Designing ultrastable P2/O3-type layered oxides for sodium ion batteries by regulating Na distribution and oxygen redox chemistry

P2/O3-type Ni/Mn-based layered oxides are promising cathode materials for sodium-ion batteries(SIBs)owing to their high energy density.However,exploring effective ways to enhance the synergy between the P2 and 03 phases remains a necessity.Herein,we design a P2/O3-type Na_(0.76)Ni_(0.31)Zn_(0.07)Mn_(0.50)Ti_(0.12)0_(2)(NNZMT)with high chemical/electrochemical stability by enhancing the coupling between the two phases.For the first time,a unique Na*extraction is observed from a Na-rich O3 phase by a Na-poor P2 phase and systematically investigated.This process is facilitated by Zn^(2+)/Ti^(4+)dual doping and calcination condition regulation,allowing a higher Na*content in the P2 phase with larger Na^(+)transport channels and enhancing Na transport kinetics.Because of reduced Na^(+)in the O3 phase,which increases the difficulty of H^(+)/Na^(+) exchange,the hydrostability of the O3 phase in NNZMT is considerably improved.Furthermore,Zn^(2+)/Ti^(4+)presence in NNZMT synergistically regulates oxygen redox chemistry,which effectively suppresses O_(2)/CO_(2) gas release and electrolyte decomposition,and completely inhibits phase transitions above 4.0 V.As a result,NNZMT achieves a high discharge capacity of 144.8 mA h g^(-1) with a median voltage of 3.42 V at 20 mA g^(-1) and exhibits excellent cycling performance with a capacity retention of 77.3% for 1000 cycles at 2000 mA g^(-1).This study provides an effective strategy and new insights into the design of high-performance layered-oxide cathode materials with enhanced structure/interface stability forSIBs.

Dislocation distribution model of mode Ⅲ propagation crack

Dislocation distribution functions of the edges of mode Ⅲ propagation crack subjected to three types of loads were studied by the methods of the theory of complex variable functions,by which,the problems researched were facilely transformed into Riemann-Hilbert problems and Keldysh-Sedov mixed boundary value problems. Analytical solutions of stresses,displacement and dynamic stress intensity factor were obtained by the measures of the theory of self-similar functions and corresponding differential and integral operation. In terms of the relationship between dislocation distribution functions and displacements,analytical solutions of dislocation distribution functions were obttained,and variational rules of dislocation distribution functions were depicted.

Spatial Distribution of Soil Total Nutrients of Farmland in Liaoning Province

[Objective]The aim was to reveal the spatial distribution characteristics of total nutrients in soil and provide a theoretical basis for farmland management and improvement of crop yield. [Method]GIS technique was used to analyze the spatial distribution characteristics of total C,total N,total P and total K for different soil layers in Liaoning Province. [Result]The results showed that the content of total C,total N,total P decrease from east to west,but the content of total K was high in north district of Liaoning Province. The content of total C,total N,total P and total K was higher in soil surface （0-20 cm） than the lower （20-40 cm）. Total K varied less with soil depth,and its mean content was respectively 17.64 g/kg and 17.08 g/kg for soil surface and soil lower layer. [Conclusion]The results of the distribution of soil total nutrients in different soil layers supplied a theory basis for farmland management.

P507溶剂浸渍树脂吸附Ga(Ⅲ)的性能研究

溶剂浸渍树脂(SIRs)分离法兼具溶剂萃取与离子交换两种分离方法的优点,且树脂制备简单,可根据实际情况灵活选用不同的载体和萃取剂,有望实现镓绿色、高效的分离回收。本文以苯乙烯-二乙烯基苯大孔吸附树脂(代号:HZ818)为载体、2-乙基己基膦酸单2-乙基己基酯(代号:P507)为萃取剂,制备P507 SIRs,研究了该SIRs在H 2SO 4体系中吸附Ga(Ⅲ)的性能。静态吸附实验表明:298 K时,P507 SIRs对Ga(Ⅲ)的最佳吸附pH值为3.3,对应吸附量为13.7 mg·g^(-1);吸附平衡时间为14 h,动力学吸附过程可用拟二级动力学方程描述;等温吸附均符合Langmuir等温吸附模型。动态吸附实验表明:低流速有利于P507 SIRs对Ga(Ⅲ)充分吸附;1.5 mol·L^(-1)的HCl可以将吸附于P507 SIRs上的Ga(Ⅲ)完全洗脱;P507 SIRs对Ga(Ⅲ)循环吸附稳定性能有待提高。在Ga(Ⅲ)-Zn(Ⅱ)、Ga(Ⅲ)-Cu(Ⅱ)二元混合体系中,P507 SIRs对Ga(Ⅲ)具有较好的吸附选择性,通过控制溶液pH值可以实现Ga(Ⅲ)的分离富集;在含Fe(Ⅲ)的Ga(Ⅲ)-Fe(Ⅲ)二元体系和Ga(Ⅲ)-Zn(Ⅱ)-Cu(Ⅱ)-Fe(Ⅲ)多元体系中,P507 SIRs对Fe(Ⅲ)表现出较好的吸附选择性,而对Ga(Ⅲ)吸附甚微,表明Fe(Ⅲ)的存在对P507 SIRs吸附Ga(Ⅲ)产生较大干扰。

慢性心力衰竭患者血清Ⅲ型前胶原氨基末端前肽、高迁移率族蛋白B1、NT-proBNP的表达及临床意义

目的:检测慢性心力衰竭(CHF)患者血清Ⅲ型前胶原氨基末端前肽(N-terminal peptide of typeⅢprocollagen,PⅢNP)、高迁移率族蛋白B1(high mobility group box-1,HMGB1)的表达水平,探讨二者与左室射血分数(LVEF)的相关性以及对CHF的诊断价值。方法:收集2021年12月至2022年11月期间于佳木斯大学附属第一医院心内科住院治疗的慢性心力衰竭患者90例为实验组,按照LVEF将其分为HFrEF组(n=33)、HFmrEF组(n=27)和HFpEF组(n=30)。此外选取排除心功能不全诊断的同期住院患者30例为对照组。对比各组患者血清中氨基末端脑钠肽前体(NT-proBNP)、PⅢNP、HMGB1水平的差异,分析PⅢNP、HMGB1水平与心功能指标的相关性,并借助ROC曲线评估NT-proBNP、HMGB1、PⅢNP单独以及联合应用对不同表型CHF患者的诊断价值。结果:HFrEF组PⅢNP、HMGB1及NT-proBNP水平均高于HFpEF组和对照组,差异有统计学意义(P<0.05)。PⅢNP与HMGB1呈正相关(P<0.05);PⅢNP、HMGB1均与NT-proBNP、LVEDD呈正相关,与LVEF呈明显负相关(P<0.05);HMGB1与LAD呈正相关(P<0.05),PⅢNP与LAD无明显相关性(P>0.05)。血清NT-proBNP、HMGB1、PⅢNP水平诊断HFrEF患者的AUC分别为0.867、0.871、0.779;诊断HFmrEF患者的AUC分别为0.840、0.804、0.760;诊断HFpEF患者的AUC分别为0.851、0.728、0.769。多生物标志物模型NT-proBNP+PⅢNP、NT-proBNP+HMGB1、NT-proBNP+PⅢNP+HMGB1诊断HFrEF患者的AUC分别为0.887、0.954、0.954;诊断HFmrEF患者的AUC分别为0.942、0.937、0.951;诊断HFpEF患者的AUC分别为0.904、0.910、0.914。结论:CHF患者血清PⅢNP、HMGB1明显升高,并且,CHF患者血清PⅢNP、HMGB1水平与心脏功能指标具有良好的相关性,说明PⅢNP、HMGB1可反映疾病的严重程度。PⅢNP、HMGB1对各表型CHF患者均具有诊断价值,并且,多生物标志物联合检测能提高对CHF患者诊断的敏感性。

纳武利尤单抗联合安罗替尼对Ⅲb~Ⅳ期NSCLC的疗效观察及对miR-1269、miR-204-5p表达的影响

目的探究纳武利尤单抗联合安罗替尼治疗Ⅲb~Ⅳ期非小细胞肺癌(NSCLC)患者的效果及对微小RNA-1269(miR-1269)、miR-204-5p表达的影响。方法选取Ⅲb~Ⅳ期NSCLC患者82例,患者分配为对照组、观察组,各41例,使用随机数字表法,对照组采用安罗替尼治疗,观察组在对照组的基础上采用纳武利尤单抗治疗;比较两组患者的疗效、治疗前后肿瘤标志物癌胚抗原(CEA)、细胞角蛋白19片段抗原21-1(CYFRA21-1)、miR-1269、miR-204-5p表达水平和不良反应的发生率。结果观察组患者治疗后疾病控制率(87.80%,36/41)显著高于对照组(68.29%,28/41)(χ^(2)=4.556,P=0.033);与治疗前相比,治疗后观察组和对照组的CEA、CYFRA21-1、miR-1269水平显著降低,miR-204-5p水平显著升高(P<0.05);治疗后与对照组相比,观察组的CEA、CYFRA21-1、miR-1269水平显著降低,miR-204-5p水平显著升高(P<0.05);不良反应两组间比较,差异无统计学意义(P>0.05)。结论纳武利尤单抗联合安罗替尼治疗Ⅲb~Ⅳ期NSCLC患者可降低患者肿瘤标志物的水平,调节miR-1269、miR-204-5p的表达,效果更好。

基于ERK/p38 MAPK信号通路探究解毒活血汤治疗Ⅲ型前列腺炎的作用机制

目的探究解毒活血汤调控ERK/p38 MAPK信号通路治疗Ⅲ型前列腺炎的作用机制。方法采用去势手术+苯甲酸雌二醇(EB)诱导慢性前列腺炎大鼠模型。36只SD大鼠随机分为空白组(生理盐水,4 mL·kg^(-1))、模型组(生理盐水,4 mL·kg^(-1))、阳性药物对照组(前列康片混悬液,4 mL·kg^(-1))、解毒活血汤低(4 mL·kg^(-1))、中(8mL·kg^(-1))、高剂量组(12 mL·kg^(-1)),每组6只,所有实验动物连续给药30 d。苏木精-伊红(HE)染色观察各组大鼠组织病理学变化;免疫组化法、RT-PCR、Western Blot技术检测相关炎症因子及蛋白表达水平。结果与正常对照组相比,慢性前列腺炎大鼠前列腺组织增生及水肿明显、炎症浸润增加,而阳性药物对照组及解毒活血汤各剂量组大鼠前列腺组织病变减轻或消失、炎症浸润减少,且与解毒活血汤剂量成正比;免疫组化表示模型组p38、P-p38、STAT3、P-STAT3表达较高,阳性药物对照组、不同剂量解毒活血汤组的p38、P-p38、STAT3、P-STAT3表达呈下降趋势,且均低于模型组。RT-PCR结果显示阳性药物对照组及解毒活血汤低、中、高剂量组均能降低大鼠前列腺组织中TNF-α、IL-2、IL-6的表达水平;Western Blot检测提示大鼠疾病发生进展过程中p38、P-p38、P-ERK1/2、STAT3、P-STAT3呈高表达状态,解毒活血汤能够降低其表达,从而降低相关炎症因子的过度激活。结论解毒活血汤能够抑制ERK/p38 MAPK信号通路的过度激活,从而降低IL-2、IL-6、TNF-α等炎症因子的表达,以改善前列腺组织炎症反应。

The Limitations of Polygenic Hypothesis and Theorizing about Dual Multiple Factors and Three Normal Distributions

The original data of Nilsson-Ehle experiment in wheat were analyzed with existent genetic knowledge. It indicated that the core of polygenic hypothesis from this experiment was that a character similarity produced by additive effect of multiple genes was the basis of continuous variation. Its precondition was for effective genes to have equal effect, to show merodominance and binomial distribution and to inherit independently. In fact, quantitative characters were determined by many genes with different property, effect and behavior. So it was difficult to solve all problems of continuous variation by the aid of polygenic hypothesis. The researchers should seek new ways. With Mendelian group as research object and by means of Lyapunov central limit theorem it was proved that both genotypic value G and the environmental effect in a niche E were subordinated to the normal distribution and respectively. According to additivity of the normal distribution the phenotype P = G + E also obeyed the normal distribution P = G + E ~ and quantitative characters showed continuous variation, whether or not the linkage was presented, whether or not every gene effect was equal, whether or not there were dominance and what kind of dominance between alleles. Moreover it was discussed that the quantitative characters in self-fertilized organism and clone were submitted to the normal distribution and presented continuous variation too.

Efficient removal of Al(Ⅲ)and P507 from high concentration MgCl_(2)solution based on in-situ reaction strategy

For a highly efficient recycling of a wastewater containing a high concentration of MgCl_(2),Al(Ⅲ)and P507 were scheduled to be removed in advance.In this study,the in-situ removal of Al(Ⅲ)and P507 from a high concentration MgCl_(2)solution at different pH values and Al/P molar ratios was investigated.The results showed that P507 formed organic complexes of Al_(x)(OH)_y^(Z+)-P507 at pH of 2.0-4.0.At pH of 4.0-5.0,Al(Ⅲ)precipitated and transferred into Al(OH)_(3)with a flocculent amorphous morphology.Active sites on the Al(OH)_(3)surface enhanced the removal efficiency of P507.At pH of 6.0-6.5,Al(Ⅲ)and Mg(Ⅱ)formed layered crystalline Al(OH)_(3)and MgAl_(2)(OH)_(8with)small pore channels and fewer active sites,resulting in a reduced removal efficiency of P507.When the Al/P molar ratio exceeded 13 and the pH was between 4.0 and 5.0,the removal rates of both Al(Ⅲ)and P507 were higher than98%,while the concentration loss of Mg(Ⅱ)was only 0.2%-0.9%.

血清PⅢNP、TIMP-1及左心室射血分数联合检测对顽固性心衰的诊断价值

目的探讨血清PⅢNP、TIMP-1、左心室射血分数(LVEF)联合检测对顽固性心衰的诊断价值。方法80例顽固性心衰患者根据NYHA心功能分级分为Ⅲ级组和Ⅳ级组,选取同期40名健康者作为对照组。对比三组的血清PⅢNP、TIMP-1以及LVEF,绘制ROC曲线分析血清PⅢNP、TIMP-1及LVEF联合检测对顽固性心衰的诊断效能。结果Ⅳ级组、Ⅲ级组、对照组的血清PⅢNP水平依次降低,血清TIMP-1及LVEF水平依次升高,差异有统计学意义(P<0.05)。ROC曲线显示,血清PⅢNP、TIMP-1及LVEF联合检测诊断顽固性心衰的AUC为0.892,高于各指标单独诊断(P<0.05)。结论血清PⅢNP、TIMP-1及LVEF对评价顽固性心衰患者的心功能具有重要价值,且三项指标联合检测可提升对顽固性心衰的诊断效能。

The Study on the Stability Constant and Species Distribution of Eu (III) and Tb (III) Complexes with BDBPH

The stability constants and species distributions of complexes of two lanthanide ions, Eu（Ⅲ） and Tb（Ⅲ）, with a macrocyclic ligand, BDBPH, in 1：1 and 2：lsystem, were determined potentiometrically at 25.0 ℃ and I=0.100 mol L^-l. The two metal ions could form deprotonated mono- or dinuclear complexes with BDBPH after the first two protons of the ligand completely neutralized. At higher pH values, Eu（Ⅲ） could not form hydroxy complexes with BDBPH, while Tb（Ⅲ） could form hydroxy complexes in the type of M2L（OH）, M2L（OH）2, and M2L（OH）3.

Analysis of the characteristics of snow drop size distribution in the Qilian Mountains

Under the Watershed Allied Telemetry Experimental Research （WATER） project, a significant amount of snow size data was collected from March to April 2008. However, because of limited observation data for the Qinghai-Tibet Plateau, the modeling behavior was not satisfactory. This paper demonstrates characteristics of the snow drop size distribution （SSD） in this region. The experimental area is located in the northeastern part of the Qinghai-Tibet Plateau. The Heihe River Basin, which is the second largest interior river basin in China and is located on the northern slopes of the Qilian Mountains, was selected as the simulation region. This basin ranges from approximately 5,000 m to 1,000 m in elevation. A new generation Parsivel disdrometer, the OTT Parsivel, was used for measurements. Four data sets were compiled to determine the average distributions for four different snowfall rates. The characteristics of the snow particle size distribution in the mountainous area were analyzed. Similar to the raindrop distribution, there was a multi-peak structure. Most peaks appear in the D 〈 2 mm region （D： diameter of the snow drop size）. An M-P distribution and a Г distribution were developed based on the precipitation data observed in Qilian mountainous area. We found that the Г distribution has a better fit than the M-P distribution for the actual distribution. In addition, we observed that the intercept parameter （N0） and the slope parameter （Λ） correlate well with the shape parameter （μ）. The disdrometer data can also be used to model the reflectivity factor （ZH） and differential reflectivity factor （ZDR）. The radar reflectivity （ZHH, ZVV） and differential reflectivity （ZDR） were modeled in order to facilitate understanding of the connections between radar and ground measurements, and were used to support work for the improvement of rainfall estimates by polarimetric radar. Rain rate estimation using radar measurements was based on empirical models, such as the Z-R relationship and R（ZH, ZDR） in the Qilian mountainous areas. The relationship of R=0.017×100.079×ZH-0.022×ZDR is better than R=0.019×100.078×ZH for estimating R （melted snow）. The normalized errors （NE） of R（ZH） and R（ZH, ZDR） are 13.22% and 5.20%, respectively.

Distribution, Function and Polymorphism Characteristics of Microsatellites in Pyropia yezoensis Transcriptome

The distribution, putative function and polymorphism characteristics of simple sequence repeats(SSRs) in P. yezoensis transcriptome were analyzed in this study. In total, 3076 SSRs were detected among 2681 unigenes. Trinucleotide types were dominant, constituting 91.87% of all the microsatellites. The most abundant SSR was CCG(71.03%) and the second abundant one was AGC(234, 7.61%). A total of 111(3.61%) dinucleotide types were found and the most abundant one was AC(51, 1.66%) which was followed by CG(34, 1.11%). SSRs identified showed a GC bases preference;GC bases constituted 89.73% of all the SSR bases. SSRs occurrence number decreased as repetitions increased. Annotation results exhibited that the majority of SSRs-containing unigenes have the functions of ‘metabolic process’,‘binding’ and ‘catalytic activity’ and existed as the forms of ‘cell’,‘cell component’ and ‘organelle’. The dominant amino acids that SSRs coded were Ala(28.59%), Arg(26.02%), Gly(14.35%) and Pro(13.65%). Amplification results showed that 3 out 23 SSRs from transcriptome(13.04%) and 8 out 77 SSRs from genome(10.39%) were polymorphic.

Content subscribing mechanism in P2P streaming based on gamma distribution prediction

P2P systems are categorized into tree-based and mesh-based systems according to their topologies. Mesh-based systems are considered more suitable for large-scale lnternet applications, but require optimization on latency issue. This paper proposes a content subscribing mechanism （CSM） to eliminate unnecessary time delays during data relaying. A node can send content data to its neighbors as soon as it receives the data segment. No additional time is taken during the interactive stages prior to data segment transmission of streaming content. CSM consists of three steps. First, every node records its historical segments latency, and adopts gamma distribution, which possesses powerful expression ability, to express latency statistics. Second, a node predicts subscribing success ratio of every neighbor by comparing the gamma distribution parameters of the node and its neighbors before selecting a neighbor node to subscribe a data segment. The above steps would not increase latency as they are executed before the data segments are ready at the neighbor nodes. Finally, the node, which was subscribed to, sends the subscribed data segment to the subscriber immediately when it has the data segment. Experiments show that CSM significantly reduces the content data transmission latency.

Hybrid ants-like search algorithms for P2P media streaming distribution in ad hoc networks

Media streaming delivery in wireless ad hoc networks is challenging due to the stringent resource restrictions,po-tential high loss rate and the decentralized architecture. To support long and high-quality streams,one viable approach is that a media stream is partitioned into segments,and then the segments are replicated in a network and served in a peer-to-peer(P2P) fashion. However,the searching strategy for segments is one key problem with the approach. This paper proposes a hybrid ants-like search algorithm(HASA) for P2P media streaming distribution in ad hoc networks. It takes the advantages of random walks and ants-like algorithms for searching in unstructured P2P networks,such as low transmitting latency,less jitter times,and low unnecessary traffic. We quantify the performance of our scheme in terms of response time,jitter times,and network messages for media streaming distribution. Simulation results showed that it can effectively improve the search efficiency for P2P media streaming distribution in ad hoc networks.

Auto Distribution of Tag Table in P2P Control System

In control system, tag table is like a dictionary mapping tagname to address. Therefore, applications on workstation may use tagname to access different data in system. Normally tag table generated by configuration software will transfer to other workstation in system manually after system configuration, which is inconvenient and failible. The development of peer-to-peer （P2P） network technology and the realization of control system based on P2P network make the auto distn＇bution of tag table possible. In this paper based on file sharing technology the presented method realizes the auto distn＇bution of tag table.

A new quantum mechanical photon counting distribution formula

By virtue of the density operator＇s P-representation in the coherent state representation, we derive a new quantum mechanical photon counting distribution formula. As its application, we calculate photon counting distributions for some given light fields. It is found that the pure squeezed state＇s photon counting distribution is related to the Legendre function, which is a new result.

A fast commonly-used algorithm of P-III distribution curve and its application

Based on theoretical analysis and studying other methods, P-III curve is transformed into an incomplete G function by means of mathematical expression transformation, thus the mathematical model of the fast commonly-used algorithm is drawn out. Algorithm comparison and practices demonstrate that the mathematical model has an easy algorithm, agile resolution process, very good commonality, faster convergence rate and better calculation accuracy, and can be applied to other respects.

基于NSGA-Ⅲ算法的分布式光伏储能系统优化配置方法

在电力系统“双高”背景下,可再生能源发电快速增长,对配电网稳定性构成挑战,研究储能优化配置对提高分布式光伏消纳能力及配电网经济可靠运行具有重要意义。针对配电网的电压支撑需求与经济运行需求,提出了一种基于NSGA-Ⅲ算法的分布式储能双层多目标优化配置方法。在外层选址定容模型中,以分布式储能的位置和容量为决策变量,综合考虑储能总成本、配电网电压偏移和负荷波动,以提升配电网电压稳定性与经济性;在内层优化运行模型中,以储能的充放电状态为决策变量,考虑储能安装后的运营收益,以提高经济性;利用电压稳定指数识别系统中电压稳定性薄弱的节点作为预选址节点,以提高求解效率。算例分析表明,该储能配置方案及运行优化策略可实现储能投资效益最优,有效改善电网电压质量和功率稳定性,提高配电网运行水平。

P-Ⅲ型分布次序统计量期望值数值计算

本文探讨了P-Ⅲ型(皮尔逊Ⅲ型)分布次序统计量期望值数值计算的公式、数值计算的精度控 制等问题,在此基础上提出了P-Ⅲ型分布次序统计量期望值的数值计算框架。经检验,该计算框架突破了 以往次序统计量期望值数值计算的瓶颈,样本长度和数值计算精度均满足科研和生产实践的要求。