This research aimed to investigate the changing mechanism of hydro-geochemistry in Ordovician limestone karst(OL) water induced by mountainous coal mining activities. Thus, the hydrogeochemistry evolution of OL water ...This research aimed to investigate the changing mechanism of hydro-geochemistry in Ordovician limestone karst(OL) water induced by mountainous coal mining activities. Thus, the hydrogeochemistry evolution of OL water over 40 years within a typical northern mountainous coal mine named Fengfeng Mine was studied by using Piper diagram, Gibbs scheme, ions correlation and Principal component analysis(PCA) methods. Results showed that, except for HCO3^-, the ions of Ca^2+, Mg^2+, SO4^2-,Na^++K^+, Cl^- and total dissolution solids(TDS) values all increased by years as mining continues. Different hydro-geochemical characteristics in different periods can reflect different water-rock interactions.Accordingly, sulfates dissolution gradually took place of carbonates in water-rock interaction. Especially,OL water-rock interactions in different periods were all affected by rock weathering and evaporationconcentration together. At last, evaporationconcentration co-effect dominated the hydrogeochemistry evolution slowly, along with significant cations exchange over years.展开更多
基金Key Laboratory of Water Resource Protection and Utilization in Coal Mining(Grant No.SHJT-17-42.17)Fundamental Research Funds for the Central Universities of China(Grant Nos.3142018009,3142017100)Key Laboratory of Mine Geological Hazards Mechanism and Control Project(KF2017-13).Figure 7 PCA plot of hydro-chemistry of Ordovician limestone karst(OL)water samples from different years.
文摘This research aimed to investigate the changing mechanism of hydro-geochemistry in Ordovician limestone karst(OL) water induced by mountainous coal mining activities. Thus, the hydrogeochemistry evolution of OL water over 40 years within a typical northern mountainous coal mine named Fengfeng Mine was studied by using Piper diagram, Gibbs scheme, ions correlation and Principal component analysis(PCA) methods. Results showed that, except for HCO3^-, the ions of Ca^2+, Mg^2+, SO4^2-,Na^++K^+, Cl^- and total dissolution solids(TDS) values all increased by years as mining continues. Different hydro-geochemical characteristics in different periods can reflect different water-rock interactions.Accordingly, sulfates dissolution gradually took place of carbonates in water-rock interaction. Especially,OL water-rock interactions in different periods were all affected by rock weathering and evaporationconcentration together. At last, evaporationconcentration co-effect dominated the hydrogeochemistry evolution slowly, along with significant cations exchange over years.