This paper quantifies organochlorine insecticides (OC1) inputs in the Jiulong River and shows the large use in the agricultural activities and analyses specifically the status of soil, fruit and vegetable contaminat...This paper quantifies organochlorine insecticides (OC1) inputs in the Jiulong River and shows the large use in the agricultural activities and analyses specifically the status of soil, fruit and vegetable contamination by these persistent pollutants in some locations of Xiamen region. From this purpose, soil samples collected from Jiulong agricultural catchment have been analyzed for 18 selected OCI using gas chromatography electron capture detection and to identify the factors that may control the distribution and persistence of organochlorines in the area. The main insecticides found in soil samples were Aldrin, Dieldrin, Endosulfan I1, Endrin aldehyde, Endosulfan sulphate and Methoxychlor. The total organochlorines detected in soil samples ranged from 3.14 to 10.35 ng/g soil. The highest values of OC1 were significantly detected in the orange trees' leaves, which range from 1203 to 2681 ng/g soil showing recent uses of these agrochemicals. Their distribution in vegetable samples were also monitored and indicating that the concentration ranged from 3.236 to 7.188 ng/g. The contamination of Jiulong River estuary by organochlorine pesticides has been then widely justified by soil runoffs from these agricultural areas. The results therefore, provide important information on the current contamination status and point to the need for urgent actions to stop the use of persistent agrochemicals. The necessity of implementing systematic monitoring of insecticide contamination is emphasized.展开更多
Persistent organic pollutants(POPs) such as organochlorine pesticides are of global concern due to their widespread occurrence and persistence. This paper reports recent research studying the distribution and fate of ...Persistent organic pollutants(POPs) such as organochlorine pesticides are of global concern due to their widespread occurrence and persistence. This paper reports recent research studying the distribution and fate of organochlorine pesticides in the Jiulong River, the Minjiang River and the Pearl River estuaries in Southeast China. Eighteen organochlorine pesticides were extracted from water, pore water and sediment samples, followed by analysis by GC ECD. The results showed that the contamination levels were similar in these three estuaries. The levels of the total organochlorine pesticides in porewater were significantly higher than those in surface water, due to the high affinity of these hydrophobic compounds for sediment phase. Among the hexachlorocyclohexane(HCH) compounds, β HCH was found to be the most important isomer. The analysis of 1,1,1 trichloro 2,2 bis chlorophenyl ethane(DDT) and its metabolites showed that 1,1 dichloro 2[ o chlorophenyl] 2[ p chlorophenyl] ethylene(DDE) was dominant in the group.展开更多
文摘This paper quantifies organochlorine insecticides (OC1) inputs in the Jiulong River and shows the large use in the agricultural activities and analyses specifically the status of soil, fruit and vegetable contamination by these persistent pollutants in some locations of Xiamen region. From this purpose, soil samples collected from Jiulong agricultural catchment have been analyzed for 18 selected OCI using gas chromatography electron capture detection and to identify the factors that may control the distribution and persistence of organochlorines in the area. The main insecticides found in soil samples were Aldrin, Dieldrin, Endosulfan I1, Endrin aldehyde, Endosulfan sulphate and Methoxychlor. The total organochlorines detected in soil samples ranged from 3.14 to 10.35 ng/g soil. The highest values of OC1 were significantly detected in the orange trees' leaves, which range from 1203 to 2681 ng/g soil showing recent uses of these agrochemicals. Their distribution in vegetable samples were also monitored and indicating that the concentration ranged from 3.236 to 7.188 ng/g. The contamination of Jiulong River estuary by organochlorine pesticides has been then widely justified by soil runoffs from these agricultural areas. The results therefore, provide important information on the current contamination status and point to the need for urgent actions to stop the use of persistent agrochemicals. The necessity of implementing systematic monitoring of insecticide contamination is emphasized.
文摘Persistent organic pollutants(POPs) such as organochlorine pesticides are of global concern due to their widespread occurrence and persistence. This paper reports recent research studying the distribution and fate of organochlorine pesticides in the Jiulong River, the Minjiang River and the Pearl River estuaries in Southeast China. Eighteen organochlorine pesticides were extracted from water, pore water and sediment samples, followed by analysis by GC ECD. The results showed that the contamination levels were similar in these three estuaries. The levels of the total organochlorine pesticides in porewater were significantly higher than those in surface water, due to the high affinity of these hydrophobic compounds for sediment phase. Among the hexachlorocyclohexane(HCH) compounds, β HCH was found to be the most important isomer. The analysis of 1,1,1 trichloro 2,2 bis chlorophenyl ethane(DDT) and its metabolites showed that 1,1 dichloro 2[ o chlorophenyl] 2[ p chlorophenyl] ethylene(DDE) was dominant in the group.