Effects of operating pressure on the key parameters of coal direct chemical looping combustion

Techno-economic development of chemical looping combustion （CLC） process has been one of the most pursued research areas of the present decade due to its ability to reduce carbon foot print during utilization of coal to generate energy. Based on a 2D computational fluid dynamics model, the present work provides a computational approach to study the effect of operating pressure--a key parameter in designing of CLC reactors, on optimum operating conditions. The effects of operating pressure have been examined in terms of reactors temperature, percentage of fuel conversion and purity of carbon dioxide in fuel reactor exhaust. The simulated results show qualitative agreement with the trends obtained by other investigators during experimental studies.

Sealing capacity evaluation of underground gas storage under intricate geological conditions

Evaluating underground gas storage(UGS)sealing capacity is essential for its safe construction and operational efficiency.This involves evaluating both the static sealing capacity of traps during hydrocarbon accumulation and the dynamic sealing capacity of UGS under intensive gas injection and withdrawal,and alternating loads.This study detailed the methodology developed by Sinopec.The approach merges disciplines like geology,geomechanics,and hydrodynamics,employing both dynamic-static and qualitative-quantitative analyses.Sinopec's evaluation methods,grounded in the in situ stress analysis,include mechanistic studies,laboratory tests,geological surveys,stress analysis,and fluid-solid interactions.Through tests on the static and dynamic sealing capacity of UGS,alongside investigations into sealing mechanisms and the geological and geomechanical properties of cap rocks and faults,A geomechanics-rock damage-seepage mechanics dynamic coupling analysis method has been developed to predict in situ stress variations relative to pore pressure changes during UGS operations and evaluate fault sealing capacity and cap rock integrity,thereby setting the maximum operational pressures.Utilizing this evaluation technique,Sinopec has defined performance metrics and criteria for evaluating the sealing capacity of depleted gas reservoirs,enabling preliminary sealing capacity evaluations at UGS sites.These evaluations have significantly informed the design of UGS construction schemes and the evaluation of fault sealing capacity and cap rock integrity during UGS operations.

Research of Pipeline Pressure Based on the Reliability Theory

The former gas pipeline operating pressure transmission determined mostly according to the determined formula into the corresponding pipeline parameters are obtained, and the parameters of the actual pipeline due to many reasons, such as measurement error, production batch, etc., is not a fixed value. This paper on pipeline integrity established limit state equation, using Monte Carlo method to calculate the gas pipeline in different pressures of reliability, according to the API （American Petroleum Institute） 579 recommended target reliability to determine the operating pressure of the different regions, and design coefficient method, the calculated results are compared, results of calculation reliability is more reasonable and improve the delivery pressure of the area, the pipeline safety management provides the basis.

The New-Generation Technology for Making Petroleum Needle Coke

The current technology for producing the petroleum needle coke is apt to cause overflow of feedstock from the coke drums, instability in operation of coking unit, low mechanical strength of petroleum coke, and high percentage of coke powder, leading to difficulties in improving the overall quality of needle coke. Therefore, we have developed a new technology for producing the needle coke,featuring the manipulation of temperature range in a narrow scale at high pressure coupled with feedstock alternations. This new kind of technology has been successfully applied in a 60kt/a commercial coking unit. Provided that demand for the feedstock quality is satisfied, petroleum needle coke meeting the international quality standard can be manufactured using RIPP's technology for producing petroleum needle coke.

Aerobic granules cultivated and operated in continuous-flow bioreactor under particle-size selective pressure

A novel method based on the selective pressure of particle size （particle-size cultivation method, PSCM） was developed for the cultivation and operation of aerobic granular sludge in a continuous-flow reactor, and compared with the conventional method based on the selective pressure of settling velocity （settling-velocity cultivation method, SVCM）. Results indicated that aerobic granules could be cultivated in continuous operation mode by this developed method within 14 days. Although in the granulation process, under particle-size selective pressure, mixed liquor suspended solids （MLSS） in the reactor fluctuated greatly and filamentous bacteria dominated the sludge system during the initial operation days, no obvious difference in profile was found between the aerobic granules cultivated by PSCM and SVCM. Moreover, aerobic granules cultivated by PSCM presented larger diameter, lower water content and higher specific rates of nitrification, denitrifieation and phosphorus removal, but lower settling velocity. Under long term operation of more than 30 days, aerobic granules in the continuous-flow reactor could remain stable and obtain good chemical oxygen demand （COD）, NH4^＋-N, total nitrogen （TN） and total phosphorus （TP） removal. The results indicate that PSCM was dependent on the cultivation and maintenance of the stability of aerobic granules in continuous-flow bioreactors.

Smart computing approach for design and scale-up of conical spouted beds with open-sided draft tubes

Open-sided draft tubes provide an optimal gas distribution through a cross flow pattern between the spout and the annulus in conical spouted beds.The design,optimization,control,and scale-up of the spouted beds require precise information on operating and peak pressure drops.In this study,a multi-layer perceptron(MLP)neural network was employed for accurate prediction of these hydrodynamic characteristics.A relatively huge number of experiments were accomplished and the most influential dimensionless groups were extracted using the Buckingham-pi theorem.Then,the dimensionless groups were used for developing the MLP model for simultaneous estimation of operating and peak pressure drops.The iterative constructive technique confirmed that 4-14-2 is the best structure for the MLP model in terms of absolute average relative deviation(AARD%),mean square error(MSE),and regression coefficient(R^(2)).The developed MLP approach has an excellent capacity to predict the transformed operating(MSE=0.00039,AARD%=1.30,and R^(2)=0.76099)and peak(MSE=0.22933,AARD%=11.88,and R2=0.89867)pressure drops.