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Process Parameters Optimization of Laser Cladding for HT200 with 316L Coating Based on Response Surface Method
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作者 KONG Huaye ZHU Xijing +2 位作者 LI Zejun ZHANG Jinzhe LI Zuoxiu 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第6期1569-1579,共11页
In order to improve the sealing surface performance of gray cast iron gas gate valves and achieve precise molding control of the cladding layer,as well as to reveal the influence of laser cladding process parameters o... In order to improve the sealing surface performance of gray cast iron gas gate valves and achieve precise molding control of the cladding layer,as well as to reveal the influence of laser cladding process parameters on the morphology and structure of the cladding layer,we prepared the 316L coating on HT 200 by using Design-Expert software central composite design(CCD)based on response surface analysis.We built a regression prediction model and analyzed the ANOVA with the inspection results.With a target cladding layer width of 3.5 mm and height of 1.3 mm,the process parameters were optimized to obtain the best combination of process parameters.The microstructure,phases,and hardness variations of the cladding layer from experiments with optimal parameters were analyzed by the metallographic microscope,confocal microscope,and microhardness instrument.The experimental results indicate that laser power has a significant impact on the cladding layer width,followed by powder feed rate;scan speed has a significant impact on the cladding layer height,followed by powder feed rate.The HT200 substrate and 316L can metallurgically bond well,and the cladding layer structure consists of dendritic crystals,columnar crystals,and equiaxed crystals in sequence.The optimal process parameter combination satisfying the morphology requirements is laser power(A)of 1993 W,scan speed(B)of 8.949 mm/s,powder feed rate(C)of 1.408 r/min,with a maximum hardness of 1564.3 HV0.5,significantly higher than the hardness of the HT200 substrate. 展开更多
关键词 HT200 laser cladding 316L stainless steel response surface methodology process parameter optimization
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Optimization Study of Active-Passive Heating System Parameters in Village Houses in the Southern Xinjiang Province
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作者 Xiaodan Wu Jie Li +1 位作者 Yongbin Cai Sihui Huang 《Energy Engineering》 EI 2024年第7期1963-1990,共28页
Aiming at the problems of large energy consumption and serious pollution of winter heating existing in the rural buildings in Southern Xinjiang,a combined active-passive heating system was proposed,and the simulation ... Aiming at the problems of large energy consumption and serious pollution of winter heating existing in the rural buildings in Southern Xinjiang,a combined active-passive heating system was proposed,and the simulation software was used to optimize the parameters of the system,according to the parameters obtained from the optimization,a test platform was built and winter heating test was carried out.The simulation results showed that the thickness of the air layer of 75 mm,the total area of the vent holes of 0.24 m^(2),and the thickness of the insulation layer of 120 mm were the optimal construction for the passive part;solar collector area of 28 m^(2),hot water storage tank volume of 1.4 m^(3),mass flow rate of 800 kg/h on the collector side,mass flow rate of 400 kg/h on the heat exchanger side,and output power of auxiliary heat source of 5∼9 kWwere the optimal constructions for active heating system.Test results showed that during the heating period,the system could provide sufficient heat to the room under different heating modes,and the indoor temperature reached over 18°C,which met the heating demand.The economic and environmental benefits of the system were analyzed,and the economic benefits of the systemwere better than coal-fired heating,and the CO_(2) emissionswere reduced by 3,292.25 kg compared with coalfiredheating.The results of the study showed that the combinedactive-passiveheating systemcouldeffectively solve the heating problems existing in rural buildings in Southern Xinjiang,and it also laid the theoretical foundation for the popularization of the combined heating systems. 展开更多
关键词 Trombe wall biomass boilers active-passive combined heating systems parameter optimization villages and towns
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High temperature deformation behavior and optimization of hot compression process parameters in TC11 titanium alloy with coarse lamellar original microstructure 被引量:4
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作者 鲁世强 李鑫 +2 位作者 王克鲁 董显娟 傅铭旺 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2013年第2期353-360,共8页
The high temperature deformation behaviors of α+β type titanium alloy TC11 (Ti-6.5Al-3.5Mo-1.5Zr-0.3Si) with coarse lamellar starting microstructure were investigated based on the hot compression tests in the tem... The high temperature deformation behaviors of α+β type titanium alloy TC11 (Ti-6.5Al-3.5Mo-1.5Zr-0.3Si) with coarse lamellar starting microstructure were investigated based on the hot compression tests in the temperature range of 950-1100 ℃ and the strain rate range of 0.001-10 s-1. The processing maps at different strains were then constructed based on the dynamic materials model, and the hot compression process parameters and deformation mechanism were optimized and analyzed, respectively. The results show that the processing maps exhibit two domains with a high efficiency of power dissipation and a flow instability domain with a less efficiency of power dissipation. The types of domains were characterized by convergence and divergence of the efficiency of power dissipation, respectively. The convergent domain in a+fl phase field is at the temperature of 950-990 ℃ and the strain rate of 0.001-0.01 s^-1, which correspond to a better hot compression process window of α+β phase field. The peak of efficiency of power dissipation in α+β phase field is at 950 ℃ and 0.001 s 1, which correspond to the best hot compression process parameters of α+β phase field. The convergent domain in β phase field is at the temperature of 1020-1080 ℃ and the strain rate of 0.001-0.1 s^-l, which correspond to a better hot compression process window of β phase field. The peak of efficiency of power dissipation in ℃ phase field occurs at 1050 ℃ over the strain rates from 0.001 s^-1 to 0.01 s^-1, which correspond to the best hot compression process parameters of ,8 phase field. The divergence domain occurs at the strain rates above 0.5 s^-1 and in all the tested temperature range, which correspond to flow instability that is manifested as flow localization and indicated by the flow softening phenomenon in stress-- strain curves. The deformation mechanisms of the optimized hot compression process windows in a+β and β phase fields are identified to be spheroidizing and dynamic recrystallizing controlled by self-diffusion mechanism, respectively. The microstructure observation of the deformed specimens in different domains matches very well with the optimized results. 展开更多
关键词 titanium alloy coarse lamellar microstructure high temperature deformation behavior processing map hot compression process parameter optimization
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Application of EBSD technique to ultrafine grained and nanostructured materials processed by severe plastic deformation:Sample preparation, parameters optimization and analysis 被引量:2
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作者 陈勇军 Jarle HJELEN Hans J.ROVEN 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2012年第8期1801-1809,共9页
With the help of FESEM, high resolution electron backscatter diffraction can investigate the grains/subgrains as small as a few tens of nanometers with a good angular resolution (~0.5°). Fast development of EBS... With the help of FESEM, high resolution electron backscatter diffraction can investigate the grains/subgrains as small as a few tens of nanometers with a good angular resolution (~0.5°). Fast development of EBSD speed (up to 1100 patterns per second) contributes that the number of published articles related to EBSD has been increasing sharply year by year. This paper reviews the sample preparation, parameters optimization and analysis of EBSD technique, emphasizing on the investigation of ultrafine grained and nanostructured materials processed by severe plastic deformation (SPD). Detailed and practical parameters of the electropolishing, silica polishing and ion milling have been summarized. It is shown that ion milling is a real universal and promising polishing method for EBSD preparation of almost all materials. There exists a maximum value of indexed points as a function of step size. The optimum step size depends on the magnification and the board resolution/electronic step size. Grains/subgrains and texture, and grain boundary structure are readily obtained by EBSD. Strain and stored energy may be analyzed by EBSD. 展开更多
关键词 electron backscatter diffraction (EBSD) sample preparation parameters optimization step size severe plastic deformation (SPD)
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Machine tool selection based on fuzzy evaluation and optimization of cutting parameters
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作者 张保平 关世玺 +2 位作者 张博 王斌 田甜 《Journal of Measurement Science and Instrumentation》 CAS CSCD 2015年第4期384-389,共6页
The paper analyzes the factors influencing machine tool selection. By using fuzzy mathematics theory, we establish a theorietical model for optimal machine tool selection considering geometric features, clamping size,... The paper analyzes the factors influencing machine tool selection. By using fuzzy mathematics theory, we establish a theorietical model for optimal machine tool selection considering geometric features, clamping size, machining range, machining precision and surface roughness. By means of fuzzy comprehensive evaluation method, the membership degree of machine tool selection and the largest comprehensive evaluation index are determined. Then the reasonably automatic selection of machine tool is realized in the generative computer aided process planning (CAPP) system. Finally, the finite element model based on ABAQUS is established and the cutting process of machine tool is simulated. According to the theoretical and empirical cutting parameters and the curve of surface residual stress, the optimal cutting parameters can be determined. 展开更多
关键词 fuzzy evaluation machine selection computer aided process planning(CAPP) parameter optimization
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Optimization of Honing Wheel Structure Parameters in Ultra-precision Plane Honing
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作者 SYOJI Katsuo 《厦门大学学报(自然科学版)》 CAS CSCD 北大核心 2002年第S1期57-58,共2页
Free abrasive particle machining in simple machine such as: honing, polishing can get higher surface finish mirror, but surface error, and working procedure is hard to control. Therefore, the vertical disposed ultra-p... Free abrasive particle machining in simple machine such as: honing, polishing can get higher surface finish mirror, but surface error, and working procedure is hard to control. Therefore, the vertical disposed ultra-precision plane honing method by ultra-particle diamond honing wheel is put forward to. The results of experiments indicate: plane-honing wheel has higher machining accuracy and machining efficiency. But at the same time the structure parameters of honing wheel effects on machining accuracy. By analyzing the relation of honing wheel structure parameters and workpiece machining accuracy, the relation of honing wheel and wear coefficient, then this paper gets honing wheel structure parameters in the condition of best accuracy coefficient and wear coefficient, and resolve the problem of choosing honing wheel structure parameters in ultra-precision plane honing at last. This paper analyses the relation of honing wheel structure parameters and workpiece machining accuracy coefficient and wear coefficient, by building relative movement math model of honing wheel and workpiece in plane honing. Through theory calculating, the result indicate: about honing machine tools for large volume manufacture, honing wheel wear is main effect factor, so honing wheel should adopt obverse triangle radial structure. About honing machining for high accuracy and low-batch quantities, machining accuracy coefficient is main factors; so honing wheel should adopt reverse triangle radial structure. Neglected the manufacturing factors of honing wheel, then we can design honing wheel with high power curve structure to meet the need of machining accuracy coefficient and honing wheel wear coefficient in higher accuracy honing. 展开更多
关键词 ultra-precision plane honing honing wheel structure machining accuracy optimization parameters
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Parameters optimization of electroless deposition of Cu on Cr-coated diamond 被引量:5
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作者 A.R.NIAZI 李树奎 +3 位作者 王迎春 刘金旭 呼陟宇 Zahid USMAN 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2014年第1期136-145,共10页
Electroless copper plating on diamond particles precoated with 1%Cr was carried out to evaluate the effects of various experimental parameters on coating quality and deposition rate to obtain the optimized reaction pa... Electroless copper plating on diamond particles precoated with 1%Cr was carried out to evaluate the effects of various experimental parameters on coating quality and deposition rate to obtain the optimized reaction parameters. The formulated samples under optimized parameters were characterized by X-ray diffraction, scanning electron microscopy, energy dispersive spectroscopy, X-ray photoelectron spectra and optical microscopy. The best parameters, where uniform and maximum coating thickness was achieved, are etching with 20%NaOH for 30 min, sensitization and activation with SnCl2 and PdCl2 for 5 and 20 min, respectively. The composition of the copper solution bath was 16 g/L CuSO4&#183;5H2O, 35 mL/L formaldehyde (HCHO), 23 g/L KNaC4H4O6 at 60 ℃, pH=13 and stirring at (350±15) r/min under ultrasonication. 展开更多
关键词 electroless copper plating Cr-coated diamond parameter optimization
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Parameters Optimization of a Novel 5-DOF Gasbag Polishing Machine Tool 被引量:8
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作者 LI Yanbiao TAN Dapeng +2 位作者 WEN Donghui JI Shiming CAI Donghai 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2013年第4期680-688,共9页
The research on the parameters optimization for gasbag polishing machine tools, mainly aims at a better kinematics performance and a design scheme. Serial structural arm is mostly employed in gasbag polishing machine ... The research on the parameters optimization for gasbag polishing machine tools, mainly aims at a better kinematics performance and a design scheme. Serial structural arm is mostly employed in gasbag polishing machine tools at present, but it is disadvantaged by its complexity, big inertia, and so on. In the multi-objective parameters optimization, it is very difficult to select good parameters to achieve excellent performance of the mechanism. In this paper, a statistics parameters optimization method based on index atlases is presented for a novel 5-DOF gasbag polishing machine tool. In the position analyses, the structure and workspace for a novel 5-DOF gasbag polishing machine tool is developed, where the gasbag polishing machine tool is advantaged by its simple structure, lower inertia and bigger workspace. In the kinematics analyses, several kinematics performance evaluation indices of the machine tool are proposed and discussed, and the global kinematics performance evaluation atlases are given. In the parameters optimization process, considering the assembly technique, a design scheme of the 5-DOF gasbag polishing machine tool is given to own better kinematics performance based on the proposed statistics parameters optimization method, and the global linear isotropic performance index is 0.5, the global rotational isotropic performance index is 0.5, the global linear velocity transmission performance index is 1.012 3 m/s in the case of unit input matrix, the global rotational velocity transmission performance index is 0.102 7 rad/s in the case of unit input matrix, and the workspace volume is 1. The proposed research provides the basis for applications of the novel 5-DOF gasbag polishing machine tool, which can be applied to the modern industrial fields requiring machines with lower inertia, better kinematics transmission performance and better technological efficiency. 展开更多
关键词 5-DOF gasbag polishing machine tool evaluation index kinematics analyses parameter optimization
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Optimization of Cutting Parameters for Trade-off Among Carbon Emissions, Surface Roughness, and Processing Time 被引量:4
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作者 Zhipeng Jiang Dong Gao +1 位作者 Yong Lu Xianli Liu 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2019年第6期124-141,共18页
As the manufacturing industry is facing increasingly serious environmental problems, because of which carbon tax policies are being implemented, choosing the optimum cutting parameters during the machining process is ... As the manufacturing industry is facing increasingly serious environmental problems, because of which carbon tax policies are being implemented, choosing the optimum cutting parameters during the machining process is crucial for automobile panel dies in order to achieve synergistic minimization of the environment impact, product quality, and processing efficiency. This paper presents a processing task-based evaluation method to optimize the cutting parameters, considering the trade-off among carbon emissions, surface roughness, and processing time. Three objective models and their relationships with the cutting parameters were obtained through input–output, response surface, and theoretical analyses, respectively. Examples of cylindrical turning were applied to achieve a central composite design(CCD), and relative validation experiments were applied to evaluate the proposed method. The experiments were conducted on the CAK50135 di lathe cutting of AISI 1045 steel, and NSGA-Ⅱ was used to obtain the Pareto fronts of the three objectives. Based on the TOPSIS method, the Pareto solution set was ranked to find the optimal solution to evaluate and select the optimal cutting parameters. An S/N ratio analysis and contour plots were applied to analyze the influence of each decision variable on the optimization objective. Finally, the changing rules of a single factor for each objective were analyzed. The results demonstrate that the proposed method is effective in finding the trade-off among the three objectives and obtaining reasonable application ranges of the cutting parameters from Pareto fronts. 展开更多
关键词 Automobile panel dies Carbon emission Parameter optimization Multi-objective optimization NSGA-Ⅱ
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Optimization of investment casting process parameters to reduce warpage of turbine blade platform in DD6 alloy 被引量:4
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作者 Jia-wei Tian Kun Bu +5 位作者 Jin-hui Song Guo-liang Tian Fei Qiu Dan-qing Zhao Zong-li Jin Yang Li 《China Foundry》 SCIE 2017年第6期469-477,共9页
The large warping deformation at platform of turbine blade directly affects the forming precision. In the present research, equivalent warping deformation was firstly presented to describe the extent of deformation at... The large warping deformation at platform of turbine blade directly affects the forming precision. In the present research, equivalent warping deformation was firstly presented to describe the extent of deformation at platform. To optimize the process parameters during investment casting to minimize the warping deformation of the platform, based on simulation with Pro CAST, the single factor method, orthogonal test, neural network and genetic algorithm were subsequently used to analyze the influence of pouring temperature, shell mold preheating temperature, furnace temperature and withdrawal velocity on dimensional accuracy of the platform of superalloyDD6 turbine blade. The accuracy of investment casting simulation was verified by measurement of platform at blade casting. The simulation results with the optimal process parameters illustrate that the equivalent warping deformation was dramatically reduced by 21.8% from 0.232295 mm to 0.181698 mm. 展开更多
关键词 PROCAST optimization of process parameters warping deformation of platform orthogonal test genetic algorithm BP-neural network
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Optimization of projectile aerodynamic parameters based on hybrid genetic algorithm
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作者 刘霖 田晓丽 +2 位作者 高小东 甘桃元 佘新继 《Journal of Measurement Science and Instrumentation》 CAS CSCD 2015年第4期364-367,共4页
Aerodynamic parameters are important factors that affect projectile flight movement. To obtain accurate aerodynamic parameters, a hybrid genetic algorithm is proposed to identify and optimize the aerodynamic parameter... Aerodynamic parameters are important factors that affect projectile flight movement. To obtain accurate aerodynamic parameters, a hybrid genetic algorithm is proposed to identify and optimize the aerodynamic parameters of projectile. By combining the traditional simulated annealing method that is easy to fall into local optimum solution but hard to get global parameters with the genetic algorithm that has good global optimization ability but slow local optimization ability, the hybrid genetic algo- rithm makes full use of the advantages of the two algorithms for the optimization of projectile aerodynamic parameters. The simulation results show that the hybrid genetic algorithm is better than a single algorithm. 展开更多
关键词 projectile aerodynamic parameters parameter optimization hybrid genetic algorithm
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Interpretable machine learning optimization(InterOpt)for operational parameters:A case study of highly-efficient shale gas development 被引量:2
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作者 Yun-Tian Chen Dong-Xiao Zhang +1 位作者 Qun Zhao De-Xun Liu 《Petroleum Science》 SCIE EI CAS CSCD 2023年第3期1788-1805,共18页
An algorithm named InterOpt for optimizing operational parameters is proposed based on interpretable machine learning,and is demonstrated via optimization of shale gas development.InterOpt consists of three parts:a ne... An algorithm named InterOpt for optimizing operational parameters is proposed based on interpretable machine learning,and is demonstrated via optimization of shale gas development.InterOpt consists of three parts:a neural network is used to construct an emulator of the actual drilling and hydraulic fracturing process in the vector space(i.e.,virtual environment);:the Sharpley value method in inter-pretable machine learning is applied to analyzing the impact of geological and operational parameters in each well(i.e.,single well feature impact analysis):and ensemble randomized maximum likelihood(EnRML)is conducted to optimize the operational parameters to comprehensively improve the efficiency of shale gas development and reduce the average cost.In the experiment,InterOpt provides different drilling and fracturing plans for each well according to its specific geological conditions,and finally achieves an average cost reduction of 9.7%for a case study with 104 wells. 展开更多
关键词 Interpretable machine learning Operational parameters optimization Shapley value Shale gas development Neural network
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Parameters Optimization and Energy-Saving of Highway Tunnel Backlighting with LED 被引量:2
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作者 杨超 范士娟 《Journal of Donghua University(English Edition)》 EI CAS 2017年第1期9-13,共5页
In order to acquire the most energy-saving luminairedistribution-parameters(LDPs)of highway tunnel interior zone backlighting,the parameters optimization model(POM)of backlighting for tunnel interior zone was establis... In order to acquire the most energy-saving luminairedistribution-parameters(LDPs)of highway tunnel interior zone backlighting,the parameters optimization model(POM)of backlighting for tunnel interior zone was established.Yanlieshan tunnel of Jiujing highway was taken as an example for the optimization.The optimal LDPs of the backlighting system of the tunnel interior zone were obtained by the POM,a comparison between the optimization results and those of Yanlieshan tunnel’s actual lighting system was performed,which showed that the optimized backlighting system with LED lamps installed according to the optimized LDPs could save energy remarkablely even under full capacity lighting condition.Illuminance and illuminance uniformity of the tunnel road surface still met the lighting demands even the LED lamp’s luminance decreased by 30%.A backlighting simulation experiment with the optimized backlighting LDPs for Yanlieshan tunnel was accomplished in the software Dialux.The simulation results basically agreed with the optimization calculated results from the POM which proved the correctness of the backlighting POM. 展开更多
关键词 tunnel lighting parameters optimization backlighting optimization model ENERGY-SAVING
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Breakage and separation mechanism of ZGM coal mill based on parameters optimization model 被引量:5
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作者 Wei Hua He Yaqun +3 位作者 Shi Fengnian Zhou Nianxing Wang Shuai Ge Linhan 《International Journal of Mining Science and Technology》 SCIE EI 2014年第2期285-289,共5页
Sampling ports were firstly drilled on a ZGM95 coal mill in the power plant in China, and the coal samples from various points in the pulverizer were collected under the different operation conditions. The prop- erty ... Sampling ports were firstly drilled on a ZGM95 coal mill in the power plant in China, and the coal samples from various points in the pulverizer were collected under the different operation conditions. The prop- erty of the sampling material from the mill was analyzed, applying the float-sink test, size distribution analysis, proximate analysis and so on. It was indicated that the +250 I^m fraction in the pulverized fuel accounted for only 0.02%, while it was 83.2% in the new feed. The circulating ratio and coal flow in the separator and the cone zone were calculated using the mass balance of the circulating load. So, the cir- culating ratio in the separator of the pulverizer was between 8 and 13, and the circulating ratio, the feed flow of separator and cone zone all raised with the increase of the air volume. Furthermore, the parameters of the separation functions were obtained based on the fitting method. It was shown that the mean value of the shape factor B was 0.7617, and the parameter D which is the particle size at 50% cumulative yield in the separator almost kept unchanged. 展开更多
关键词 ZGM mill Coal grinding parameters optimization Mass balance
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Parameters Optimization of the Heating Furnace Control Systems Based on BP Neural Network Improved by Genetic Algorithm 被引量:4
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作者 Qiong Wang Xiaokan Wang 《Journal on Internet of Things》 2020年第2期75-80,共6页
The heating technological requirement of the conventional PID control is difficult to guarantee which based on the precise mathematical model,because the heating furnace for heating treatment with the big inertia,the ... The heating technological requirement of the conventional PID control is difficult to guarantee which based on the precise mathematical model,because the heating furnace for heating treatment with the big inertia,the pure time delay and nonlinear time-varying.Proposed one kind optimized variable method of PID controller based on the genetic algorithm with improved BP network that better realized the completely automatic intelligent control of the entire thermal process than the classics critical purporting(Z-N)method.A heating furnace for the object was simulated with MATLAB,simulation results show that the control system has the quicker response characteristic,the better dynamic characteristic and the quite stronger robustness,which has some promotional value for the control of industrial furnace. 展开更多
关键词 Genetic algorithm parameter optimization PID control BP neural network heating furnace
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Multi-channel signal parameters joint optimization for GNSS terminals 被引量:1
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作者 WANG Qian ZHANG Chuanding XIAN Deyong 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2018年第1期39-47,共9页
Traditional global navigation satellite system(GNSS)terminals for satellite navigation adopt independent channels to track the signals from different satellites, which results in a lack of information interaction betw... Traditional global navigation satellite system(GNSS)terminals for satellite navigation adopt independent channels to track the signals from different satellites, which results in a lack of information interaction between the channels. Inspired by the vector tracking idea, and drawing lessons from the principle that in the position domain the Taylor expanded pseudorange observations can be used for positioning via the least squares method, this paper proposes a novel least squares-based multi-channel parameter joint estimation(MPJE) method in the signal domain, which not only retains the advantages of channel fusion, but also maintains the flexibility and diversity of the localization algorithm. With achieving optimal carrier to noise ratio as the goal, the proposed method obtains the required code loop and carrier loop parameters for signal tracking in the domain of whole channels. Experimental results indicate that this method fully achieves the assistant fusion advantages of frequency lock loop(FLL), phase lock loop(PLL)and delay lock loop(DLL), making good use of the robustness and dynamic properties of the FLL and the measurement accuracy of the DLL, and is helpful for achieving stable and accurate signal tracking under weak signals and high dynamic stress environments. 展开更多
关键词 least squares method signal parameter optimization vector tracking global navigation satellite system(GNSS) weight matrix
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Optimization of parameters, characterization and thermal property analysis of hafnium ethoxide synthesized by electrochemical method
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作者 Chang-hong WANG Sheng-hai YANG +3 位作者 Yong-ming CHEN Yan-zeng WU Jing HE Chao-bo TANG 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2017年第3期694-700,共7页
Hafnium ethoxide was synthesized using electrochemical method.Optimization experiments were used to optimizevarious parameters namely Et4NBr concentration(c):0.01?0.06mol/L,solution temperature(t):30?78°C,polar d... Hafnium ethoxide was synthesized using electrochemical method.Optimization experiments were used to optimizevarious parameters namely Et4NBr concentration(c):0.01?0.06mol/L,solution temperature(t):30?78°C,polar distance(D):2.0?4.0cm and current density(J):100?400A/m2.The electrolytic products obtained under optimum conditions of c=0.04mol/L,t=78°C,D=2.0cm and J=100A/m2were further isolated by vacuum distillation under5kPa.The product was characterized byFourier transform infrared(FT-IR)spectra,nuclear magnetic resonance(NMR)spectra.The results indicated that the product washafnium ethoxide.ICP analysis suggested that the content of hafnium ethoxide in the final product exceeded99.997%.Thermalproperties of the product were analyzed by TG/DTG.The vaporization enthalpy of hafnium ethoxide was found to be79.1kJ/mol.The result confirmed that hafnium ethoxide was suitable for the preparation of hafnium oxide by atomic layer deposition. 展开更多
关键词 hafnium ethoxide electrochemical synthesis parameter optimization CHARACTERIZATION thermal analysis
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Study on optimization of parameters in a biological model
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作者 Wan Zhenwen, Qiao Fangli, Yuan Yeli (1. First Institute of Oceanography, State Oceanic Administration, Qingdao 266061, China) 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2001年第2期215-220,共6页
According to the data observed in a China- Japan Joint Investigation, the parameters of an ecosystem dynamics model (Qiao et al., 2000) were optimized. The values of eighteen parameters for the model were obtained, wi... According to the data observed in a China- Japan Joint Investigation, the parameters of an ecosystem dynamics model (Qiao et al., 2000) were optimized. The values of eighteen parameters for the model were obtained, with nutrient half saturation constant, Kn= 1.4μmol/dm3, Kp = 0.129 μmol/dm3 and K3= 1. 16μmol/dm3 for the diatom and Kn= 0.345μmol/dm3, Kp=0. 113μmol/dm3 for the flagellate. The proposals to set up a function for this multiple objective problem were discussed in detail. 展开更多
关键词 PHYTOPLANKTON biological model parameter optimization
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Pulsed gas–liquid discharge plasma catalytic degradation of bisphenol A over graphene/Cd S:process parameters optimization and O_(3)activation mechanism analysis
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作者 姜楠 李学川 +4 位作者 李举 李杰 廖兵 彭邦发 刘国 《Plasma Science and Technology》 SCIE EI CAS CSCD 2023年第10期81-90,共10页
In the present work,pulsed gas–liquid hybrid discharge plasma coupled with graphene/Cd S catalyst was evaluated to eliminate bisphenol A(BPA)in wastewater.The optimization of a series of process parameters was perfor... In the present work,pulsed gas–liquid hybrid discharge plasma coupled with graphene/Cd S catalyst was evaluated to eliminate bisphenol A(BPA)in wastewater.The optimization of a series of process parameters was performed in terms of BPA degradation performance.The experimental results demonstrated that nearly 90%of BPA(20 mg l^(-1))in the synthetic wastewater(p H=7.5,σ=10μS m^(-1))was degraded by the plasma catalytic system over 0.2 g l^(-1)graphene/Cd S at 19k V with a 4 l min^(-1)air flow rate and 10 mm electrode gap within 60 min.The BPA removal rate increased with increasing the discharge voltage and decreasing the initial BPA concentration or solution conductivity.Nevertheless,either too high or too low an air flow rate,electrode gap,catalyst dosage or initial solution p H would lead to a decrease in BPA degradation.Moreover,optical emission spectroscopy was used to gain information on short-lived reactive species formed from the pulsed gas–liquid hybrid discharge plasma system.The results indicated the existence of several highly oxidative free radicals such as·O and·OH.Finally,the activation pathway of O_(3)on the catalyst surface was analyzed by density functional theory. 展开更多
关键词 pulsed discharge gas-liquid discharge wastewater treatment parameters optimization DFT calculation
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Investigation of influence factors on CO_(2) flowback characteristics and optimization of flowback parameters during CO_(2) dry fracturing in tight gas reservoirs
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作者 Xiao-Mei Zhou Lei Li +4 位作者 Yong-Quan Sun Ran Liu Ying-Chun Guo Yong-Mao Hao Yu-Liang Su 《Petroleum Science》 SCIE EI CAS CSCD 2023年第6期3553-3566,共14页
CO_(2) dry fracturing is a promising alternative method to water fracturing in tight gas reservoirs,especially in water-scarce areas such as the Loess Plateau.The CO_(2) flowback efficiency is a critical factor that a... CO_(2) dry fracturing is a promising alternative method to water fracturing in tight gas reservoirs,especially in water-scarce areas such as the Loess Plateau.The CO_(2) flowback efficiency is a critical factor that affects the final gas production effect.However,there have been few studies focusing on the flowback characteristics after CO_(2) dry fracturing.In this study,an extensive core-to-field scale study was conducted to investigate CO_(2) flowback characteristics and CH_(4) production behavior.Firstly,to investigate the impact of core properties and production conditions on CO_(2) flowback,a series of laboratory experiments at the core scale were conducted.Then,the key factors affecting the flowback were analyzed using the grey correlation method based on field data.Finally,taking the construction parameters of Well S60 as an example,a dual-permeability model was used to characterize the different seepage fields in the matrix and fracture for tight gas reservoirs.The production parameters after CO_(2) dry fracturing were then optimized.Experimental results demonstrate that CO_(2) dry fracturing is more effective than slickwater fracturing,with a 9.2%increase in CH_(4) recovery.The increase in core permeability plays a positive role in improving CH_(4) production and CO_(2) flowback.The soaking process is mainly affected by CO_(2) diffusion,and the soaking time should be controlled within 12 h.Increasing the flowback pressure gradient results in a significant increase in both CH_(4) recovery and CO_(2) flowback efficiency.While,an increase in CO_(2) injection is not conducive to CH_(4) production and CO_(2) flowback.Based on the experimental and field data,the important factors affecting flowback and production were comprehensively and effectively discussed.The results show that permeability is the most important factor,followed by porosity and effective thickness.Considering flowback efficiency and the influence of proppant reflux,the injection volume should be the minimum volume that meets the requirements for generating fractures.The soaking time should be short which is 1 day in this study,and the optimal bottom hole flowback pressure should be set at 10 MPa.This study aims to improve the understanding of CO_(2) dry fracturing in tight gas reservoirs and provide valuable insights for optimizing the process parameters. 展开更多
关键词 CO_(2)fracturing Tight gas reservoir Fracturing fluid flowback Parameter optimization
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