For evaluation of the rheological and mechanical properties of highly filled wood plastic composites （WPCs）, polypropylene/polyethylene （PP/PE） blends were grafted with maleic anhydride （MAH） to enhance the inte...For evaluation of the rheological and mechanical properties of highly filled wood plastic composites （WPCs）, polypropylene/polyethylene （PP/PE） blends were grafted with maleic anhydride （MAH） to enhance the interfacial adhesion between wood fiber and matrix. WPCs were prepared from wood fiber up to 60 wt.% and modified PP/PE was blended by extrusion. The rheological properties were studied by using dynamic measurement. According to the strain sweep test, the linear viscoelastic region of composites in the melt was determined. The result showed that the storage modulus was independent of the strain at low strain region （〈0.1%）. The frequency sweep resuits indicated that all composites exhibited shear thinning behavior, and both the storage modulus and complex viscosity of MAH modified composites were decreased comparing to those unmodified. Flexural properties and impact strength of the prepared WPCs were measured according to the relevant standard specifications. The flexural and impact strength of the manufactured composites significantly increased and reached a maximum when MAH dosage was 1.0 wt%, whereas the flexural modulus after an initial decreased, also increased with MAH dosage. The increase in mechanical properties indicated that the presence of anhydride groups enhanced the interracial adhesion between wood fiber and PP/PE blends.展开更多
To date,there is no research that deals with biological waste as fillers in polyphenylene sulfide(PPS).In this study,oyster shells were recycled and treated to prepare thermally-treated oyster shells(TOS),which were u...To date,there is no research that deals with biological waste as fillers in polyphenylene sulfide(PPS).In this study,oyster shells were recycled and treated to prepare thermally-treated oyster shells(TOS),which were used as PPS fillers to make new bio-based antibacterial composite materials.The effect of varying the content of TOS was studied by means of structure and performance characterization.PPS/TOS composites were demonstrated to have an antibacterial effect on the growth of E coli and S.aureus.Qualitative analysis showed that when the TOS content was≥30%and 40%,the composite materials had an apparent inhibition zone.Quantitative analysis showed that the antibacterial activity increased with the TOS content.Fourier transform infrared spectroscopy indicated the formation of hydrogen bonds between the molecular chains of TOS and PPS and the occurrence of a coordination reaction.At 10%TOS,the composite tensile strength reached a maximum value of 72.5 MPa,which is 9.65%higher than that of pure PPS.The trend of bending properties is the same as that of tensile properties,showing that the maximum property was reached for the composite with 10%TOS.At the same time,the crystallinity and contact angle were the highest,and the permeability coefficient was the lowest.The fatigue test results indicated that for the composite with 10%TOS,the tensile strength was 23%lower than static tensile strength,and the yield strength was 10%lower than the static yield strength.The results of the study showed that TOS not only could reduce the cost of PPS,but also could impart antibacterial properties and enhance the mechanical and,barrier properties,the thermostability,as well as the crystallinity.展开更多
A novel metal matrix composites(MMC)with Mg matrix reinforced with natural filler in the form of Didymosphenia geminata frustules(algae with distinctive siliceous shells)are presented in this work.Pulse plasma sinteri...A novel metal matrix composites(MMC)with Mg matrix reinforced with natural filler in the form of Didymosphenia geminata frustules(algae with distinctive siliceous shells)are presented in this work.Pulse plasma sintering(PPS)was used to manufacture Mg-based composites with 1,5 and 10 vol.%ceramic filler.As a reference,pure Mg was sintered.The results show that the addition of 1 vol.%Didymosphenia geminata frustules to the Mg matrix increases its corrosion resistance by supporting passivation reactions,and do not affect the morphology of L929 fibroblasts.Addition of 5 vol.%the filler does not cause cytotoxic effects,but it supports microgalvanic reactions leading to the greater corrosion rate.Higher content than 5 vol.%the filler causes significant microgalvanic corrosion,as well as increases cytotoxicity due to the greater micro-galvanic effect of the composites containing 10 and 15 vol.%diatoms.The results of contact angle measurements show the hydrophilic character of the investigated materials,with slightly increase in numerical values with addition of amount of ceramic reinforcement.The addition of Didymosphenia geminata frustules causes changes in a thermo-elastic properties such as mean apparent value of coefficient of thermal expansion(CTE)and thermal conductivity(λ).The addition of siliceous reinforcement resulted in a linear decrease of CTE and reduction in thermal conductivity over the entire temperature range.With the increasing addition of Didymosphenia geminata frustules,an increase in strength with a decrease in compressive strain is observed.In all composites an increase in microhardness was attained.The results clearly indicate that filler in the form of Didymosphenia geminata frustules may significantly change the most important properties of pure Mg,indicating its wide potential in the application of Mg-based composites with a special focus on biomedical use.展开更多
Solid state NMR was successfully used to determine the proton spin-lattice relaxation time in the rotating frame (T1ρH) for systems based on polypropylene (PP) and PP with titanium dioxide (TiO<sub>2</sub>...Solid state NMR was successfully used to determine the proton spin-lattice relaxation time in the rotating frame (T1ρH) for systems based on polypropylene (PP) and PP with titanium dioxide (TiO<sub>2</sub>) organically modified or unmodified incorporated, in order to understand the molecular behavior of these systems. These techniques were employed in the samples organically modified and unmodified TiO<sub>2</sub> to investigate the effect of organic modification on the dispersion and distribution of the particles in the PP matrix. The results were analyzed in terms of the effect of the particles organic modified or not according to the intermolecular interaction in the composites. According to the T1ρH values, all composites showed at least two domains: the short values were related to the rigid part, which included the crystalline and amorphous phase constricted in it, while the longer times were attributed to the amorphous region, which had higher molecular mobility compared to the rigid region of the materials. The increase in the relaxation time parameter in the composites compared to the pure PP was associated to the strong interaction between titanium dioxide particles and the polymer chains. This effect was more pronounced for the systems containing organically modified TiO<sub>2</sub>. According to the results, it could be inferred that intermolecular interaction occurred in the CH<sub>2</sub> and CH groups, being more intense with CH<sub>2</sub> groups. Finally, the solid state NMR techniques were able to evaluate the molecular dynamics of those systems.展开更多
This study investigates the properties of Baosteel steel slag and blast furnace （BF） slag in order to develop high-performance steel slag and BF slag composite admixture by optimizing the composite mixing technique....This study investigates the properties of Baosteel steel slag and blast furnace （BF） slag in order to develop high-performance steel slag and BF slag composite admixture by optimizing the composite mixing technique. Based on the investigation of the stability of steel slag powder and the performance of cement mortar in different mixing ratios and different adding amounts of steel slag and BF slag composite admixture, rational mixing ratios and the adding amount range of steel slag and BF slag composite admixture were determined.展开更多
To improve performance of PTFE-based damping material,composites with several fillers were prepared by compressing and sintering. The dynamic mechanical properties of the composites were investigated by means of visco...To improve performance of PTFE-based damping material,composites with several fillers were prepared by compressing and sintering. The dynamic mechanical properties of the composites were investigated by means of viscoanalyser. Temperature-dependent loss factors,storage modulus and loss modulus were obtained. And SEM was employed to study the compatibility between PTFE and fillers. The results show that,when blending PPS and PEEK at proper content,the loss factor curve appears double peaks,which can widen the high-damping temperature region of the composites. Blending graphite or alumina can increase the storage modulus obviously,but decrease the value of loss factor. And because graphite or alumina combines with matrix poorly,glide would happen at interface when bearing external load. The interface friction can dissipate vibration energy,which increases the loss modulus of the composites. Blending PPS,PEEK and graphite or alumina at right content,PTFE-based composites can meet demands as damping material in practical engineering.展开更多
The thermal and mechanical properties of the polyamide 6/boron nitride and polyphenylene sulfide/graphite composites have been investigated as a function of composition and size of fillers. The addition of highly ther...The thermal and mechanical properties of the polyamide 6/boron nitride and polyphenylene sulfide/graphite composites have been investigated as a function of composition and size of fillers. The addition of highly thermal conductive h-BN and graphite gives rise to large increase （about 2 times） of thermal conductivity of individual polymer. In PPS/graphite system, the higher conductivity value was obtained when smaller graphites were added. Meanwhile, the tensile and flexural strength are reduced upon increasing filler loading.展开更多
In order to improve the mechanical properties of polypyrrole, composites were made by electropolymerizing polypyrrole in a polyurethane matrix. Polypyrrole/polyurethane (PPY/PU) composite films containing CLO_4^-, BF_...In order to improve the mechanical properties of polypyrrole, composites were made by electropolymerizing polypyrrole in a polyurethane matrix. Polypyrrole/polyurethane (PPY/PU) composite films containing CLO_4^-, BF_4^- or CH_3-C_6H_4-SO_3^- counter ions were made in a variety of solvent systems and characterized by SEM, electronic conductivity, FTIR, and mechanical properties. Composite films showing much greater fiexibility than pure polypyrrole were obtained, but their electronic conductivities were substantially lower. Measured eonductivities ranged from 0.001 to 8 S/cm, tensile strengths from 44 to 592 psi, and elongation to failure from 3 to 70%.展开更多
文摘For evaluation of the rheological and mechanical properties of highly filled wood plastic composites （WPCs）, polypropylene/polyethylene （PP/PE） blends were grafted with maleic anhydride （MAH） to enhance the interfacial adhesion between wood fiber and matrix. WPCs were prepared from wood fiber up to 60 wt.% and modified PP/PE was blended by extrusion. The rheological properties were studied by using dynamic measurement. According to the strain sweep test, the linear viscoelastic region of composites in the melt was determined. The result showed that the storage modulus was independent of the strain at low strain region （〈0.1%）. The frequency sweep resuits indicated that all composites exhibited shear thinning behavior, and both the storage modulus and complex viscosity of MAH modified composites were decreased comparing to those unmodified. Flexural properties and impact strength of the prepared WPCs were measured according to the relevant standard specifications. The flexural and impact strength of the manufactured composites significantly increased and reached a maximum when MAH dosage was 1.0 wt%, whereas the flexural modulus after an initial decreased, also increased with MAH dosage. The increase in mechanical properties indicated that the presence of anhydride groups enhanced the interracial adhesion between wood fiber and PP/PE blends.
基金Sichuan Province Science and Technology Support Program (2022JDTD0016,2020YFG0176)Chengdu Science and Technology (2021-RC02-00005-CG)+5 种基金Sichuan Golden-Elephant Sincerity Chemical Co.,Ltd (HX2020019)Zigong City Science and Technology (2019CXRC01,2020YGJC13)Opening Project of Material Corrosion and Protection Key Laboratory of Sichuan Province (2019CL05,2020CL19,2018CL07)Opening Project of Sichuan Province,the Foundation of Introduced Talent of Sichuan University of Science and Engineering (2017RCL16,2019RC05,2019RC07,2020RC16)the Opening Project of Key Laboratories of Fine Chemicals and Surfactants in Sichuan Provincial Universities (2020JXY04)Xi’an Weijingyi Art and Culture Communication Co.,Ltd (HX2021385)。
文摘To date,there is no research that deals with biological waste as fillers in polyphenylene sulfide(PPS).In this study,oyster shells were recycled and treated to prepare thermally-treated oyster shells(TOS),which were used as PPS fillers to make new bio-based antibacterial composite materials.The effect of varying the content of TOS was studied by means of structure and performance characterization.PPS/TOS composites were demonstrated to have an antibacterial effect on the growth of E coli and S.aureus.Qualitative analysis showed that when the TOS content was≥30%and 40%,the composite materials had an apparent inhibition zone.Quantitative analysis showed that the antibacterial activity increased with the TOS content.Fourier transform infrared spectroscopy indicated the formation of hydrogen bonds between the molecular chains of TOS and PPS and the occurrence of a coordination reaction.At 10%TOS,the composite tensile strength reached a maximum value of 72.5 MPa,which is 9.65%higher than that of pure PPS.The trend of bending properties is the same as that of tensile properties,showing that the maximum property was reached for the composite with 10%TOS.At the same time,the crystallinity and contact angle were the highest,and the permeability coefficient was the lowest.The fatigue test results indicated that for the composite with 10%TOS,the tensile strength was 23%lower than static tensile strength,and the yield strength was 10%lower than the static yield strength.The results of the study showed that TOS not only could reduce the cost of PPS,but also could impart antibacterial properties and enhance the mechanical and,barrier properties,the thermostability,as well as the crystallinity.
基金Izabela B.Zgłobicka acknowledges the funding provided by National Science Center for providing financial support to project Metal Matrix Composites with natural filler(Grant No.2018/31/D/ST8/00890).The authors are grateful to Dr Matt P.Ashworth from the University of Texas at Austin(USA)for critically reading the manuscript and correcting the language.
文摘A novel metal matrix composites(MMC)with Mg matrix reinforced with natural filler in the form of Didymosphenia geminata frustules(algae with distinctive siliceous shells)are presented in this work.Pulse plasma sintering(PPS)was used to manufacture Mg-based composites with 1,5 and 10 vol.%ceramic filler.As a reference,pure Mg was sintered.The results show that the addition of 1 vol.%Didymosphenia geminata frustules to the Mg matrix increases its corrosion resistance by supporting passivation reactions,and do not affect the morphology of L929 fibroblasts.Addition of 5 vol.%the filler does not cause cytotoxic effects,but it supports microgalvanic reactions leading to the greater corrosion rate.Higher content than 5 vol.%the filler causes significant microgalvanic corrosion,as well as increases cytotoxicity due to the greater micro-galvanic effect of the composites containing 10 and 15 vol.%diatoms.The results of contact angle measurements show the hydrophilic character of the investigated materials,with slightly increase in numerical values with addition of amount of ceramic reinforcement.The addition of Didymosphenia geminata frustules causes changes in a thermo-elastic properties such as mean apparent value of coefficient of thermal expansion(CTE)and thermal conductivity(λ).The addition of siliceous reinforcement resulted in a linear decrease of CTE and reduction in thermal conductivity over the entire temperature range.With the increasing addition of Didymosphenia geminata frustules,an increase in strength with a decrease in compressive strain is observed.In all composites an increase in microhardness was attained.The results clearly indicate that filler in the form of Didymosphenia geminata frustules may significantly change the most important properties of pure Mg,indicating its wide potential in the application of Mg-based composites with a special focus on biomedical use.
文摘Solid state NMR was successfully used to determine the proton spin-lattice relaxation time in the rotating frame (T1ρH) for systems based on polypropylene (PP) and PP with titanium dioxide (TiO<sub>2</sub>) organically modified or unmodified incorporated, in order to understand the molecular behavior of these systems. These techniques were employed in the samples organically modified and unmodified TiO<sub>2</sub> to investigate the effect of organic modification on the dispersion and distribution of the particles in the PP matrix. The results were analyzed in terms of the effect of the particles organic modified or not according to the intermolecular interaction in the composites. According to the T1ρH values, all composites showed at least two domains: the short values were related to the rigid part, which included the crystalline and amorphous phase constricted in it, while the longer times were attributed to the amorphous region, which had higher molecular mobility compared to the rigid region of the materials. The increase in the relaxation time parameter in the composites compared to the pure PP was associated to the strong interaction between titanium dioxide particles and the polymer chains. This effect was more pronounced for the systems containing organically modified TiO<sub>2</sub>. According to the results, it could be inferred that intermolecular interaction occurred in the CH<sub>2</sub> and CH groups, being more intense with CH<sub>2</sub> groups. Finally, the solid state NMR techniques were able to evaluate the molecular dynamics of those systems.
文摘This study investigates the properties of Baosteel steel slag and blast furnace （BF） slag in order to develop high-performance steel slag and BF slag composite admixture by optimizing the composite mixing technique. Based on the investigation of the stability of steel slag powder and the performance of cement mortar in different mixing ratios and different adding amounts of steel slag and BF slag composite admixture, rational mixing ratios and the adding amount range of steel slag and BF slag composite admixture were determined.
基金the National Natural Science Foundation of China (Grant No. 50575054)the Science and Technology Tackle Key Problem Plan Foun-dation of Harbin, China (Grant No. 2004AA2CG126).
文摘To improve performance of PTFE-based damping material,composites with several fillers were prepared by compressing and sintering. The dynamic mechanical properties of the composites were investigated by means of viscoanalyser. Temperature-dependent loss factors,storage modulus and loss modulus were obtained. And SEM was employed to study the compatibility between PTFE and fillers. The results show that,when blending PPS and PEEK at proper content,the loss factor curve appears double peaks,which can widen the high-damping temperature region of the composites. Blending graphite or alumina can increase the storage modulus obviously,but decrease the value of loss factor. And because graphite or alumina combines with matrix poorly,glide would happen at interface when bearing external load. The interface friction can dissipate vibration energy,which increases the loss modulus of the composites. Blending PPS,PEEK and graphite or alumina at right content,PTFE-based composites can meet demands as damping material in practical engineering.
文摘The thermal and mechanical properties of the polyamide 6/boron nitride and polyphenylene sulfide/graphite composites have been investigated as a function of composition and size of fillers. The addition of highly thermal conductive h-BN and graphite gives rise to large increase （about 2 times） of thermal conductivity of individual polymer. In PPS/graphite system, the higher conductivity value was obtained when smaller graphites were added. Meanwhile, the tensile and flexural strength are reduced upon increasing filler loading.
文摘In order to improve the mechanical properties of polypyrrole, composites were made by electropolymerizing polypyrrole in a polyurethane matrix. Polypyrrole/polyurethane (PPY/PU) composite films containing CLO_4^-, BF_4^- or CH_3-C_6H_4-SO_3^- counter ions were made in a variety of solvent systems and characterized by SEM, electronic conductivity, FTIR, and mechanical properties. Composite films showing much greater fiexibility than pure polypyrrole were obtained, but their electronic conductivities were substantially lower. Measured eonductivities ranged from 0.001 to 8 S/cm, tensile strengths from 44 to 592 psi, and elongation to failure from 3 to 70%.
