A new method for the determination of aniline in environmental water based on oscillopolarographic titration was presented in this paper. Several factors including the kind, concentration, and volume of acid, the dosa...A new method for the determination of aniline in environmental water based on oscillopolarographic titration was presented in this paper. Several factors including the kind, concentration, and volume of acid, the dosage of potassium bromide, the temperature and concentration of concomitant substances were investigated in detail. The experimental results indicated that this method was simple, rapid, and sensitive. The linear range was 8.367 × 10(?4) to 2.789 × 10(?2) mol L(?1), the relative standard deviation (R.S.D.) was lower than 0.96%, and the spiked recoveries of aniline in environmental water samples were in the range of 99.4–106.9% under the optimal conditions. The results indicated that the present method could be used as an alternative method for aniline determination in realworld water samples.展开更多
A rapid, simple and sensitive method was demonstrated for the determination of phenolic compounds in water samples by alternating-current oscillopolarographic titration. With the presence of sulfuric acid, phenol coul...A rapid, simple and sensitive method was demonstrated for the determination of phenolic compounds in water samples by alternating-current oscillopolarographic titration. With the presence of sulfuric acid, phenol could be transferred into a nitroso-compound by reacting with NaNO2. The titration end-point was obtained by the formation of a sharp cut in the oscillopolarographic with infinitesimal NaNO2 on double platinum electrodes. The results showed that phenol had an excellent linear relationship over the range of 4.82×10^-6 -9.65×10^-3 mol/L, the RSD of the proposed method was lower than 1.5%, and the spiked recoveries of three real water samples were in the range of 95.6%-106.9%.展开更多
This paper reviews the development of exchange oscillopolarographic titration research, and focuses on its change in the past 20 years. At different temperatures, indicators, pH, and other situations, exchange oscillo...This paper reviews the development of exchange oscillopolarographic titration research, and focuses on its change in the past 20 years. At different temperatures, indicators, pH, and other situations, exchange oscillopolarographic titration was used to detect phosphorus, silver, lead, thallium, cobalt, nickel, potassium bromate, potassium ferricyanide sodium tetraphenylborate, hydroxyquinoline. It also can be used in the determination of sulfate in extracted phosphoric acid, vitamin C, and trace mercury in industrial waste water. This method is high sensitive and selective. Further it can omit the separating steps, simplify the testing procedures, save analyte samples, and detect the very weak acids and alkalis. Phenomena are obvious and deviation is negligible.展开更多
文摘A new method for the determination of aniline in environmental water based on oscillopolarographic titration was presented in this paper. Several factors including the kind, concentration, and volume of acid, the dosage of potassium bromide, the temperature and concentration of concomitant substances were investigated in detail. The experimental results indicated that this method was simple, rapid, and sensitive. The linear range was 8.367 × 10(?4) to 2.789 × 10(?2) mol L(?1), the relative standard deviation (R.S.D.) was lower than 0.96%, and the spiked recoveries of aniline in environmental water samples were in the range of 99.4–106.9% under the optimal conditions. The results indicated that the present method could be used as an alternative method for aniline determination in realworld water samples.
基金Project supported by the Creative Talented Person's Fund of Henan Province (High Teaching [2005]-126)the Natural Science Foundation of Henan Province (No. 0511053000)+1 种基金the Youth Science Foundation of Henan Normal University (No. 2004005)the Henan Key Laboratory for Environmental Pollution Control.
文摘A rapid, simple and sensitive method was demonstrated for the determination of phenolic compounds in water samples by alternating-current oscillopolarographic titration. With the presence of sulfuric acid, phenol could be transferred into a nitroso-compound by reacting with NaNO2. The titration end-point was obtained by the formation of a sharp cut in the oscillopolarographic with infinitesimal NaNO2 on double platinum electrodes. The results showed that phenol had an excellent linear relationship over the range of 4.82×10^-6 -9.65×10^-3 mol/L, the RSD of the proposed method was lower than 1.5%, and the spiked recoveries of three real water samples were in the range of 95.6%-106.9%.
文摘This paper reviews the development of exchange oscillopolarographic titration research, and focuses on its change in the past 20 years. At different temperatures, indicators, pH, and other situations, exchange oscillopolarographic titration was used to detect phosphorus, silver, lead, thallium, cobalt, nickel, potassium bromate, potassium ferricyanide sodium tetraphenylborate, hydroxyquinoline. It also can be used in the determination of sulfate in extracted phosphoric acid, vitamin C, and trace mercury in industrial waste water. This method is high sensitive and selective. Further it can omit the separating steps, simplify the testing procedures, save analyte samples, and detect the very weak acids and alkalis. Phenomena are obvious and deviation is negligible.
