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基于Aspen Plus软件的芳烃异构化工艺模拟与优化 被引量:1
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作者 符卓珍 《石油炼制与化工》 CAS CSCD 北大核心 2024年第4期79-84,共6页
针对中国石化海南炼油化工有限公司第二套对二甲苯(PX)装置C_(8)芳烃异构化反应流程,利用Aspen Plus软件建立了稳态模型,并优选Rplug模块作为反应器模块;模型验证结果表明,模拟计算值与工业实际标定值具有很好的吻合性,说明该模型预测... 针对中国石化海南炼油化工有限公司第二套对二甲苯(PX)装置C_(8)芳烃异构化反应流程,利用Aspen Plus软件建立了稳态模型,并优选Rplug模块作为反应器模块;模型验证结果表明,模拟计算值与工业实际标定值具有很好的吻合性,说明该模型预测结果合理且可靠。运用该模型进一步分析了反应温度、反应压力、进料氢烃比等工艺参数对C_(8)芳烃异构化反应性能的影响,结果表明:优选的反应温度为347℃,反应压力为0.46 MPa,氢烃摩尔比为3.9;温度、压力对PX产率几乎无影响,氢烃摩尔比为3.9时PX产率最高;降低温度、升高压力和适宜氢烃比有利于乙苯(EB)转化,低温、小氢烃摩尔比和中等压力有利于减少C_(8)芳烃损失;根据模拟优化结果调整异构化操作参数,可有效提高EB转化率、PX产率和PX的质量流量。 展开更多
关键词 ASpEN pLUS软件 C_(8)芳烃 异构化 稳态模拟 对二甲苯
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多模式出行信息对小汽车出行者转向P+R的影响
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作者 王馨玉 干宏程 +3 位作者 朱妍 黄玥 陆欢 温金鹏 《交通运输研究》 2024年第3期75-82,共8页
为倡导绿色出行理念,解决以往研究在处理重复观测数据时容易忽视的潜在相关性和个体异质性问题,针对如何利用智能手机APP提供的多模式出行信息引导小汽车出行者转向停车换乘(Park-and-Ride,P+R)模式进行了探究,同时引入广义线性混合模型... 为倡导绿色出行理念,解决以往研究在处理重复观测数据时容易忽视的潜在相关性和个体异质性问题,针对如何利用智能手机APP提供的多模式出行信息引导小汽车出行者转向停车换乘(Park-and-Ride,P+R)模式进行了探究,同时引入广义线性混合模型(Generalized Linear Mixed Model,GLMM)分析了多模式出行信息对小汽车出行者转向P+R意向的影响。首先,基于上海市路网设计意向调查问卷,整合了自驾和P+R两种出行方式的道路拥堵程度、出行时间、停车费用及地铁车厢座位情况等信息,并运用全因子设计法构建了24种不同信息水平组合的假设情景。然后,通过智能手机APP界面示意图向小汽车出行者展示这些多模式出行信息,并收集其转向P+R的意向数据。最后,运用GLMM方法处理同一个体重复决策数据中潜在的相关性和捕捉个体间的异质性。结果显示,GLMM的应用不仅解决了同一个体重复决策间的相关性,还揭示了不同个体对道路拥堵程度和地铁车厢座位情况的差异化关注;智能手机APP整合的多模式出行信息显著提升了小汽车出行者转向P+R的意愿,且这一转变占比达29.2%;高收入、长驾龄以及对P+R政策不了解的出行者转向P+R的意愿较低。研究表明,通过智能手机APP整合自驾和P+R的多模式出行信息能显著增强P+R方式的吸引力,可为提升P+R的普及率提供新思路,有效促进小汽车出行者向绿色出行方式的转变。 展开更多
关键词 绿色出行 多模式出行信息 停车换乘 意向调查 广义线性混合模型
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基于可重构PRS的一维电子波束转向Fabry-Perot天线设计
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作者 张海燕 石喜玲 +1 位作者 高丽珍 赵俊梅 《电子技术应用》 2024年第9期52-58,共7页
设计了一种具有一维电子波束转向的新型Fabry-Perot(F-P)谐振腔天线。该天线由同轴探针馈电的方形微带贴片天线作为辐射源,并采用加载PIN二极管的可重构部分反射表面(Partially Reflective Surface,PRS)实现波束转向。所设计的可重构PRS... 设计了一种具有一维电子波束转向的新型Fabry-Perot(F-P)谐振腔天线。该天线由同轴探针馈电的方形微带贴片天线作为辐射源,并采用加载PIN二极管的可重构部分反射表面(Partially Reflective Surface,PRS)实现波束转向。所设计的可重构PRS由6×6个花瓣型单元组成,并均分为相等的两部分Part 1和Part 2,分别由两个控制信号独立控制,因此可以有选择地调节每部分PIN二极管的开关状态。所设计的天线具有三种不同的辐射模式。测量结果表明,天线主波束能够在+9°、0°、-9°三种离散状态下自由切换。所有状态下重叠的阻抗带宽(|S_(11)|<-10 dB)为5.5%(5.43~5.74 GHz),最大增益达到14.2 dBi。 展开更多
关键词 Fabry-perot(F-p)谐振腔天线 电子波束转向 可重构pRS pIN二极管 离散状态
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基于ESO和分数阶PID的改进P&O控制策略
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作者 施昕昕 李冠飞 《电力工程技术》 北大核心 2023年第3期179-187,共9页
为了提高光伏电池转换效率、降低能量损失,有必要研究最大功率点跟踪(maximum power point tracking,MPPT)方法。针对传统扰动观察法(perturbation observation method,P&O)存在无法兼顾跟踪速度与稳态精度、在光照度发生较大变化... 为了提高光伏电池转换效率、降低能量损失,有必要研究最大功率点跟踪(maximum power point tracking,MPPT)方法。针对传统扰动观察法(perturbation observation method,P&O)存在无法兼顾跟踪速度与稳态精度、在光照度发生较大变化时会产生误判现象的问题,文中提出一种能适应环境变化的变步长P&O控制策略。首先,利用光伏电池刚启动时类似恒流源的特性获取当前光照度下的短路电流,通过固定电流法推导出最大功率点(maximum power point,MPP)的参考电压;其次,当光照度突变时,提出功率修正方法,并给出突变时的变步长调整策略;最后,设计基于线性扩张状态观测器(linear extended state observer,LESO)的分数阶比例积分微分(fractional order proportion integration differentiation,FOPID)控制器,可以对算法输出的参考电压进一步进行跟踪补偿。仿真结果表明,所提控制策略可以提高稳态精度和跟踪速度,有效提高光伏电池的输出功率。 展开更多
关键词 变步长 扰动观察法(p&O) 线性扩张状态观测器(LESO) 功率修正 分数阶比例积分微分(FOpID)控制 最大功率点(Mpp)
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On neutrino Oscillations and Predicting the 125 GEV Two Photon Emission State from p-p Collisions Based on the 5D Homogeneous Space-Time Projection Model 被引量:3
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作者 K. W. Wong G. Dreschhoff H. Jungner 《Journal of Modern Physics》 2012年第10期1450-1457,共8页
Previously the 5D homogeneous space-time metric was introduced with explicitly given projection operators in matrix form which map the 5D space-time manifold into a Lorentzian space-time. Based on this projection mode... Previously the 5D homogeneous space-time metric was introduced with explicitly given projection operators in matrix form which map the 5D space-time manifold into a Lorentzian space-time. Based on this projection model, vector field and spinor solutions are found to be expressible in terms of SU(2)xL and SU(3)xL, where L is the 4D Lorentz space-time group. The spinor solutions give the SU(2) leptonic states arising from space-time projection, whereas the SU(3) representation arises from conformal projection and gives the quarks, and due to gauge requirement leads to mesons and baryons. This process of mapping the 5D space-time manifold into the 4D space-time is at the basis of an analysis of the recent CERN experimental results, the presence of neutrino oscillations and the observed 125 GeV resonance in the p-p collisions, respectively. In fact, it is found that the spinor solution contains an oscillating phase, and the 125 GeV resonance is shown to be predictable, thereby 1) eliminating the need to introduce a Higgs vacuum, and 2) can be shown possibly to be an indicator for a missing heavy baryon octet. 展开更多
关键词 Neutrino Oscillation 125 GEV p-p Bound state HADRON Mass Levels 5D HOMOGENEOUS SpACE-TIME
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Reduction of Dimerization Tendency Due to the Decrease in Hybridization Index by Inclusion of 4s and 4p Semicore States as Valence States in Mo_(n)(n=2-18)Clusters:A First-Principles Study
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作者 Zhao-ye Gong Zhi-qiang Sun +5 位作者 Yan-wen Ding Shuai Zhang Zhen-long Lv Xiao-fei Wang Li-ben Li Hai-sheng Li 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2021年第5期639-648,I0004,共11页
Owing to the unique structural,electronic,and physico-chemical properties,molybdenum clusters are expected to play an important role in future nanotechnologies.However,their ground states are still under debate.In thi... Owing to the unique structural,electronic,and physico-chemical properties,molybdenum clusters are expected to play an important role in future nanotechnologies.However,their ground states are still under debate.In this study,the crystal structure analysis by particle swarm optimization(CALYPSO)approach is used for the global minimum search,which is followed by first-principles calculations,to detect an obvious dimerization tendency in Mo_(n)(n=2-18)clusters when the 4s and 4p semicore states are not regarded as the valence states.Further,the clusters with even number of atoms are usually magic clusters with high stability.However,after including the4 s and 4 p electrons as valence electrons,the dimerization tendency exhibits a drastic reduction because the average hybridization indices H_(sp),H_(sd),and H_(pd) are reduced significantly.Overall,this work reports new ground states of Mo_(n)(n=11,14,15)clusters and proves that semicore states are essential for Mo_(n) clusters. 展开更多
关键词 Density functional theory First-principles calculations Mo clusters Hybridization indices 4s and 4p Semicore states
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Relations Between Characteristic Function,Positive P-Representation and Coherent Thermal State 被引量:1
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作者 FAN Hong-Yi XU Xing-Lei Department of Material Science and Engineering,University of Science and Technology of China,Hefei 230026,China2 Department of Physics,Shanghai Jiao Tong University,Shanghai 200030,China3 Department of Physics,Heze University,Heze 274015,China 《Communications in Theoretical Physics》 SCIE CAS CSCD 2007年第7期67-70,共4页
We employ the coherent thermal states(a kind of entangled states)in thermal field dynamics to establisha complete entangled state formalism expressing pseudo-classical representations of density operator for light fie... We employ the coherent thermal states(a kind of entangled states)in thermal field dynamics to establisha complete entangled state formalism expressing pseudo-classical representations of density operator for light field.Especially,the relationship between the coherent thermal state and the characteristic function and the positive Prepresentation in quantum optics theory are obtained. 展开更多
关键词 coherent thermal state characteristic function positive p-representation
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Derivation of Martin-Hou Equation of State from Hard-particle Perturbation Theory 被引量:2
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作者 ZHANG Bing-jian (Department of Chemistry, Zhejiang University, Hangzhou 310027, P. R. China) HOU Yu-chun (Department of Chemical Engineering, Zhejiang University, Hangzhou 310027, P. R. China) 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2000年第1期49-56,共8页
In this paper, the Martin-Hou equation of state is derived by using a power series representation of radial distribution function and an analytic representation of multi-section potential based on the Barker-Henderso... In this paper, the Martin-Hou equation of state is derived by using a power series representation of radial distribution function and an analytic representation of multi-section potential based on the Barker-Henderson hard-particle perturbation theory including high-order terms. In the derivation, a theoretical form of Martin-Hou equation was obtained. It had a similar form and the same capability to predict P-V-T properties as the Martin-Hou equation and no additional data were required for evaluating the constants. The characteristic constants of the theoretical expression have certain relationships with the molecular parameters. 展开更多
关键词 perturbation theory Martin-Hou equation of state Theoretical expression p-V-T properties Molecular parameter
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BOUND STATES FOR A CLASS OF QUASILINEAR SCALAR FIELD EQUATIONS WITH POTENTIALS VANISHING AT INFINITY
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作者 Athanasios N.Lyberopoulos 《Acta Mathematica Scientia》 SCIE CSCD 2012年第1期197-208,共12页
We study the existence and non-existence of bound states (i.e., solutions in W1,P(RN)) for a class of quasilinear scalar field equations of the for -△pu+V(x)|u|p-2u=a(x)|u|q-2u,x∈RN,1〈P〈N,mwhen the po... We study the existence and non-existence of bound states (i.e., solutions in W1,P(RN)) for a class of quasilinear scalar field equations of the for -△pu+V(x)|u|p-2u=a(x)|u|q-2u,x∈RN,1〈P〈N,mwhen the potentials V(.)≥ 0 and a(.) decay to zero at infinity. 展开更多
关键词 p-LApLACIAN bound states decaying potentials Hardy potential weightedSobolev spaces
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EXISTENCE OF FAST-DECM GROUNDSTATE OF P-LAPLACIAN EQUATION
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作者 宣本金 陈祖墀 《Acta Mathematica Scientia》 SCIE CSCD 1999年第4期382-390,共9页
Using the shooting argument and an approximating method, this paper isconcerncd with the existence of fast-decay ground state of p-Laplacian equation: Apu+f(u)=0, in Rn, where f(u) behaves just like f(u) = uq - us, a... Using the shooting argument and an approximating method, this paper isconcerncd with the existence of fast-decay ground state of p-Laplacian equation: Apu+f(u)=0, in Rn, where f(u) behaves just like f(u) = uq - us, as s>q>np/(n-p) - 1. 展开更多
关键词 fast-decay ground state p-Laplacian equation shooting method
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ON THE RADIAL GROUND STATE OF P-LAPLACIAN EQUATION WITH GRADIENT TERM PERTURBATION
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作者 宣本金 陈祖墀 《Acta Mathematica Scientia》 SCIE CSCD 2000年第2期219-228,共10页
In this paper, authors consider the existence, uniqueness and nonexistence of the radial ground state to the following p-laplacian equation: Delta(p)u + u(q) - \Du\(sigma) = 0, x epsilon Rn, where 2 less than or equal... In this paper, authors consider the existence, uniqueness and nonexistence of the radial ground state to the following p-laplacian equation: Delta(p)u + u(q) - \Du\(sigma) = 0, x epsilon Rn, where 2 less than or equal to p < n, q is subcritical exponent, i.e. p < p* - 1 = [n(p - 1) + p]/(n - p), sigma > 0. Applying the shooting argument, Schauder's fixed point theorem and some delicate estimates of auxiliary funtions, they study the influence of the parameters n, p, q, sigma > 0 on the existence, uniqueness and nonexistence of the radial ground state to the above p-laplacian equation. 展开更多
关键词 p-Laplacian equation radial ground state shooting argument
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Congratulatory Letter to WFAS from Wu Yi the Vice-Premier of State Council of P.R.C.
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作者 WFAS Secretariat 《World Journal of Acupuncture-Moxibustion》 2007年第4期21-21,共1页
October 19,2007 Vice Premier Wu Yi,PRC On behalf of Chinese government,I would like to congratulate the 20th Foundation of World Federation of Acupuncture-Moxibustion Societies(WFAS)and International Acupuncture Congr... October 19,2007 Vice Premier Wu Yi,PRC On behalf of Chinese government,I would like to congratulate the 20th Foundation of World Federation of Acupuncture-Moxibustion Societies(WFAS)and International Acupuncture Congress which is to be held in Beijing,China.And also I give my warm welcome and regards to TCM/Acupuncture colleagues all over the world. 展开更多
关键词 Congratulatory Letter to WFAS from Wu Yi the Vice-premier of state Council of p.R.C
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一类p-Laplace方程束缚态解的存在性与集中性
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作者 石影 曾德华 《嘉兴学院学报》 2023年第6期35-43,共9页
研究p-Laplace方程-Δ_(p)u+|u|p^(-2)u=Q_(n)(x)|u|q^(-2)u,x∈ℝ^(N),其中:Δ_(p)u=div(|▽u|p^(-2)▽u),1<p<N,p<q<p^(*):=Np/N-p.当n→∞时,有界函数Q_(n)(x)的自焦核supp{Q^(+)_(n)}收缩到两个不同的点.采用惩罚函数和... 研究p-Laplace方程-Δ_(p)u+|u|p^(-2)u=Q_(n)(x)|u|q^(-2)u,x∈ℝ^(N),其中:Δ_(p)u=div(|▽u|p^(-2)▽u),1<p<N,p<q<p^(*):=Np/N-p.当n→∞时,有界函数Q_(n)(x)的自焦核supp{Q^(+)_(n)}收缩到两个不同的点.采用惩罚函数和山路引理方法证明了p-Laplace方程束缚态解的存在性和关于H^(1)范数的集中性. 展开更多
关键词 p-Laplace 束缚态解 存在性 集中性
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Valence band structure and density of states effective mass model of biaxial tensile strained silicon based on k·p theory
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作者 匡潜玮 刘红侠 +2 位作者 王树龙 秦珊珊 王志林 《Chinese Physics B》 SCIE EI CAS CSCD 2011年第12期335-340,共6页
After constructing a stress and strain model, the valence bands of in-plane biaxial tensile strained Si is calculated by k·p method. In the paper we calculate the accurate anisotropy valance bands and the splitti... After constructing a stress and strain model, the valence bands of in-plane biaxial tensile strained Si is calculated by k·p method. In the paper we calculate the accurate anisotropy valance bands and the splitting energy between light and heavy hole bands. The results show that the valance bands are highly distorted, and the anisotropy is more obvious. To obtain the density of states (DOS) effective mass, which is a very important parameter for device modeling, a DOS effective mass model of biaxial tensile strained Si is constructed based on the valance band calculation. This model can be directly used in the device model of metal-oxide semiconductor field effect transistor (MOSFET). It also a provides valuable reference for biaxial tensile strained silicon MOSFET design. 展开更多
关键词 biaxial tensile strained Si k · p theory valance band density of state effective mass
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Theoretical Study of Specific Heat and Density of States of MgB<sub>2</sub>Superconductor in Two Band Model
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作者 Anuj Nuwal Shyam Lal Kakani 《World Journal of Condensed Matter Physics》 2013年第1期33-42,共10页
MgB2 with Tc ≈ 40 K, is a record-breaking compound among the s-p metals and alloys. It appears that this material is a rare example of the two band electronic structures, which are weakly connected with each other. E... MgB2 with Tc ≈ 40 K, is a record-breaking compound among the s-p metals and alloys. It appears that this material is a rare example of the two band electronic structures, which are weakly connected with each other. Experimental results clearly reveal that boron sub-lattice conduction band is mainly responsible for superconductivity in this simple compound. Experiments such as tunneling spectroscopy, specific heat measurements, and high resolution spectroscopy show that there are two superconducting gaps. Considering a canonical two band BCS Hamiltonian containing a Fermi Surface of π- and σ-bands and following Green’s function technique and equation of motion method, we have shown that MgB2 possess two superconducting gaps. It is also pointed out that the system admits a precursor phase of Cooper pair droplets that undergoes a phase locking transition at a critical temperature below the mean field solution. Study of specific heat and density of states is also presented. The agreement between theory and experimental results for specific heat is quite convincing. The paper is organized in five sections: Introduction, Model Hamiltonian, Physical properties, Numerical calculations, Discussion and conclusions. 展开更多
关键词 Green’s Function p and d Holes Specific Heat Density of states
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具有AIE和ESIPT双重性质的荧光分子的合成及光物理性质初探
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作者 刘思阳 孙宇 +1 位作者 李云妍 张岩 《大学化学》 CAS 2023年第4期269-276,共8页
化学实验训练是化学专业教学中不可或缺的一环,但陈旧的实验方案在一定程度上限制了学生的探索和创新精神。本实验方案深入结合科学前沿的热门领域,利用羰基的亲核加成反应,制备了一种具有聚集诱导发光(AIE)和激发态分子内质子转移(ESI... 化学实验训练是化学专业教学中不可或缺的一环,但陈旧的实验方案在一定程度上限制了学生的探索和创新精神。本实验方案深入结合科学前沿的热门领域,利用羰基的亲核加成反应,制备了一种具有聚集诱导发光(AIE)和激发态分子内质子转移(ESIPT)性质的荧光小分子。实验研究了该分子的基本光物理性质及酸碱刺激响应能力。整个反应过程不使用有毒或危险性试剂,反应物只需在乙醇中回流0.5 h即可完成,充分体现绿色有机合成的策略。实验过程紧凑有序,现象明显且荧光色彩变化丰富,能够更好地激发学生的实验热情。同时,本实验充分融合了有机合成基本操作及核磁共振、红外光谱、紫外可见吸收光谱、荧光光谱等多种现代分析和表征方法,是一个直观有效的开放性实验,可有效提升学生的专业综合素质、培养学生的创新性研究能力。 展开更多
关键词 聚集诱导发光 激发态分子内质子转移 绿色合成 水杨醛 对苯二胺
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保留非线性的快速P-Q分解状态估计法 被引量:17
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作者 刘浩 侯博渊 《电力系统自动化》 EI CSCD 北大核心 1995年第1期26-30,34,共6页
提出了一种新的状态估计方法。该法保留了量测方程的非线性,同时又利用P-Q分解方法,提高状态估计的计算速度。
关键词 非线性 快速p-Q分解 状态估计 电力系统
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城市P&R出行者选择行为模型 被引量:5
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作者 何保红 王炜 陈峻 《哈尔滨工业大学学报》 EI CAS CSCD 北大核心 2009年第4期243-246,共4页
为了获得P&R用户出行特征以及选择影响因素,通过对南京市小汽车出行者的偏好调查,应用二项Logit模型建模分析,结果显示个人特征、出行特性以及对出行环境的评价等都在不同程度上影响出行者P&R的选择行为.其中出行者驾龄、收入... 为了获得P&R用户出行特征以及选择影响因素,通过对南京市小汽车出行者的偏好调查,应用二项Logit模型建模分析,结果显示个人特征、出行特性以及对出行环境的评价等都在不同程度上影响出行者P&R的选择行为.其中出行者驾龄、收入、出行目的以及道路拥挤、中心区停车位供给和停车收费对P&R的选择最为显著. 展开更多
关键词 p&R 偏好调查 LOGIT模型
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P-R方程在天然气热物性计算中的应用研究 被引量:9
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作者 杨帆 陈保东 +3 位作者 姜文全 石宇 李理 刘赫铭 《当代化工》 CAS 2013年第5期649-650,656,共3页
随着液化天然气(LNG)产业的兴起,天然气在我国能源结构中占有越来越重要的位置,对于天然气液化流程、LNG储存运输以及气化流程模拟的要求越来越高,天然气热物性质计算的精度在流程模拟中至关重要。采用P-R方程计算了密度和粘度的精度,... 随着液化天然气(LNG)产业的兴起,天然气在我国能源结构中占有越来越重要的位置,对于天然气液化流程、LNG储存运输以及气化流程模拟的要求越来越高,天然气热物性质计算的精度在流程模拟中至关重要。采用P-R方程计算了密度和粘度的精度,为天然气的流程模拟提供进一步的理论基础。 展开更多
关键词 天然气 热物性质 p-R方程 密度 粘度
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LKP方程在天然气相平衡计算中的应用 被引量:7
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作者 杨帆 陈保东 《节能技术》 CAS 2011年第6期502-505,共4页
由于液化天然气(LNG)所具有的低温特性,其在储运中必然会发生相态的变化。目前,对于天然气相平衡的计算大多应用状态方程法,采用P-R方程和SRK方程进行计算。本文采用了LKP方程进行了气液相平衡的计算,通过与实验值的对比表明:应用LKP状... 由于液化天然气(LNG)所具有的低温特性,其在储运中必然会发生相态的变化。目前,对于天然气相平衡的计算大多应用状态方程法,采用P-R方程和SRK方程进行计算。本文采用了LKP方程进行了气液相平衡的计算,通过与实验值的对比表明:应用LKP状态方程用于天然气及混合制冷剂的相平衡计算具有较好的精度,能够满足进一步天然气热物性计算的要求。 展开更多
关键词 天然气(NG) 液化流程 相平衡计算 LKp状态方程 p-R方程
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