SHS Flame Spraying TiC-TiB_(2) Multiphase Coatings

Utilizing SHS Reactive Flame Spraying (RFS) technology, TiC-TiB2-Al2O3 multiphase ceramics coatings were produced on steel substrate. Phase constituents and microstructure of the ceramic coatings were analyzed. The procedure of chemical combustion and structure transformation, reactive mechanism, and solidifying behavior during spaying were emphasized. Reactants which influenced on SHS spraying was discussed. SHS reactive spraying processes were studied. Mechanical properties of the coatings were tested.

Properties of PA(polyamide) coating and PA/MoS2 composite coatings by flame spraying

PA and PA/MoS2 composite coatings were prepared by flame-spraying. The thermal properties, crystallinity, microstructure and tribological properties were investigated with Fourier transform infrared (FTIR), differential scanning calorimetry (DSC), scanning electron microscopy(SEM), and MM-200 model wear tester. Temperature influences the final morphological structure of the coatings. Tribological experiment results indicate that the MoS2 filled PA coating has different wear resistance compared with the PA coating without MoS2 filler. A high content of MoS2 decreases the hardness of composite coating and enhances the wear rate. The 1 %-3% content of MoS2 has advantages to the tribological ProPerties of PA composite coatings.

Flame Pyrolysis Spraying of Alumina-Yttria Ceramic Coating

Alumina yttria composite oxide coating was obtained on the stainless steel through the pyrolysis of aluminium nitrate and yttrium nitrate by flame spraying in the open atmospheric environment. The isothermal oxidation behaviour of the specimens coated with alumina yttria was investigated in air at the temperature of 1273 K. The results show that coating can promote the selective oxidation of chromium in the alloy and improve the high temperature corrosion resistance of the stainless steel.

TiC-Fe coatings prepared by flame spray synthesis process

A new process, flame spray synthesis (FSS), has been developed for producing ceramic containing composite coatings. By combining self propagation high temperature synthesis (SHS) and flame spraying, the cermet based material was synthesized and deposited simultaneously. TiC Fe coatings were deposited from commercial ferrotitanium, iron and graphite powders by the flame spraying synthesis process. Microstructure analyses revealed that TiC was synthesized during spraying, and that submicron and round TiC particles were dispersed within an iron matrix. Flame spray synthesized coatings were composed of alternate soft and hard layers, whose hardness were 3.0～6.0 GPa and 11～13 GPa, respectively.

A New Process for Preparing Fine-ceramic-containing Composite Coatings──Flame Spray Synthesis

Flame spray synthesis (FSS), a combination of the flame spray technology and Self-propagation High-temperature Synthesis (SHS) was developed for preparing fine-ceramic-containing composite coatings. It can simplify the preparations of powder to synthesize and deposit the desired materials in one step. The preliminary results obtained from TiC-Fe cermet coatings by FSS process are reported. The peculiar microstructure of the composite coatings, which contains very fine (<1m) and round TiC and alternate TiC-rich (Hv=11€*13GPa) and TiC-poor layers (Hv=3.0 -6.0GPa), is expected to play an important role in their tribological properties.

Study on the subsonic speed flame spraying coating of hydroxyapatite

A new method of preparation of biomaterial composite coating by the techniqueof subsonic thermal spraying was discussed in this paper. Ti_6Al_4V and pure Ti were chosen assubstrate and sublayer material respectively and the working layer was sprayed with biomaterialhydroxyapatite (HAP), forming the composite coating. The experiments of heat shock and tensilestrength showed that the bonding strength between coating and substrate is almost as same as that ofspecimen in which Ni/Al powder was adopted as sublayer. The phases of TiN, TiO_2, and Ti_2O_3 wereformed in the sublayer, which are free of toxic and have no side effects. The powder of workinglayer HAP was decomposed partly during spraying, but it can be solved by later treatment.

Enhancement of Corrosion Resistance of NiCrFeBSi Coatings Obtained by Flame Thermal Spray Process Adding an Electroless Nickel Coating Ni-P

Flame Thermal Spray (FTS) coatings frequently show some porosity and reduced adherence to substrate, which affect its properties, especially its corrosion resistance. In this work, the corrosion resistance of AISI 1018 carbon steel coated by different methods is compared: electroless nickel (EN) coating, NiCrFeBSi obtained by FTS, duplex coatings of an EN deposit on a layer of NiCrFeBSi obtained by FTS and a layer of NiCrFeBSi on an EN deposit. The coatings were characterized using optical microscopy and scanning electron microscopy techniques, EDS microprobe microanalysis, roughness as well as electrochemical polarization tests to obtain the corrosion rate. The results show the enhancement in the corrosion resistance in saline medium of the duplex coatings, especially of the EN coating on FTS layer.

Applying Thermal Spraying to Forming Glass Enamel Coatings

Applying thermal spraying to forming glass enamel coatings is explored in present paper. Four kinds of glass enamel frits suited to flame spraying have been prepared and the flame spraying experiments have conducted. It is possible to form glass enamel coatings on still substrates by a proper flame spraying technique. Besides the obvious mechanical adhesion obtained by roughening the surface of the still substrates, the element micro diffusion between glass enamel coatings and substrates have been produced during the spraying process, Hence metallurgical chemical adhesion is derived.

Microstructure and Properties Characterization of WC-Co-Cr Thermal Spray Coatings

WC-Co-Cr coatings are widely employed due to their improved wear resistance and mechanical properties, however, the properties and performance of these coatings are compromised by the processing parameters of each spraying technique. Therefore, this study is aimed to evaluate and determine the effect of the deposition parameters on the properties and microstructural characteristics of WC-Co-Cr coatings using a more economical thermal spray technique. In particular, the influence of flame spray parameters on the microstructure, crystal structure, hardness, and sliding wear resistance of WC- Co-Cr coatings was examined. Two parameters were considered: Type of flame (reducing, neutral and oxidizing), and the spray torch nozzle exit area. Results indicated that WC particles undergo considerable degree of decarburization and dissolution during spraying, showing substantial amounts of W2C, W, and Co3W3C, for all the considered conditions. However, the extent of phase transformation depended largely on the flame chemistry. The microstructure of the coatings was mainly affected by the spray nozzle. Regarding the sliding wear behavior, the coatings with uniform distribution of hard particles provided the best wear resistance. The decomposition of WC into W2C phase seems to have meaningless significance in the mass loss, nevertheless, the WC phase transformation to metallic tungsten and η-phase (Co3W3C) produce higher wear rates due to deficiency of carbide particles and embrittlement of the binder phase which induces cracking and delamination of the splats.

CORROSION FAILURE ANALYSIS OF FLAME SPRAYED Zn-A115 COATING IN SEA WATER

The morphology,microstructure,chemical composition and electrochemical behavior of the flame sprayed Zn-Al15 coating after corrosion test in sea water have been investigated.The results show that the selective dissolution of the laminar euteetic structure of the Zn-AI15 coating is the fundamental cause for its similarity in electrochemical behavior with Zn coating and kinetic behavior with Al coating.In the beginning period of sea water corrosion,the com- bined action of the laminar eutectic structure of the coating together with the residual stress may induce the stress corrosion cracking of the coating,and result in the crevice corrosion. The coating then will bulge and.fail in local areas due to embrittlement itself,stacking and ex- pansion of corroded products under the residual stress.

一种声学覆盖层用弹性防护涂层的制备及性能研究

以液化MDI、端氨基聚醚、胺类扩链剂等原材料制备了一种用于橡胶类声学覆盖层表面的弹性聚脲防护材料,并对该材料进行阻燃性能改性。考察了该喷涂聚脲材料的力学性能、声学性能、耐环境性能以及阻燃性能。结果表明,该材料力学性能和耐环境性能优异,阻燃改性后材料的氧指数可以达到27。在配合专用底漆后,该材料与声学覆盖层的附着力良好,可以对声学覆盖层提供有效防护。

碳化钨复合涂层的制备技术及其耐磨耐蚀性的研究进展

碳化钨涂层具有化学稳定性高、硬度大和耐磨性好等特点,常用于金属表面涂层的制备。从碳化钨涂层的不同制备原理出发,综述了超声速火焰喷涂、等离子喷涂、等离子熔覆、激光熔覆和真空熔覆等碳化钨涂层制备技术的国内外研究进展,分析了不同制备技术下涂层的耐磨性和耐蚀性,探讨了涂层制备技术存在的问题和未来的研究方向。

煤油流量对HVOF喷涂FeCrMoSi-Ti_(3)SiC_(2)涂层高温摩擦磨损性能的影响

目的提高燃煤锅炉四管的耐磨性能。方法使用喷雾造粒技术制备FeCrMoSi/Ti_(3)SiC_(2)复合粉末,并利用超音速火焰喷涂技术(HVOF)在12CrMoV基体上制备煤油流量分别为26、28、30、32 L/h的复合涂层。使用X射线衍射仪(XRD)、扫描电镜(SEM)及其自带的能谱仪(EDS)、Raman、维氏显微硬度计和摩擦磨损试验机研究FeCrMoSi/Ti_(3)SiC_(2)粉末及其涂层相组成、组织结构,检测涂层的力学性能,并对涂层在800℃下的摩擦学性能和磨损机理进行系统分析。结果粉末物相主要由Ti_(3)SiC_(2)、Fe-Cr和TiC组成,涂层的物相与粉末类似,但是新产生了SiC相,且随着煤油流量的升高,Ti_(3)SiC_(2)物相逐渐分解。当煤油流量为30、32 L/h时,涂层内Ti_(3)SiC_(2)物相大量分解。涂层的硬度和断裂韧性随着煤油流量的升高表现出先升高、后降低的趋势,孔隙率和磨损率呈现先减小、后增大的趋势。当煤油流量为28 L/h时,涂层磨损率最低,约为5.44×10^(-15)m^(3)/(N·m)。结论煤油流量为28 L/h时,涂层表面生成的SiO_(2)、TiO_(2)和Fe_(2)O_(3)等氧化物均匀分布在磨痕和对偶球表面,有效阻挡了对偶球和涂层的直接接触,使得涂层显示出最优异的摩擦学性能。涂层的主要磨损机制为氧化磨损和黏着磨损。

玻璃粉改性Ni60复合涂层的制备及其摩擦磨损性能

采用火焰喷涂技术在45钢表面制备了Ni基合金/玻璃粉复合涂层,通过扫描电镜(SEM)、能谱分析(EDS)、X射线衍射(XRD)、显微硬度分析以及销-盘式摩擦磨损试验等方法,研究了玻璃粉添加量对Ni基合金涂层微观结构、物相组成、硬度及摩擦学性能的影响.结果表明:随着玻璃粉含量的增加,复合涂层的显微硬度值呈现先升高后降低的趋势,最高达到681 HV 0.2.复合涂层的摩擦系数和体积磨损率均呈现先降低后升高的趋势.10%玻璃粉添加量的复合涂层摩擦系数低至0.13,磨损率低至0.21×10^(-5) mm^(3)/(N·m).表明适量玻璃粉的添加有利于Ni基合金涂层摩擦学性能的改善.

重熔处理对火焰喷涂Ni55A合金涂层组织和性能的影响

采用火焰喷涂技术在316L不锈钢表面制备Ni55A合金涂层,对涂层分别进行火焰重熔和真空重熔处理,分析了重熔处理对涂层微观形貌、硬度分布和孔隙率的影响。结果表明:火焰重熔和真空重熔可将火焰喷涂涂层的孔隙率从4.2%分别降低到0.34%和0.86%,并将基体与涂层界面处的结合状态由机械结合变为冶金结合;与火焰重熔相比,真空重熔后涂层与基体界面处的扩散层厚度更大,组织更粗大,孔隙形状更加不规则;火焰重熔和真空重熔后涂层的平均硬度分别提高了60,15 HV,火焰重熔后涂层的硬度较高且硬度波动较小。

热喷涂陶瓷-树脂复合涂层的研究现状

陶瓷-树脂复合涂层兼具陶瓷材料和树脂材料的优异性能,具有良好的力学性能、摩擦磨损性能、耐腐蚀性能等,可用于防腐、减摩等领域,是当前热喷涂领域的新兴研究方向。如在先进航空发动机制造领域,通过在陶瓷涂层中添加树脂材料以增加涂层孔隙率,使高温可磨耗封严涂层的可磨耗性显著提升。然而,陶瓷与树脂的热物理性质和化学性质差异较大,导致复合涂层沉积时粒子的熔融沉积行为呈现复杂多样性,对涂层性能的影响规律尚不清晰。目前,国内外对陶瓷-树脂复合涂层的制备和应用开展了大量的研究,在不同热喷涂方法下,陶瓷材料和树脂材料对复合涂层结构、性能的影响取得了显著成果。基于此,本文综述了采用火焰喷涂、等离子喷涂、反应等离子喷涂三种热喷涂技术制备陶瓷-树脂复合涂层的国内外相关研究;比较分析了喷涂过程中,不同热喷涂技术对陶瓷材料与树脂材料的影响规律;梳理了等离子喷涂工艺的优化方法;展望了未来陶瓷-树脂复合涂层的研究重点与应用方向。

低碳WC-12Co涂层制备工艺参数优化及熔锌腐蚀性能研究

为优化镀锌沉没辊表面涂层的抗熔锌腐蚀性能,采用超音速火焰喷涂技术在316L不锈钢基体上制备了低碳WC-12Co涂层,并设计了4因素3水平[L9(3^(4))]正交试验对喷涂工艺进行了优化,分别对低碳WC-12Co涂层的相结构、显微组织、孔隙率、结合强度和抗熔锌腐蚀性能进行了测试。结果表明:喷涂工艺参数的变化对涂层的相结构的影响很小,但对涂层的孔隙率影响显著,喷涂工艺参数中各因素对涂层孔隙率的影响按从大到小排列顺序为:煤油流量>喷涂距离>送粉率>氧气流量。获得最低孔隙率WC-12Co涂层喷涂工艺参数如下:煤油流量为26.5 L/h,氧气流量为55.2 m^(3)/h,送粉率为60 g/min,喷涂距离为326 mm,在这一参数下制备的高致密度的低碳WC-12Co涂层对熔融的锌液能起到很好的隔离作用,适合用于镀锌沉没辊的表面防护。

WC-10Co-4Cr含量对HVOF制备WC-10Co-4Cr/Ni60涂层性能的影响

为改善农业机械工作部件的耐磨性和耐腐蚀性能,提高其使用寿命,采用超音速火焰喷涂的技术,在45#钢表面制备WC-10Co-4Cr/Ni60涂层。在Ni60粉末中分别添加质量分数为0、10%、20%和30%的WC-10Co-4Cr粉末,探究WC-10Co-4Cr含量对WC-10Co-4Cr/Ni60涂层性能的影响。结果表明,制备的WC-10Co-4Cr/Ni60涂层组织均匀致密,涂层主要由γ(NiCr)相和WC相组成,含有少量的W_(2)C、Ni_(3)Fe和Cr_(3)Si相,没有明显的氧化脱碳现象。30%WC-10Co-4Cr/Ni60涂层的硬度达到9.35 GPa,是Ni60涂层的1.23倍,该涂层的耐磨性能最好,在摩擦115 m后,单位面积的总磨损量47.2 mg/cm^(2),比Ni60涂层减少了35.3%。20%WC-10Co-4Cr/Ni60涂层的断裂韧性最高为6.04 MPa·m^(1/2),相较于Ni60涂层提高了24.3%,此外,该涂层在酸性环境中的耐腐蚀性能均最佳。

火焰喷涂NiCrFe-Al-hBN涂层的高温稳定性研究

采用火焰喷涂方法在GH4169合金基体表面制备了NiCrFe-Al-hBN涂层,将NiCrFe-Al-hBN涂层在700℃和815℃进行热处理,分析了涂层的硬度、结合强度和微观形貌变化,并对不同温度热处理后的涂层与高温合金叶片的可磨耗性能进行了评价和分析。研究结果表明:NiCrFe-Al-hBN涂层经700℃高温处理50h、100h和150h后,随着热处理时间的延长,硬度变化不明显,硬度增加1.37%,结合强度与喷涂态相比相当。通过对涂层显微组织分析发现,在该温度热处理后涂层的显微组织未发生明显变化。在700℃,线速度450μm/s,50μm/s进给速度刮擦试验条件下,喷涂态NiCrFe-Al-hBN涂层的IDR值为3.36%,经700℃下处理150h后涂层的IDR值为3.86%,均满足压气机的使用要求,涂层在700℃下热稳定性能优异,可在该温度条件下长时间应用。涂层在815℃热稳定性不理想,随着热处理时间的延长,涂层硬度和结合强度均增加,可磨耗性能明显下降。

火焰喷涂尼龙1010涂层强度测量方法研究

利用理论分析与实验相结合的方法,模拟平面火焰喷涂,设计了一套简单、方便的平面结合强度拉拔实验模具及配套夹具,用于测量火焰喷涂聚合物涂层与基体的结合强度。试验结果表明:所得实验值与理论分析相符,当拉拔试件活塞直径为2mm左右时,比较适合用于火焰喷涂聚合物涂层与基体的结合强度的测量。证明这套模具在评价火焰喷涂聚合物涂层与基体结合强度方面有一定的实用价值。