This study explores a symmetric configuration approach in anion exchange membrane(AEM)water electrolysis,focusing on overcoming adaptability challenges in dynamic conditions.Here,a rapid and mild synthesis technique f...This study explores a symmetric configuration approach in anion exchange membrane(AEM)water electrolysis,focusing on overcoming adaptability challenges in dynamic conditions.Here,a rapid and mild synthesis technique for fabricating fibrous membrane-type catalyst electrodes is developed.Our method leverages the contrasting oxidation states between the sulfur-doped NiFe(OH)2 shell and the metallic Ni core,as revealed by electron energy loss spectroscopy.Theoretical evaluations confirm that the S–NiFe(OH)_(2) active sites optimize free energy for alkaline water electrolysis intermediates.This technique bypasses traditional energy-intensive processes,achieving superior bifunctional activity beyond current benchmarks.The symmetric AEM water electrolyzer demonstrates a current density of 2 A cm^(-2) at 1.78 V at 60℃ in 1 M KOH electrolyte and also sustains ampere-scale water electrolysis below 2.0 V for 140 h even in ambient conditions.These results highlight the system's operational flexibility and structural stability,marking a significant advance-ment in AEM water electrolysis technology.展开更多
The free-piston engine generator(FPEG)is regarded as the next generation of energy conversion system which may replace traditional engines in the future.The effect of key operational parameters like excess air ratio o...The free-piston engine generator(FPEG)is regarded as the next generation of energy conversion system which may replace traditional engines in the future.The effect of key operational parameters like excess air ratio of input mixture and ignition position on the engine performance of a dual-cylinder FPEG was investigated,and their sensitivity was analyzed in this paper.The operating compression ratio of the system is susceptible to changes in excess air ratio and ignition position.At the same time,it decreases from 15.8 to 6.6 when excess air ratio increases from 0.85 to 1.15,but it increases from 6.1 to 13.3 as ignition position increases from 15 mm to 20 mm.The operating frequency and indicated power are more sensitive to changes in excess air ratio than ignition position.But it is the opposite for the indicated thermal efficiency and friction loss.Excess air ratio and ignition position have a quite similar influence on heat transfer.Therefore,from the perspective of system operation and performance,it is preferable to keep excess air coefficient slightly below 1.0.In contrast,when selecting ignition position,it is of great importance to comprehensively consider the risk of structural damage caused by the increase in the compression ratio and in-cylinder gas pressure.展开更多
As the dynamic equations of space robots are highly nonlinear,strongly coupled and nonholonomic constrained,the efficiency of current dynamic modeling algorithms is difficult to meet the requirements of real-time simu...As the dynamic equations of space robots are highly nonlinear,strongly coupled and nonholonomic constrained,the efficiency of current dynamic modeling algorithms is difficult to meet the requirements of real-time simulation.This paper combines an efficient spatial operator algebra（SOA） algorithm for base fixed robots with the conservation of linear and angular momentum theory to establish dynamic equations for the free-floating space robot,and analyzes the influence to the base body＇s position and posture when the manipulator is capturing a target.The recursive Newton-Euler kinematic equations on screw form for the space robot are derived,and the techniques of the sequential filtering and smoothing methods in optimal estimation theory are used to derive an innovation factorization and inverse of the generalized mass matrix which immediately achieve high computational efficiency.The high efficient SOA algorithm is spatially recursive and has a simple math expression and a clear physical understanding,and its computational complexity grows only linearly with the number of degrees of freedom.Finally,a space robot with three degrees of freedom manipulator is simulated in Matematica 6.0.Compared with ADAMS,the simulation reveals that the SOA algorithm is much more efficient to solve the forward and inverse dynamic problems.As a result,the requirements of real-time simulation for dynamics of free-floating space robot are solved and a new analytic modeling system is established for free-floating space robot.展开更多
Based on the solution to the Bargmann Wigner equations, a direct derivation of the projection operator and Feynman propagator for a free massive particle of arbitrary spin is worked out. The projection operator constr...Based on the solution to the Bargmann Wigner equations, a direct derivation of the projection operator and Feynman propagator for a free massive particle of arbitrary spin is worked out. The projection operator constructed by Behrends and Fronsdal is re-deduced and confirmed, and simplified in the case of half-integral spin, the general commutation rules and Feynman propagator with additional non-covariant terms for a free massive particle with any spin are derived, and explicit expressions for the propagators for spins 3/2, 2, 5/2, 3, 7/2, and 4 are provided.展开更多
Development of Shanghai Free Trade Zone, pushing up the logistics support industrial transformation and upgrading, boosting the overall domestic demand for modem logistics services. In this paper, trade logistics comp...Development of Shanghai Free Trade Zone, pushing up the logistics support industrial transformation and upgrading, boosting the overall domestic demand for modem logistics services. In this paper, trade logistics company, for example, through the report analyzes the main indicators of change in company focus on capital before and after the Shanghai Free Trade Zone, it analyze the impact and significance of argumentation Shanghai Free-Trade Zone for logistics and warehousing industry in the region, hoping to fund operations management who inspire.展开更多
为研究插入道岔施工(Turnout Inserting Construction,TIC)对既有高速道岔锁定轨温(StressFree Rail Temperature of Existing high-speed Turnout,SFRTET)的影响,提出基于双向应变法的锁定轨温变化测试方案,推导不同因素影响下的锁定...为研究插入道岔施工(Turnout Inserting Construction,TIC)对既有高速道岔锁定轨温(StressFree Rail Temperature of Existing high-speed Turnout,SFRTET)的影响,提出基于双向应变法的锁定轨温变化测试方案,推导不同因素影响下的锁定轨温变化测量原理,确定监测数据的处理方法,并开展道岔锁定轨温变化现场试验研究.研究结果表明:基于锁定轨温变化监测方法确定的传感器安装时轨温与实测数据差异仅1.4%,验证了测试方案的合理性和数据处理方法的正确性;高速道岔的锁定轨温会受插入道岔各工序施工的影响,其在轨道结构拆除、轨道结构施工、道岔形位精调和工电联调3个工序中表现出显著的动态变化特征,即锁定轨温经历多次循环变化才达到稳定状态;既有高速道岔锁定轨温受侧股钢轨重新焊接施工影响最为显著,尤其是靠近焊接位置的侧股钢轨,其锁定轨温变化达12.87℃,建议侧股钢轨重新焊接工序尽可能选择在轨温接近既有道岔原锁定轨温时开展.展开更多
基金This research was supported by the“Regional Innovation Strategy(RIS)”through the National Research Foundation of Korea(NRF)funded by the Ministry of Education(MOE)(2021RIS-002)This work was supported by an NRF grant funded by the Ministry of Science,ICT,and Future Planning(No.NRF-2018R1C1B6005009,NRF-2021R1C1C1012676,and 2009-0082580).
文摘This study explores a symmetric configuration approach in anion exchange membrane(AEM)water electrolysis,focusing on overcoming adaptability challenges in dynamic conditions.Here,a rapid and mild synthesis technique for fabricating fibrous membrane-type catalyst electrodes is developed.Our method leverages the contrasting oxidation states between the sulfur-doped NiFe(OH)2 shell and the metallic Ni core,as revealed by electron energy loss spectroscopy.Theoretical evaluations confirm that the S–NiFe(OH)_(2) active sites optimize free energy for alkaline water electrolysis intermediates.This technique bypasses traditional energy-intensive processes,achieving superior bifunctional activity beyond current benchmarks.The symmetric AEM water electrolyzer demonstrates a current density of 2 A cm^(-2) at 1.78 V at 60℃ in 1 M KOH electrolyte and also sustains ampere-scale water electrolysis below 2.0 V for 140 h even in ambient conditions.These results highlight the system's operational flexibility and structural stability,marking a significant advance-ment in AEM water electrolysis technology.
基金Projects(51675043,52005038)supported by the National Natural Science Foundation of China。
文摘The free-piston engine generator(FPEG)is regarded as the next generation of energy conversion system which may replace traditional engines in the future.The effect of key operational parameters like excess air ratio of input mixture and ignition position on the engine performance of a dual-cylinder FPEG was investigated,and their sensitivity was analyzed in this paper.The operating compression ratio of the system is susceptible to changes in excess air ratio and ignition position.At the same time,it decreases from 15.8 to 6.6 when excess air ratio increases from 0.85 to 1.15,but it increases from 6.1 to 13.3 as ignition position increases from 15 mm to 20 mm.The operating frequency and indicated power are more sensitive to changes in excess air ratio than ignition position.But it is the opposite for the indicated thermal efficiency and friction loss.Excess air ratio and ignition position have a quite similar influence on heat transfer.Therefore,from the perspective of system operation and performance,it is preferable to keep excess air coefficient slightly below 1.0.In contrast,when selecting ignition position,it is of great importance to comprehensively consider the risk of structural damage caused by the increase in the compression ratio and in-cylinder gas pressure.
基金supported by National Natural Science Foundation of China (Grant No. 50375071)Commission of Science, Technology and Industry for National Defense Pre-research Foundation of China (Grant No. C4220062501)
文摘As the dynamic equations of space robots are highly nonlinear,strongly coupled and nonholonomic constrained,the efficiency of current dynamic modeling algorithms is difficult to meet the requirements of real-time simulation.This paper combines an efficient spatial operator algebra（SOA） algorithm for base fixed robots with the conservation of linear and angular momentum theory to establish dynamic equations for the free-floating space robot,and analyzes the influence to the base body＇s position and posture when the manipulator is capturing a target.The recursive Newton-Euler kinematic equations on screw form for the space robot are derived,and the techniques of the sequential filtering and smoothing methods in optimal estimation theory are used to derive an innovation factorization and inverse of the generalized mass matrix which immediately achieve high computational efficiency.The high efficient SOA algorithm is spatially recursive and has a simple math expression and a clear physical understanding,and its computational complexity grows only linearly with the number of degrees of freedom.Finally,a space robot with three degrees of freedom manipulator is simulated in Matematica 6.0.Compared with ADAMS,the simulation reveals that the SOA algorithm is much more efficient to solve the forward and inverse dynamic problems.As a result,the requirements of real-time simulation for dynamics of free-floating space robot are solved and a new analytic modeling system is established for free-floating space robot.
基金The project supported partially by National Natural Science Foundation of China under Grant Nos.19947001,90103010,and 19991480+2 种基金the Foundation of National Key Program for Basic Research of China under Grant No.2001CCB01000the Doctoral Program Foundation
文摘Based on the solution to the Bargmann Wigner equations, a direct derivation of the projection operator and Feynman propagator for a free massive particle of arbitrary spin is worked out. The projection operator constructed by Behrends and Fronsdal is re-deduced and confirmed, and simplified in the case of half-integral spin, the general commutation rules and Feynman propagator with additional non-covariant terms for a free massive particle with any spin are derived, and explicit expressions for the propagators for spins 3/2, 2, 5/2, 3, 7/2, and 4 are provided.
文摘Development of Shanghai Free Trade Zone, pushing up the logistics support industrial transformation and upgrading, boosting the overall domestic demand for modem logistics services. In this paper, trade logistics company, for example, through the report analyzes the main indicators of change in company focus on capital before and after the Shanghai Free Trade Zone, it analyze the impact and significance of argumentation Shanghai Free-Trade Zone for logistics and warehousing industry in the region, hoping to fund operations management who inspire.
文摘为研究插入道岔施工(Turnout Inserting Construction,TIC)对既有高速道岔锁定轨温(StressFree Rail Temperature of Existing high-speed Turnout,SFRTET)的影响,提出基于双向应变法的锁定轨温变化测试方案,推导不同因素影响下的锁定轨温变化测量原理,确定监测数据的处理方法,并开展道岔锁定轨温变化现场试验研究.研究结果表明:基于锁定轨温变化监测方法确定的传感器安装时轨温与实测数据差异仅1.4%,验证了测试方案的合理性和数据处理方法的正确性;高速道岔的锁定轨温会受插入道岔各工序施工的影响,其在轨道结构拆除、轨道结构施工、道岔形位精调和工电联调3个工序中表现出显著的动态变化特征,即锁定轨温经历多次循环变化才达到稳定状态;既有高速道岔锁定轨温受侧股钢轨重新焊接施工影响最为显著,尤其是靠近焊接位置的侧股钢轨,其锁定轨温变化达12.87℃,建议侧股钢轨重新焊接工序尽可能选择在轨温接近既有道岔原锁定轨温时开展.
