C<sub>2</sub>6H<sub>3</sub>1GeO<sub>5</sub>P is monoclinic,space group P2<sub>1</sub>/c,a=14.287（4）,b=8.045（2）,c=23.381（6）,β=103.79（2）°,V=2622.7,Mr=527.10,...C<sub>2</sub>6H<sub>3</sub>1GeO<sub>5</sub>P is monoclinic,space group P2<sub>1</sub>/c,a=14.287（4）,b=8.045（2）,c=23.381（6）,β=103.79（2）°,V=2622.7,Mr=527.10,Z=4,Dx=1.34g/cm3,μ=12.4cm.F（000）=1096.The final R=0.051 and R<sub>w</sub>=0.057 for 2446 observed unique reflections[I≥3σ（I）.The results indicated that all non-hydrogen atoms between phosphorus and germanium in the title compound were located almost in coplane with farthest deviation of atom Ge defined by 0. 3657.The values of Ge-C（phenyl） and Ge-C（alkyl） bond distance are 1.938（5）,1.945（5） and 1.976（5）,respectively.展开更多
文摘C<sub>2</sub>6H<sub>3</sub>1GeO<sub>5</sub>P is monoclinic,space group P2<sub>1</sub>/c,a=14.287（4）,b=8.045（2）,c=23.381（6）,β=103.79（2）°,V=2622.7,Mr=527.10,Z=4,Dx=1.34g/cm3,μ=12.4cm.F（000）=1096.The final R=0.051 and R<sub>w</sub>=0.057 for 2446 observed unique reflections[I≥3σ（I）.The results indicated that all non-hydrogen atoms between phosphorus and germanium in the title compound were located almost in coplane with farthest deviation of atom Ge defined by 0. 3657.The values of Ge-C（phenyl） and Ge-C（alkyl） bond distance are 1.938（5）,1.945（5） and 1.976（5）,respectively.
