Petrology,geochemistry,and crystal size distribution of the basaltic andesite-dacite association at Mt.Sumbing,Central Java,Indonesia:Insights to magma reservoir dynamics and petrogenesis

Ten rock samples consisting of one pyroclastic density current(PDC1)deposit,seven lava flows(LF1–7),and two summit lava domes(LD1,2)were studied to understand the petrogenesis and magma dynamics at Mt.Sumbing.The stratigraphy is arranged as LF1,PDC1,LF2,LF3,LF4,LF5,LF6,LF7,LD1,and LD2;furthermore,these rocks were divided into two types.TypeⅠ,observed in the oldest(LF1)sample,has poor MgO and high Ba/Nb,Th/Yb and Sr.The remaining samples(PDC1–LD2)represent typeⅡ,characterized by high MgO and low Ba/Nb,Th/Yb and Sr values.We suggest that type I is derived from AOC(altered oceanic crust)-rich melts that underwent significant crustal assimilation,while typeⅡoriginates from mantle-rich melts with less significant crustal assimilation.The early stage of typeⅡmagma(PDC1–LF3)was considered a closed system,evolving basaltic andesite into andesite(55.0–60.2 wt%SiO_(2))with a progressively increasing phenocryst(0.30–0.48φ_(PC))and decreasing crystal size distribution(CSD)slope(from-3.9 to-2.9).The evidence of fluctuating silica and phenocryst contents(between 55.9–59.7 wt%and 0.25–0.41φ_(PC),respectively),coupled with the kinked and steep(from-5.0 to-3.3)CSD curves imply the interchanging condition between open(i.e.,magma mixing)and closed magmatic systems during the middle stage(LF4–LF6).Finally,it underwent to closed system again during the final stage(LF7–LD2)because the magma reached dacitic composition(at most 68.9 wt%SiO_(2))with abundant phenocryst(0.38–0.45φ_(PC))and gentle CSD slope(from-4.1 to-1.2).

Zircon U-Pb geochronologic,geochemical and Sr-Nd-Pb isotope characteristics of the Beidaban granites in the North Qilian Orogenic Belt:Petrogenesis and tectonic implications

The tectonic evolution and crustal accretion process of the North Qilian Orogenic Belt(NQOB)are still under debate because of a lack of integrated constraints,especially the identifi cation of the tectonic transition from arc to initial collision.Here we present results from zircon U-Pb geochronology,whole-rock geochemistry,and Sr-Nd-Pb isotope geochemistry of the Beidaban granites to provide crucial information for geodynamic evolution of NQOB.Zircon U-Pb dating yields an age of 468±10 Ma for the Beidaban granites and most of the Beidaban samples contain amphibole,are potassium-rich,and have A/CNK values ranging from 0.7 to 0.9,illustrating that the Middle Ordovician Beidaban granites are K-rich,metaluminous,calc-alkaline granitoid.The geochemical characteristics indicate that the Beidaban granites are transitional I/S-type granitoids that formed in an arc setting.The isotopic compositions of initial(87 Sr/86 Sr)i values ranging from 0.70545 to 0.71082(0.70842 on average)andεNd(t)values ranging from−10.9 to−6.7(−8.8 on average)with two-stage Nd model ages(T DM2)of 1.74-2.08 Ga suggest that the Beidaban granites originated from Paleoproterozoic crustal materials.In addition,the initial Pb isotopic compositions(^(206)Pb/^(204)Pb=19.14-20.26;^(207)Pb/^(204)Pb=15.71-15.77;^(208)Pb/^(204)Pb=37.70-38.26)and geochemical features,such as high Th/Ta(17.43-30.12)and Rb/Nb(6.01-15.49)values,suggest that the Beidaban granite magma source involved recycled crustal components with igneous rocks.Based on these results in combination with previously published geochronological and geochemical data from other early Paleozoic igneous rocks,we suggest that the timing of the tectonic transition from arc to the initial collision to the fi nal closure of the North Qilian Ocean can be constrained to the Middle-Late Ordovician(ca.468–450 Ma).

Petrogenesis and tectonic implications of the Silurian adakitic granitoids in the eastern segment of the Qilian Orogenic Belt,Northwest China

Geodynamic mechanism responsible for the generation of Silurian granitoids and the tectonic evolution of the Qilian orogenic belt remains controversial. In this study, we report the results of zircon U–Pb age, and systematic whole-rock geochemical data for the Haoquangou and Liujiaxia granitoids within the North Qilian orogenic belt and the Qilian Block, respectively, to constrain their petrogenesis, and the Silurian tectonic evolution of the Qilian orogenic belt. Zircon U–Pb ages indicate that the Haoquangou and Liujiaxia intrusions were emplaced at423 ± 3 Ma and 432 ± 4 Ma, respectively. The Haoquangou granodiorites are calc-alkaline, while the Liujiaxia granites belong to the high-K calc-alkaline series.Both are peraluminous in composition and have relatively depleted Nd isotopic [ε_(Nd)(t) =(-3.9 – + 0.6)] characteristics compared with regional basement rocks, implying their derivation from a juvenile lower crust. They show adakitic geochemical characteristics and were generated by partial melting of thickened lower continental crust. Postcollisional extensional regime related to lithospheric delamination was the most likely geodynamic mechanism for the generation of the Haoquangou granodiorite, while the Liujiaxia granites were generated in a compressive setting during continental collision between the Qaidam and Qilian blocks.

Geochronology,Geochemistry and Petrogenesis of the Bangbule Quartz Porphyry:Implications for Metallogenesis

The Bangbule skarn lead-zinc(Pb-Zn)deposit(>1 Mt Zn+Pb)is located in the western Nyainqentanglha polymetallic metallogenetic belt,central Tibet.Lenticular orebodies are all hosted in skarn and developed in the contact zone between the quartz porphyry and carbonate strata of the mid Paleozoic Middle to Upper Chaguoluoma Formation as well as in carbonate and sandstone beds of the Upper Paleozoic Laga Formation.As a newly discovered skarn deposit,the geological background and metallogenesis of this deposit remain poorly understood.Detailed petrological,geochemical and geochronological data of the ore-related quartz porphyry,helps constrain the mineralization age and contributes to discussion on the ore genesis of the Bangbule deposit.Both endoskarn and exoskarn are identified in the Bangbule deposit.From quartz porphyry to carbonate formation,the exoskarn is zoned from proximal garnet skarn to distal pyroxene skarn.Zircon U-Pb dating results show that the quartz porphyry formed at 73.9±0.8 Ma.Geochemical analysis results show that the quartz porphyry has high contents of SiO_(2)(71.40–74.94 wt%)and K_(2)O+Na_(2)O(3.76–8.46 wt%)with A/CNK values of 0.69 to 1.06.Besides,the quartz porphyry is enriched in large ion lithophile elements(LILEs)and light rare earth elements(LREEs)and have lowεNd(t)(from-8.25 to-8.19)and high initial(^(87)Sr/^(86)Sr)i values(0.713611–0.714478).Major,trace elements and whole-rock F concentration analysis results from the endoskarn samples show higher TFe_(2)O_(3),MgO,CaO,Pb+Zn,W,Sn,Mo and F etc.,and lower alkalis(K_(2)O,Na_(2)O,Sr and Ba)than those of fresh quartz porphyry,indicating that the early ore-forming fluids were an Ca-Fe-F-enriched fluid.Massive ore in the proximal skarn might be related to the high F content in the magma,which lowered the solidus temperature of the quartz porphyry magma and caused a lower temperature of the ore-forming fluids,as well as facilitating the precipitation of sphalerite and galena.Based on the geochemical characteristics presented in this study,we propose that the ore-related quartz porphyry was formed by partial melting of crust materials with some juvenile crustal component input.The partial melting of the middle-upper crust after the initial enrichment of lead and zinc elements are important for the formation of Pb-Zn deposits.The case study of the Bangbule deposit has proven that there is still a crust-derived magmatic source region in the western segment of the central Lhasa terrane.Therefore,there is still great potential for Pb-Zn mineralization and Pb-Zn exploration.

Petrogenesis of the Carboniferous Intrusive Rock in the Xiaobaishitou District of East Tianshan,Northwest China:Magma Evolution and Tectonic Significance

The Xiaobaishitou gabbro-diorite pluton comprises a medium-grained gabbro-diorite suite and a fine-grained diorite suite,which intrude the Kawabulag Group in the East Tianshan Orogen of the Central Asian Orogenic Belt(CAOB).A combination of mineral chemistry,zircon U-Pb age,whole-rock geochemistry,Sr-Nd isotopes,and in situ zircon Hf isotopes for newly found gabbro-diorite from the Xiaobaishitou district in the Central Tianshan Terrane(CTT)is presented to investigate the petrogenesis and tectonic or even crustal evolution of the East Tianshan Orogen.Laser ablation inductively coupled plasma mass spectrometry(LA-ICP-MS)zircon U-Pb analyses indicate that the gabbro-diorite was formed at 324.7±2.4 Ma.The isolated clinopyroxene formed under higher P-T-fO_(2)melt conditions(10.7–14.6 kbar;1199–1269℃;high fO_(2))than those for the hornblende,plagioclase,and zircon(557–687℃;moderate fO_(2))in the gabbro-diorite,which reveals a multilevel,magmatic storage system.The gabbro-diorite is characterized by fractioned REE patterns,enriched LILEs(e.g.,Ba and Pb),negative anomalies of HFSEs(e.g.,Nb and Ta),and low La/Yb and Sr/Y ratios,which are typically indicative of crustal contamination and accounted for by subduction-related fluids.The rock also characterized by typical features of high compatible elements(MgO=3.14–11.65 wt%,Cr=1–157 ppm,Ni=6–830 ppm),high Mg^(#)(47–74),positiveε_(Hf)(t)values(+5.1 to+10.3)andε_(Nd)(t)values(+2.3 to+4.4).These features suggest that the Xiaobaishitou gabbro-diorite was most likely derived from metasomatic mantle and contaminated minor crustal components.Taking into account the spatial and temporal distribution of the Carboniferous magmatic rocks in the CTT,we suggest the formation of the Xiaobaishitou gabbro-diorite was attributed to southward subduction of the Kangguer Ocean.

Petrogenesis and Rb-Sr Isotopic Characteristics of Paleo-Mesoproterozoic Mirgarani Granite Sonbhadra Uttar Pradesh India:Geodynamics Implication for Supercontinent Cycle

The Rb-Sr whole-rock isochron,age 1636±66 Ma of Mirgarani granite,is the one of the oldest granite dated in the northwestern part of the Chhotanagpur Granite Gneiss Complex(CGGC).The initial Sr ratio is 0.715±0.012(MSWD=0.11),showing an S-type affinity.The Mirgarani granite has intruded the migmatite complex of the Dudhi Group and forms the Mirgarani formation comparable to the granites of the Bihar Mica Belt around Hazaribagh(1590±30 Ma).The present studies have established the chronostratigraphy of the Dudhi Group and adjoining areas in CGGC.Petro-graphic and geochemical studies revealed that the granite is enriched in Rb(271 ppm),Pb(77 ppm),Th(25 ppm),and U(33 ppm)and depleted in Sr(95 ppm),Nb(16 ppm),Ba(399 ppm)and Zr(143 ppm)contents as compared to the normal granite.The Mirgarani granite is a peraluminous(A/CNK=1.23),high potassic(K_(2)O 6.42%),Calc-Alkalic to Alkali-Calcic{(Na_(2)O+K_(2)O)-CaO=6.29}S-Type granite,a feature supported by the presence of modal garnet and normative corundum(2.68%).The Mirgarani granite is considered to have been formed by the anatexis of a crustal sedimentary protolith at a depth of approximately 30 km with temperatures ranging from 685-700℃ during the Co-lumbian-Nuna Supercontinent.

Geochemistry of intrusive rock in Dachang tin-polymetallic ore field, Guangxi, China: Implications for petrogenesis and geodynamics

The major element, trace element and rare earth element（REE） of the intrusion rock from the Dachang ore field in Guangxi, China, were analyzed. The results show that the phenocryst（about 15%） and matrix（about 85%） mainly consist of quartz, K-feldspar and plagioclase. The rock is composed of low content of Si and high content of Al2O3, low contents of Ca, Fe2O3, Na, TiO2, etc. The intrusion rock has the medium alkali content, attributing to K-rich type rock; and contains medium to low REE contents, of which light rare earth elements（LREEs） and heavy rare earth elements（HREEs） are highly fractionated, showing a weak negative Ce anomaly and a negative Eu anomaly. These rocks are enriched in LREE, and the large ion lithophytes elements（LILE） are rich in Rb, Sr, and U; the high-field-strength elements（Nb, Th, etc） are relatively depleted. The REE chondrite-normalized patterns are consistent with the overall, roughly indicating their similar characteristics, sources and evolution. The intrusion rock mainly formed during the collisional and within-plate periods.

Petrogenesis of skarn in Shizhuyuan W-polymetallic deposit, southern Hunan,China:Constraints from petrology,mineralogy and geochemistry

Skarn is the main altered rock type and is of great importance to mineralization and ore-prospecting in the Shizhuyuan area of Hunan province, China. Its features of petrography, mineralogy and geochemistry were studied systematically. The results show that the skarn mainly consists of garnet skarn, secondary wollastonite-garnet skarn, tremolite-clinozoisite skarn, and few wolframine garnet skarn, idocrase-garnet skarn and wollastonite skarn with granoblastic texture, granular sheet crystalloblastic texture, and massive structure, disseminated structure, mesh-vein structure, comb structure, and banded structure. And, it is mainly composed of garnet, fluorite, chlorite, hornblende, epidote, tremolite, plagioclase, biotite, muscovite, plagioclase, quartz, idocrase, and calcite and so on. The chemical components mainly include SiO2, Al2O3, Fe2O3, MgO and CaO, and the trace elements and REEs consist of Li, Be, V, Co, Zn, Ga, Rb, Sr, Y, Ce, Nd, Pb and Bi, etc. And, the obvious fractionation exists between LREE and HREE, and it shows typical features of Nanling ore-forming granite for W？Sn polymetallic deposit. Skarn is derived from the sedimentary rock, such as limestone, mudstone, argillaceous rock, and few pelitic strips. It is affected by both Shetianqiao formation strata and Qianlishan granite during the diagenesis, indicating a strong reduction environment. The occurrence of skarn, whose mutation site is favorable to the mineralization enrichment, is closely related to the mineralization and prospecting.

Zircon LA-ICP MS U-Pb Age,Sr-Nd-Pb Isotopic Compositions and Geochemistry of the Triassic Post-collisional Wulong Adakitic Granodiorite in the South Qinling,Central China,and Its Petrogenesis

The Indosinian post-collisional Wulong pluton intruded into the Mesoproterozoic Fuping Group, South Qinling, central China. In the southern part of the pluton, some mafic enclaves have sharp or gradational contact relationships with the host biotite granodiorite. Geochemistry, zircon LA-ICP MS （laser ablation inductively-coupled plasma mass spectrometry） U-Pb chronology and Sr- Nd-Pb isotope geochemistry of the pluton are reported in this paper. The biotite granodiorite shows close compositional similarities to high-silica adakite. Its chondrite-normalized REE patterns are characterized by strong HREE depletion （Yb = 0.33--0.96 10-6 and Y = 4.77-11.19 ×10^-6）, enrichment of Ba （775-1386 x 10-6） and Sr （643-1115 × 10^-6） and high Sr/Y （57.83-159.99） and Y/Yb （10.99-14.32） ratios, as well as insignificant Eu anomalies （6Eu = 0.70-0.83）, suggesting a feldspar-poor, garnet±amphibole-rich residual mineral assemblage. The mafic enclaves have higher MgO （4.15- 8.13%）, Cr （14.79-371.31 × 10-6）, Ni （20.00-224.24× 10^-6） and Nb/Ta （15.42-21.91） than the host granodiorite, implying that they are mantle-derived and might represent underplated mafic magma. Zircon LA-ICP MS dating of the granodiorite yields a ^206pb/^238U weighted mean age of 208±2 Ma （MSWD=0.50, 1σ）, which is the age of emplacement of the host biotite granodiorite. This age indicates that the Wulong pluton formed during the late-orogenic or post-collisional stage （〈242±21 Ma） of the South Qinling belt. The host biotite granodiorite displays ^87Sr/^86Sr = 0.7059-0.7062, Isr = 0.7044-- 0.7050,^143Nd/^144Nd = 0.51236-0.51238, εNd（t）= -2.26 to -2.66 to ^206Pb/^204pb = 18.099-18.209, ^207pb/^204pb = 15.873-15.979 and ^208pb/^204pb = 38.973-39.430. Those ratios are similar to those of the Mesoproterozoic Yaolinghe Group in the South Qinling. Furthermore, its Nd isotopic model age （-1.02 Ga） is consistent with the age （-1.1 Ga） of the Yaolinghe Group. Based on the integrated geological and geochemical studies, coupled with previous studies, the authors suggest that the Wulong adakitic biotite granodiorite was probably generated by dehydration melting of the Yaolinghe Group-like thickened mafic crust, triggered by underplating of mafic magma at the boundary of the thickened mafic crust and hot lithospheric mantle, and that the Wulong adakitic biotite granodiorite may have resulted from thinning and delamination of the lower crust or breakoff of the subducting slab of the Mianlue ocean during the Indosinian post-collisional orogenic stage of the Qinling orogenic belt.

Petrogenesis of Indosinian Granitoids in Middle-Segment of South Qinling Tectonic Belt:Constraints from Sr-Nd Isotopic Systematics

South Qinling Tectonic Belt（SQTB）is located between the Shangzhou-Danfeng and Mianxian-Lueyang sutures.There are a lot of early Mesozoic granitoid plutons in its middle segment, comprising the Dongjiangkou-Zhashui granitoid plutons at the northeast,Huayang-Wulong-Laocheng granitoid plutons at the central part,Xiba granitoid pluton at the northwest and Guangtoushan-Liuba granitoid plutons at the southwest.These Indonisian granitoids contain a mass of various scale mafic enclaves,which show sometimes clear boundaries and sometimes transitional boundaries with their host granitoids.These granitoids also exhibit metaluminous to peraluminous series,commonly higher Mg# and a wide range of petrochemistry from low-K tholeiite series,through mid-K and high-K calc-alkaline series to shoshonite series and predominated samples are attributed to mid-K and high-K calc-alkaline series.Detailed analyses in Sr-Nd isotopic systematics and petrochemistry reveal that there may be regionally initial granitoid magma of the Indonisian granitoid plutons,comprising Dongjiangkou-Zhashui,Huayang-Wulong-Laocheng,Xiba,and Guangtoushan-Liuba granitoid plutons,which were produced by hybrids of magmas in various degrees,and the initial magmas were derived from both the mantle and the lower continental crust（LCC）sources in the SQTB.The initial granitoid magma further did the magma hybrid with the magmas from the LCC,crystallization fractionation,and assimilation with upper crustal materials during their emplacement to produce these granitoid plutons in the SQTB.These magmatism processes are most likely to occur under continent marginal arc and syn-collision to post-collision tectonic backgrounds.

Petrogenesis of the Xihuashan Granite in Southern Jiangxi Province,South China:Constraints from Zircon U-Pb Geochronology,Geochemistry and Nd Isotopes

Mesozoic granitic intrusions are widely distributed in the Nanling region, South China. Yanshanian granites are closely connected with the formation of tungsten deposits. The Xihuashan granite is a typical representative of tungsten-bearing granite. The Xihuashan granite consists mainly of medium-grained porphyritic biotite granite, medium-grained biotite granite and fine-grained twomica granite, which correspond to LA-ICP-MS zircon U-Pb ages of 555.5±0.4 Ma, 553.0±0.6 Ma and 552.8±0.9 Ma, respectively. Rocks from the Xihuashan mining area displays high SlOe （73.85% to 76.49%） and NaeO＋K20 contents （8.09% to 9.43%）, belonging to high-K calc-alkaline series. They are metaluminous to weakly peraluminous with A/CNK values ranging from 0.96 to 5.06. All granites in this study area are rich in Rb, Th, U and Pb, and depleted in Ba, Sr, P, Ti, Nb and Eu, especially depleted in medium-grained biotite granite and fine-grained two-mica granite. The medium-grained porphyritic biotite granites usually have high LREE concentrations, whereas medium-grained biotite granite and fine-grained two-mica granite displays high HREE contents. Our geochemical data reveal that the studied rocks are highly fractionated I-type granite. The magma underwent strong magma differentiation with decreasing temperature and increasing oxygen fugacity, which may explain the formation of three types of distinct granites. Variations of Rb, Sr and Ba concentrations in different type granites were controlled by fractional crystallization of biotite and feldspar. Fractional crystallization of monazite, allanite and apatite resulted in LREE changes in granite, and formation of garnet mainly caused HREE changes. Granites from the Xihuashan mining area have relatively high εd（t） values （-9.77 to -55.46）, indicating that they were probably generated by partial melting of underlying Proterozoic metasedimentary rocks with minor addition of juvenile crust or mantlederived magmas.

Geochronology and Geochemistry of Mafic Rocks in the Xuhe, Shaanxi, China: Implications for Petrogenesis and Mantle Dynamics

The Xuhe mafic rocks, located in Ziyang county of Shaanxi Province, are dominated by diabase-porphyrite, gabbro-diabase, diabase, and pyroxene diorite. Primitive mantle-normalized multi-element patterns show that, the Xuhe marie rocks are enriched in large ion lithophile elements （LITE）, such as Ba and Pb, depleted in K and Sr for basic rocks, and are depleted in Sr, P and Ti for pyroxene diorite. Chondrite-normalized REE patterns display LREE enrichment （LaN/YbN = 9.34- 13.99） and have normalized patterns for trace element and REE similar to that of typical OIB. Detailed SIMS zircon U-Pb dating yields emplacement ages of 438.4 ± 3.1 Ma for Xuhe mafic rocks. The relatively low MgO （basic rock： 3.11-7.21 wt%; pyroxene diorite： 0.89-1.21 wt% ） and Mg# （0.20- 0.49） for Xuhe mafic rocks suggest that they were possibly originated from an extremely evolved magma. The rising parental mafic magmas underwent pyroxene and plagioclase fractionation. Crustal contamination of pyroxene diorite before emplacement occurred at a higher crustal level compared to other lithology in Xuhe mafic rocks. The degree of partial melt was low （5%-10%） and in garnetspinel transition facies. Sr-Nd isotope of pyroxene diorite and enrichment mantle characteristics for Xuhe mafic rocks suggest that mafic rocks in the North Daba Mountains were derived from a mixture of HIMU, EMII and small amount of EMI components. Furthermore, this study discusses mantle geodynamic significance of Xuhe mafic rocks in the Silurian, which indicates subduction and uplift of magma caused back-arc extension.

Geology,Geochemistry and Zircon U-Pb Geochronology of Porphyries in the Dabate Mo-Cu Deposit,Western Tianshan,China:Petrogenesis and Tectonic Implications

The Dabate Mo-Cu deposit is a medium-sized porphyry-type deposit in the Sailimu Lake region, western Tianshan, China. We present the geology, geochemistry and zircon U-Pb geochronology of granite porphyries from the Dabate district with the intent to constrain their tectonic setting and petrogenesis. Porphyries in the Dabate district include granite porphyry I（gray white color with large phenocrysts）, granite porphyry II（pink color with small phenocrysts） and quartz porphyry. Granite porphyry II is the Cu and Mo ore-bearing granitoid in the Dabate deposit. LA-ICPMS zircon U-Pb analyses indicate that granite porphyry II was emplaced at 284.2±1.8 Ma. Granite porphyry I and II have similar geochemical features and are both highly fractionated granites：（1） They have high SiO2 content（70.93–80.18 wt% and 72.14–72.64 wt%, respectively）, total alkali（7.58–8.95 wt% and 9.35–9.68 wt%, respectively）, mafic index（0.95–0.98 and 0.93–0.94, respectively） and felsic index（0.79–0.94 and 0.89–0.91, respectively）;（2） They are characterized by pronounced negative Eu anomaly, ＂seagullstyle＂ chondrite-normalized REE patterns and ＂tetrad effect＂ of REE;（3） They are rich in Rb, K, Th, Ta, Zr, Hf, Y and REE, but depleted in Sr, P, Ti and Nb. The magma of granite porphyries in Dabate can be interpreted to have been generated by partial melting of the upper crust due to mantle-derived magma underplating in a post-collisional extensional setting.

Guandishan Granitoids of the Paleoproterozoic Lüliang Metamorphic Complex in the Trans-North China Orogen:SHRIMP Zircon Ages,Petrogenesis and Tectonic Implications

The Paleoproterozoic Liiliang Metamorphic Complex （PLMC） is situated in the middle segment of the western margin of the Trans-North China Orogen （TNCO）, North China Craton （NCC）. As the most important lithological assemblages in the southern part of the PLMC, Guandishan granitoids consist of early gneissic tonalities, granodiorites and gneissic monzogranites, and younger gneissic to massive monzogranites. Petrochemical features reveal that the early gneissic tonalities and granodiorites belong to the medium-K calc-alkaline series; the early gneissic monzogranites are transitional from high-K calc-alkaline to the shoshonite series; the younger gneissic to massive monzogranites belong to the high-k calc-alkaline series, and all rocks are characterized by right- declined REE patterns and negative Nb, Ta, Sr, P, and Ti anomalies in the primitive mantle normalized spidergrams. SHRIMP zircon U-Pb isotopic dating reveals that the early gneissic tonalities and granodiorites formed at -2.17 Ga, the early gneissic monzogranites at -2.06 Ga, and the younger gneissic to massive monzogranites at -1.84 Ga. Sm-Nd isotopic data show that the early gneissic tonalities and granodiorites have eNd（t） values of ＋0.48 to -3.19 with Nd-depleted mantle model ages （TDM） of 2.76--2.47 Ga, and early gneissic monzogranites have eNd（t） values of -0.53 to -2.51 with TDM of 2.61--2.43 Ga, and the younger gneissic monzogranites have eNd（t） values of -6.41 to -2.78 with a TDM of 2.69--2.52 Ga.These geochemical and isotopic data indicate that the early gneissic tonalities, granodiorites, and monzogranites were derived from the partial melting of metamorphosed basaltic and pelitic rocks, respectively, in a continental arc setting. The younger gneissic to massive monzogranites were derived by partial melting of metamorphosed greywackes within the continental crust. Combined with previously regional data, we suggest that the Paleoproterozoic granitoid magmatism in the Guandishan granitoids of the PLMC may provide the best geological signature for the complete spectrum of Paleoproterozoic geodynamic processes in the Trans-North China Orogen from oceanic subduction, through collisional orogenesis, to post-orogenic extension and uplift.

Xiba Granitic Pluton in the Qinling Orogenic Belt, Central China: Its Petrogenesis and Tectonic Implications

Xiba granitic pluton is located in South Qinling tectonic domain of the Qinling orogenic belt and consists mainly of granodiorite and monzogranite with significant number of microgranular quartz dioritic enclaves. SHRIMP zircon U-Pb isotopic dating reveals that the quartz dioritic enclaves formed at 214±3 Ma, which is similar to the age of their host monzogranite （218±1 Ma）. The granitoids belong to high-K calc-alkaline series, and are characterized by enriched LILEs relative to HFSEs with negative Nb, Ta and Ti anomalies, and right-declined REE patterns with （La/Yb） N ratios ranging from 15.83 to 26.47 and δEu values from 0.78 to 1.22 （mean= 0.97）. Most of these samples from Xiba granitic pluton exhibit εNd（t） values of 8.79 to 5.38, depleted mantle Nd model ages （T DM ） between 1.1 Ga and 1.7 Ga, and initial Sr isotopic ratios （ 87 Sr/ 86 Sr） i from 0.7061 to 0.7082, indicating a possible Meso-to Paleoproterozoic lower crust source region, with exception of samples XB01-2-1 and XB10-1 displaying higher （ 87 Sr/ 86 Sr） i values of 0.779 and 0.735, respectively, which suggests a contamination of the upper crustal materials. Quartz dioritic enclaves are interpreted as the result of rapid crystallization fractionation during the parent magmatic emplacement, as evidenced by similar age, texture, geochemical, and Sr-Nd isotopic features with their host rocks. Characteristics of the petrological and geochemical data reveal that the parent magma of Xiba granitoids was produced by a magma mingling process. The upwelling asthenosphere caused a high heat flow and the mafic magma was underplated into the bottom of the lower continent crust, which caused the partial melting of the lower continent crustal materials. This geodynamic process generated the mixing parent magma between mafic magma from depleted mantle and felsic magma derived from the lower continent crust. Integrated petrogenesis and tectonic discrimination with regional tectonic evolution of the Qinling orogen, it is suggested that the granitoids are most likely products in a post-collision tectonic setting.

Age and geochemistry of the Neoproterozoic granitoids in the the Songnen–Zhangguangcai Range Massif, NE China: Petrogenesis and tectonic implications

The Songnen–Zhangguangcai Range Massif(SZRM)is located in the eastern Central Asian Orogenic Belt and crops out over an extensive part of NE China.The massif was originally thought to contain numerous Precambrian terranes(e.g.,Xingdong,Dongfengshan,Yimianpo and Zhangguangcailing groups).However,more recent zircon U–Pb dating indicates that the majority of these so-called Precambrian sedimentary and igneous rocks actually formed during either the Paleozoic or Mesozoic and contain only minor Precambrian components(Wang et al.,2014).The presence of Neoproterozoic and Paleoproterozoic detrital zircons with magmatic origins from and Paleozoic units of the SZRM indicating that this area occurs Proterozoic magmatism(Wang et al.,2014),whereas no Proterozoic magmastism has been found.Recently,Pei et al.(2007)reported the ca.1800Ma magmastism,as evidenced by the data of exploration drillholes in the southern Songliao basin.However,an alternative view is that the basement within the SZRM is predominantly Phanerozoic,as evidenced by the presence of Paleozoic fossils and comparatively rare geochronological data(Guo and Liu,1985;Wu et al.,2011),meaning that the ca.1800 Ma rocks in this area may be a tectonically emplaced slice of the North China Craton(Zhang et al.,2005).All of this means that the age and nature of the SZRM basement,and whether this area records Neoproterozoic magmatism,remain unclear.This study presents new geochronological,whole-rock geochemical,and zircon Hf isotopic data for early Proterozoic granitoids within the eastern margin of the SZRM of NE China.These data provide insights into the Neoproterozoic tectonic setting of the SZRM and the links between this magmatism and the evolution of the Rodinia supercontinent.The zircon U–Pb dating indicates that the Neoproterozoic magmatism within the SZRM can be subdivided into two stages:(1)a^917–911 Ma suite of syenogranites and monzogranites,and(2)an^841 Ma suite of granodiorites.The 917–911 Ma granitoids contain high concentrations of Si O2(67.89–71.18 wt.%),K2O(4.24–6.91 wt.%),and Al2O3(14.89–16.14 wt.%),and low concentrations of TFe2O3(1.63–3.70 wt.%)and Mg O(0.53–0.88 wt.%).They are enriched in the light rare earth elements(LREE)and the light ion lithophile elements(LILE),are depleted in the heavy REE(HREE)and the heavy field strength elements(HFSE;e.g.,Nb,Ta,and Ti),and have slightly positive Eu anomalies,indicating they are geochemically similar to high-K adakitic rocks.They have zirconεHf(t)values and TDM2 ages from–4.4 to+1.5and from 1915 Ma to 1592 Ma,respectively,suggesting they were derived from a primary magma generated by the partial melting of ancient thickened lower crustal material.In comparison,the 841 Ma granodiorites contain relatively low concentrations of Al2O3(14.50–14.58 wt.%)and K2O(3.27–3.29 wt.%),relatively high concentrations of TFe2O3(3.78–3.81 wt.%)and the HREE,have negative Eu anomalies,and have zirconεHf(t)values and TDM2ages from–4.7 to+1.0 and from 1875 to 1559 Ma,respectively.These granodiorites formed from a primary magma generated by the partial melting of ancient crustal material.The^917–911 Ma magmatism within the SZRM is inferred to have formed in an orogenic setting,whereas the^841 Ma magmatism formed in an anorogenic setting related to either a post-orogenic tectonic event or the onset of Neoproterozoic continental rifting.It is proposed that the microcontinental massifs within the SZRM formed during or following the final stage of assembly of Rodinia before rifting away from the Tarim Craton in response to Rodinia breakup.

Petrogenesis of the～2115 Ma Haicheng Mafic Sills in the Eastern North China Craton and Their Implications for An Intra-Continental Rifting

It is well known that there are widespread igneous events at;100 Ma in the Eastern North China Craton;however,their tectonic environments are controversial.They were thought to be either related to an intra-continental rifting or

Petrogenesis of the Paleoproterozoic Guandishan Granitoids in Shanxi Province:Constraints from Geochemistry and Nd Isotopes

The Guandishan granitoids consist mainly of various granitoid intrusions with different scales, including the Huijiazhuang intrusion, Shizhuang intrusion and Hengjian intrusion, which were formed between 1906 Ma and 1848 Ma. On the basis of geological and petrological characteristics, these granitoids can be classified into two groups： the earlier gneissic granodiorites and monzogranites, and the later massive leuco-monzogranites. Their geochemical and Nd isotopic features indicate that they could be derived from complicated partial melting of supracrustal rocks with an affinity of continental arc materials, such as sandy shale and pelite, and with garnet, pyroxene, hornblende and plagioclase as residual phases. Biotite, feldspar and other minerals were most likely fractionated during the magma evolution. Their source may have an affinity with continental arcs, and the granitoids could be derived from the main syn-collisional to late-orogenic tectonic environment, which may be related to the final amalgamation between the Eastern and Western continental blocks in the North China Craton.

Petrogenesis and Tectonic Significance of the Xiuwacu Two-Period Magmatism in Geza Arc of Yunnan Province： Constraints from Lithogeochemistry, Zircon U-Pb Geochronology and Hf isotopic Compositions

Objective The Late Cretaceous Xiuwacu ore-bearing porphyry is located in the Geza area of southern Yidun arc, SW China. In this area, the rock mass is mainly composed of three lithofacies： biotite granite porphyry, monzonitic granite and light alkali feldspar granite. As a part of the Yidun arc, the Geza arc has common structure and temporal- spatial evolution with the ~idun arc, which has experienced three stages of oceanic crust subduction, collision orogeny and intracontinent convergence stages. The molybdenite ores in the area are mainly hosted in monzonitic granite-porphyry and structural fracture zone, and the ore bodies are strictly controlled by faults. In recent years, great geological prospecting results have been achieved in Xiuwacu, and the deposit has reached a medium scale. However, there are few researches on the metallogenic porphyry. Based on the previous research, we determined the rock-forming and ore-forming age of the porphyry, and found that there were two stages of magmatism intrusion in Xiuwacu： Indosinian and Yanshanian. We also discussed the geochemical characteristics and source area of the rocks in the area.

Geochemistry and Petrogenesis of Late Cretaceous–Paleocene Granites from the Tengchong Block, Western Yunnan: Implications for Angle-switching of Subducting Slab

The Cenozoic geological hallmark of Western Yunnan is the characteristic voluminous Late Cretaceous-Eocene granites;however, their geological background and petrogenesis have not been well constrained and elucidated. In this study, we present new zircon U-Pb dating, along with geochemical and Sr-Nd-Hf isotopic data for granites from the Tengchong–Lianghe granitoid belt(as abbreviated to Tengliang belt) and West Yingjiang batholiths from the Tengchong block. The mineralogical and geochemical features of the Tengliang granites and the West Yingjiang batholiths are ascribed to aluminous S-type granites and weak peraluminous I-type, respectively. Zircon U-Pb analyses yielded consistent ages ranging from 67.5 Ma, 68.4 Ma and 66.2 Ma from the Tengliang granitoid belt and 50.4 Ma to 60.8 Ma for three samples from the west Yingjiang batholiths. The Tengliang granites were emplaced during the Late Cretaceous(68-66 Ma) and demonstrate negative ε_(Hf)(t) values(-24 to-4) and initial ~(87)Sr/~(86)Sr ratios of 0.7101–0.7139 and significant negative ε_(Nd)(t) values from-8.91 to-13.2, indicating a Proterozoic sedimentary source or enriched components. The hornblende-bearing I-type granites from West Yingjiang are characterized by lower initial ~(87)Sr/~(86)Sr ratios of 0.7076–0.7106, compared to Tengliang granite and negative whole-rock ε_(Nd)(t) values from-4.0 to-11.9. The early Eocene west Yingjiang gneissic granites show wide ranges of ε_(Hf)(t) values from +7.4 to-8.5 and T_(2DM) of 1.30–0.65 Ga, indicating partial melting of ancient crust with contributions of depleted mantle materials. In combination with the regional background and previous studies, we propose that such a spatio-temporal distribution of the Tengchong granitoid belt might be related to the rollback or angleswitching of the Neo-Tethyan subducting slab. This study sheds new light on the evolutionary history of the Tengchong block.