quality utilizing the environmental Kuznets curve(EKC)methodological approach.Our empirical analysis is based on the novel dynamic autoregressive distributed lag simulations approach for South Africa between 1960 and 2020.The results,which used five distinct financial development measures,demonstrate that financial develop-ment boosts ecological integrity and environmental sustainability over the long and short terms.In the instance of South Africa,we additionally confirm the validity of the EKC theory.More importantly,the outcomes of the indirect channels demonstrate that financial development increases energy usage’s role in causing pollution while attenuating the detrimental impacts of economic growth,trade openness,and foreign direct investment on ecological quality.Moreover,the presence of an inadequate financial system is a requirement for the basis of the pollution haven hypothesis(PHH),which we examine using trade openness and foreign direct investment variables.PHH for both of these variables disappears when financial development crosses specified thresholds.Finally,industrial value addition destroys ecological quality while tech-nological innovation enhances it.This research provides some crucial policy recom-mendations and fresh perspectives for South Africa as it develops national initiatives to support ecological sustainability and reach its net zero emissions goal.

基于CAPE-OPEN标准的乙苯脱氢反应器模块开发与全流程模拟

基于某乙苯负压绝热脱氢制苯乙烯装置转化率低于设计值的现状,建立了包括小分子水蒸气转化反应在内的乙苯绝热脱氢制苯乙烯反应动力学模型和反应器模型,基于工业数据,估计了模型动力学参数,模型具有较高的精度;采用C++语言和COM技术开发了符合CAPE-OPEN标准的乙苯脱氢制苯乙烯反应器单元模块;在Aspen Plus平台构建了内嵌反应器模块的乙苯脱氢制苯乙烯全流程模型,反应器与精馏塔的模拟结果与实际相吻合;进一步考察了工艺参数对装置运行中期反应的影响,提出了适宜的工艺参数,为乙苯脱氢制苯乙烯的工艺设计、生产优化提供有益的支持。

NPV risk simulation of an open pit gold mine project under the O'Hara cost model by using Gas

This paper analyzes an open pit gold mine project based on the O'Hara cost model. Hypothetical data is proposed based on different authors that have studied open pit gold projects, and variations are proposed according to the probability distributions associated to key variables affecting the NPV, like production level, ore grade, price of ore, and others, so as to see what if, in a gold open pit mine project of 3000 metric tons per day of ore. Two case scenarios were analyzed to simulate the NPV, one where there is low certainty data available, and the other where the information available is of high certainty. Results based on genetic algorithm metaheuristic simulations, which combine basically Montecarlo simulations provided by the Palisade Risk software, the O'Hara cost model, net smelter return and financial analysis tools offered by Excel are reported, in order to determine to which variables of the project is more sensitive the NPV.

基于SolidWorks Flow Simulation的矿用烟雾传感器气室结构流体仿真分析

针对矿用烟雾传感器气室结构容易进水且烟雾进出困难、影响烟雾传感元件响应时间的问题,为改善烟雾传感器气室结构对探测元件的影响并提高其防水性能,通过SolidWorks Flow Simulation对3种不同夹角投影的开孔气室结构进行流体仿真分析,研究了不同夹角开孔影响的气流、水流分布特征及变化规律。结果表明:气室结构设计为60°夹角投影的开孔防水、进烟雾程度对传感元件的影响最小,能极大地提高烟雾传感元件的检测灵敏性。

Effect of Valence Band Tail Width on the Open Circuit Voltage of P3HT:PCBM Bulk Heterojunction Solar Cell:AMPS-1D Simulation Study

The effect of the valence band tail width on the open circuit voltage of P3HT：PCBM bulk heterojunction solar cell is investigated by using the AMPS-1D computer program. An effective medium model with exponential valence and conduction band tail states is used to simulate the photovoltaic cell. The simulation result shows that the open circuit voltage depends Iinearly on the logarithm of the generation rate and the slope depends on the width of the valence band tail. The open circuit voltage decreases with the increasing width of the band tail. The dark and light ideality factors increase with the width of the valence band tail.

Large-scale simulations of CO_(2) diffusion in metal-organic frameworks with open Cu sites

Understanding CO_(2) diffusion behavior in functional nanoporous materials is beneficial for improving the CO_(2) adsorption,separation,and conversion performances.However,it is a great challenge for studying the diffusion process in experiments.Herein,CO_(2) diffusion in 962 metal–organic frameworks(MOFs)with open Cu sites was systematically investigated by theoretical methods in the combination of molecular dynamic simulations and density functional theory(DFT)calculations.A specific force field was derived from DFT-D2 method combined with Grimme’s dispersion-corrected(D2)density functional to well describe the interaction energies between Cu and CO_(2).It is observed that the suitable topology is conductive to CO_(2) diffusion,and 2D-MOFs are more flexible in tuning and balancing the CO_(2) adsorption and diffusion behaviors than 3D-MOFs.In addition,analysis of diffusive trajectories and the residence times on different positions indicate that CO_(2) diffusion is mainly along with the frameworks in these MOFs,jumping from one strong adsorption site to another.It is also influenced by the electrostatic interaction of the frameworks.Therefore,the obtained information may provide useful guidance for the rational design and synthesis of MOFs with enhanced CO_(2) diffusion performance for specific applications.

Landslide forecasting based on hydrological process simulation for a dump slope in an open mining pit

There are concerns about the safety issues of dump slope in the open-cast mining pit because of the risk of catastrophic destruction caused by slope failures that are related to several factors, such as atmospheric conditions(especially precipitation), vegetation and some others. The aim of this study is to investigate the hydrological regime in a dump slope and the influence of the saturation degree on the stability of dump slopes with consideration of precipitation and vegetation using the program of PCSiWaPro~?. Based on the hydrological simulation conducted through PCSiWaPro~?, the calculation of the Factor of Safety(Fs) in the dump slope using Geo-slope Software was improved with further consideration of soil-water weight in the unsaturated dump slope and the influence of water content on the variation of soil property parameters(e.g. cohesion).

Simulation on venting process and valve opening control method for gas trunk pipelines

Determining the venting time of a gas trunk pipeline segment provides an important basis for formulating an emergency plan in the advent of unexpected accidents.As the natural gas venting process corresponds to the transient flow,it is necessary to establish a transient hydraulic-thermal simulation model in order to determine the venting time.In this paper,based on two kinds of venting scenarios in which there is only one venting point in the venting system of a gas trunk pipeline segment—namely,where the venting point is either at one of the two ends or at the junction of two gas trunk pipeline segments—transient hydraulic-thermal simulation models are established.The models consist of gas flow governing equations,the gas state equation,gas physical property equations,initial conditions,and appropriate boundary conditions.The implicit central difference method is used to discretize the gas flow partial differential equations,and the trust-region-dogleg algorithm is used to solve the equations corresponding to each time step,in order to dynamically simulate the whole venting process.The judgment condition for the end of the venting process is that the average pressure of gas trunk pipeline segment is less than 0.11 MPa(actual pressure).Comparing the simulation results of the proposed model with those of the OLGA software and real operational data,we find that the venting time error is less than 10%.On this basis,a venting valve opening control principle is proposed,which prevents the venting noise from exceeded the specified noise value(85 d B)in the venting design of domestic gas pipeline projects.The established calculation model for venting time(dynamic simulation model)for a gas trunk pipeline segment and the proposed opening control principle of venting valve provide reference for the optimal operation of gas pipeline venting systems.

Optimization Design of Open Spaces Based on Wind Tunnel and CFD Simulation： Case Study of a Street Canyon in Northern China

Airflow in open spaces can significantly affect spatial quality. Therefore, according to the type of building structures, the airflow also has different forms. Studies have been conducted on the relation between airflow and pedestrian comfort; however, only few of them have focused on comprehensive urban planning that considers different weather conditions and people＇s ability to adapt. This research focuses on the differences in wind conditions caused by different spatial forms in different seasons. On the basis of a field survey in both summer and winter in a public open space, evaluation standards developed from environmental meteorological data and public feedback were used to evaluate simulation results. Next, several assumptions about canyon orientation and building types were proposed. Wind tunnel and CFD （computational fluid dynamics） simulations were conducted to evaluate the assumptions. The results showed that the canyon orientation significantly affected overall wind conditions and different building structures affected airflow. This research also provides a method to evaluate urban areas that have complicated wind environments.

Study on numerical simulation to water lowering in an open coal mine digging

In view of the situation of excavation of should carry out simulation studies for the numerical open coal mine for the underground water disaster, we value of the water lowering project and improve the accuracy and the level of the water lowering project. On the basis of the hydrological geological conditions of certain open mine digging, a more reasonable seepage numerical model was built according to MODFLOW. It was simulated in advance that the process of the confined water level descending with the time, and combining with the actual observations to test the correctness of the model. The calculation showed that the results coincided well with the results of actual measurement. Based on this, different water lowering numerical simulations were built for the open coal mine digging. It could be simulated and forecast that the changes of the groundwater level in drainage process within and outside the mine pit, and it was quantitatively assessed that the possible water lowering result of the opencast water drainage process, which provide an important basis for the actual water lowering project and the possible project disposal.

Numerical Simulation of Flow over an Open Cavity with Self-Sustained Oscillation Mode Switching

Numerical simulations are used to investigate the self-sustained oscillating flows past an open cavity. The two-dimensional incompressible Navier-Stokes equations are solved directly by using the finite difference method for cavities with an upstream laminar boundary layer. A series of simulations are performed for a variety of cavity length-to-depth ratio. The results show the switching among some flow modes including non-oscillation mode, shear layer mode and wake mode. The variation of the Strouhal number is in favorable agreement with available experimental data. The results of flow fields in the cavity reveal the relationship between the cavity shear layer oscillation modes and recirculating vortices in the cavity.

A study of fire propagation in coal seam with numerical simulation of heat transfer and chemical reaction rate in mining field

Spontaneous combustion of coal is a problem that affects the mining operation and generates environ-mental,economic,social and geotechnical impacts.This phenomenon has been divided into two pro-cesses:ignition and propagation.Fire propagation develops in coal seams because of a set of factors such as direction and wind speed,fracturing and temperature.In this work,heat transfer and chemical kinetics are studied from conservation equations of energy and species,respectively,using the software COMSOL Multiphysics to simulate the propagation of fires in coal seams.Two possible scenarios were analyzed that usually occur in the walls of the coal seams,such as fire focus and fire complete screens.It was found that the propagation kinetics of the fire changes depending on the temperature,the fractur-ing of rock mass and the area of fire influence.For temperature values lower than 300℃,there is con-sumption around 250 cm^3/h,values around 700℃,the consumption is 1500 cm^3/h,and for fires of 1200℃ have values of 3000 cm^3/h.Depending on the speed of propagation can vary from 4 to 17cm/day,considering on the level and fracturing of the final wall of the open pit.

Numerical simulation of roof cavings in several Kuzbass mines using finite-difference continuum damage mechanics approach

An essential stage of mine design is an estimation of the steps of the first and periodic roof caving in longwall mines.Generally,this is carried out using the field experience and can be much enhanced by numerical simulation.In this work,the finite-difference method was applied coupled with the continuum damage mechanics(CDM)approach to simulate the stress-strain evolution of the rock mass with the underground opening during coal extraction.The steps and stages of roof caving were estimated relying on the numerical simulation data,and they were compared with the field data from several operating mines in the south of the Kuznetsk Basin,Russia.The dependence of the first roof caving step in simulation linearly correlates with field data.The results correspond to the actual roofs of longwall panels of the flat-dipping coal seams and the average rate of face advancement is approximately 5 m/day.

基于CAPE-OPEN标准的SINOALKY烷基化反应器模块开发与全流程模拟

基于SINOALKY烷基化工艺,建立了二十集总反应动力学模型和反应器模型,并在此基础上开发了符合CAPE-OPEN标准的SINOALKY烷基化反应器模块,模块包含符合CAPE-OPEN标准的6个物流接口、数值求解器以及可视化的交互界面。将该反应器模块加载于Aspen Plus平台中,搭建了某0.2 Mt a的SINOALKY烷基化装置全流程模型,模型的模拟效果较好;进而,考察了反应工艺参数对烷基化产品组成和性质的影响,结果表明,模型模拟值与实际烷基化工艺相符,获得了适宜的烷基化反应工艺参数。表明包含SINOALKY烷基化反应器模块的烷基化全流程模型可为SINOALKY烷基化装置的模拟优化提供重要参考。

Numerical Simulation of the Flow around Marine Propeller Series

The objective of marine propeller design optimization study is to obtain a propeller with minimum power absorption, maximum efficiency and good materials resistance. In this study, results of numerical simulation carried out on the flow around a conventional marine propeller are presented. The investigation focused on the aspects related to the influence of skew magnitude, thickness and blade number on the propeller performances. First, open water performances of a conventional propeller model DTMB 4148 was estimated using RANS （Reynolds Averaged Navier-Stokes） method. The flow around rotating propeller model was analyzed in the steady state using RANS approach of the commercial CFD （computational fluid dynamics） code fluent. The results provide good agreement with literature data. Numerical results show that the number of blades has an influence on the open water performances of marine propellers. It＇s noticed that the best propeller has four or five blades from only the hydrodynamic aspect. The thickness blade effect has been studied for the same propeller model and compared to the blade with three different thickness values. Results of the calculation show that the blade thickness increases moderately the propeller efficiency. Finally, numerical simulation is performed to study the magnitude skew effect on the propeller blade performance, so three different models were generated. The results of the simulation show that the skew distribution has a positive effect on the open water performances of the marine propellers.

Simulation Calculation and Distribution Characteristics of Terrain Reflected Radiation in Fujian Province

[Objective] The aim was to study the distribution characteristics of terrain reflected radiation in Fujian Province.[Method] Based on solar radiation data,digital elevation model (DEM) and surface meteorological observation data in Fujian Province,plus surface albedo obtained by using remote sensing inversion method,the distribution of terrain reflected radiation in Fujian Province from 1988 to 2007 was simulated,and then its temporal and spatial distribution characteristics was studied.[Result] The simulation results of terrain reflected radiation in Fujian Province was credible.Terrain reflected radiation in Fujian Province was the highest in July (about 160 MJ/m2) and lowest in January (about 60 MJ/m2),and it was obviously higher from May to August compared with other months,while the order of terrain reflected radiation in four seasons was summer>spring>autumn>winter,and complex terrain affected the distribution of terrain reflected radiation greatly,especially in autumn and winter when sun elevation angle was small.In addition,terrain reflected radiation in most areas of Fujian Province was below 100 MJ/m2,and it was high in Ningde,Sanming and Nanping City in northern Fujian,while the maximum value (630 MJ/m2) could be found in Dong’an Island in Xiapu County in Ningde City and had good utilization value.[Conclusion] The study could provide theoretical foundation for the development and utilization of solar energy resources under complex terrain in China.

Theoretical analysis of ground displacements induced by deep fluid injection based on fully-coupled poroelastic simulation

Observations of surface displacements are expected to aid in geomechanical analyses of injectioninduced seismicity.However,the controlling factors of the displacement magnitude remain poorly understood except the elastic modulus of the fluid-bearing reservoir.Here,an experiment scheme of numerical simulation based on fully-coupled poroelasticity is designed to investigate the displacements induced by deep underground fluid injection.According to the sealing ability of deep reservoirs,the numerical experiments are classified into two scenarios:injection into open and sealed reservoirs.Potential effects from both geological and operational parameters are considered during the experiments,which include the hydromechanical properties,the reservoir geometry,injection rates and volumes.Experimental results reveal that in addition to the reservoir depth and Young’s modulus,the porosity also has significant influences on the surface displacements.Geodetic modeling of injection-induced displacements should include the parameter of reservoir porosity.When the reservoir is characterized by a good sealing ability,fluid injection is prone to induce larger horizontal displacements than vertical uplifts.Most of injection activities including hydraulic fracturing can probably induce detectable surface displacements.Geodetic surveying,especially using Global Navigation Satellite System(GNSS)with both horizontal and vertical observations,should become an essential monitoring task for anthropogenic fluid injection/production activities,which is conducive to assess and mitigate some geohazards including earthquakes.

Geopolymer-based modification of blasting sealing materials and optimization of blasting block size in coal seams of open pit mines

This research proposes the utilization of a geopolymer-based blasting sealing material to improve the profitability of coal sales and reduce the rate of coal fragmentation during blasting in open pit mines.The study first focused on optimizing the strength of the sealant material and reducing curing time.This was achieved by regulating the slag doping and sodium silicate solution modulus.The findings demonstrated that increasing slag content and improving the material resulted in an early rise in strength while increasing the modulus of the sodium silicate solution extended the curing time.The slag doping level was fixed at 80 g,and the sodium silicate solution modulus was set at 1.5.To achieve a strength of 3.12 MPa,the water/gel ratio was set at 0.5.The initial setting time was determined to be 33 min,meeting the required field test duration.Secondly,the strength requirements for field implementation were assessed by simulating the action time and force destruction process of the sealing material during blasting using ANSYS/LS-DYNA software.The results indicated that the modified material meets these requirements.Finally,the Shengli Open Pit Coal Mine served as the site for the field test.It was observed that the hole-sealing material’s hydration reaction created a laminated and flocculated gel inside it.This enhanced the density of the modified material.Additionally,the pregelatinized starch,functioning as an organic binder,filled the gaps between the gels,enhancing the cohesion and bonding coefficient of the material.Upon analyzing the post-blasting shooting effect diagram using the Split-Desktop software,it was determined that the utilization of the modified blast hole plugging material resulted in a decrease in the rate of coal fragmentation from 33.2%to 21.1%.This reduction exhibited a minimal error of 1.63%when compared to the field measurement,thereby providing further confirmation of the exceptional plugging capabilities of the modified material.This study significantly contributes to establishing a solid theoretical basis for enhancing the blasting efficiency of open pit mines and,in turn,enhancing their economic advantages.