The Callovian-Oxfordian carbonate reservoirs are the most important hydrocarbon reservoir in the Samandepe gas field,Amu Darya basin,Turkmenistan.Based on the analysis of Fe,Mn and Sr trace elements,and carbon,oxygen ...The Callovian-Oxfordian carbonate reservoirs are the most important hydrocarbon reservoir in the Samandepe gas field,Amu Darya basin,Turkmenistan.Based on the analysis of Fe,Mn and Sr trace elements,and carbon,oxygen and strontium isotopes,the genesis and evolutionary characteristics of the carbonate reservoirs were studied,and the conclusions were follows:1) Sustained transgressive-regressive cycles played an important role during Callovian-Oxfordian.The reservoir of reef-bank facies was well developed in the period of transgression,while the regional dense cap rocks developed in the period of regression;2) The 87 Sr/86 Sr ratio measured from rudist shells yields an age of 157.2 Ma according to the global strontium isotope curve;3) As diagenetic intensity increased,δ 13 C changed little,and δ 18 O showed strong negative deviation but was still limited to the range of Late Jurassic seawater.High Fe and Sr contents,and low Mn content,and the evolutionary trend of δ 13 C and δ 18 O all indicate that diagenesis occurred in a relatively confined environment,where the fluids were relatively reducing and contained hot brine.The stage of diagenesis reached is mesodiagenesis,which is very favorable for preservation of primary pores in carbonates;4) Strong dissolution of reef limestones,burial dolomitization and hydrothermal calcite precipitation were all the results of the interaction between the 87 Sr-rich diagenetic fluid and rocks;5) The analysis results of isotopes,fluid inclusions and vitrinite reflectance show that the diagenetic fluid was compaction-released water that originated from the deep,coal-bearing clastic strata.展开更多
Global climate during the Jurassic has been commonly described as a uniform greenhouse climate for a long time.However,the climate scenario of a cool episode during the Callovian-Oxfordian transition following by a wa...Global climate during the Jurassic has been commonly described as a uniform greenhouse climate for a long time.However,the climate scenario of a cool episode during the Callovian-Oxfordian transition following by a warming trend during the Oxfordian(163.53 to157.4 Ma)is documented in many localities of the western Tethys.It is still unclear if a correlatable climate scenario also occurred in the eastern Tethys during the same time interval.In this study,a detailed geochemical analysis on the 1060 m thick successions(the Xiali and Suowa formations)from the Yanshiping section of the Qiangtang Basin,located in the eastern Tethys margin during the Callovian-Oxfordian periods,was performed.To reveal the climate evolution of the basin,carbonate content and soluble salt concentrations(SO_(4)^(2-),Cl^(-))were chosen as climatic indices.The results show that the overall climate patterns during the deposition of the Xiali and Suowa formations can be divided into three stages:relatively humid(164.0 to 160.9 Ma),dry(160.9 to159.6 Ma),semi-dry(159.6 to 156.8 Ma).A similar warming climate scenario also occurred in eastern Tethys during the Callovian-Oxfordian transition(160.9 to159.6 Ma).Besides,we clarify that the Jurassic True polar wander(TPW),the motion of the lithosphere and mantle with respect to Earth’s spin axis,inducing climatic shifts were responsible for the aridification of the Qiangtang Basin during the Callovian-Oxfordian transition with a review of the paleolatitude of the Xiali formation(19.7+2.8/-2.6°N)and the Suowa formation(20.7+4.1/-3.7°N).It is because the TPW rotations shifted the East Asia blocks(the North and South China,Qiangtang,and Qaidam blocks)from the humid zone to the tropical/subtropical arid zone and triggered the remarkable aridification during the Middle-Late Jurassic(ca.165-155 Ma).展开更多
Within the framework of feasibility studies for a reversible, deep geological repository of high-and intermediate-level long-lived radioactive waste(HLW, IL-LLW), the French National Radioactive Waste Management Agenc...Within the framework of feasibility studies for a reversible, deep geological repository of high-and intermediate-level long-lived radioactive waste(HLW, IL-LLW), the French National Radioactive Waste Management Agency(Andra) is investigating the Callovo-Oxfordian(COx) formation near Bure(northeast part of France) as a potential host rock for the repository. The hydro-mechanical(HM) behaviour is an important issue to design and optimise different components of the disposal such as shaft, ramp, drift,and waste package disposal facilities. Over the past 20 years, a large number of laboratory experiments have been carried out to characterise and understand the HM behaviours of COx claystones. At the beginning, samples came from deep boreholes drilled at the ground surface with oil base mud. From2000 onwards, with the launch of the construction of the Meuse/Haute-Marne Underground Research Laboratory(MHM URL), most samples have been extracted from a large number of air drilled boreholes in the URL. In parallel, various constitutive models have been developed for modelling. The thermohydro-mechanical(THM) behaviours of the COx claystones were investigated under different repository conditions. Core samples are subjected to a complex HM loading path before testing, due to drilling, conditioning and preparation. Various kinds of effects on the characteristics of the claystones are highlighted and discussed, and the procedures for core extraction and packaging as well as a systematic sample preparation protocol are proposed in order to minimise the uncertainties on test results. The representativeness of the test results is also addressed with regard to the in situ rock mass.展开更多
Based on the detailed research on petrologic and geochemical characteristics of deposi- tion and diagenesis of Oxfordian carbonate rocks in Amu Darya Basin, Turkmenistan, carbon and oxygen isotopes were analyzed. The ...Based on the detailed research on petrologic and geochemical characteristics of deposi- tion and diagenesis of Oxfordian carbonate rocks in Amu Darya Basin, Turkmenistan, carbon and oxygen isotopes were analyzed. The results show that the paleoenvironmental evolution reflected by the samples with well-preserved original carbon isotopes coincides with the carbon-isotope stratigraphic curve and is almost consistent with the global sea-level curve, the Mid-Oxfordian wide transgression, and the positive carbon-isotope excursion event. The Mid-Oxfordian continuing transgression not only laid the foundation for the development of the Oxfordian reef and shoal reservoirs in Amu Darya Basin but also provided an example for the Oxfordian global transgression and the resulting development of reefs and banks and high-speed organic carbon burial events. The response of oxygen isotopes in diagenetic environment showed that micrite limestones and granular limestones underwent weak diagenetic alteration, and the samples largely retained the original seawater features. Dolomitization and the precipitation of hydrothermal calcites filling solution vugs and fractures before hydrocarbon accumulation occurred in a closed diagenetic environment where the main controlling factor is the temperature, and the diagenetic fluids were from the deep hot brine. The chalkification of the lime- stones after hydrocarbon accumulation occurred in the oilfield water systems.展开更多
The Kutch Basin of western India is famous for its rich assemblages of the Callovian-Oxfordian ammonites.The family Oppelidae Douvillé is the second most diverse ammonite group after perisphinctids during the Mid...The Kutch Basin of western India is famous for its rich assemblages of the Callovian-Oxfordian ammonites.The family Oppelidae Douvillé is the second most diverse ammonite group after perisphinctids during the Middle-Upper Jurassic.Hecticoceratinae is the most diverse subfamily within Oppelidae and has wide palaeobiogeographic(near cosmopolitan) and temporal distributions(Bathonian-Oxfordian).Some species were well timediagnostic and thus help in interprovincial correlation.The taxonomy of the subfamily Hecticoceratinae of Kutch was in a state of flux until recently.It was not revised since Spath’s(1927-1933) great contribution.Many genera and species were morphogenera or morphospecies and they again suffer from excessive subjective splitting.It was therefore badly needed for a comprehensive taxonomic revision of the subfamily with modern aspects of systematics i.e.,sexual dimorphism and population dynamics.A lithostratigraphic framework has already been well documented in the Kutch Basin of western India.A high resolution biostratigraphy incorporating stage-intrastage fossil assemblages have been used in interbasinal correlation based on the Callovian-Oxfordian hecticoceratins.Near cosmopolitan distribution of many hecticoceratin genera were widely used for biostratigraphic zonation as well as an understanding of the palaeobiogeographic pattern.The phylogeny of the subfamily Hecticoceratinae has been used to construct the cladograms depicting area relationships among different provinces during the Callovian-Oxfordian.展开更多
The Oxfordian (Late Jurassic) carbonate-dominated ptatform outcropping in the Swiss Jura Mountains offers a good biostratigraphic, sequence-stratigraphic, and cyclostratigraphic framework to reconstruct changes in f...The Oxfordian (Late Jurassic) carbonate-dominated ptatform outcropping in the Swiss Jura Mountains offers a good biostratigraphic, sequence-stratigraphic, and cyclostratigraphic framework to reconstruct changes in facies distribution at a time-resolution of 100 ka. It thus allows interpreting the dynamic evolution of this platform in much more detail than conventional palaeogeographic maps permit. As an example, a Middle to Late Oxfordian time slice is presented, spanning an interval of about 1.6 Ma. The study is based on 12 sections logged at cm-scale. The interpreted depositional environments include marginal-marine emerged ;ands, fresh-water lakes, tidal fiats, shallow lagoons, ooid shoals, and coral reefs. Although limestones dominate, marly intervals and dolomites occur sporadically. Major facies shifts are related to m-scale sea-level changes linked to the orbital short eccentricity cycle (100 ka). The 20-ka precession cycle caused minor facies changes but cannot always be resolved. Synsedimentary tectonics induced additional accommodation changes by creating shallow basins where days accumulated or highs on which shoals or islands formed. Autocyclic processes such as lateral migration of ooid and bioclastic shoals added to the sedimentary record. CEimate changes intervened to control terrestrial run-off and, consequently, siliciclastic and nutrient input. Coral reefs reacted to such input by becoming dominated by microbialites and eventually by being smothered. Concomitant occurrence of siliciclastics anddolomite in certain intervals further suggests that, at times, it was relatively arid in the study area but there was rainfall in more northern latitudes, eroding the Hercynian substrate. These examples from the Swiss Jura demonstrate the highly dynamic and (geologically speaking) rapid evolution of sedimentary systems, in which tectonically controlled basin morphology, orbitally induced climate and sea-level changes, currents, and the ecology of the carbonate-producing organisms interacted to form the observed stratigraphic record. However, the interpretations have to be treated with caution because the km-wide spacing between the studied sections is too large to monitor the smaU-scale facies mosaics as they can be observed on modern platforms and as they certainly also occurred in the past.展开更多
文摘The Callovian-Oxfordian carbonate reservoirs are the most important hydrocarbon reservoir in the Samandepe gas field,Amu Darya basin,Turkmenistan.Based on the analysis of Fe,Mn and Sr trace elements,and carbon,oxygen and strontium isotopes,the genesis and evolutionary characteristics of the carbonate reservoirs were studied,and the conclusions were follows:1) Sustained transgressive-regressive cycles played an important role during Callovian-Oxfordian.The reservoir of reef-bank facies was well developed in the period of transgression,while the regional dense cap rocks developed in the period of regression;2) The 87 Sr/86 Sr ratio measured from rudist shells yields an age of 157.2 Ma according to the global strontium isotope curve;3) As diagenetic intensity increased,δ 13 C changed little,and δ 18 O showed strong negative deviation but was still limited to the range of Late Jurassic seawater.High Fe and Sr contents,and low Mn content,and the evolutionary trend of δ 13 C and δ 18 O all indicate that diagenesis occurred in a relatively confined environment,where the fluids were relatively reducing and contained hot brine.The stage of diagenesis reached is mesodiagenesis,which is very favorable for preservation of primary pores in carbonates;4) Strong dissolution of reef limestones,burial dolomitization and hydrothermal calcite precipitation were all the results of the interaction between the 87 Sr-rich diagenetic fluid and rocks;5) The analysis results of isotopes,fluid inclusions and vitrinite reflectance show that the diagenetic fluid was compaction-released water that originated from the deep,coal-bearing clastic strata.
基金supported by the National Basic Research Program of China(Grant No.2011CB403003)the College Innovation Research Program of Gansu Province(Grant No.2020B320)the College Innovation Foundation of Gansu Province(Grant No.S202013933013)。
文摘Global climate during the Jurassic has been commonly described as a uniform greenhouse climate for a long time.However,the climate scenario of a cool episode during the Callovian-Oxfordian transition following by a warming trend during the Oxfordian(163.53 to157.4 Ma)is documented in many localities of the western Tethys.It is still unclear if a correlatable climate scenario also occurred in the eastern Tethys during the same time interval.In this study,a detailed geochemical analysis on the 1060 m thick successions(the Xiali and Suowa formations)from the Yanshiping section of the Qiangtang Basin,located in the eastern Tethys margin during the Callovian-Oxfordian periods,was performed.To reveal the climate evolution of the basin,carbonate content and soluble salt concentrations(SO_(4)^(2-),Cl^(-))were chosen as climatic indices.The results show that the overall climate patterns during the deposition of the Xiali and Suowa formations can be divided into three stages:relatively humid(164.0 to 160.9 Ma),dry(160.9 to159.6 Ma),semi-dry(159.6 to 156.8 Ma).A similar warming climate scenario also occurred in eastern Tethys during the Callovian-Oxfordian transition(160.9 to159.6 Ma).Besides,we clarify that the Jurassic True polar wander(TPW),the motion of the lithosphere and mantle with respect to Earth’s spin axis,inducing climatic shifts were responsible for the aridification of the Qiangtang Basin during the Callovian-Oxfordian transition with a review of the paleolatitude of the Xiali formation(19.7+2.8/-2.6°N)and the Suowa formation(20.7+4.1/-3.7°N).It is because the TPW rotations shifted the East Asia blocks(the North and South China,Qiangtang,and Qaidam blocks)from the humid zone to the tropical/subtropical arid zone and triggered the remarkable aridification during the Middle-Late Jurassic(ca.165-155 Ma).
文摘Within the framework of feasibility studies for a reversible, deep geological repository of high-and intermediate-level long-lived radioactive waste(HLW, IL-LLW), the French National Radioactive Waste Management Agency(Andra) is investigating the Callovo-Oxfordian(COx) formation near Bure(northeast part of France) as a potential host rock for the repository. The hydro-mechanical(HM) behaviour is an important issue to design and optimise different components of the disposal such as shaft, ramp, drift,and waste package disposal facilities. Over the past 20 years, a large number of laboratory experiments have been carried out to characterise and understand the HM behaviours of COx claystones. At the beginning, samples came from deep boreholes drilled at the ground surface with oil base mud. From2000 onwards, with the launch of the construction of the Meuse/Haute-Marne Underground Research Laboratory(MHM URL), most samples have been extracted from a large number of air drilled boreholes in the URL. In parallel, various constitutive models have been developed for modelling. The thermohydro-mechanical(THM) behaviours of the COx claystones were investigated under different repository conditions. Core samples are subjected to a complex HM loading path before testing, due to drilling, conditioning and preparation. Various kinds of effects on the characteristics of the claystones are highlighted and discussed, and the procedures for core extraction and packaging as well as a systematic sample preparation protocol are proposed in order to minimise the uncertainties on test results. The representativeness of the test results is also addressed with regard to the in situ rock mass.
基金supported by the Important National Science & Technology Specific Projects of China(No.2008ZX05030-003-02)
文摘Based on the detailed research on petrologic and geochemical characteristics of deposi- tion and diagenesis of Oxfordian carbonate rocks in Amu Darya Basin, Turkmenistan, carbon and oxygen isotopes were analyzed. The results show that the paleoenvironmental evolution reflected by the samples with well-preserved original carbon isotopes coincides with the carbon-isotope stratigraphic curve and is almost consistent with the global sea-level curve, the Mid-Oxfordian wide transgression, and the positive carbon-isotope excursion event. The Mid-Oxfordian continuing transgression not only laid the foundation for the development of the Oxfordian reef and shoal reservoirs in Amu Darya Basin but also provided an example for the Oxfordian global transgression and the resulting development of reefs and banks and high-speed organic carbon burial events. The response of oxygen isotopes in diagenetic environment showed that micrite limestones and granular limestones underwent weak diagenetic alteration, and the samples largely retained the original seawater features. Dolomitization and the precipitation of hydrothermal calcites filling solution vugs and fractures before hydrocarbon accumulation occurred in a closed diagenetic environment where the main controlling factor is the temperature, and the diagenetic fluids were from the deep hot brine. The chalkification of the lime- stones after hydrocarbon accumulation occurred in the oilfield water systems.
基金completed under UGC Minor Research Project Scheme [F.PSW008/11-12(ERO)]
文摘The Kutch Basin of western India is famous for its rich assemblages of the Callovian-Oxfordian ammonites.The family Oppelidae Douvillé is the second most diverse ammonite group after perisphinctids during the Middle-Upper Jurassic.Hecticoceratinae is the most diverse subfamily within Oppelidae and has wide palaeobiogeographic(near cosmopolitan) and temporal distributions(Bathonian-Oxfordian).Some species were well timediagnostic and thus help in interprovincial correlation.The taxonomy of the subfamily Hecticoceratinae of Kutch was in a state of flux until recently.It was not revised since Spath’s(1927-1933) great contribution.Many genera and species were morphogenera or morphospecies and they again suffer from excessive subjective splitting.It was therefore badly needed for a comprehensive taxonomic revision of the subfamily with modern aspects of systematics i.e.,sexual dimorphism and population dynamics.A lithostratigraphic framework has already been well documented in the Kutch Basin of western India.A high resolution biostratigraphy incorporating stage-intrastage fossil assemblages have been used in interbasinal correlation based on the Callovian-Oxfordian hecticoceratins.Near cosmopolitan distribution of many hecticoceratin genera were widely used for biostratigraphic zonation as well as an understanding of the palaeobiogeographic pattern.The phylogeny of the subfamily Hecticoceratinae has been used to construct the cladograms depicting area relationships among different provinces during the Callovian-Oxfordian.
基金the financial support of the Swiss National Science Foundation,which is gratefully acknowledged(Projects No.20 41888,20-43150,20-46625,20-67736,and 20-109214)
文摘The Oxfordian (Late Jurassic) carbonate-dominated ptatform outcropping in the Swiss Jura Mountains offers a good biostratigraphic, sequence-stratigraphic, and cyclostratigraphic framework to reconstruct changes in facies distribution at a time-resolution of 100 ka. It thus allows interpreting the dynamic evolution of this platform in much more detail than conventional palaeogeographic maps permit. As an example, a Middle to Late Oxfordian time slice is presented, spanning an interval of about 1.6 Ma. The study is based on 12 sections logged at cm-scale. The interpreted depositional environments include marginal-marine emerged ;ands, fresh-water lakes, tidal fiats, shallow lagoons, ooid shoals, and coral reefs. Although limestones dominate, marly intervals and dolomites occur sporadically. Major facies shifts are related to m-scale sea-level changes linked to the orbital short eccentricity cycle (100 ka). The 20-ka precession cycle caused minor facies changes but cannot always be resolved. Synsedimentary tectonics induced additional accommodation changes by creating shallow basins where days accumulated or highs on which shoals or islands formed. Autocyclic processes such as lateral migration of ooid and bioclastic shoals added to the sedimentary record. CEimate changes intervened to control terrestrial run-off and, consequently, siliciclastic and nutrient input. Coral reefs reacted to such input by becoming dominated by microbialites and eventually by being smothered. Concomitant occurrence of siliciclastics anddolomite in certain intervals further suggests that, at times, it was relatively arid in the study area but there was rainfall in more northern latitudes, eroding the Hercynian substrate. These examples from the Swiss Jura demonstrate the highly dynamic and (geologically speaking) rapid evolution of sedimentary systems, in which tectonically controlled basin morphology, orbitally induced climate and sea-level changes, currents, and the ecology of the carbonate-producing organisms interacted to form the observed stratigraphic record. However, the interpretations have to be treated with caution because the km-wide spacing between the studied sections is too large to monitor the smaU-scale facies mosaics as they can be observed on modern platforms and as they certainly also occurred in the past.