Solid electrolytes(CeO2)0.7-x(MO)x (La2O3) 0.3(M = Mg,Ca,Sr)were synthesized.Their crystal structure,conductivity, XPS spectrum,ionic transferance number and the V-1 curve of the obtained fuel cell were measured.(CeO2...Solid electrolytes(CeO2)0.7-x(MO)x (La2O3) 0.3(M = Mg,Ca,Sr)were synthesized.Their crystal structure,conductivity, XPS spectrum,ionic transferance number and the V-1 curve of the obtained fuel cell were measured.(CeO2)0.7z (La2O3)0.3 doped with Ca2+,Mg2+,and Sr2+can perform the oxygen ionic electrolyte,and so enhance the open voltage and power output of the fuel cell.展开更多
Composite oxide ionic conductors consisting of Zr_(0.85)Y_(0.15)O_(1.925)(YSZ)and La_(9.33)Si_(6)O_(26)(LSO)have been synthesized by a modified coprecipitation method.X-ray diffraction,electron microscope,and complex ...Composite oxide ionic conductors consisting of Zr_(0.85)Y_(0.15)O_(1.925)(YSZ)and La_(9.33)Si_(6)O_(26)(LSO)have been synthesized by a modified coprecipitation method.X-ray diffraction,electron microscope,and complex impedance were adopted to investigate the phase component,microstructures,and conductivities,respectively.The results show that the average grain sizes of the composite powders and as-sintered pellets are less than 20 nm and 200 nm,respectively.The conductivity of the composite materials composed of 94 wt%YSZ and 6 wt%LSO is 0.215 S/cm at 700℃.The conductivity of the composite is three times higher than that of the polycrystalline YSZ and has two orders in magnitude higher than that of the polycrystalline LSO at 700℃.By analyzing the impedance spectra and modulus spectra,the grain-boundary effect on the conductivity improvement is investigated and the conductive mechanisms of the composite materials are discussed.展开更多
文摘Solid electrolytes(CeO2)0.7-x(MO)x (La2O3) 0.3(M = Mg,Ca,Sr)were synthesized.Their crystal structure,conductivity, XPS spectrum,ionic transferance number and the V-1 curve of the obtained fuel cell were measured.(CeO2)0.7z (La2O3)0.3 doped with Ca2+,Mg2+,and Sr2+can perform the oxygen ionic electrolyte,and so enhance the open voltage and power output of the fuel cell.
基金the National Nature Science Foundation of China(Nos.50872155 and 51172287)。
文摘Composite oxide ionic conductors consisting of Zr_(0.85)Y_(0.15)O_(1.925)(YSZ)and La_(9.33)Si_(6)O_(26)(LSO)have been synthesized by a modified coprecipitation method.X-ray diffraction,electron microscope,and complex impedance were adopted to investigate the phase component,microstructures,and conductivities,respectively.The results show that the average grain sizes of the composite powders and as-sintered pellets are less than 20 nm and 200 nm,respectively.The conductivity of the composite materials composed of 94 wt%YSZ and 6 wt%LSO is 0.215 S/cm at 700℃.The conductivity of the composite is three times higher than that of the polycrystalline YSZ and has two orders in magnitude higher than that of the polycrystalline LSO at 700℃.By analyzing the impedance spectra and modulus spectra,the grain-boundary effect on the conductivity improvement is investigated and the conductive mechanisms of the composite materials are discussed.
