The establishment of Boron nitride@sodium alginate foam/polyethyleneglycol composite phase change materials with high thermal conductivity, shape stability, and reusability

Adopting organic phase change materials(PCMs) for the management of electronic devices is restricted by low thermal conductivity. In this paper, the composite PCMs are established by freeze-drying and vacuum impregnation. Herein, polyethylene glycol(PEG) is induced as heat storage materials, boron nitride(BN) is embedded as filler stacking in an orderly fashion on the foam walls to improve thermal conductivity and sodium alginate(SA) is formed as supporting material to keep the shape of the composite stable. X-ray diffractometry, scanning electron microscopy-energy dispersive spectrometer, thermal gravimetric analysis, thermal conductivity meter, differential scanning calorimeter, and Fourier transform infrared were used to characterize the samples and thermal cycles were employed to measure the shape stability. The results exhibit the BN@SA/PEG composite PCMs have good chemical compatibility, stable morphology, and thermal stability. Due to the high porosity of foam, PEG endows the composite PCMs with high latent heat(149.11 and 141.59 J·g^(-1)). Simultaneously, BN@SA/PEG shows an excellent heat performance with high thermal conductivity(0.99 W·m^(-1)·K^(-1)), reusability, and shape stability, contributing the composite PCMs to application in the energy storage field. This study provides a strategy to manufacture flexible, long-serving, and shape-stable PCMs via introducing BN@SA foam as a storage framework, and these PCMs have great potential in thermal management in the electronic field.

Soil Organic Carbon Pools in Particle-Size Fractions as Affected by Slope Gradient and Land Use Change in Hilly Regions,Western Iran

This study was conducted to explore the effects of topography and land use changes on particulate organic carbon(POC),particulate total nitrogen(PTN),organic carbon(OC) and total nitrogen(TN) associated with different size primary particle fractions in hilly regions of western Iran.Three popular land uses in the selected site including natural forest(NF),disturbed forest(DF) and cultivated land(CL) and three slope gradients(0-10 %,S1,10-30 %,S2,and 30-50%,S3) were employed as the basis of soil sampling.A total of 99 soil samples were taken from the 0-10 cm surface layer in the whole studied hilly region studied.The results showed that the POC in the forest land use in all slope gradients was considerably more than the deforested and cultivated lands and the highest value was observed at NF-S1 treatment with 9.13%.The values of PTN were significantly higher in the forest land use and in the down slopes(0.5%) than in the deforested and cultivated counterparts and steep slopes(0.09%) except for the CL land use.The C:N ratios in POC fraction were around 17-18 in the forest land and around 23 in the cultivated land.In forest land,the silt-associated OC was highest among the primary particles.The enrichment factor of SOC,EC,was the highest for POC.For the primary particles,EC of both primary fractions of silt and clay showed following trend for selected land uses and slope gradients:CL> DF> NF and S3 > S2> S1.Slope gradient of landscape significantly affected the OC and TN contents associated with the silt and clay particles,whereas higher OC and TN contents were observed in lower positions and the lowest value was measured in the steep slopes.Overall,the results showed that native forest land improves soil organic carbon storage and can reduce the carbon emission and soil erosion especially in the mountainous regions with high rainfall in west of Iran.

Impact of land use/cover changes on carbon storage in a river valley in arid areas of Northwest China

Soil carbon pools could become a CO_2 source or sink, depending on the directions of land use/cover changes. A slight change of soil carbon will inevitably affect the atmospheric CO_2 concentration and consequently the climate. Based on the data from 127 soil sample sites, 48 vegetation survey plots, and Landsat TM images, we analyzed the land use/cover changes, estimated soil organic carbon（SOC） storage and vegetation carbon storage of grassland, and discussed the impact of grassland changes on carbon storage during 2000 to 2013 in the Ili River Valley of Northwest China. The results indicate that the areal extents of forestland, shrubland, moderate-coverage grassland（MCG）, and the waterbody（including glaciers） decreased while the areal extents of high-coverage grassland（HCG）,low-coverage grassland（LCG）, residential and industrial land, and cultivated land increased. The grassland SOC density in 0–100 cm depth varied with the coverage in a descending order of HCG〉MCG〉LCG.The regional grassland SOC storage in the depth of 0–100 cm in 2013 increased by 0.25×1011 kg compared with that in 2000. The regional vegetation carbon storage（S_（rvc）） of grassland was 5.27×10~9 kg in2013 and decreased by 15.7% compared to that in 2000. The vegetation carbon reserves of the under-ground parts of vegetation（S_（ruvb）） in 2013 was 0.68×10~9 kg and increased by approximately 19.01%compared to that in 2000. This research can improve our understanding about the impact of land use/cover changes on the carbon storage in arid areas of Northwest China.

Spatial analysis of land use change effect on soil organic carbon stocks in the eastern regions of China between 1980 and 2000

Spatial distributions of 0-20 cm soil carbon sources/sinks caused by land use changes from the year 1980 to 2000 in an area of 2.97 ~ 106 km2 in eastern China were investigated using a land use dataset from a recent soil geochemical survey. A map of soil carbon sourcesJsinks has been prepared based on a spatial analysis scheme with GIg. Spatial statistics showed that land use changes had caused 30.7 ＋ 13.64 Tg of surface soil organic carbon loss, which accounts for 0.33% of the total carbon storage of 9.22 Pg. The net effect of the carbon source was estimated to be ~ 71.49 Tg soil carbon decrease and ~ 40.80 Tg increase. Land use changes in Northeast China （NE） have the largest impact on soil organic carbon storage compared with other regions. Paddy fields, which were mainly transformed into dry farmland in NE, and constructed land in other regions, were the largest carbon sources among the land use types. Swamp land in NE was also another large soil carbon source when it was transformed into dry farmland or paddy fields. Dry farmland in the NE region formed the largest soil organic carbon sink, as some were trans- formed into paddy fields, forested land, and other land use types with high SOCD.

Changes in soil organic carbon and nitrogen after 26 years of farmland management on the Loess Plateau of China

Soil carbon（C） and nitrogen（N） play a crucial role in determining the soil and environmental quality. In this study, we investigated the effects of 26 years（from 1984 to 2010） of farmland management on soil organic carbon（SOC） and soil N in abandoned, wheat（Triticum aestivum L.） non-fertilized, wheat fertilized（mineral fertilizer and organic manure） and alfalfa（Medicago Sativa L.） non-fertilized treatments in a semi-arid region of the Loess Plateau, China. Our results showed that SOC and soil total N contents in the 0–20 cm soil layer increased by 4.29（24.4%） and 1.39 Mg/hm2（100%）, respectively, after the conversion of farmland to alfalfa land. Compared to the wheat non-fertilized treatment, SOC and soil total N contents in the 0–20 cm soil layer increased by 4.64（26.4%） and 1.18 Mg/hm2（85.5%）, respectively, in the wheat fertilized treatment. In addition, we found that the extents of changes in SOC, soil total N and mineral N depended on soil depth were greater in the upper soil layer（0–30 cm） than in the deeper soil layer（30–100 cm） in the alfalfa land or fertilizer-applied wheat land. Fertilizer applied to winter wheat could increase the accumulation rates of SOC and soil total N. SOC concentration had a significant positive correlation with soil total N concentration. Therefore, this study suggested that farmland management, e.g. the conversion of farmland to alfalfa forage land and fertilizer application, could promote the sequestrations of C and N in soils in semi-arid regions.

Spatial Variation of Dissolved Organic Carbon in Soils of Riparian Wetlands and Responses to Hydro-geomorphologic Changes in Sanjiang Plain, China

Spatial variation of dissolved organic carbon(DOC) in soils of riparian wetlands and responses to hydro-geomorphologic changes in the Sanjiang Plain were analyzed through in situ collecting soil samples in the Naoli River and the Bielahong River. The results showed that the average contents of DOC for soil layer of 0–100 cm were 730.6 mg/kg, 250.9 mg/kg, 423.0 mg/kg and 333.1 mg/kg respectively from riverbed to river terrace along the transverse directions of the Naoli watershed. The content of the soil DOC was the highest in the riverbed, lower in the high floodplain and much lower in the river terrace, and it was the lowest in the low floodplain. The difference in the content and vertical distribution of DOC between the riverbed and the three riparian wetlands was significant, while it was not significant among the low floodplain, the high floodplain and the river terrace. The variability of soil DOC was related to the hydrological connectivity between different landscape position of the riparian wetlands and the adjacent stream. Extremely significant correlations were observed between DOC and total organic carbon(TOC), total iron(TFe), ferrous iron(Fe(II)) whose correlation coefficients were 0.819, –0.544 and –0.709 in riparian wetlands of the Naoli River. With the increase of wetland destruction, soil p H increased and soil DOC content changed. The correlation coefficients between soil DOC and TOC, TFe, Fe(II) also changed into 0.759, –0.686 and –0.575 respectively in the Bielahong River. Under the impact of drainage ditches, the correlations between soil DOC and TFe, Fe(II) were not obvious, while the soil p H was weakly alkaline and was negatively correlated with soil DOC in the previous high floodplain. It indicates that riparian hydro-geomorphology is the main factor that could well explain this spatial variability of soil DOC, and the agricultural environmental hydraulic works like ditching also must be considered.

Reconstructing Environmental Changes of a Coastal Lagoon with Coral Reefs in Southeastern Hainan Island

Coastal lagoons with small catchment basins are highly sensitive to natural processes and anthropogenic activities. To figure out the environmental changes of a coastal lagoon and its contribution to carbon burial, two sediment cores were collected in Xincun Lagoon, southeastern Hainan Island and (210) ~Pb activities, grain size parameters, total organic carbon(TOC), total nitrogen(TN), total inorganic carbon(TIC) and stable carbon isotopes(δ^(13)C) were measured. The results show that in 1770–1815, the decreasing water exchange capacity with outer open water, probably caused by the shifting and narrowing of the tidal inlet, not only diminished the currents and fined the sediments in the lagoon, but also reduced the organic matter of marine sources. From 1815 to 1950, the sedimentary environment of Xincun Lagoon was frequently influenced by storm events. These extreme events resulted in the high fluctuation of sediment grain size and sorting, as well as the great variation in contributions of terrestrial(higher plants, soils) and marine sources(phytoplankton, algae, seagrass). The extremely high content of TIC, compared to TOC before 1950 could be attributed to the large-scale coverage of coral reefs. However, with the boost of seawater aquaculture activities after 1970, the health growth of coral species was severely threatened, and corresponding production and inorganic carbon burial flux reduced. The apparent enhanced inorganic carbon burial rate after 1990 might result from the concomitant carbonate debris produced by seawater aquaculture. This result is important for local government long-term coastal management and environmental planning.

Special Issue on "Response of Polar Organisms and Natural Environment to Global Changes"

High altitude and high latitude regions on Earth are experiencing rapid changes in climate, with impacts on polar organisms and the environment. The persistent cold and sometimes inhospitable conditions create unique ecosystems and habitats for polar organisms.

Inviting Contributions to a Special Issue on "Response of Polar Organisms and Natural Environment to Global Changes"

Dear Colleagues, We would like to invite you to submit manuscripts to a special issue of the journal Advances in Polar Science （APS） on ＂Response of Polar Organisms and Natural Environment to Global Changes＂.

Influence of Climate on Soil Organic Carbon in Chinese Paddy Soils

Soil organic carbon(SOC) is a major component of the global carbon cycle and has a potentially large impact on the greenhouse effect. Paddy soils are important agricultural soils worldwide, especially in Asia. Thus, a better understanding of the relationship between SOC of paddy soils and climate variables is crucial to a robust understanding of the potential effect of climate change on the global carbon cycle. A soil profile data set(n = 1490) from the Second National Soil Survey of China conducted from 1979 to 1994 was used to explore the relationships of SOC density with mean annual temperature(MAT) and mean annual precipitation(MAP) in six soil regions and eight paddy soil subgroups. Results showed that SOC density of paddy soils was negatively correlated with MAT and positively correlated with MAP(P < 0.01). The relationships of SOC density with MAT and MAP were weak and varied among the six soil regions and eight paddy soil subgroups. A preliminary assessment of the response of SOC in Chinese paddy soils to climate indicated that climate could lead to a 13% SOC loss from paddy soils. Compared to other soil regions, paddy soils in Northern China will potentially more sensitive to climate change over the next several decades. Paddy soils in Middle and Lower Yangtze River Basin could be a potential carbon sink. Reducing the climate impact on paddy soil SOC will mitigate the positive feedback loop between SOC release and global climate change.

Detecting the storage and change on topsoil organic carbon in grasslands of Inner Mongolia from 1980s to 2010s

Soil carbon sequestration and potential has been a focal issue in global carbon research. Under the background of global change, the estimation of the size as well as its change of soil organic carbon（SOC） storage is of great importance. Based on soil data from the second national soil survey and field survey during 2011–2012, by using the regression method between sampling soil data and remote sensing data, this paper aimed to investigate spatial distribution and changes of topsoil（0–20 cm） organic carbon storage in grasslands of Inner Mongolia between the 1980 s and 2010 s. The results showed that：（1） the SOC storage in grasslands of Inner Mongolia between the 1980 s and 2010 s was estimated to be 2.05 and 2.17 Pg C, with an average density of 3.48 and 3.69 kg C·m–2, respectively. The SOC storage was mainly distributed in the typical steppe and meadow steppe, which accounted for over 98% of the total SOC storage. The spatial distribution showed a decreased trend from the meadow steppe, typical steppe to the desert steppe, corresponding to the temperature and precipitation gradient.（2） SOC changes during 1982–2012 were estimated to be 0.12 Pg C, at 7.00 g C·m–2·yr–1, which didn＇t show a significant change, indicating that SOC storage in grasslands of Inner Mongolia remained relatively stable over this period. However, topsoil organic carbon showed different trends of carbon source/sink during the past three decades. Meadow steppe and typical steppe had sequestered 0.15 and 0.03 Pg C, respectively, served as a carbon sink; while desert steppe lost 0.06 Pg C, served as a carbon source. It appears that SOC storage in grassland ecosystem may respond differently to climate change, related to vegetation type, regional climate type and grazing intensity. These results might give advice to decision makers on adopting suitable countermeasures for sustainable grassland utilization and protection.

Large Scale Infrastructure Projects: The Art of Project or Change Management?

Although it is generally understood that change is a fundamental component of managing projects in the construction industry in general and an inevitable challenge for large scale infrastructure project in particular, there has been little to no attention in the literature to understand change in this context from a more holistic perspective. For this purpose, this work looks at change through the eyes of a framework of six batteries of change that seem essential to charge an organization's capabilities for change. The framework brings together the expertise of four specialists that all have developed their insights over many years of study and practice, and has been validated through an extensive review of the management literature on organization development and change. Reflections on the application of this model in the construction industry and in large scale infrastructure projects demonstrate that energizing organizations to successfully deal with change goes beyond the traditional techniques of managing change from a program or project management perspective. Assessing the six batteries of change in this context can help organizations to develop capabilities for change that build change energy by balancing formal/rational methods with informal/emotional interventions at both a local(department/subproject) and global(business) level.