The second order effect is the interaction between the vertical load and the deformation in a vertically forced element. In order to deduce a more brief but practical method, which has considered the second order effe...The second order effect is the interaction between the vertical load and the deformation in a vertically forced element. In order to deduce a more brief but practical method, which has considered the second order effect in a sway frame, some factors which affect the second order deformation in a sway frame should be generalized based on a more accurate method. Nonlinear finite element is adopted in this paper, and according to this theory, a program, which can calculate the inner force and the deformation of the sway frame considering the second order effects is coded.展开更多
The second-order effect of axial force on horizontal vibrating characteristics of a large-diameter pipe pile is theoretically investigated.Governing equations of the pile-soil system are established based on elastodyn...The second-order effect of axial force on horizontal vibrating characteristics of a large-diameter pipe pile is theoretically investigated.Governing equations of the pile-soil system are established based on elastodynamics.Threedimensional wave equations of soil are decoupled through differential transformation and variable separation.Consequently,expressions of soil displacements and horizontal resistances can be obtained.An analytical solution of the pile is derived based on continuity conditions between the pile and soil,subsequently from which expressions of the complex impedances are deduced.Analyses are carried out to examine the second-order effect of axial force on the horizontal vibrating behavior of the pipe pile.Some conclusions can be summarized as follows： stiffness and damping factors are decreased with the application of axial force on the pile head; distributions of the pile horizontal displacement and rotation angle are regenerated due to the second-order effect of the applied axial force; and redistributions of the bending moment and shearing force occur due to the second-order effect of the applied axial force.展开更多
A chiral lanthanide metal-organic framework based on enantiopure camphoric acid （D-H2cam）, [Nd3（D-cam）8（H2O）4Cl]n （1）, has been synthesized and characterized by single-crystal X-ray structural analysis, elemen...A chiral lanthanide metal-organic framework based on enantiopure camphoric acid （D-H2cam）, [Nd3（D-cam）8（H2O）4Cl]n （1）, has been synthesized and characterized by single-crystal X-ray structural analysis, elemental analysis, IR, thermal gravimetric, and X-ray powder diffraction. Crystal data for the title compound are as follows： orthorhombic system, space group P212121 with a = 13.8287（7）, b = 14.0715（7）, c = 25.7403（12） A^°, V = 5008.8（4） A^°3, Mr = 1333.08, Z = 4, F（000） = 2644, Dc = 1.768 g/cm^3, μ（MoKα） = 3.189 mm^-1, the final R = 0.0351 and wR = 0.0814 （I 〉 2σ（I））. Compound 1 displays an 8-connected bcu topology 3D framework and hydrogen-bonding interactions stabilize the solid-state structure. The vibrational circular dichroism （VCD） spectrum and second-order nonlinear optical effect of compound 1 have been studied in the solid state.展开更多
This paper is a continuation of [1]. An example is discussed in derail to illustrate the second order effects. Numerical calculations for the second order elastic material for the z-direction displacement and the stre...This paper is a continuation of [1]. An example is discussed in derail to illustrate the second order effects. Numerical calculations for the second order elastic material for the z-direction displacement and the stress t(rz) are carried out. It is found that the second order effect is to reduce z-direction displacement and to decrease t(rz)inside the circle but to increase its value outside the circle.展开更多
This paper is a continuation of [1]. A closed form solution to the second order elasticity problem, when an isotropic compressible elastic half-space undergoes a deformation owing to a non-uniformly distributed shear ...This paper is a continuation of [1]. A closed form solution to the second order elasticity problem, when an isotropic compressible elastic half-space undergoes a deformation owing to a non-uniformly distributed shear load, is presented. The method of integral transform is employed to determine the solutions.展开更多
A novel transition appeared above thc glass transition temperature of chlorinated polyethylene (CPE) for binaryblends of CPE and additives such as organic small molecules or oligomers. This transition was assigned to ...A novel transition appeared above thc glass transition temperature of chlorinated polyethylene (CPE) for binaryblends of CPE and additives such as organic small molecules or oligomers. This transition was assigned to the dissociation ofintermolecular hydrogen bonds between the polymer ard additive within the edditive rich phase. Of particular interest is thata novel pyramid crystal was observed in the annealed CPE/hindered phenol blends. Another intriguing observation is thatthese polymer/small molecule blends organized by intermolecular hydrogen bonding have several potential properties, suchas shape-memorization, self-restoration, self-adhesiveness and super damping.展开更多
文摘The second order effect is the interaction between the vertical load and the deformation in a vertically forced element. In order to deduce a more brief but practical method, which has considered the second order effect in a sway frame, some factors which affect the second order deformation in a sway frame should be generalized based on a more accurate method. Nonlinear finite element is adopted in this paper, and according to this theory, a program, which can calculate the inner force and the deformation of the sway frame considering the second order effects is coded.
基金National Natural Science Foundation of China under Grant Nos.51622803 and 51708064the National Key Research and Development Program of China under Grant No.2016YFE0200100
文摘The second-order effect of axial force on horizontal vibrating characteristics of a large-diameter pipe pile is theoretically investigated.Governing equations of the pile-soil system are established based on elastodynamics.Threedimensional wave equations of soil are decoupled through differential transformation and variable separation.Consequently,expressions of soil displacements and horizontal resistances can be obtained.An analytical solution of the pile is derived based on continuity conditions between the pile and soil,subsequently from which expressions of the complex impedances are deduced.Analyses are carried out to examine the second-order effect of axial force on the horizontal vibrating behavior of the pipe pile.Some conclusions can be summarized as follows： stiffness and damping factors are decreased with the application of axial force on the pile head; distributions of the pile horizontal displacement and rotation angle are regenerated due to the second-order effect of the applied axial force; and redistributions of the bending moment and shearing force occur due to the second-order effect of the applied axial force.
基金supported by National Natural Science Foundation of China(21401147)Basic Research Program of Natural Science from Shaanxi Provincial Government(2015JQ2032)+2 种基金Scientific Research Program from Education Department of Shaanxi Provincial Government(2013JK0654)Opening Foundation from State Key Laboratory of Coordination Chemistry in Nanjing University(201219)the Program for Distinguished Young Scholars of Xi’an Polytechnic University(201403)
文摘A chiral lanthanide metal-organic framework based on enantiopure camphoric acid （D-H2cam）, [Nd3（D-cam）8（H2O）4Cl]n （1）, has been synthesized and characterized by single-crystal X-ray structural analysis, elemental analysis, IR, thermal gravimetric, and X-ray powder diffraction. Crystal data for the title compound are as follows： orthorhombic system, space group P212121 with a = 13.8287（7）, b = 14.0715（7）, c = 25.7403（12） A^°, V = 5008.8（4） A^°3, Mr = 1333.08, Z = 4, F（000） = 2644, Dc = 1.768 g/cm^3, μ（MoKα） = 3.189 mm^-1, the final R = 0.0351 and wR = 0.0814 （I 〉 2σ（I））. Compound 1 displays an 8-connected bcu topology 3D framework and hydrogen-bonding interactions stabilize the solid-state structure. The vibrational circular dichroism （VCD） spectrum and second-order nonlinear optical effect of compound 1 have been studied in the solid state.
文摘This paper is a continuation of [1]. An example is discussed in derail to illustrate the second order effects. Numerical calculations for the second order elastic material for the z-direction displacement and the stress t(rz) are carried out. It is found that the second order effect is to reduce z-direction displacement and to decrease t(rz)inside the circle but to increase its value outside the circle.
文摘This paper is a continuation of [1]. A closed form solution to the second order elasticity problem, when an isotropic compressible elastic half-space undergoes a deformation owing to a non-uniformly distributed shear load, is presented. The method of integral transform is employed to determine the solutions.
文摘A novel transition appeared above thc glass transition temperature of chlorinated polyethylene (CPE) for binaryblends of CPE and additives such as organic small molecules or oligomers. This transition was assigned to the dissociation ofintermolecular hydrogen bonds between the polymer ard additive within the edditive rich phase. Of particular interest is thata novel pyramid crystal was observed in the annealed CPE/hindered phenol blends. Another intriguing observation is thatthese polymer/small molecule blends organized by intermolecular hydrogen bonding have several potential properties, suchas shape-memorization, self-restoration, self-adhesiveness and super damping.
